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By Liuming Wu, Willis Forsling

The complexation of Alizarin Red S (ARS) at the surface of hydrous fluorapatite particles has been investigated at 25.0 C by means of potentiometric titrations, adsorption experiments in 0.1 M NaCI ionic medium, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT) studies. A chemical model describing the reaction at the aqueous mineral surface has been established under equilibrium conditions according to the reaction [== -CaOH2 + HA2 - « _ =PO CaA2 - z + H30&apos;; to (int.) = -5.61 ± 0.02 3 a =PO- logBs-1110(int.) ( ) within the range 8.40 <_ -log[H ] <_ 9.80.] Experimental data were evaluated using the computer program FITEQL on the basis of a constant capacitance model for the electric double layer. The surface complex structure, has been proposed to involve the quinoid and alpha phenolic oxygens of ARS coordinated to the calcium sites on the fluorapatite surface.

Jan 1, 1993

By Manuel Diaz del Rio

At the present time there are over 5,000 Kms of railway tunnels in existence throughout the world. In many cases these tunnels were built over a century ago using techniques obsolete today. Supervision and maintenance of these tunnels is essential to the economy of each country involved. For this purpose an electro-optical measuring system has been designed incorporating highly complex soft and hardware (15 mW laser, high resolution TV camera and processing computer), mounted on a vehicle. Its job is to scan, record and compare sectional gauge values (profiles) and strains inside tunnels both momentarily in situ and on permanent record, as an aid to the supervision work. From the state of the strains observed, in conjunction with an infrared spectrum of the tunnel lining and soil involved, the mechanical stresses in the tunnel can be deduced by applying the boundary elements method.

Jan 1, 1981

By J. R. England, W. J. Taylor

The Sudbury Basin is the scene of the mining operations of the Ontario Division of the International Nickel Company of Canada, Limited. Around the rim of the geological formation and within thirty miles of the City of Sudbury are located twelve operating mines and one open pit operated by the Company. The City, with a metropolitan population of some 100,000 lies 240 miles Northwest of Toronto. In addition, there is one mine in Northwestern Ontario, at Shebandowan, 700 miles Northwest of Sudbury. In 1973 these mines produced 16.5 million short tons of ore of which 14.9 million tons were from underground and the balance from open pit operations. Mining methods include blasthole, sublevel caving, induced caving, shrinkage, cut-and-fill and undercut-and-fill. Raise boring commenced at Inco in 1964 and is now applied at all mines in the Sudbury District (Figure 1). [ ]

Jan 1, 1974

By J. Mersch Ward

Homestake Mining Company has identified a significant native sulfur resource at its Cinnabar Canyon prospect in Mono County, California. Elemental sulfur occurs as replacements, fracture coatings and breccia fillings in a thick sequence of Miocene-Pliocene intermediate volcanic rocks. The deposit extends along a northwest trending regional fault and measures approximately 900&apos; in width, at least 1800&apos; in length, and has a thickness in excess of 200&apos;. The deposit lies approximately 150&apos; below the surface and is covered by a silicified cap of volcaniclastic strata. The deposit has been delineated by rotary and core drilling. Utilizing a grade cutoff of 5% elemental sulfur, the delineated deposit has a probablelpossible resource of 16.1 million tons of ore averaging 17.9% elemental sulfur containing 2.57 million long tons sulfur. Assay grades within the resource area range up to 40% sulfur over a 40-foot intercept.

Jan 1, 1992

By Denis Murphy, James Gusek, Carl Mann, Thomas Wilderman

An active underground lead mine produces water having a pH of 8.0 with 0.4 to 0.6 mg/L of Pb and 0.36 mg/L. of Zn. This water is pumped at the rate of 1.200 gpm into a five-cell, bioreactor system covering about 5 acres. The gravity flow system is composed of a settling basin followed by two anaerobic bioreactors arranged in parallel which discharge into a rock filter polishing cell that is followed by a final aeration polishing pond. The primary lead removal mechanism is sulfate reduction/sulfide precipitation. The discharge has met stringent in-stream water quality requirements since its commissioning in 19%. However, there have been startup and operational difficulties. The system was designed to last about 12 years, but estimates suggest a much longer life based on anticipated carbon consumption in the anaerobic cells.

Jan 1, 2000

By S. R. S. Sastri, D. K. Senguta, S. K. Bhaumik, G. V. Rao

The amenability of a calcite-bearing ore to the reduction of silica to below 0.2% by physical beneficiation was studied. The objective was to use the ore as a raw material for seawater magnesia production. The ore contains complex gangue minerals such as diopside, forsterite, phlogopite, clinohumite, graphite and quartz. These contribute to around 25% acid insolubles with 6% SiO2. Reverse-flotation studies using various cationic collectors with tannin as a depressant indicated the possibility of reducing the acid insolubles to around 5%. Direct flotation of calcite with anionic sodium oleate in the presence of sodium silicate and lactic acid as a depressant indicated the possibility of reducing the acid insolubles to below 3% and the SiO2 to from 0.2% to 0.3%. Lactic acid was found to be an effective depressant of the complex gangue minerals in the ore.

Jan 1, 2000

By Conrad G. C. Douglas, Parris A. Lyew-Ayee, Vincent G. Hill

ABSTRACT Distinct patterns are identified in the associations, distributions, and levels of concentration of the silica minerals, boehmite, aluminous goethite, and phosphate minerals in the bauxite deposits of Jamaica. These result from syngenetic and diagenetic reactions associated with post-bauxitization tectonic and associated activities. Three basic types of bauxite are identified, viz., Jamaica-1 (< 3.0% boehmite), Jamaica-2 (> 3.0% boehmite and 30-80% of the iron as aluminous goethites), and Jamaica-3 (> 3.0% boehmite and > 90% of the iron as aluminous goethites). The Jamaica-1 type has a mean value of < 2% boehmite as A1203, while this level in the Jamaica-2 type is usually about 3.5%, and > 4% in the Jamaica-3 type. Similar discrete associations were found for the species and concentrations of aluminous goethite and phosphate minerals. The process and geological implications of these are discussed.

Jan 1, 1984

By S. K. Kawatra, S. J. Ripke

During 1998, 62 million tons of iron ore pellets valued at $1.7 billion were shipped from U.S. mines. These pellets are the primary source for domestic iron and steel production. During pelletization, binders are required to improve the green strength of the pellets. Each year, bentonite binder costs a typical plant from $3 million to $5 million. Reducing the bentonite dosage has the advantages of significant cost savings while producing higher quality, lower silica pellets. The authors have recently identified a new and important bentonite binding mechanism, the fiber theory. During this study, procedures were developed that took advantage of the ability of bentonite to form fibers, and resulted in a dramatic decrease in the necessary bentonite dosage. Acceptable quality pellets were produced with the bentonite dosages reduced in half from 14 lb/lt (0.66%) to 7 lb/lt (0.33%).

Jan 1, 2001

By Rod Knopp

Each year approximately 5,000 tons of a sulfide concentrate grading 1 ounce gold per ton are produced at this operation. The material is refractory and as shipping costs and custom smelter charges increase, options to process it on site are becoming more attractive. Three methods of treating the ore have been investigated in detail. The first option of ultra fine grinding the concentrate produces a 35% gold recovery with relatively low capital and operating costs. A second option of pressure oxidation is very capital intensive and has high operating costs but recoveries in the order of 95% are achievable. The final option, biological leaching offers both capital and operating costs which are less than pressure oxidation, while still achieving 90% gold recoveries. Bioleaching of gold concentrates has been gaining acceptance but there is a risk factor associated with this or any emerging technology.

Jan 1, 1990

By Harry M. Castrantas

Caro's acid (peroxymonosulfuric acid-H2SO5) is used to destroy cyanides in tailings slurries due to its rapid reaction and low capital and operating costs. Due to its instability, Caro's acid is generated at the mine site using a hot or cold process. The majority of gold mines that use Caro's acid use the FMC hot process. In the FMC hot process, it is not necessary to cool the Caro's acid to minimize decomposition since it is used immediately upon generation. In contrast, the cold process uses a chiller to cool the raw materials and product. This paper will show, using laboratory and field data, that there is virtually no difference in Caro's acid yield between the cold and the FMC hot processes. Caro's acid yield depends on the mole ratio and concentration of sulfuric acid and hydrogen peroxide and is independent of operating temperature.

Jan 1, 1997

By A. Goulsbral, D. Harrison, R. Dunne

A programme to reduce cyanide consumption at the New Celebration Gold Mine, situated 32kms South of Kalgoorlie, Western Australia, commenced in the latter part of 1990. Cyanide speciation studies at the time identified that the major loss and consequently consumption was due to the hydrolysis of cyanide, The use of artesian hypersaline waters of high magne­sium content on gold plants in Western Australian Goldfields has meant that economically viable operating pH values during cyanide leaching are around 8.9 to 9.5. The high ionic strength in these waters does to some degree retard the hydrolysis reac­tion. Notwithstanding this, the formation of hydrogen cyanide and its loss due to volatilisation is the cause of the major loss of cyanide on most gold plants in the Kalgoorlie Goldfields. This paper discusses the aspect of oxygen addition during cyanide leaching to decrease cyanide consumption and increase gold recovery.

Jan 1, 1996

By Dave Willis

Two hundred and thirty million tons of coal! That is what the Burlington Northern (BN) railroad anticipates that it and the Chicago North Western railroad (CNW) will haul out of the southern Powder River Basin l (see map on page 966) in 1994. Put that 209 Mt (230 million st) into railroad perspective. Current average train size is 113 cars. With each car transporting 94 t (103.5 st) of coal, each train averages 10.6 kt (11,700 st) of coal. Simple division shows that 209 Mt (230 million st) of coal equals 19,658 trains a year. So BN and the CNW must move 54 loads a day out of the Basin. Every load, of course, has an empty side of its cycle. This means that 54 loads a day translates into 108 total trains a day, or 39,420 trains a year through the southern PRB.

Jan 1, 1994

By B. Das, B. K. Mohapatra, K. S. Narasimhan, S. K. Bhaumik

The iron ore slimes (d80 ~ 50 µm) generated at Noamundi iron ore washing plant (TISCO), assaying 57% Fe, 4% Si02 and 8.3% A1203, have been subjected to hydrocyclone studies. The effects of different design and operating parameters have been studied to get a product suitable for subsequent use in the sinter mix. The studies indicate that it is possible to obtain a product containing 64% Fe, 1.4% Si02 and 3.5% A1203 with a recovery of 49% iron. The process involves classification followed by separation in a hydrocyclone. By this method, the overall yield of iron ore production in the plant is expected to increase by 8%. Microscopic examinations and X-ray diffraction studies were conducted to elucidate the mineralogy and liberation characteristics of Noamundi iron ore slimes. This paper deals with the findings of the investigations.

Jan 1, 1993

By Robert C. White, Kurt W. Keskimaki

The Henderson Mine is a large underground panel cave molybdenum mine located near Empire, Colorado. Diesel equipment is employed for all development work, as well as production ore handling. Due to fluctuating demand for molybdenum, production rates have varied from 16,000 to 32,000 metric tons per day (18,000 to 36,000 short tons per day) over the last four years. In order to obtain the maximum air flow for minimum power cost the Henderson mine has completed the following modifications to the ventilation system: removal of large intake fans, elimination of underground booster fans, shutdown of tunnel exhaust fans, completion of the number 5 exhaust ventilation shaft, and use of partially debladed main exhaust fans. These changes have reduced the annual cost of mine ventilation at the Henderson Mine by over 80 per cent, a very critical cost savings in today&apos;s competitive molybdenum marketplace.

Jan 1, 1989

By Cherie M. Tilley

The Stillwater Mining Company has acquired a Tunnel Boring Machine to expedite the mine development operations at its Stillwater Mine. The machine purchased by Stillwater was previously owned by Melbourne Metropolitan Board of Works, Melbourne, Australia. The machine was manufactured by Robbins Co. of Kent, Washington. The Stillwater Mine has an extensive system of footwall laterals which are required by the mine development scheme. The initial mine plan called for in excess of 30,500 linear meters (100,000 linear feet) of footwall lateral drifts at a cross section of approximately 3.0 meters in width by 3.75 meters in height (10 feet x 12 feet). A Tunnel Boring Machine was selected for this work. The Robbins machine number is 146-193. This machine is approximately 4 meters (13 feet 5 inches) in diameter. The machine was modified extensively prior to commencing operation at the Stillwater Mine.

Jan 1, 1989

By G. G. O. O. Uwadiale, M. A. U. Nwoke

The flotation of Azara barite tailings was investigated using crude rubber nut oil (RNOc), refined rubber nut oil (RNOR) and oleic acid as fatty acid collectors. Chemical characterization of the rubber nut oils indicated high acidity, high saponification values and high iodine indexes, which are indicative of a high fatty acid compositions. The Azara barite tailings analyzed 64.6% BaSO4 by atomic absorption spectrophotometry. Gravity and magnetic separation techniques yielded a BaSO4 concentrate with a grade of 74.8% and a recovery of 92.5%. Barium sulfate grades of 90.0%, 92.8% and 94.8% with recoveries of 80.3%, 85.4% and 86.7% were achieved with collector dosages of 750g/t crude rubber nut oils, refined rubber nut oils and oleic acid, respectively. Hence, rubber nut oils are effective fatty acid collectors for the flotation of barite tailings.

Jan 1, 1998

By H. L. O. Huyck

A microcomputer equipped with spreadsheet, data management, and FOR- TRAN programming software is used to update and quantify a model for ranking seventeen economically important metal commodities in terms of market potential (Huyck, 1982). Weighted factors are used for the ranking: (1) demand growth trends, (2) end-use substitution vulnerability, (3) recycling trends, (4) price trends, and (5) cumulative demand versus world reserves factor. Price trends are defined using (1) price-vs.-year slopes (with prices in 1967 constant dollars) and (2) standard deviations of slopes (to indicate price volatility). Substitution vulnerability is defined as the percent of end-use which is replace- able by other commodities, and a factor indicating the likelihood of such substitution. Factors are normalized and linearly combined to produce a ranking of the seventeen metals. Microcomputer software is essential for organizing data and calculating statistical parameters and linear combinations of factors.

Jan 1, 1986

By A. Pratt, G. Deschênes

This paper quantifies the detrimental effects of pyrite and stibnite on gold leaching kinetics. Means to reduce the effect of these minerals by addition of lead nitrate and oxygen are presented. A significant retarding effect was observed when the pyrite concentration was 20%. A pretreatment with lead nitrate reduced the extent of gold surface coating by Ag, Fe and S. Stibnite, at a concentration as low as 20 ppm, significantly affected the gold leaching kinetics through forming a passivating film of Sb(V) oxide possibly Sb2O5. The most practical way to alleviate the effect of stibnite is to leach the materials at a moderate pH with addition of lead nitrate. A low temperature reduced the efficiency of lead nitrate to counteract the effect of stibnite. The increase of dissolved oxygen is not favourable to alleviate the coating of stibnite on gold.

Jan 1, 2004

By H. Singh

Principal source of rhenium is molybdenite. Depending on the mineral processing route, rhenium can be recovered by one of the several alternative solvent extraction processes. Extensive experimental work has been carried out on the development of tertiary amine extraction process for treating very dilute highly impure scrub solutions obtained during scrubbing flue-gases of molybdenite oxidative roasting. Equilibrium data has been obtained under various process conditions by tracer analysis using radioactive Re-186. Extraction with 1% solution of a high molecular weight tertiary amine in kerosene, followed by scrubbing of organic extract with a solution of sulphuric acid and stripping with ammoniacal ammonium sulphate yields high recovery, concentration, and purification.

Jan 1, 1982

By Calvin R. Davis

The bucket elevator is probably the oldest known form of conveyor. Its history can be traced back to the days of Babylon where wicker baskets lined with a natural pitch and fastened to ropes operating over wooden sheaves turned by slaves, were used for the elevating of water into irrigation ditches. It is not unnatural for the bucket elevator to be the first in history, for even today engineers and designers recognize that well designed, correctly applied bucket elevators offer unequaled advantages over other bulk material elevating methods. The bucket elevator&apos;s vertical design saves valuable floor space. It provides flexibility of machinery layout with lowest initial capital expenditure, which is its principal advantage. While the advantages of the bucket elevator have long been recognized, there has been a tendency to lean away from its use because of high maintenance without reliability. CHAIN Belt Company found that the bucket elevator, if correctly applied, can be built to be as dependable and reliable as any other piece of machinery in today&apos;s modern processing plants. It is not difficult to understand why the bucket elevator is looked upon sometimes as a necessary evil in the material handling system. Very little has been published or written about the specific use or application of bucket elevators other than in manufacturers catalogs. Most of today&apos;s elevator application was set forth at the turn of the century by Hetzel (1). There have been many improvements made in the manufacturing techniques of elevator components, improvements in material selections, all which can be used to improve today&apos;s bucket elevator. To best understand the improvements which have taken place recently in the design and application of bucket elevators, an understanding of basic elevator principles is desirable. In general, it can be said that bucket elevators are classified into two basic types : (1) centrifugal discharge and (2) continuous. Elevators in use today are either of the centrifugal discharge type or the continuous type, or a combination of both in special applications.

Jan 1, 1958