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By M. Ahmadiantehrani

The concept of hypochlorite treatment prior to cyanidation in the heap leaching of low grade carbonaceous gold ores is discussed. Laboratory column leach tests using a low grade carbonaceous ore were performed to investigate the effects of pH, concentration, hypochlorite consumption, and bed height on the total gold extraction. At high pH, the hypochlorite stability increases and thus, hypochlorite consumption is decreased. At room temperature, the total gold extraction is proportional to the hypochlorite consumption. However, at some point additional hypochlorite consumption does not increase gold extraction. Gold recoveries of 10 and 80 percent are obtained for 12 and 167 lbs/ton hypochlorite consumption, respectively. Increasing hypochlorite concentration increases the rate of extraction. For a given hypochlorite consumption gold extraction was increased by shortening the ore column height. Finally, calcium hypochlorite is more effective than sodium hypochlorite.

Jan 1, 1990

By J. E. Rourke, O&apos

This paper describes the use of rock index property testing to obtain rock properties that a.re useful in the design and construction planning of an underground development for civil engineering or mining projects. The index properties discussed include (1) point load; (2) Schmidt hammer hardness; (3) abrasion hardness; and (4) total hardness. The first two index properties correlate to uniaxial compressive strength and Young's modulus. Discussions are given on the relationship to rock mass properties and the integrated use with semi-empirical, geotechnical design methods. The latter two properties correlate to construction performance parameters and some experience is cited. Examples of data are presented from an index testing program carried out on siltstone, sandstone and limestone rock core samples from a deep borehole drilled in the Paradox Basin of Utah for a nuclear waste repository site investigation.

Jan 1, 1988

By Michael J. Nicol

Hydrometallurgical processes involve the recovery of metals from ores, concentrates, calcines, mattes and scrap materials by a series of operations involving leaching or dissolution, separation, purification and reduction of metals in aqueous solutions. The underlying theoretical basis of many of these operations is electrochemical in nature and it is the purpose of this review to identify and illustrate, by way of examples from the author's experience and that of others, the central role of interfacial electrochemistry in the understanding, design and control of these operations.

Jan 1, 1993

By David L. Bradfield

This paper covers the development of the Yeelirrie Uranium Project from the discovery of the Yeelirrie deposit in 1970 to the present time, with emphasis on the mining, processing, and environmental requirements of the project. The Yeelirrie Uranium Project is managed by the "Yeelirrie Uranium Joint Venture Partnership", which, when formed, consisted of Yeelirrie Development Company Pty., Ltd., Urangesellschaft, Australia Pty. Ltd. and Esso Exploration and Production Australia Inc. The Yeelirrie Uranium Joint Venture Partnership holds mineral claims over the Yeelirrie uranium ore deposit in Western Australia. This deposit encompasses some 35 million tonnes of ore containing in excess of 50,000 tonnes of uranium as U308. Agreement has been reached with the State of Western Australia to mine and process the ore to produce uranium ore concentrate. The Project scope provides for an open-cut mine, alkaline leach hydrometallurgy plant, power plant, township, airstrip, access roads, community services and utilities. The Yeelirrie Uranium Project described herein has progressed through the stages of exploration, mine evaluation, process testing, project scope definition, environmental approval, Pilot Plant operation, preliminary engineering and the publishing of a definitive Project Feasibility Study. This article summarizes the project development through the above stages.

Jan 1, 1984

By K. L. Johnson

Networks of monitoring wells were established prior to mining at four longwall mine sites in the Appalachians to monitor the effect of mining on water levels, water quality and well yield. Two of the sites were located in stream valleys and the other two sites were located on hilltops. The depth to the mined seam ranged from 500-850 feet with the deeper cover being associated with the hilltop sites. Maximum declines in groundwater levels during and after mining were an order of magnitude less in the stream valley aquifers than in the hilltop aquifers. However, water levels in hilltop wells located outside the area immediately above the panel were unaffected. Water quality changes in wells as a result of longwall mining were negligible at all four sites. Increases in aquifer transmissivity and well yield were much more pronounced in the stream valley aquifers than in the hilltop aquifers. The significantly larger recharge area for the stream valley aquifers than that for the hilltop aquifers may partially account for the differing responses of these two classes of aquifers to longwall mining. These observations appear to be consistent with the stress-relief fracture model for Appalachian Plateau groundwater hydrology proposed by Wyrick and Borchers in 1981.

Jan 1, 1986

By Joseph R. Hatch

Previous studies of the Thompson and Temperly ore bodies show alteration aureoles in the Middle Ordovician host-rock limestones, dolomites and shales extending laterally as much as 60m from the ore. Thickness, texture, carbonate and clay mineralogy, major-, minor-, and trace-element contents; and carbonate carbon and carbonate oxygen Isotope compositions of the host rocks all have been significantly altered by hydrothermal processes. Organic geochemical analyses of samples from the basal 8-cm-thick carbonaceous shale bed and immediately overlying limestone bed of the Quimbys Mill Member of the Platteville Formation, collected from within the ore, the alteration aureole, and the unaltered country rock show: 1) solution of carbonates and residual concentration of organic matter, 2) decreases in the volatile (Si) and pyrolytic (S2) hydrocarbon yields In samples of the basal shale from within the ore, 3) decreases in the relative amounts of the lower molecular weight (<nC25) saturated hydrocarbons in samples from the ore, and 4) no changes in either the organic carbon isotope composition or the Rock-Eval or biomarker thermal maturation Indicators. In light of the 125-170°C depositional temperatures documented for the early marmatitic sphalerltes in these deposits by fluid Inclusion studies, the lack of thermal alteration of the organic matter suggests a relatively short mineralization episode, a conclusion supported by the relatively simple sphalerite band stratigraphy. The decreases in the volatile and pyrolytic hydrocarbon yields for shale samples from the ore supports a model for mineral deposition which obtains sulfide through reaction of brine sulfate and indigenous organic matter.

Jan 1, 2013

By Dale D. Teeters

Today, I would like to talk about ways to maximize the efficiency of surface coal operations. I doubt I will present any startling new ideas, but my comments may, hopefully, stimulate some conversation today and later back at your own operations. Strip mining is a very old technique used by ancient societies. Only with the coming of the machine age in the early twentieth century did we attempt to increase the magnitude of our operations. The industry, as we know it today, really only got started in the early 1900s with the advent of steam shovels. In the first portion of this presentation, I will attempt to show that we have, in many cases, not changed the basics of strip mining, only the scale. In doing so, quite often we have complicated the operations to the point of being unmanageable and unprofitable.

Jan 1, 1981

By R. Bleischwitz, R. Delzeit

"Tantalum, a heavy metal with characteristics such as superconductivity and high terminal resistance, nowadays is the most efficient material for production of capacitors, which are essential for production of small electronic applications like notebooks and cell-phones. It is one of the strategic resources for information societies. With supply extracted from Central Africa (Congo / DRC), China, Australia, and Canada, it can serve as an example for sustainability efforts in the management of non-renewable resources in Developing Countries, Newly Industrializing Countries and Industrialized Countries alike. The paper analyzes the life cycle of tantalum in its environmental, social, and economic dimensions. The first section highlights the importance of tantalum, showing a demand-driven market. The second section analyzes current and future supply. The third section tackles environmental and social impacts of tantalum mining in different legislations. The fourth section especially deals with the Case of the Democratic Republic of Congo since companies have been accused of participating in a civil ‘resource war’. Section five will draw conclusions for sustainable resource management. Written in an interdisciplinary manner, the article has a bearing on economics, especially on resource economics and new institutional economics, as well as on geography. It deals with questions such as security implications of physical scarcity in rapidly growing markets. In doing so it can, firstly, be shown that information exchange in combination with reputational risks lead to a shift in extraction activities from a Developing Country (DRC) to an Industrialized Country (Australia); i.e. a ‘race to the bottom’ does not take place. This, however, does not mean that market mechanisms work properly since information exchange (especially with China) is incomplete, moral hazard still prevails, and inadequate institutions hamper development processes in an exporting country like Congo. Any sustainable resource management for tantalum not only should foster gathering and exchanging better information on environmental and social impacts, but also incentives for upstream metal recycling in industry as well as support for governance processes in Developing Countries"

Jan 1, 2005

My "outside exploration" began in November 1908, only 16 months after I had come to Bisbee as a raw engineer. The well publicized reputations of eminent engineers up to that time, including John Hayes Hammond, Herbert Hoover, James Douglas, D.C. Jack- ling, J. Park Channing, and a few others had been due to new mines they had found or brought to successful operation. And here was I, a mere youngster, given a chance to join the group. I knew there would be disappointments but I had no idea how many of them. In spite of the many prospects that turned out to be worthless I never looked at a new one without the feeling that this one might turn out to be the big success. This confidence, blind as it was, gave every arduous examination a zest and it made me climb every mountain on which the owner said there was something worth seeing, or on which T could see a distant staining that might mean ore. If I looked at every showing the owner suggested he at least would think I was honest and would bring other properties to our attention. This reputation of never refusing to go to see an outcrop, no matter how hot the desert sun or how rough the terrain, was probably one of my best assets. High as my hopes were at the start, they proved not to be exaggerated and if I were given a chance to do it again I would not hesitate, in spite of the jaundice, rheumatic fever, and other maladies that beset some of the expeditions. On the whole the results have equaled all my hopes. Toward the end of my years of active exploration I totaled up the score. Out of the prospects submitted to us about two out of three were eliminated after questioning the owner or prospector, without an examination. This left about a 1000 mines or prospects that seemed worth at least a preliminary look. One out of seven of these was worth a little development and a seventh of this seventh turned out to be a modest success or better. And nine or ten in all, or one out of 1000

Jan 1, 1976

By J. B. Knapp, J. W. G. Betts, Scott L. Burreill, J. H. Bassarear, E. A. Lowe, W. J. N. Davis, John L. Bolles, Gaylord P. Dopson, William H. Keener, N. S. L. Steenkamp

This chapter contains moderately detailed descriptions of some typical and well known mills that treat predominantly sulfide copper ores, some containing secondary values in gold, silver, and molybdenum. The descriptions are general in nature, because most of the specific data will be found in tabulations elsewhere in this section, covering a large number of mills in such matters as flotation reagents, crushing and grinding equipment and steel consumption, thickener and filter operating data, power consumption, and many others, in a manner that the reader will find convenient and comprehensive for reference and comparison. On the other hand, the plant descriptions selected for this chapter emphasize the kind of information that cannot be readily tabulated.

Jan 1, 1985

By E. Sehner, G. Van Weert

Metal chloride pyrohydrolysis is a fifty year old technology, operating satisfactory in many plants around the world, mainly on ferrous chloride, The capabilities and costs of its two equipment options (spray roaster and fluid bed pyrohydrolysis) are well known. Why is the technology not more widely used in mineral processing, beyond the production of MgO and upgraded TiO2slag? After briefly reviewing chloride vs. sulphate process characteristics and existing plant operations, this paper will discuss pyrohydrolysis options for the mine developer using the processing of ilmenite, siliceous zinc oxides and oxidic nickel / cobalt ores as examples.

Jan 1, 2003

By Roderick G. Eggert, John E. Tilton

During much of the 1970s and 1980s, world metal consumption grew more slowly than during the 19505 and 1960s. The slowdown contributed to surplus capacity and low real prices because actual consumption was consistently less than expected as new mining and mineral processing capacity came on stream. Over the last year or so, however, world metal consumption has picked up noticeably, raising the question, Has metal demand returned to the long-run growth rates more typical of the 1950s and 1960s than of the 1970s and 1980s? This paper examines this possibility and, more generally, assesses the factors that will shape demand for the major metals over the longer term. TRENDS IN METAL CONSUMPTION The extent to which metal consumption has recaptured the brisk growth rates typical of the 1950s, 1960s, and early 1970s is shown in Figure 1. This figure traces the consumption of crude steel, primary aluminum, refined copper, refined lead, and refined zinc between 1960 and 1987 for the western world, consisting of the OECD countries (including the United States), and the developing countries. Consumption increased in 1987 for all five metals, and preliminary data for the first six months of 1988 suggest even more substantial increases, at least for the United States (U.S. Bureau of Mines, 1988). However, Figure 1 also shows that the recent increases in consumption are not untypical of similar surges during earlier periods of economic expansion and thus may reflect only cyclical or temporary factors. In short, the available data are unable to provide a clear indication of whether recent increases in metal consumption reflect the beginning of a new era of faster growth or simply a cyclical and temporary upturn associated with the expansionary phase of the business cycle. Consequently, to pursue this issue, we are forced to examine the underlying forces that will shape metal demand trends over the next decade. The approach we have taken involves two steps. The first examines the prospects for overall economic growth. The expectation is, the faster the economy expands, the faster the production of metal-containing goods grows.2

Jan 1, 1989

By R. A. Jankowski

Although the number of operating longwall mining systems has remained relatively constant, longwall production levels during the last five years have increased significantly. In the United States, longwall mining now accounts for approximately 50% of all underground coal production. While longwalls are highly productive and offer other advantages, operations employing this method of mining continue to experience dust-compliance problems. This increased longwall productivity has meant that far more dust is being produced. An improved understanding of the longwall face-ventilation system and the advancement of face-ventilation technologies are necessary to ensure all face personnel are allowed to work in an environment that is free of excessive levels of airborne respirable coal mine dust. The Dust and Toxic Substances Control Branch, National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, examined several basic principles of the long wall face-ventilation system and has evaluated the effectiveness of numerous improved face-ventilation techniques for longwall mining systems. These include identifying improved techniques for measuring face-ventilation parameters on longwall mining sections and investigating the fundamental relationship between face airflow and the entrainment and dilution of respirable coal mine dust. Studies have been completed to determine the impact on face dust levels of using belt entry air to ventilate the longwall. Novel methods have been identified to increase the face air¬flow and to manage face airflow to effectively minimize dust exposure to face workers. Unique systems of auxiliary face ventilation have been developed and evaluated at full-scale, simulated longwall test facilities. The theoretical and applied aspects of each of these principles and technologies are discussed. Application of these results throughout the longwall mining industry, as documented from surveys conducted in the early 1980s and 1990s, have reduced the health hazard associated with excessive exposure to respirable coal mine dust.

Jan 1, 2000

Due Dilligance does not only lie in the statistics, but rather in the practical process aspects, which is the window to understanding the statistics.

Jan 1, 2005

By Mark R. Bowie

Air-fall tuffs have been altered to zeolite via reaction of volcanic glass with local pore solutions at the six localities discussed in this paper. These are in the southern Basin and Range Province of Arizona and New Mexico, and in the Trans-Pecos and Coastal Plain regions of Texas. Zeolitization occurred in either closed- hydrologic, open-hydrologic, or hydrothermal groundwater systems. The tripping Spring Valley (DSV) chabazite in Arizona and the Buckhorn clinoptilolite in New Mexico originated in a late Cenozoic network of closed-hydrologic, lacustrine basins extending from southeast Arizona into southwest New Mexico. At DSV, two potentially commercial chabazite-rich tuffs are interbedded with lacustine mudstone. The main zeolite tuft contains up to 90 percent chabazite. The upper zeolite tuff averages approximately 67 precent chabazite. At the Buckhorn deposit, two clinoptilolite-rich tuffs are interbedded with lacustrine m udstone in the upper part of the Gila Conglomerate. The lower zeolite tuff contains up to 90 percent clinoptilolite. The upper zeolite tuff contains over 60 percent clinoptilolite. The Casa Piedra clinoptilolite is in the Trans-Pecos region of Texas. It formed during the Tertiary in a closed basin containing a playa lake. The Casa Piedra tuff averages about 60 percent clinoptilolite. Air-fall tuffs of the Cuchillo Negro, New Mexico and Tilden, Texas clinoptilolite deposits were zeolitically altered by either percolating ground waters in open-hydrologic systems or locally by ponded, saline, alkaline solutions. Cuchillo Negro tuffs are Tertiary and average approximately 50 percent clinoptilolite. Clinoptilolite-rich tuffs of Ebcene age have been mined from four quarries at the Tilden deposits. Tufts from the Kuykendall and Buck Martin quarries contain approximately 50 to 60 percent clinoptilolite. Low temperature, SiO2 - rich, hydrothermal solutions altered air-fall tuff to clinoptilolite and chabazite in the Foster Canyon area of the Tertiary Cedar Hills and Seldon Hills volcanic-vent zone in southcentral New Mexico. Poster Canyon tuffs contain up to 60 percent zeolite and average 40 to 50 percent clinoptilolite. The dominant mineral in the zeolite tufts at the six deposits studied is generally microcrystalline and either chabazite or clinoptilolite. Lithic fragments, unaltered volcanic glass, other zeolites, quartz, calcite, opal-CT, cristobalite, feldspar, evaporites, clays, and mafic minerals are also constituents of the tufts.

Jan 1, 1987

By H. I. Morrison, A. J. deVilliers, D. T. Wigle, H. Stocker

INTRODUCTION At the end of 1959, high levels of radioactivity attributed to radon and its daughter products were discovered in the fluorspar mines at St. Lawrence, Newfoundland. These levels were presumed to be the cause of an unusually high incidence of lung cancer among the fluorspar miners (deVilliers & Windish, 1964) (Parsons et al. 1964). The mining of fluorspar (calcium fluoride) began in 1933 as open pit operations but converted to standard underground mining procedures in 1936. During the second world war, production was greatly expanded as a result of increased demand for fluorspar used in the production of steel. Wet drilling was first introduced into general use in 1942. Ventilation was mainly by natural draft occasionally supplemented by small blowers. The amount of ventilation varied greatly between mines as well as over time. For example, one large mine, the Iron Springs mine, had only a single small raise to the surface some 600&apos; from the central shaft. Other mines, such as the Director mine, had a number of raises to the surface and, as a result, had far better ventilation. Mines also varied by the amount of ground-water which seeped into them. In the early 1950&apos;s, an unusually large number of lung cancer cases were diagnosed among the fluorspar miners. As a result, in 1956 and 1957, J.P. Windish of Canada&apos;s Department of Health and Welfare tested for possible causative agents in the mines. Unfortunately, radon measurements were not conducted until 1959 and 1960 when Windish tested Director mine as did the A.D. Little company in 1960. As a result of the high radon levels found, mechanical ventilation was introduced and the concentration of radon dauthers fell, on the average to well below 1 WL. During this period, lung cancer cases continued to be diagnosed with 29 lung cancer deaths recorded by 1964 and 71 by 1971. As of July 1981, 105 lung cancer cases had been identified (Hollywood, 1981). Previous reports concerning the fluorspar miners have dealt in detail with the factors in the occupational environment and discussed occupational mortality patterns. The purpose of this paper is to review further the mortality experience with particular reference to lung cancer in relation to cumulated radiation exposure and to describe briefly our ongoing study of this group. METHODS Occupational histories were prepared for men who had been employed by the mining companies at St. Lawrence during the period 1933 to 1977. The histories were compiled from company records except for the period 1933 to 1936, records for which were lost in a fire; however, the occupational histories for this period were completed by searching census records and interviewing company officials, ex-employees and others. In addition, occupational and smoking histories were also obtained for some miners during a survey conducted in 1978. Occupational records included name and date of birth as well as the type, place and hours of work by year. For each year prior to 1960, hours of work were converted to working months (1 WM = 167 hours) and were multiplied by the estimated average radon daughter concentration in working levels (WL) to yield the annual radiation exposure in working level months (WLM). Pre-1960 radiation levels were estimated on the basis of the history of mining methods employed, ventilation history of the mine, type and place of work and conditions under which the first radiation measurements were made in 1959 and 1960 (deVilliers and Windish, 1964). During the period from 1960 to 1967, the average exposure was about 0.5 WL. Beginning in 1968, radiation levels were measured more frequently, and, beginning in 1969, daily exposures for each worker were recorded based on radiation levels in the place worked on a given day. Mortality data were obtained from medical certificates of death. In a small number of cases, medically certified death certificates were unavailable. In these cases, probable cause of death were obtained from forms completed by the local clergyman (returns of death), parish records, information obtained from interviews with family members of the deceased and/or hospital information, before assigning a cause of death. Data obtained from these sources were found in Tables 1, 2 and 4, cover the time period 1933 to 1971. Data in Table 3 as well as in Figures 1 through 3 cover deaths from 1933 to 1977, and includes only those miners for whom medical certificates of death were available. Two medically certified causes of death were changed from other causes to lung cancer on the basis of pathology reports.

Jan 1, 1981

By Dennis Molvik, Omar Fulton, Chris D. Breeds, Don Gonzales

The Tolt Pipeline No. 2, West Snoqualmie Valley project, is part of a water supply project linking the Tolt reservoir in East King County to the City of Seattle through a nominal 2.13 m (7-ft) inside diameter conveyance. Receipt of the National, 2002Microtunnel Award provided recognition of the many challenges overcome by this project. Baseline conditions revealed in the Geotechnical Documentation included over-consolidated glacial deposits, landslide and alluvial deposits, artesian water, boulders up to 36-in in diameter, logs, heaving sands, and liquefiable soils beneath the river. Schedule constraints associated with setting the shafts in the floodplain of a salmon bearing river and the fickle performance of the river during those times it was not supposed to flood added to the challenge.

Jan 1, 2003

By R. A. Speirer, T. C. Bettinger, L. P. Richardson

INTRODUCTION The Bureau of Mines (The Bureau) remote sensing researchers at the Denver (CO) Research Center, have been investigating computerized methods to detect and map surface linear features called "lineaments" for ground hazard assessment in mines. Many of these lineaments at the test mine site were found to correlate to subsurface geologic discontinuities such as faults, fractures, and joints that intersect coal seams at depth. These features adverse1 y affect the roof and rib integrity in underground mines, thus contributing to rock failures that may result in injuries to mine workers and loss of production. Advance knowledge of the existence of such hazardous geologic features can aid in mine planning and development. Lineaments may be observed in a variety of images of the earth&apos;s surface. Linear features that can be observed using Landsat mu1ti spectral scanner data (MSS) images range from regional (greater than 3 miles in length) to an intermediate length of from 1 to 3 miles. These images are recorded in discrete radiation bands in the green, red, and near-infrared portions of the el ectromaynetic spectrum. These data are acquired from the EROS Data Center of the U.S Geological Survey, Sioux Falls, SD, in digital format on magnetic tapes that are suitable for processing on certain minicomputers. Shorter lineaments length (less than 1 mile) can be observed in high- to low-a1titude aerial photography, radar, and infrared images with image scale ratios of 1:1,000,000 or less. These linear features can correlate to smaller dimensioned faults, and to fracture and joint sets at the local geologic scale. Other informational sources can help substantiate 1ineament analyses, such as well logs, mine naps, topographic data, and geophysical data acquired over the study site. These data must be in a digital format to process on the "DEC PDP 11/23 minicomputer system1". Data can be acquired in

Jan 1, 1986

By S. Henley

There is much in common between the requirements of open-pit mining and quarrying operations. Both involve the extraction of large volumes of material from surface excavations. The principal differences are of degree: open-pit mining of materials such as coal or gold generally involves the extraction of only small volumes of &apos;mineral&apos; and large volumes of waste-they are operations with very high stripping ratios, and are made viable only because of the high unit value of the extracted mineral. In quarrying operations, the unit value of the mineral - sand, aggregate, limestone, or clay - is much lower, but stripping ration Are also lower. Thus the same techniques of geological modelling, reserve estimation, and pit planning are applicable, as is shown in two examples from the British quarrying industry. In each case, a primary requirement is the definition of production volume or tonnage. Sometimes, this need may be addressed simply by the use of a survey data processing package. However, in other cases, such as the two examples addressed in this paper, of sand and clay quarries, detailed assessment of the variation of mineral grades is a vital part of the exercise, and simple volumetric modelling cannot in itself be sufficient. In these cases, a block model approach using simple logical and numerical post-processing is also required to obtain required parameters for commercial classification of the products to be extracted. Pit designs themselves may be optimised by use of algorithms such as Lerchs-Grossmann, but the value of mineral produced can be dependent on factors other than its grade in any one part of a single pit, and the &apos;optimised&apos; pit itself must be considered only a good sub-optimal. Given the right degree of healthy skepticism, and a software package with sufficient flexibility to be adapted readily to the rather different requirements of the quarrying industry, there is no reason why the quarrying industry should not benefit from the many years of investment in mining software technology.

Jan 1, 1989

By C. E. Capes

INTRODUCTION In the coal industry, ever greater amounts of fine coal must be processed due to the need to crush to finer sizes for impurity liberation in low cost physical cleaning processes. Fine coal processing is a major problem for the industry, both through the cost of disposal of reject fines and through the mining cost of lost coal values. Of the available disposal methods, impoundment has always been the most popular. In many cases, when the coal fines were of sufficient quality, froth flotation and expensive filtration methods were used to recover the coal in these waste streams. The coal fines are not always of a marketable quality, however, and flotation, due to poor yields and difficult dewatering, has always been an expensive and not necessarily profitable process. The oil agglomeration method is increasingly important as a technology for the treatment of fine coal-in-water suspensions. These fines can be preferentially wetted and agglomerated by many different oils mixed with the suspensions. Ash-forming impurities remain in suspension and are rejected when the agglomerates are recovered, for example, by screening. Agglomeration-based methods provide perhaps the only practical means for upgrading extremely fine coal to useful products on a large scale. As with froth flotation, oil agglomeration relies on differences in the surface properties of coal and impurities to effect separation. Whereas flotation be- comes less effective with particles finer than 200 mesh (0.075 mm) or coarser than 50 mesh (0.3 mm), there appears to be no lower limit on particle size for oil agglomeration while particles % in. (3.175 mm) diameter or larger can also be treated, if desirable. In addition to this ability to clean a broader size range of coal particles, oil agglomeration can produce a dense, coarse granular product of acceptable strength and low water content without the need for vacuum or thermal drying. The preferential wetting of solid surfaces by immiscible liquids has been utilized, if not fully understood, for a long time. Indeed Gaudin,229 in tracing the ancestry of froth flotation, refers to a 15th century oil-pulp kneading procedure in which water-wetted particles were freed under water from an oiled mass. An understanding of the physical chemistry involved in such

Jan 1, 1991