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By Nathaniel Herz, R. J. Adamson, C. M. Romanowitz, Frank W. Jr. McQuiston, C. D. Hoyt, Robert S. Shoemaker, P. H. O’Neil

1. INTRODUCTION In this section, precious metals are defined as gold, silver, and the platinum group metals comprised of platinum, palladium, iridium, osmium, and rhodium. If the first three years of the 1970's are the criteria, gold, silver, and platinum seem destined for a bright future. Gold advanced in price from the historic figure of $35 established in 1934 to over $100 per oz (1973). For the five years 1966 to 1970, silver consumption exceeded production by about 50%. The silver price appears to be definitely on the uptrend, and a price of over $3 per oz seems probable. On this basis (at 1964 costs) the United States has an estimated 5 billion oz of unmined silver. The fresh burst of interest in platinum with a surge of renewed price strength (end of 1972) is due to the activity in the automobile emission control area, where platinum re¬mains the front runner in the catalyst area. Some international financial experts believe that governments will not rush into reform of the monetary system, and "Special Drawing Rights" (SDR's) will gain increased standing as international mone¬tary reserve assets. Gold will continue to be reviewed as the ultimate store of value and will remain the global monetary base. Devaluation of the U.S. dollar caused by imbalance of import payments over ex¬ports is the basic reason that the price of gold will likely remain above the $90 per oz figure for the balance of the 1970's. Gold and silver usually occur intimately associated, and recovery methods are often closely related; however, they were assigned sepa¬rate chapters, because the major production of each metal is from ore deposits classified as either gold or silver. For example, the gold ore occurrences in South Africa, the world's leading gold producer, have a ratio of gold to silver of approximately 10 to 1. The ores at the Homestake Mine, Lead, S.D., the largest U.S. gold producer, are predominantly gold with a ratio to silver of approximately 5 to 1. Silver in each example is a byproduct. By this same classification, the largest U.S. silver producers are the silver ores of the Sunshine, Galena, and Lucky Friday mines in the Coeur d'Alene district, Idaho. However, the largest single-mine silver producer in the Free World is the Kidd Creek Mine at Timmins, Ont., where the occurrence is with sulfides of copper, lead, and zinc. Thus, the major gold production of the world is derived from those ores classified as gold ores; whereas, less than one-half of the silver production is from silver ores, and only a small percentage of the silver production is from gold ores. 2. GOLD Gold, the noblest of metals, has been mined for thousands of years. Its chemical symbol, Au, is derived from the Latin "aurum," meaning "shining dawn." A precious substance because it is one of the rarest metals, it has unique physical properties: it does not tarnish; it exceeds all other metals or alloys in malleability and ductility; it is a good conductor of electricity and is one of the most nonreactive metals. Its greatest strength is its indestructibility. It is the only metal mined at depths exceeding 10,000 ft. Since the early 1800s, its chief role has been as a medium of exchange, providing the basis for interna¬tional trade. In the past 15 years, however, gold has emerged as a useful industrial commodity. This role has been fortified by the estab¬lishment of a two-tier pricing system which maintains monetary gold prices at an established U.S. Government price, with industrial gold being priced higher by the free-market system. Occurrences and Production Native gold furnishes most of the world's production, since gold forms stable natural compounds with few other elements. Neverthe¬less, the metal is widespread with traces of it found in seawater and in the ashes of plants and animal material. Next to the native metal, the tellurides have been the most important gold-bearing minerals; these include calaverite, krennerite, slyvanite, hessite, and nagyagite. Native gold is invariably alloyed with more or less silver, but it is exceptional to find any other metal in the alloy. It is found in veins associated with quartz, calcite, alunite, other gangue minerals, and with various sulfides. Sulfide minerals in order of frequent associa¬tion are: pyrite, galena, chalcopyrite, sphalerite, arsenopyrite, tetrahe¬drite, and pyrrhotite. Small amounts of metallic gold are commonly disseminated through such sulfides. When considerable amounts of silver occur in gold, the mineral electrum is formed. In a few deposits, gold and mercury form natural amalgam. Native mercury is formed by weathering from cinnabar and other mercury minerals. Among the minerals sometimes mistaken for gold, pyrite, marcasite, and especially chalcopyrite may be men¬tioned. The flakes of biotite and other micas, especially when partially oxidized, also may imitate it closely. World gold reserves never have been estimated carefully. Esti¬mates indicate that present world reserves approximate I billion oz, of which about 60% occurs in South Africa and 20% in the USSR. World gold output is dominated by South Africa which produces two-thirds of the world's production from reserves that are adequate to maintain existing output levels. South African gold output comes from approximately 50 large underground operations that mine and mill 70 to 80 million tons of ore annually to recover 30 to 32 million oz of gold. The USSR is the second largest gold producer, followed by Canada and the United States (see Table 1). Gold production in the United States and Canada rose to high levels in the 1930's, following the increase in price from $20.67 to $35 per oz and with an abundance of good labor due to depression in other industries. Production of over 10 million oz in 1940 was behind only that of South Africa. World War II caused a precipitous drop in gold output due to the imposition of War Production Board Limitation Order L-208 issued in October 1942, which caused over 9,000 gold mines in the United States to shut down, most of which never reopened. The U.S. Treasury, which suspended purchases of newly mined gold in 1968, had been the sole buyer of U.S. produced gold since 1934. This created the two-tier pricing system, and in March 1972 the President signed into law a bill authorizing a $3 increase in the official price of gold to $38 per oz. In February 1973 the President ordered a second devaluation of the dollar, amounting to about 10% which raised the official price to $42.22 per oz. The erratic development of the gold market, which has seen the

Jan 1, 1985

The classical slope analysis and a statistical technique were used in order to determine the iron complexes formed in the organic phase during the extraction of Fe(III) from Fe-Ni-Co sulfate solutions with Di-(2-ethylhexyl) phosphoric acid (D2EHPA) in kerosene. Equilibrium constants for the extraction based on these complexes were also calculated. The complexes determined were of the general form (Fe(OH)3-nRn?sHR)x' where n varied between 1 and 2.5 and s between 0 and 3, and both were found to be decreasing as the iron loading in the organic phase increased. Values of 1,2 and 3 were generally found for x, indicating that the complexes were monomers, dimers and trimers.

Jan 1, 1988

By S. Behl, S. Mathur

It was previously reported that dolomite samples from different locations showed varying flocculation behavior with poly(ethylene oxide) (PEO). In this study, a Florida dolomite sample was examined, and it was determined that palygorskite associated with dolomite was responsible for its flocculation with PEO. A detailed characterization of dolomite samples from different locations was made by electrokinetic, XRD and FT-IR analyses, and the relevance of these characteristics to flocculation with PEO is discussed.

Jan 1, 1996

By C. C. Clark, S. J. Jung

Determining the correct combination of mix components and water for high-density paste backfills that have the transport and deposition properties necessary for a mining operation is a difficult task. Rheologic properties cannot be determined without conducting full-scale pumping tests, and data from existing tests tire very limited. This paper presents the findings of investigations undertaken to determine if paste-backfill rheology can be determined using existing techniques and to determine which mix and system variables have the greatest influence on transport-pressure loss. Data from laboratory-scale pumping tests were used to produce a rheologic model of flow behavior for comparison, and a statistical analysis was conducted to determine the most significant factors affecting transport-pressure loss.

Jan 1, 1996

By Michael E. Mcllwain, Lee O. Nelson, Robert D. Rogers, James H. Wolfram

Examination of the economics and environmental consequences associated with phosphate fertilizer production documents the necessity for development of innovative production technologies. Evidence of phosphate ore's susceptibility to microbial alteration indicates that it will be an ideal candidate for industrial-scale bioseparation. There are at least two applications for the biosolu- bilization technology: (1) an industrial-scale bio- process similar to the presently used wet acid process and (2) production of small prills (bio- bead) containing unprocessed rock phosphate and the biological ingredients necessary to promote phosphate solubilization. At the present stage of development, the biobead technology is the preferred application. It is an energy-efficient "green" technology that will dramatically reduce the amount of solid waste and air emissions produced by the phosphate industry.

Jan 1, 1999

By M. P. Hardy, C. J. H. Brest van Kempen, H. N. Maleki

To evaluate the influence of uniformly tensioned roof bolts on roof stability, mechanically anchored roof bolts were installed using the conventional bolter and a specially developed thrust and torque controlled retrofitable box mounted on a bolting machine. Thirteen thousand bolts were installed over 19 crosscuts in a 4 heading development in an operating coal mine. Geological , bolt and mine parameters were recorded at bolt installation, and bolt tension histories, roof sag and other changes evident in the rooms, crosscuts and intersections were recorded over a 2 month period. In all, 24 variables and 11 responses were quantified at 67 bolt clusters. These data were analyzed statistically to determine the significant variables influencing roof stability. As the mine development was safe and stable during the monitoring period, roof sag after two months was used as an index to quantify "stability." The variables of significance were shown to be coefficient of variation of bolt tension, bolt anchorage capacity, roof lithology, roof shape, standard deviation of bolt tension, and dip of roof lithologies. It was concluded that of the variables with which the mine operator has control, bolt tension uniformity was the most significant parameter at this mine. Other variables, such as intersection type and time between mining and bolting , were not significant, whereas, some other potentially significant variables such as horizontal stress or roof joint frequency did not vary sufficiently for their influence on stability to be evaluated.

Jan 1, 1986

By M. K. Han, K. N. Han, P. B. Queneau, W. J. Dawson

The development and scale up of hydrothermal synthesis processes for manufacture of high performance materials is discussed. Traditional hydrometallurgical processes are reviewed, leading into a discussion of process development concerns for manufacture of modern materials. Three case studies are presented, including a piezoelectric ceramic, barium titanate for multiyear capacitors, and high purity chromium metal. Factors for selection of reactor design are presented, as well as results of scale-up studies on the three products.

Jan 1, 1993

By Y. Topkaya, R. E. Johnson, B. R. Palmer, R. B. Bhappu, Ronald J. Roman

The hydrodynamics of the leaching solution in leach heaps is known to be one of the important variables in the performance of the heap. The solution hydrodynamics are also important in the decommissioning of a heap where the aim is to flush out the residual dissolved metals and the remaining reagents. Chemical engineers have studied the hydrodynamics of "trickle bed" reactors for 40 years in an attempt to relate the performance of trickle bed reactors to flow conditions. Their work is reviewed with emphases on areas of similarity to heap leaching.

Jan 1, 1993

By P. R. A. Andrews, R. K. Collings

The beneficiation of barite has been the subject of many investigations at CANMET, thus reflecting barite's importance as an industrial mineral. Fifty-one studies relating to various aspects of beneficiation were conducted between 1920 and 1986, and a review of some of the more important studies is presented. The information, including mineralogy, beneficiation methods and results, flotation parameters, and reagent concentration data, is presented in tabular form. By so arranging the principal data, the research worker and production metallurgist will be assisted in the evaluation of barite ores from a variety of origins.

Jan 1, 1990

By Kiseong Hyeong

Geochemical characteristics, shapes and surface textures of manganese nodules from two blocks located in the southern (9°N~11°N) (KR5) and northern parts (16°N~17°N) (KR2) of the Clarion-Clipperton fracture zone between 130°W and 133°W were investigated in terms of sediment distribution and metal contents for better understanding of controlling factors of seabed manganese nodule genesis. Two blocks, ~700 km away, are dominated by the nodules with different origins, each of which has distinctive chemical compositions and shapes. KR2 block is dominated by irregular and poly-type nodules of hydrogenetic origin with low Mn/Fe, Cu, and Ni contents and high Fe and Co contents, while KR5 block is dominated by discoidal and ellipsoidal nodules of diagenetic origin with high Mn/Fe, Cu, and Ni contents and low Fe and Co contents. In addition, nodules from two blocks show different surface textures: smooth and transitional in KR2 and dimorphic and rough in KR5. Sediment distribution is also distinctly different in two blocks. The study area consists of three sediment types: Unit 1 ? dark brown mud with an intermediate metal content, Unit 2 - yellowish brown mud with poor metal content, and Unit 3 ? black metalliferous mud. KR2 is characterized by the thick occurrences (<250 cm) of Unit 1 at the surface while Unit 1 distributes thin (<12 cm) in KR5. Higher primary production rate in the southern block proximal to equator and resulting high supply rate of metals to the sediment might be the cause for the dominance of diagenetic nodules in the southern block, but potential controls of different sediment distribution on the nodule genesis can not be excluded. If it is the case, Unit 1 with an intermediate metal content likely has been acting as a sink for metals by precipitating micro-nodules within the sediment column. Within the KR5, the hydrogenetic nodules occur preferentially on the seabed where Unit 3 distributes at shallower depth (<50 cm). Unit 3 has 2 or 3 times higher metal contents than other types of sediments. It might play the same role as Unit 1 in the northern block that prevents the supply of metals to the sediment surface. It also supports the potential effect of sediment distribution on nodule genesis. Keywords: Nodules genesis, Sediment distribution, Supply rate of metals

Jan 1, 2008

By A. B. Holland-Batt

In the 1960s and 1970s, incremental development rather than innovation was the norm for gravity separation. However, the last 15 years have seen a number of new developments in this area. The article reviews the traditional gravity-separation techniques and then examines the newer developments such as centrifugal separators. Emphasis is placed on novel devices or improvements that offer better control or improved performance.

Jan 1, 1998

By V. Rajaram

A mine fire or roof collapse may necessitate the reversal of main fans to isolate the fire or provide an escapeway. Hence, to assist the mine operator in estimating the flow and pressure during reversal, Engineers International Inc. conducted a laboratory and field study of the reverse performance characteristics of main mine fans. Laboratory tests were performed using a 2.4-m (96-in.) diam vane axial fan to establish the forward and reverse performance characteristics under controlled conditions. Subse¬quently, a field test was conducted in a Colorado oil shale mine during which two 2-m (79-in.) diam fans were reversed. The data obtained indicate that reverse performance characteristics depend on the blade angle and the hub-to-tip ratio. The quantity in the reverse mode ranged from 30% to 65% less than in the forward mode, and the static pressure was directly proportional to the square of the quantity.

Jan 1, 1987

By David Pentz, Paul Hodges

GENERAL INTRODUCTION The object of this paper is to discuss those aspects of open pit mine design which are affected by geotechnical factors. The temptation exists for some practitioners of geotechnical engineering to believe that this relatively new engineering discipline is the ‘be all and end all of mining.’ In the opinion of the authors, this is fallacious but, as our ability to put numbers to the behaviour of rocks and soils improves, it is clear that geotechnical engineering will become an integral and important part of designing and operationg mines success- fully. Open pit mines in the context of this paper also includes open cast mines, where the &apos;ore" is extracted and the waste material is immediately replaced or &apos; backfilled in the mined portion of the pit. Open pit mines operating today move from very small tonnages a day to in excess of 400,000 tons per day. Several mines are operating and are being designed to capital expenditure for such projects in some cases exceeds five hundred million dollars and in a few cases will exceed one billion dollars. The size of this investment means that financing will have to be provided from banks or joint partnerships. This financial environment means that planning will be carefully scrutinized by experienced representatives of financial institutions or other mining companies. All too often a project has been put in jeopardy because the personal desire of one or two men to make a project proceed has caused incomplete planning or perhaps in some instances deliberately leading observers &apos;down the garden path.’ In our opinion the day is rapidly arriving when the quality, logic, practicability and completeness of the planning will make the difference between securing financing or not and, in the cases of existing open pit mines, of the difference between survival and closure.

Jan 1, 1977

By A. Ersoy, M. D. Waller

Because of a shortage of diamonds for the drilling industry in the 1970s, efforts were made to develop synthetic diamonds. The resulting development of polycrystalline diamond compacts (PDC) enabled the evolution of a new generation of rotary-drilling drag bits. Bits based on PDC cutters were very successful in drilling soft, abrasive and medium strength rocks. However, because of their thermal instability, they failed rapidly when drilling hard rocks. Thermally stable diamond (TSD) was then developed for hard-rock drilling. The rate of penetration (ROP) and bit life significantly influence the drilling cost. The ROP and the life of the TSD bits or cutters are affected by a number of complex factors. However, in laboratory testing and infield operations, the principal factors that need to be considered in predicting drilling and wear rates are bit design characteristics, bit operating parameters and the characteristics of the penetrated rock. These characteristics are comprehensively reviewed for both laboratory and field drilling results using TSD bits. Optimization of these parameters increases the drilling rate, prolongs the bit life and reduces the drilling cost.

Jan 1, 1998

By Robert G. Moorhead

Fine-coal screening can be one of the most critical operations in a modern coal-cleaning plant. The yield and quality of clean coal produced in fine-coal circuits is controlled as much by how efficiently 0.15 mm (100 mesh) particles are sized as on the performance traits of the fine-coal cleaning device itself. In addition, the increased interest in effective fine-coal sizing operations indicates that many operators have also discovered its importance in affecting the quality and yield of clean coal produced in fine-coal circuits. This paper describes the three most prevalently used fine-coal screening technologies and discusses their sizing mechanism, performance, and application.

Jan 1, 1988

By Regina N. Tempel, Mae S. Gustin, Mark A. Engle

This study characterizes the hydrogeochemistry of groundwaters near opalite-hosted epithermal hot-spring type mercury deposits in the Ivanhoe mining district, Elko County, Nevada. Local groundwaters generally range from Ca-HCO3 to Ca-Mg-Na-SO4 type waters with background mercury concentrations ranging from 0.014 to 0.32 ug/l. Leaching experiments conducted on mineralized rocks, using typical water chemistries to represent local groundwaters, yield total mercury concentrations ranging from 6.3 ug/l to 27.4 ug/l after one year of reaction. Geochemical modeling indicates dissolved mercury is dominated by HgO(,) and that precipitation of quicksilver controls mercury concentrations to an upper limit of 63 ug/l.

Jan 1, 2000

By R. Houot, C. Leschevin, G. Gillet

In mineral processing, conventional magnetic separators are equipped with traditional magnetic circuits (magnetic iron yoke with copper coils or iron-clad solenoid) that develop magnetic fields of less than 2 T&apos;. For minerals of low magnetic susceptibility, use of these circuits has many disadvantages. Only a separator with a superconducting magnet can contribute to solving the problems and produce a high magnetic field. This paper presents and describes a magnetic separator having a superconducting magnet with integrated closed circuit for helium liquefaction. The system generator and maintenance are simplified by extensive automation realized by a versatile program- mable autocontrol unit. A comparative study if the results on concentration and purification of different raw materials with the new and with conventional separators is described.

Jan 1, 1987

By Robert Snow, Francisco Sotillo

Six types of amines were evaluated in the cleaning step of the rougher concentrate for the Crago “Double Float” process in terms of relative selectivity. Selectivity of these amines was ranked based on both batch and locked cycle flotation tests. Two parameters were used for selectivity ranking, the Selectivity Index, SI, and the ratio of insol rejection to the tailings weight percentage, R*. The comparison of the flotation results of the batch tests of the cleaning step of the Crago process for an unsized amine feed generated the following ranking from the most selective to the least selective mine: Quaternary > Primary [ ]Tertiary [ ] Condensate > Ether > Secondary(?).

Jan 1, 2002

By Albert E. Ketler

The techniques for fire monitoring of conveyor belts in underground coal mines have been revolutionized by the advent of sensitive carbon monoxide sensors and computer monitoring systems. These new systems are rapidly replacing the previous thermal (fixed-point temperature) sensors that have been shown to be considerably less sensitive for early fire warning. CO is generally an excellent indicator of spontaneous combustion. However, the most recent non-flammable conveyor belt materials have been shown to "burn" with dense smoke, but without sufficiently high temperatures to produce much carbon monoxide. To cover this fire detection void, a smoke detector was developed to augment CO sensing for these new conveyor materials. However, computer monitoring provides the flexibility for handling this and other additional instrumentation as fire monitoring techniques evolve. CO, smoke and temperature sensing may eventually be advocated for complete fire monitoring.

Jan 1, 1987

By J. L. Hendrix, M. Ahmadiantehrani, G. Ramadorai

The concept of hypochlorite treatment prior to cyanidation in the heap leaching of low grade carbonaceous gold ores is discussed. Laboratory column leach tests using a low grade carbonaceous ore were performed to investigate the effects of pH, hypochlorite consumption and concentration, and bed height on total gold extraction. At high pH, hypochlorite stability increases and thus, hypochlorite consumption decreases. At room temperature, total gold extraction is proportional to hypochlorite consumption. However, at some point additional hypochlorite consumption does not increase gold extraction. Gold recoveries of 10% and 80% are achieved at 12 and 167 lb/ton hypochlorite consumption, respectively. Increasing hypochlorite concentration increases the rate of extraction. For a given hypochlorite consumption, gold extraction increased with decreasing ore bed height. Finally, using calcium hypochlorite results in higher gold extraction than using sodium hypochlorite at a fixed hypochlorite consumption.

Jan 1, 1992