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By Gabriel K. Nzulu, Lars Hultman, Per Eklund, Martin Magnuson, Abu Yaya, Prosper M. Nude, Hans Högberg

Pyrite is the most common among the group of sulfide minerals in the Earth and abundant in most geological settings. This gangue mineral in association with garnet, hematite, magnetite, and other sulfide minerals acts as an indicator mineral in the Kubi concession of the Asante Gold corporation in Ghana. X-ray diffraction (XRD), air annealing in a furnace, energydispersive x-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS) were applied to investigate the crystal structure, identify individual elements, permanence, transformation, and chemical/electronic properties of such pyrite. The study aims to identify individual elements and to gain an understanding of the surface reaction mechanisms, as well as the properties of precipitated pyrite particles observed during the hydrothermal formation of the ore deposit. XRD shows that pristine and annealed samples contain some hematite and quartz besides pyrite. Results from air annealing indicate that the relationship between pyrite and hematite-magnetite is controlled by temperature. EDX reveals that the sample has O and C as contaminants, while XPS in addition reveals Ba, Au, P, Al, and N. These elements are attributed to pyrite that bonds metallically or covalently to neighboring ligands/impurity minerals such as oxides, chalcogenide sulfides, as well as the gangue alteration minerals of magnetite and hematite in the pyrite sample. These findings suggest that during the hydrothermal flow regime, pyrite, pathfinder elements, and impurity minerals/metals were in contact with quartz minerals before undergoing hematite transformation, which thus becomes an indicator mineral in the Kubi gold concession.

Feb 27, 2024

By Zong‑yu Li, Shao‑jian Ma, Xiao‑jing Yang, Jin‑lin Yang, Xing‑nan Huo, Heng‑jun Li

Optimizing and adjusting the particle size composition of grinding products is of great significance for improving economic benefits and resource recovery and utilization. In this study, grinding contribution and quantitative separation of impact and grinding mechanism in cylindrical mill were creatively researched, and the grinding technical efficiency of impact and grinding was coupled to the grinding technical efficiency of grinding in drop-off mode. The results showed that the contribution rate of impact and grinding in grinding in drop-off mode varied with the grinding time. On the whole, the contribution rate of impact action increases with the grinding time and gradually becomes stable, and the contribution rate of grinding effect was just the opposite. Under the experimental conditions, the main contribution of the grinding process is impact action, and the contribution of grinding action is auxiliary. In addition, the contribution rate of impact and grinding effect in grinding in drop-off mode was also related to the feed particle size. The contribution rate of impact effect decreased with the decrease of feed particle size, while the contribution rate of grinding increased inversely.

Aug 3, 2023

By Suresh K. Bhatt

A mathematically simulated modeling technique is used in this U.S. Bureau of Mines paper to represent a hypothetical mining operation with existing mining technology and prevalent mining costs. Mining scenarios are prepared and evaluated for potential benefits and costs available through computer-assisted mining. Base criteria, parameters, and methodology are described.

Jan 1, 1991

By John B. Goddard

Crystallization of ammonium paratungstate (APT) is frequently the last effective purification step in producing high-purity tungsten. However, crystallizer mother liquors are often several times higher in tungsten than predicted by the solubility of APT. The formation of heteropoly anions, particularly those containing phosphorus and silicon, is largely responsible. Solubility of tungsten in APT mother liquor can be linearly correlated with the concentration of these and other impurities. The problem can be overcome by direct treatment of the crystallizer feed solution with alum. By appropriate treatment, the aluminum hydroxide flocculates and is easily filtered, resulting in a purified low-aluminum crystallizer feed from which high APT yields can be attained.

Jan 1, 1984

By Calvin L. Stevenson

The probability of a particle passing through a maze is predictable and consistent. This principle may be utilized to effect a particle size separation of materials by presenting a physical maze to a stream of material that will allow the fine particles to pass, while deflecting the coarse particles. A maze is effective even though all apertures encountered are many times larger than the particles being separated. By designing a machine that allows the probability parameters to be controlled and varied without changing physical dimensions, probability sizing becomes a useful tool for the separation of granular materials.

Jan 1, 1967

By I. Iwasaki

Differential flotation of bulk sulfide concentrates from Duluth gabbro into copper and nickel concentrates could be implemented by first destroying the hydrophobic coating with ozone and then by recovering the copper concentrate with a copper-selective collector. A number of parameters involved in the use of ozone; such as the sequence and the conditioning time of ozone treatment, the pulp pH, and the level of xanthate addition, were investigated.

Jan 1, 1985

By James K. Hallenburg

Geophysical borehole logging is a valuable and inexpensive tool for coal deposit evaluation, development, and production. In addition to the usual determinations of depth and seam thickness, geophysical borehole logs can effectively and accurately determine the coal ash, moisture, and heat contents in situ. Location and evaluation of the partings can be done quickly and accurately. Overburden character determination, such as roof competence, dewatering parameters, ripability, trace element content of the coal and overburden, and sulfur content can be done with existing tools and techniques. The quality of such determinations depends upon the quality of planning and calibration.

Jan 1, 1984

By Alvaro Lucio

The continuous increase of the fuel oil price compelled CV3D to look for an alternative fuel. Charcoal was selected as the alternative energy source. This paper justifies its selection, describes charcoal properties, the methods for using charcoal in the pelletizing and shows the results of the in-plant tests.

Jan 1, 1982

By Keshavan Nair

In connection with Project Payette, which is concerned with the detection of underground nuclear explosions, it was necessary to determine the technical feasibility of constructing and maintaining a large (approximately 315 feet in diameter) unsupported underground cavity at a depth of approximately 2700 feet in the Tatum Salt Dome in Mississippi. The dimensions and the location of the cavity in the salt dome were governed by criteria laid down by the Atomic Energy Commission. Within the framework of the specified criteria, cavities of various shapes and dimensions could be utilized. One aspect of the feasibility study was to investigate the structural stability of various cavity shapes and to recommend a preferred shape. This paper summarizes the studies that were conducted to evaluate the structural stability of various proposed cavities.(l)

Jan 1, 1968

By D. W. Gunkle

Processing of various ores and materials in a reducing atmosphere has been done for many years. However, the typical device currently used is a large, often high maintenance, expensive piece of equipment; the rotary kiln. While it is a very reliable and a proven technology, the rotary kiln also has its limitations. It is limited by its ability to process very fine materials without creating a huge dust loss to the air pollution control equipment. This leads us towards the development of an alternate technology; the Gas Suspension System. Gas suspension preheating of various materials has been in commercial use since the early 1950's, but recently has been expanded to include Gas Suspension Reduction. Laboratory experience has proven successful on several materials; Nickel Laterite Fines, Iron Ore Fines, Fluorspar, and Clays. The gas suspension reduction system has many advantages over the conventional reduction kiln when processing fines. They are; lower cost, more fuel efficient, able to process fines, less real estate required, etc.

Jan 1, 1998

By Louis P. Gignac

The Lac Shortt gold deposit is located in Northwestern Quebec, at some 115 km west of the Opemiska Division and 380 km northeast of the Lac Dufault Division, as shown on Figure 1. Falconbridge's exploration crews drilled the first six holes in the gold-bearing ore zone in 1979. After further diamond drilling from surface in 1980, the decision was taken to carry out an underground exploration program. A three-compartment shaft was sunk to a depth of 340 metres in 1981 and 1982; it was followed by an extensive exploration program, which included 1073 metres of cross-cutting and footwall drifting, 645 metres of ore drifting and 11 200 metres of diamond drilling. The underground work was completed by mid-winter 1983. It was followed by a complete feasibility study of the Lac Shortt Project. After some $Can 14.2 millions in exploration expenditures, the Board of Directors of Corp. Falconbridge Copper approved in July 1983 additional expenditures of $Can 45 millions to bring the Lac Shortt Mine in production at the capacity of 261 000 tonnes per year. Gold price was $US 425 per ounce at the time.

Jan 1, 1985

By S. S. Peng

In this paper, the precise definitions for a number of commonly used subsidence parameters are given. The subsidence parameters have been determined using an integrated approach for 110 subsidence cases collected in the major US coal fields. Attempts have been made to establish empirical formulae for the parameters. The results of this study indicate that some traditionally-held concepts should be changed.

Jan 1, 1995

By G. S. S. Raman, M. S. Klima

The effects of pressure and cake thickness were studied using a split-plot design for pressure filtration of a fine refuse slurry obtained from a bituminous coal preparation facility. Pressure filtration offers the potential to significantly reduce the moisture content of the fine refuse stream with the addition of little to no flocculants, thereby minimizing the volume of refuse stored in impoundments and providing a recycle water stream for use within the plant. Experimental results showed that the final cake moisture decreased with increase in pressure and decrease in cake thickness. In addition, specific cake resistances calculated for the various tests indicated an increasing trend with increasing pressure and decreasing cake thickness. With increase in cake thickness, an increase in cake moisture and the weight of solids deposited in the cake was observed. An ANOVA analysis indicated that both cake thickness and pressure significantly affected the cake moisture, while only cake thickness statistically influenced the weight of solids in the cake. A regression model was developed with an R2 value of about 0.99 to relate cake thickness, the single largest statistically significant factor, with the weight of solids in the cake. Filter capacities were calculated in terms of the solids deposited per unit time based on a product specification of 25 percent cake moisture, and it was observed that the thinnest cake had the highest filter capacity.

By J. Y. Kim

Lead ions originating from galena during processing of complex sulphide ores migrate to "cover" the surface of sphalerite and iron sulphide mineral particles, and cause poor selectivity in differential flotation. Generally in sulphide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. Subsequently, surface lead complicates the zinc flotation circuit by lowering the concentrate grade due to the co-flotation of lead-activated iron sulphide minerals. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zn and Pb-Zn ores is discussed. Plant and laboratory test data are interpreted by determining the surface composition of individual grains of sphalerite and iron sulphide particles using two surface analytical techniques, Laser Ionization Mass Spectrometer (LIMS) and Time of Flight-Secondary Ion Mass Spectrometer (TOF-SIMS). Cationic and anionic species on the surface were analyzed to elucidate the phenomena.

Jan 1, 1995

By P. E. Damon

An arsenal of isotopic techniques is avail-able that can date the full range of hydrothermal ore deposits. The following are prerequisites for ideal results: (1) Careful collection of samples that are related to the event in a field and process context; (2) Optical examination of the component selected for dating to be sure that it has not been altered; (3) Careful preparation of a pure component of the sample selected for dating; (4) Precise and accurate measurement; (5) Knowledgeable interpretation of the data with reference to decay systematics, properties of the component analyzed as well as the field context and thermochemical environment of the ore process.

Jan 1, 1992

By Kenneth A. Grace

Introduction The 1980s have not been kind to the mining industry, especially in the United States. As mineral commodities prices plunged, marginal producers were squeezed out and then major players were forced to cut back or close down operations. Base metal miners suffered the most. Gold was all that glittered. As had been the case throughout min¬ing's history, exploration activity was an early victim of these depressed conditions. Mining companies had to economize drasti¬cally and exploration was deemed a nones¬sential activity. Funding for new explora¬tion ventures dried up as mining was seen as a poor investment. A national magazine even proclaimed the death of the industry. Indeed, ignoring matters of independ¬ence of supply and the relationship of min¬eral production to national security, it was argued that mining was but a small cog in the overall scheme of things in the United States. The industry made a relatively small contri¬bution to the gross national output. We were becoming a service industry economy, re¬member? But what of those countries where mining plays a major role in the economic well-being? In some, mining is the national economy. In a few specific cases, special conditions actually brought prosperity. Copper production in Chile is one example. There, high grade copper, low production costs, and a technically advanced industry reaped the benefits of mine closures else¬where. In most other cases, however, par¬ticularly in the lesser developed countries, whole economies were devastated. This article will show what one major mineral producer, Canada, did to ensure the survival and even growth of its minerals exploration activity during these lean years. Background While Canada is among the world's mining leaders, mining is not its dominant industry. Still, it plays a far more important role than in the United States. It is a major earner of foreign exchange, currently accounting for about 25% of the total value of exports. Through spinoffs and a multiplying effect, it is a significant employer. In the far north, particularly, mining is the major nongovernment industry and a leading factor in the opening up of frontier territory. The industry cannot be allowed to die because it is often the main economic underpinning for vast, remote areas. Thus, exploration for new deposits cannot be cur¬tailed significantly without it having a long¬term negative impact on the very fabric that melds such a large, sparsely-populated ex¬panse of country into a nation. Over the years, Canadian governments have employed various means to encourage the development of new mines. Often, these incentives were tax-oriented, such as the three-year income tax holiday that applied to new mines in the 1950s and 1960s. The advantage of the tax connection is that any such incentive policy can be applied across the board to the 10 provinces and two territories that make up the federation of Canada. This is important because mining, except for the two federally-administered northern territories, comes under provincial government jurisdiction. Mining taxation is a complex give-and-take between the central and provincial authorities. In Canada, expenditure on mineral exploration is an allowable cost against reve¬nue for tax purposes. This works well pro¬vided there is some revenue from which to deduct. New exploration companies, those with no income from mining activities, de¬rive little benefit from this type of tax provi¬sion. Similarly, in times of depressed prices and reduced or nonexistent profits, the tax deductibility of exploration spending loses its value even for the major mining compa¬nies. To encourage exploration in Canada during the lean years, a different sort of incentive was required. The instrument used during the 1980s was again tax connected. It became known as flow-through financing or, simply, flow-through shares. When it assumed its final shape, it worked dramati¬cally. Flow-through shares Flow-through shares are so-named because they permit tax benefits earned by a corporation to 'flow-through' to the share¬holder. Basically, when an investor buys a flow-through share and the proceeds de¬rived by the company from this transaction are used for Canadian exploration, the in¬vestor can claim a deduction for tax pur¬poses as if the exploration expenditure was made by him personally. Flow-through shares go back to the early 1970s when Canada revamped its mineral income tax law. At that time, it permitted full deduction of exploration and development expenditures and provided for an automatic depletion allowance of one¬ third of operating profits from mining. There was also the three-year income tax holiday for new mines. New legislation replaced the depletion allowance with an earned depletion arrange¬ment whereby one dollar of depletion was earned for every three dollars spent on ex¬ploration and development. This earned depletion was `banked' during a transitional period (to 1974). After that it could be deducted from resource profits up to a maximum of 25% of such profits in any one year, with the excess carried forward. To promote exploration and mine de¬velopment in Canada, the earned depletion allowance plus the continued deductibility of exploration and development expendi¬tures permitted the recovery of risk capital before taxation. The three-year tax holiday, however, disappeared. Also, mining com¬panies that did not reinvest in exploration lost the depletion allowance benefit.

Jan 1, 1989

By B. F. Dickerson

STRATEGIC METALS! Recently, this money accented cry has been heard in such diverse locales as Mining company boardrooms, Banker's offices, Stockbroker's quarters, Swindler's dens and Congressional committee rooms. (In some cases, these locales are one and the same). Is the strategic metals rush for real? Should it be? Our paper attempts to give a very generalized view of the subject for a few metals, points to a few potential, but generally overlooked sources of these metals, and offers conclusions based on our studies.

Jan 1, 1981

By Kenneth N. Han

The effect of anions such as sulfate, chloride and nitrate on the solubility of rare earth element (REE)-bearing phosphates and fluoro-carbonates was examined using relevant thermodynamic data. The study found that these anions have significant influences on the overall dissolution of REEs from various sources in the aqueous media.

By Guy D. Bruno

Through the remainder of this century, world consumption of fluorine per ton of primary aluminum produced will continue to be substantially reduced. Growth of the primary industry will offset some of the unit consumption, but demand for new fluorine sources will decline sharply. Continued application of dry fume scrubbing systems will be the most significant factor in reducing demand.

Jan 1, 1978

By Mark J. Zdunczyk

"Frac sand is industrial silica sand much like glass, foundry, filtration and blast sand. The sand must meet certain specifications set forth by the industry that consumes the product. The production and consumption of frac sand has experienced record growth in the last 10 years because of new oil and gas drilling, new horizontal well drilling, multi-stage fracturing and the stimulation of older wells that have little or no production. Frac sand is needed to “prop open” the fractures in the rock reservoirs to allow oil and gas to flow out more freely.According to the U.S. Geological Survey (USGS), the estimated production of frac sand in 2015 was 71 percent of the total production of industrial silica sand or 67.4 Mt (74.3 million st). This is a decrease of about 12 percent from 2014. However, the silica sand industry and other industry sources estimate only 50 Mt (55 million st) of frac sand were produced in 2015. In recent years both the USGS and industry studies have been very close in estimating the production of frac sand but with the recent downturn in frac sand production, perhaps, reporting to the USGS was not as accurate. These discrepancies may be that the USGS statistics are based on voluntary reporting by the industry and some companies report their approximate production, others may not. It is always difficult to obtain accurate production figures of any industrial mineral or construction aggregate operation as most companies tend to keep those figures somewhat confidential. It is certainly accurate to report that the production of frac sand had decreased since the last quarter of 2014 and through 2015. The oversupply of oil and natural gas has led to this decline in frac sand usage. Oversupply has idled drilling rigs and well completion activities. World Oil Magazine reports that 2015 was the worst year for rigs in a quarter century. The only wells being completed are those that have contract agreements to do so, others have been capped. Very few new wells are being drilled. Since about 98 percent of well completion is sand and water, the sand supply has caught up with the demand. There are some bright spots in the “oil patch” as the Permian Basin in Texas and the Woodford Shale in Oklahoma have kept pace somewhat with drilling and completion. It has been reported that the frac sand producers in the Brady-Voca, TX area are producing to nearly capacity. The northern frac sand producers like those in Wisconsin, Illinois and Minnesota are feeling the downturn because of the cost of shipping sand to these moderately active basins and plays. The “rule of thumb” is that freight is 2/3 and sand is 1/3 the cost."

Jul 1, 2016