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By Firoze E. Katrak, John R. H. Black, Paul R. Ammann, Michael J. Loreth, Servi. Italo S.

Germanium is produced primarily as a by product from zinc concentrates. The important sources of gallium are alumina ores (bauxites) and zinc concentrates and residues from zinc processing. In addition, gallium as well as germanium may soon be recovered from a depleted copper mine near St. George, Utah. The major uses for germanium are in semiconductors, lenses in infrared optical systems, catalysts, and gamma radiation detectors. The major markets for gallium are in light-emitting diodes, solar cells, laser diodes, integrated circuits, microwave devices, and magnetic bubble memories. CRA projects a healthy growth in the demand for both metals. However, the role of scrap metal will continue to be important over the next decade, thus decreasing the overall demand for primary gallium and primary germanium. This paper summarizes the key elements and the economics of the markets for germanium and gallium. Much of the information, such as plant-by-plant costs of production and estimates of consumption by end use for various countries is from proprietary databases of Charles River Associates.

Jan 1, 1986

By S. A. Matthews, M. L. Nave

AC variable frequency motor drives are emerging technology for belt conveyors. The success of the application in mining depends on adequate and timely consideration of drive, motor, and conveyor features. The purpose of this paper is to familiarize and inform possible mining users of AC variable frequency drive attributes.

Jan 1, 1998

By B. Cavender

Investments in new technology are often intended to improve the production or cost performance of existing operations. The economics used to justify these projects can be flawed, however, if they do not adequately consider the potential benefits of the alternative: the fully optimized use of the facility's present equipment and personnel. While new technology can be effective, dramatic improvements in production performance can also be achieved through the rigorous application of standard industrial engineering and operations management practices. An intermediate approach may also be effective: many basic improvements in the mine or plant necessary to support new technology will be equally effective when implemented for the facility's present operators. Firms that optimize their present operations are able to save the capital and avoid the risk associated with new technology. These firms will also be able to capitalize more quickly on new technology when it is implemented.

Jan 1, 2000

By S. Monette, D. B. Dreisinger, D. Vleeschhouwer, G. B. Harris, G. A. Kordosky

A new process for the recovery of pure (>99.95%) palladium and platinum is described. The process, which has been tested at the pilot scale, comprises (i) the simultaneous solvent extraction of palladium and platinum by a new Schering Berlin reagent, TN 1911, (ii) washing of the loaded extractant to remove co- extracted impurities, and (iii) differential stripping of first platinum at pH 3, and secondly palladium with strong hydrochloric acid, and (iv) precipitation of palladium and platinum salts, followed by reduction to metal. The process is, unusually, a non-ammonia one requiring only small amounts of ammonia at the end where final purification may be necessary for particularly complex feed solutions.

Jan 1, 1993

By J. A. Chermak, D. D. Runnells

Sulfide-bearing waste rock, ore and tailings have the potential for generating acid rock drainage (ARD) when exposed to an oxidizing environment. The possibility exists of utilizing the acid produced to react with lime and/or limestone to form a self-sealing cap on the reactive waste rock and tailings. Laboratory column experiments were conducted using acid-generating waste rock with a surface amendment of limestone and/or lime. Artificial rainwater was introduced and allowed to drain through the columns. Results demonstrated that the limestone and lime reacted with the acidic rock, resulting in the precipitation of a hardpan layer of gypsum and amorphous iron oxyhydroxide at the surface. The hardpan layer significantly reduced the effective permeability of the column. Based on the results of this study, it should be possible to create hardpan layers as chemical caps to significantly reduce the infiltration of rainwater and snowmelt into acidic waste rock or tailings material in the field. Unlike traditional capping methods, e.g., clay and high-density polyethylene (HDPE) covers, chemical caps should be self-healing.

Jan 1, 1998

By S. Chander

Neutralization of acidity by addition of alkaline materials is a commonly used method to treat acid mine drainage. However, this procedure requires large amounts of reagents based on acid-base accounting. The potential use of organic additives in preventing or ameliorating acid mine drainage was investigated in this research. The tests were conducted in weathering columns using refuse samples from a coal cleaning plant. Both cationic and anionic compounds were tested. For a comparison, tests were made in the presence of limestone and lime. The results show that some of the reagents substantially retarded the rate of oxidation whereas others even enhanced it. The suppression of the rate of pyrite oxidation was ascribed to surface chelation. Formation of surface compounds prevented the pyrite particles from further oxidation. Such a treatment required only small quantities of reagents since the reaction was confined to the surface.

Jan 1, 1992

By K. G. Sutterer, P. T. Wang, R. Sweigard

One possible alternative for the disposal of flue gas desulfurization (FGD) by-products is to use it as backfilling support material in highwall mine adits. The finite element method was used to analyze the variation in stresses and displacements within and around a highwall adit backfilled with FGD materials. The engineering properties of the rock material and the optimum mix of the FGD materials were obtained from laboratory tests. Finite element analyses show that, for the case in question, the roof displacement would decrease about 48% and the peak stress could be decreased by about 58%. The study indicates that fairly weak FGD materials can eventually lead to the stability of backfilled highwall adits.

Jan 1, 1998

By Thomas P. Meloy

As the importance of particle shape in mineral processing is increasingly recognized as an major variable in predicting the behavior of both individual particles and particle systems, whether it be in dense media, froth flotation, comminution or the flow of particles, new method of shape characterization are being developed, particularly for use on image analyzers. These shape characterization methods may be broadly classified into the analytical, empirical and physical formation methods. Discussed are approaches and the strengths and weakness of each of these methods. Moreover old and new shape measuring techniques are reviewed, particularly the new image analysis methods techniques such as Fourier, Haar, Fractal, Walsh and Delta as well as a variety of other techniques such as tabling, the Cascadograph, settling and L/D ratios. Also discussed are the problems of doing shape research, current progress and the future of the field.

Jan 1, 1990

By J. Scott McDougall, J. Herman P. Eng. Vanderlaag

An underground mine fire can seriously threaten the lives of all personnel in the mine. This fact makes fire emergency planning a high priority in the mining industry. The optimum warning alarm must be fast and able to reach all miners, regardless of their location or work activity. Current means of fire warning are varied, and include such methods as stench, telephones, and word-of-mouth (messengers). Unfortunately, none of these methods are entirely satisfactory. A novel fire warning alarm which enables instantaneous warning of all underground personnel, the Canary Nine Messenger System, has been developed by VLF Magnetic Systems Inc. in conjunction with Noranda Technology Centre and the U.S. Department of the Interior - Bureau of Nines. The warning is sent by an electromagnetic signal which penetrates through mine rock to receivers housed in the battery packs which also power each miner's cap lamp. A loud buzzer in the integrated battery/receiver unit and the flashing of the cap lamp alerts miners to incoming messages. Testing of prototype equipment has demonstrated that the transmitted signal is capable of penetrating through over a mile of mine rock and activating the receiver. This report describes the theoretical basis for through-the-rock ultra-low frequency electromagnetic transmission, and the design of recently available transmitter and receivers.

Jan 1, 1995

By A. J. Monhemius, S. Raghavan, G. W. Warren, E. Peters, D. W. Furerstenau

A lyometallurgical process for extracting copper from an ore containing chrysocolla by leaching it with a kerosene solution containing LM 63 in the presence of small amounts of aqueous ammonia is described. The experimental results indicate that 70 to 75 percent of the copper can be extracted from the ore using an ammonia content that is about one-fourth the stoichiomeaic quantity required to leach copper in an aqueous leaching system. The rate of copper extraction was found to be a function of particle size, ammonia concentration and temperature. The large quantity of physically adsorbed water together with ammonia in the pores of chrysocolla provides a mechanism for the transport of copper to the external surface of the particles where it is complexed by the LM molecules and transferred into the organic phase. When size reduction accompanies leaching, the extraction process was found to proceed when only "trace" quantities of ammonia are present in the system. The kinetics of the extraction process appear to be controlled by a mixed (reaction and diffusion) mechanism.

Jan 1, 1993

By R. A. Jankowski

Laboratory tests were conducted to evaluate the silica collection efficiency of flooded-bed scrubbers using six different filter panel designs at two operating velocities. Test results indicated that reductions in filter density negatively impacted respirable dust collection. Silica collection efficiency for the least-dense filter was as much as 33 % lower than the collection efficiency of the most-dense filter. At the low operating velocity, the least-dense filter allowed more than 40% of the respirable silica dust in the scrubber intake air to pass through the unit and back into the mine environment. Operation of the scrubber at the higher test air velocity increased silica collection efficiency regardless of the filter panel tested The density of the filter panels also impacted the quantity of air moved through the scrubber, with higher-density filters reducing scrubber airflow. For each filter, the relationship between dust-collection efficiency and air-moving capacity must be considered to determine the overall effectiveness for each mine application.

Jan 1, 2000

By Richard Hogg, Erol Kaya, Jan M. Mutmansky

Characterization of the size, shape, chemical composition, and mineralogical content of mine airborne dusts generally requires a larger mass of dust particles than is typically collected using traditional sampling devices. In this paper, the general design of a passive dust collector is described and the field results are presented. The collector was constructed of galvanized sheet metal duct with a resin-coated honeycomb to provide an elutriation-type system for particle collection. Several versions of the collector were used in the field portions of the research. The dust samples collected from underground coal mines were found to possess angular particle shapes, relatively consistent size distributions, and elemental compositions that showed relatively little variation, at least for the more prevalent elements. In addition, the distributions of particles sizes obtained from the passive dust collector appear to be similar to those of samples collected at the same time in a conventional personal sampler except that the passive device seems to collect a larger quantity of coarse, non- respirable particles. Conclusions on the suitability of this dust collector for collecting characterization samples are presented. In addition, the potential for using such a dust collection system for supplying dusts for biomedical research is discussed.

Jan 1, 1993

By Leslie G. McMillion

A field project to develop and demonstrate a method for alleviating problems of highly-mineralized ground water where they occur as isolated zones or pockets in fresh-water aquifers is being conducted in the Ogallala Aquifer of eastern New Mexico by the Robert S. Kerr Water Research Center. Removal of contaminated water is by a large-capacity well and the pumped poor-quality water is used locally for secondary recovery of oil, Benefits of the operation are threefold in that the aquifer is being reclaimed for future fresh water production, contaminated water is being used beneficially, and fresh water which otherwise would have been used for waterflooding is available for other purposes. Ground-water quality in the site has improved markedly after 21 months of operation. Water quality in 15 specially-drilled monitoring wells has returned to the original quality level of the aquifer, and chloride concen¬trations in the pumping well have dropped to half the maximum level recorded thus far. Project results are very favorable and provide guidelines for initiation of similar undertakings in localities where needed.

Jan 1, 1970

By J. T. Crawford

A comprehensive strategic-planning model was developed for the phosphate strip-mining and chemical operations at White Springs, FL. The computerized model covers orebody modeling, production simulation and financial analysis. The model has several innovative features, including the use of NPV techniques in orebody block economics, the adaptation of the floating-cone method to a floating template for generating dragline mining units automatically, the use of interactive graphics for designing mining units, and the use of a dragline move economics algorithm for the automatic scheduling of mining-unit assignments and moves. The simulation of chemical-plant production uses linear programming and concentrate inventory levels to control mine-operating schedules.

Jan 1, 1999

Traditionally, production volume has been considered the major determinant of cost. As volume increases, total cost increases but unit cost decreases. This concept has been so widespread in industry that many of the tools used to analyze costs are based on production volume as the sole measure of activity and driver of unit cost-fixed and variable costs, cost-volume-price and breakeven analysis, contribution margin, flexible budgets, and others. Clearly, volume is a driver of cost. It is important in both a tactical sense (to the manager at an operating mine) and a strategic sense (as one determinant to the firm's overall cost position). However, many other factors influence costs as well, even though they have not been studied to the same extent. For example, production managers know that their costs will be reduced if the workforce does not have accidents. Safety costs are to a large extent independent of volume. Other cost components increase as volume increases, such as some environmental charges. Some costs may or may not reflect volume changes. Maintenance, for example, may appear as either a fixed or variable cost, as can operating labor in facilities that are highly automated. In the strategic sense, where the firm is selecting a strategy to pursue competitive advantage and increased profitability, all costs are variable. This reflects both the strategic intent and the long-term time frame associated with strategic positioning. Tactically, on a month-by-month basis, some costs are essentially fixed. Cost driver analysis must therefore consider the relevant time frame.

Jan 1, 1999

By J. Michael Howard

Holes cored through the Prairie Creek lamproite volcanic complex at the Crater of Diamonds State Park by companies interested in the site's commercial diamond potential give an opportunity to redefine the size and shape of the Prairie Creek pipe. Relationships of cored rock sequences and the discovery of a previously unrecognized major rock type allow a reinterpretation of the sequence and type of intrusive activity. Trench sampling of diamondiferous rock units yielded a diamond content far below what was anticipated based on an estimate from historical records. Inadequacies of shallow bulk-testing methods for a diamondiferous pipe are examined.

Jan 1, 1999

By P. K. Ackerman, F. F. Aplan, G. H. Harris, R. R. Klimpel

Fourteen reagents that are potentially capable of chelating with a metal ion on the surface of the major copper sulfide minerals and pyrite were evaluated for their effectiveness in floating these sulfides. The reagents studied fall into the classes of mercaptobenzole mutations, thiouronium, thionocarbamates, thiourea, imidazole mutations, oximes, hydroxyquinoline and xanthogen formate. The best overall copper sulfide collector was an imidazoline (1-Hydoxyethyl - 2-Heptadecenyl), but it also proved to be an excellent collector for pyrite. Its potency as a pyrite collector can be reduced by structural alteration, but at some loss in its collecting power for the copper sulfides. The effectiveness of many of these potential collectors can be changed by minor alterations to the collector molecule and, to a lesser extent, by pH adjustment. The general order of mineral floatability with these reagents is chalcopyrite = chalcocite > covellite =bornite >> pyrite. The flotation of malachite is generally similar to that of the copper sulfides, indicating the special effectiveness of copper in the crystal lattice for collector attachment.

Jan 1, 2000

By V. B. Achanti, A. W. Khair

This paper deals with the effects of various bit geometric parameters on the failure characteristics of rock material. Improving the rock-cutting efficiency of continuous mining machines has proven to be an interesting research topic during the last few decades. In the current study, an automated rotary rock-cutting simulator, duplicating a continuous miner, was used to study these parameters in the laboratory. The improvement of bit performance in terms of its life, cutting efficiency, dust production and energy consumption has drawn widespread attention. Research has demonstrated that optimizing bit parameters can result in efficient fragmentation of rock. Indiana limestone rock material was used in this study. The bit tip angle, bit tip size, bit spacing, depth of cut and cutting velocity of the rotary drum were varied to investigate the failure characteristics. The cutting pressure, penetrating pressure and the depth of cut were monitored on the simulator during the cutting process. Airborne dust and settled dust were measured for each experiment. Then, the specific airborne dust and specific energy were determined for each type of bit. Triaxial tests were carried out to correlate the failure angle of the rock in the static case to the dynamic cutting process failure. The physical and mechanical properties of the rock were also determined to assess their influence on the wear characteristics of each bit.

Jan 1, 2000

By W. J. Deutsch, W. J. Martin, R. J. Serne

At the termination of mining, the quality of ground water in the ore-zone aquifer must be returned to a condition predetermined by the permitting agency. To immobilize the redox-sensitive elements (e.g., uranium, arsenic, selenium, molybdenum), it has been suggested that a reducing agent be circulated through the leached ore zone. We have conducted laboratory experiments to test the ability of sodium sulfide as such a reducing agent. Sodium sulfide lowered the redox potential of the effluent such that insoluble minerals containing the redox-sensitive elements should be stable. The uranium concentration of the solution decreased by more than three orders of magnitude. In column experiments, by the time 10 pore volumes of the sulfide solution had flowed through, sulfide minerals were forming. The experimental results indicate that the addition of sodium sulfide should cause chemical reduction of the leached sediments, thereby producing long-term stability of the ground-water/sediment system.

Jan 1, 1988

By David M. Mchaina, Michel Grenier, Stephen G. Hardcastle

An airborne dust survey was conducted at the Arthur W. White mine of Dickenson Mines Limited by CANMET/MRL and Dickenson Mines Limited Staff in April 1990 for the purpose of evaluating environmental conditions underground and in the surface mining plants. The survey was designed to measure respirable silica, total arsenic and lead concentrations at several workplaces. In addition, settled dust and rock samples were collected from workplaces and analysed for total arsenic content. More importantly, arsenic exposure data were needed to evaluate the impact of Ontario Regulation 176/86 as amended by Ontario Regulation 23/87. A total of 165 area and personal air filter samples were collected during the study. Of these, 85, 67 and 13 samples were for arsenic, silica and lead respectively. Sampling aid analyses were performed according to the Ontario Ministry of Labour Regulations. More than 90% of the workplaces sampled for respirable silica, total arsenic and lead were below the Ontario Ministry of Labour Regulations; and 10% of the workplaces sampled for arsenic shaved concentrations above the Threshold Limit value (TLV) proposed in the Ontario Regulation 176/86 as amended by Ontario Regulation 23/87. These results were used to identify occupations and/or workplaces where more sampling and control measures were required respirable silica, total arsenic and lead. This paper describes the results of the dust sampling program conducted at Dickenson Mines Limited.

Jan 1, 1991