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By M. J. U. T. Van Wijngaarden, R. J. Dippenaar, P. M. Van Den Heever

Some of the important properties of solid electrolytes that influence the performance of electrochemical oxygen probes are discussed in the first part of this paper. It is shown that accurate and reproducible measurements of oxygen in liquid steel are possible with commercial oxygen probes only if great care is exercised in the make-up of the chemical and phase composition, as well as the microstructure of the solid electrolytes used in these probes. To prove this premise, the second part of this study reports on the results of an experimental evaluation of new commercially available oxygen probe. An evaluation of the solid electrolytes used in this probe indicated that the consistency of the chemical composition, degree of stabilization, and microstructure of the electrolytes used are well controlled. The successful application of this particular oxygen probe under industrial conditions was confirmed. It was also found possible to make reliable and reproducible measurements, with acceptable uncertainty, by proper handling of the probe. Some recommendations are made as to the interpretation of the e.m.f. response curve and the use of the electronic processing unit supplied with the probe.

Jan 1, 1987

By SHM Harkema, MKG Vermaak, D R. Groot

Surface Plasmon Resonance spectroscopy (SPR), combined with cyclovoltammetry, has been successfully used to study the interactions between ethyl xanthate, heptyl xanthate, dithiophosphate and propyl trithiocarbonate flotation collectors and a gold surface. Large, easily measurable responses have been obtained in the potential areas where the thiol collectors are known to interact with gold. The four collector types lead to differing SPR maximum values, with longer alkyl chains resulting in higher SPR responses, and the trithiocarbonate leading to the highest response values. The SPR responses differ considerably from the current density response at very anodic and cathodic potentials. There are indications that thiols might still be adsorbed at potentials as low as -300 mV (vs SHE). Keywords Flotation collectors; thiol collectors; cyclovoltammetry; surface plasmon resonance spectroscopy.

Jan 1, 2005

By H. S. Sichel, Kleingeld

A frequency distribution model plays a fundamental role in ore evaluation, especially for the feasibility study of new deep gold mines. The geological complexity of the reefs being mined at present in the Witwatersrand basin poses some difficulties regarding the modeling of the underlying ore-value distribution. This geological complexity has given rise to a need for more applicable distributional models. This paper places the geology of the Witwatersrand basin in perspective and draws some important conclusions from the genesis of the deposition. In addition to the three-parameter lognormal model, two more-general distributional models are proposed. These are the compound lognormal (CLD) and log-generalized inverse Gaussian (LN-GIG) distributions. A detailed, although preliminary, comparative study of these two more-general models with the three-parameter lognormal model is described, and the efficiencies of the estimates and modeling are analysed. It is found that the broad assumption that gold grades follow a three-parameter lognormal law is not always the case, and the need to test for departures from log normality should be emphasized so as to ensure the use of appropriate models.

Jan 1, 1992

A brief overview is given of the issues regarding the processing of waste electrical and electronic equipment (WEEE). The printed circuit board component of WEEE is an exceptionally complex feed to possible recycling processes. Scrap printed circuit boards were selectively smelted at 1 200°C to produce a metallic alloy. Iron and aluminium were found not to be part of the alloy. The alloy was characterized by SEM-EDS, and three phases were identified: alpha and delta bronzes, and a lead-rich phase. Calculations show that about 56 mass per cent of the alloy is the alpha phase, 35 per cent delta phase and 9 per cent lead phase. A simplified approach using appropriate binary phase diagrams was used to derive a phase composition for the alloy. This was further backed by FactSage calculations, which showed that the simplified approach was appropriate for this alloy. The experimental findings and theory were found to agree well.

Jan 1, 2009

The kinetics of adsorption of gold di-cyanide onto activated carbon has been investigated extensively over the past two decades. These studies have demonstrated that both film and intra-particle mass transfer affect the kinetics. The dominant mechanism of intra-particle mass transfer has not yet been identified. In the work described, surface diffusion and pore diffusion are considered as possible rate-determining mechanisms of intra-particle mass transfer. Mathematical models are described that incorporate film mass transfer and the respective intra-particle mass transfer mechanism with equilibrium described by a Freundlich isotherm. Rate constants of film mass transfer and pore or surface diffusivities were estimated by the fitting of the respective models to experimental carbon adsorption data. The estimated pore diffusivities, after they had been corrected for the porosity and tortuosity of the carbon, were found in most instances to be higher than the molecular diffusivity of dilute gold di-cyanide in aqueous solution. This situation is not physically viable. The surface diffusion mechanism acting in parallel with the pore-diffusion mechanism is thus responsible for the intra-particle transportation of most of the gold.

Jan 1, 1996

By A. Ball

This paper addresses the need for a unifying model that will permit the selection and design of optimum materials for a given wear situation. With this objective in view, the characteristics of the various forms of abrasive, adhesive, and erosive wear are described in terms of localized stress, strain, strain rate, and frictional heating. The measured performance of a variety of metallic, ceramic, and polymeric materials and coated or surface treated materials are described briefly. These results were obtained under conditions of dry-particle abrasion, abrasion in conjunction with corrosion, cavitation erosion in liquids, erosion by particles in low- and high-velocity gas streams, and erosion by particles in a liquid stream. Electron microscopy was used extensively, together with microhardness profiles, in the determination of the modes of material detachment and the underlying deformations and structural changes. As a result of the experimental work, a model based upon a critical strain to microfracture is presented. The microstructural features and materials properties that determine wear resistance are discussed.

Jan 1, 1986

By L. A. Vermeulen, D. D. Howat

A study was made of the performance of a rod mil operating without liter bars and with different arrangements of liter bars in the lining. . The results show that striking improvements in performance, increased throughput, and reduced consumption of liner metal and electrical energy can be obtained by a change in the geometry of the liter-bar arrangements within a mil. Rod mils of equal size fitted with the same arrangement of liter bars but operating at different speeds presented apparent anomalies in the relative consumption efficiency of electrical energy for the production of material smaller than 75 µ m. Marked savings in the consumption of liner metal were achieved by the use of an arrangement of alternating lines of higher and lower liter bars. A study of the relative performances of two large tube mils showed that the use of liter bars in one of the mils resulted in a marked reduction in the consumption of liner metal and electrical energy per ton of material smaller than 75 µ m in the product.

Jan 1, 1986

By M. W. Hildyard, J. A. L. Napier

The improved design of support systems and stoping strategies when changes in depth, stratigraphy, or mine layouts are considered must rely on the designer's fundamental understanding of the deformation mechanisms adjacent to underground openings so that he can extrapolate and predict expected mining conditions. This paper presents a numerical approach to the modeling of the growth and interaction of mining-induced fractures near the edges of deep tabular excavations in brittle rock. Fractures are represented by displacement-discontinuity elements that are allowed to propagate according to prescribed growth rules. This procedure is justified by the reproduction of several features observed in laboratory simulations of fracturing around openings in blocks of rock subjected to uniaxial and biaxial compression. An attempt is then made to explain some of the attributes of the fracture zone surrounding tabular stopes. Particular questions of interest are the sequence in which fractures form and are mobilized in front of the mining face, the effect of parting planes parallel to the plane of the excavation, and the distribution of stress parallel to the hangingwall and footwall.

Jan 1, 1992

By D. D. Howat, J. van der Colf

This paper is the first in a series of three dealing with this subject and also with the rate of oxygen removal from the slags in the presence of solid carbon and with the physicochemical properties of the reduced slags. For selected members of the system, the melting temperatures and primary crystallization products were determined. as were the viscosity and the electrical resistivity of the corresponding melts. All the experiments were conducted in a neutral atmosphere. Where determined, the primary phase was found to be either perovskite or magnesium aluminium titanate. The composition variable exerting the most pronounced influence on viscosity or resistivity was found to be the basicity expressed as the mass ratio (CaO + MgO)jSiO,. The ratio CaOjMgO became important only at Iow basi<:ity values. Although generally there is a direct proportionality between log (viscosity) and log (resistivity), slags h&apos;lving either a very high silica content or a very high titania content have anomalously Iow electrical resistance.

Jan 1, 1979

Edward J. Stephenson. Extractive metallurgy. Recent advances. Park Ridge (New Jersey), Noyes Data Corporation. James L. McCall and P. M. French (eds.). Interpretive techniques for microstructural analysis. 1977. Institution of Mining and Metallurgy. Prospecting in areas of glaciated terrain. London, the Institution, 1977. £16 ($D.S. 30). NIM reports Report no. 1928 A liquid-nitrogen monitor for lithium-drifted germanium detectors. (21st Nov., 1977). Report no. 1931 The equilibrium between the slag and the metal in the production of low-carbon ferromanganese. (14th Nov., 1977). Report no. 1934 The spectrometric analysis of chromium-bearing materials with particular reference to ferrochromium slags and chromite ores. (30th Nov., 1977). Report no. 1935 The construction and testing of a small mixer-settler for use in the laboratory. (30th Nov., 1977). Report no. 1933 The determination of trace elements by thin-film X-rayfluorescence spectrometry, and its application to zirconium. (30th Nov. 1977). Report no. 1942 The accuracy of assays for platinum -group metals and gold. (30th Nov., 1977). Courses on geostatistics In view of the continuing demand, the University of Leeds will offer two further courses on geostatistics in 1978, each covering ten working days (3rd to 14th April, and 3rd to 14th July).

Jan 1, 1978

By NONEn NA

1. Book reviews . Rudiments of mining practice, oy C.E. Gregory.Clausthal-Zellerfeld (West Germany), Trans Tech Publications.OS$24.Reviewer: A.N. BrownProfessor Gregory has had a wide experience of hardrockmetalliferous mining throughout the world, beinga well-known academic who has taught at many universitiesin the Western World. His basic training was obtainedin his native land of Australia. In this publication he identified the need for a basic, simple book on miningpractice to provide new students of mining with a backgroundto their studies. He also designed the book to providea background to persons operating on the fringesof the industry such as students of economics and journalists.The text extends to only some 120 pages, and containsa sufficient number of monochrome sketches, diagrams,and photographs. It is written in a straight-forward, easyto-read style. The book contains an index and elementarytable of conversion from imperial to SI (metric) units,and there is also a glossary of mining terms that mostreaders would find useful.The author has succeeded in keeping the contentssimple, as indicated by the title. However, after each chapter, there are references to further recommendedreading. The book could be useful in the South African context, although the coverage of coal and opencast mining operations is slender.

Jan 1, 1987

By S. Vorberg, B. Fischer, U. Glatzel, R. Völkl, D. Lupton, M. Wenderoth

Owing to their excellent oxidation and corrosion resistance, Pt and its alloys are being used preferentially at elevated temperatures and in aggressive environments. For example, an important application field is the glass industry. Alongside the discovery of new potential application fields, the knowledge of material properties is essential for computer simulations, design configuration, process optimization, research and development or quality assurance purposes. Due to the importance for technical applications high-temperature properties have been investigated for currently available Pt-base alloys with ongoing improvements. For the determination of tensile creep test data up to 3000°C, including precise strain measurement, special experimental equipment has been developed at the University of Applied Sciences Jena, Germany. An overview of the existing and newly obtained mechanical property data on pure Pt, solid-solution strengthened Pt-Rh alloy, oxide dispersion-hardened materials Pt DPH and Pt 10%RhDPH as well as cutting-edge results on Pt-base superalloys hardened by intermetallic precipitates will be presented and discussed. Furthermore, some important application examples for the abovementioned Pt-materials will be given.

Jan 1, 2006

Underground mining and particularly dipping narrow tabular orebodies are difficult to mechanize appropriately, given the low gold price and other external factors. Particularly in the deep level mines in South Africa, there is little choice left but to mechanize if the industry is to remain competitive and a significant global player. This paper presents a design philosophy for appropriate mechanization intended to generate solutions that can be implemented using the people currently employed in South Africa mines. The design philosophy is based on the ability of high-pressure water (hydropower technology) to deliver enhanced performance to users and on simplicity in the eyes of the user. Four examples of systems and equipment are described to illustrate the approach to Appropriate Mechanization. These include: • The Development End System, • The Monorail Raise Climber, • Automatic Pump Control Valves, and • The Energy Recovery Pump. The equipment is presented with the following critical issues foremost in mind: Safety, Working Environment, Performance, Cost effectiveness and Implementation. Although the appropriate mechanization approach is described in the context of the South African underground mining industry, much of the Appropriate Mechanization equipment has worldwide applications. Key Words: Hydropower, Mechanization, Tunnel Development, Raise Development, Monorail, Raise Climber, Pump Control Valve, and Energy Recovery

Sep 1, 2001

By F. L. D. Cloete, A. K. Haines, T. D. Sampson, T. H. Tunley, W. A. M. te Riele

The recovery of zinc from pickle liquors by ion exchange A. K. HAINES. Ph.D. (Visitor) T. H. TUNLEY. B.Sc;.(Chem.Eng.)(Visitor), W. A. M. TE RIELE. pr, Eng.. Ph. D. (Visitor), F. L. D. CLOETE. M.Sc. (Chem..Eng.)(Visitor), and T. P. SAMPSON. Pr. Eng.. BSc, (Chem.Eng,). B. Econ. (Visitor) Picklers and galvanizers in and around Johannesburg are encountering an ever-increasing problem in disposing of spent liquors from their hydrochloric acid pickling baths. Particularly troublesome is the zinc-contaminated liquor that is produced as a result of the clean-up of rejects from the galvanizing operation. Because of the volatility of zinc chloride. this liquor presents difficulties when processed in a conventional pyrohydrolysis acid-recovery unit. The paper describes the Metsep Process. developed by the National Institute for Metallurgy and Woodall-Duckham S.A. (Pty) Ltd. which involves the use of continuous ion exchange for the separation of the zinc from the pickle liquor. and the use of liquid-liquid extraction for the conversion of zinc chloride eluate to salable zinc sulphate. A description of laboratory and pilot-plant tests is given. and the approach used in the design of a full-scale continuous- ionexchange plant is outlined.

Jan 11, 1973

By G. Raspa

The paper describes a computer procedure for evaluating and selecting recoverable reserves in a mine worked by sublevel stoping. The boundaries of the volume to be mined are optimally defined by means of the 3-dimensional Lerchs-Grossmann algorithm, separately applied to both sides of the panels. The procedure, which has been developed for Masua Mine (Sardinia), also provides for smoothing the optimized boundaries, positioning the drilling drifts, interactive design of drilling fans and calculation of tonnage and grade of each volley. These tonnages and grades form the input of another procedure evolved for production planning.

Jan 1, 1987

By A. García-Gutiérrez, A. Aragón-Jerónimo, R. Salazar-Mendoza

A theoretical analysis of a two-region solid-liquid flow system in horizontal pipes is presented, which considers a stationary bed of drill cuttings as a porous medium (-region) below of a two-phase dispersed flow (-region).The method of volume averaging was applied in this study to derive a rigorous mathematical model in which each variable is precisely defined. This model includes the volume-averaged transport equations for both the two-phase dispersed flow and the porous medium regions and terms from a macroscopic forces balance. The solution of the two-region model allowed evaluation of the behaviour of pressure gradient as a function of velocity, total volume fraction of cuttings and the relationship of the height of the stationary bed and pipe diameter. The solution is based on a backward finite difference explicit scheme. The simulated physical system is a pipe of 4.135 m in horizontal length and 0.0508 m in diameter. A one-dimensional, mesh-centred grid, consisting of 100 nodes, is used. The numerical results were compared with experimental data on slurry flows and a good agreement was found. Keywords: two-phase, cuttings transport, solid-liquid flow, drilling modelling, volume averaging.

Jan 1, 2007

By M. M. Oosterveld

Diamonds are mined from ancient raised beach deposits in southern Namibia where complex geological controls have resulted in patchy diamond distribution, largely related to irregularities (trapsites) in the bedrock. The distribution of the number of diamonds per sample is a discrete, reverse- J shape distribution which can be characterized by two parameters. These parameters have been transformed into a Beta and Theta Contribution which can be interpreted as reflecting the &apos;quantity&apos; and &apos;quality&apos; of the trapsites. The relationship of statistical parameters, obtained during the sampling of an ore deposit, to the geology of the deposit is an important element of ore reserve estimation. The large-scale regional trends in the contributions have been explained in terms of the geology.

Jan 1, 1987

By G. Whittle

An important aspect of the project evaluation process is the achievement of a clear and quantitative understanding of the primary drivers influencing project value and risk. A business scenario-based approach is required to ensure that the project meets value and risk hurdles over the short, medium and longer term. Adopting an optimising approach can aid significantly in the development of a project concept into a business that is optimal and sustainable in the longer term. Through the application of case studies, based on work performed with various mining organisations during the last five years, this paper will demonstrate how project value and robustness can be optimised. Experience has demonstrated that applying this approach results in significant value improvements and risk reduction - primarily by application of a rigorous, fact-based analysis and optimisation process that rapidly increases management team understanding and insight of key driver of value and risk.

Jan 1, 2007

By P. Valicek, M. Farren, G. Harrison, G. van den Berg, P. van Dorssen, P. Kramers

Full mechanization of the stoping operation using rockbreaking methods other than blasting has been a target of research for decades because of the considerable payoffs in terms of increased face advance rates, productivity and safety. However, the unavailability of economically viable rock breaking tools has prevented progress so far. This has changed with the invention of activated cutting tools, which achieve significantly reduced operating forces, power consumption and wear compared to non-activated tools and thereby permitted the development and evaluation of the first mining system using this technology. Targets for the mining system were a face advance of 100 metres per month on a double shift basis for a 30 metre long panel and eventually fully automated man-free stoping. The purpose of this paper is to describe the design, development and evaluation of the mining system. This was a major collaborative effort between Anglo Platinum’s Rustenburg Platinum Mines Rustenburg Section — Townlands Business Area, Anglo Platinum’s Research and Development Department within the Mining Technology Division, the inventor of the technology Bechem GmbH, the equipment manufacturers Long-Airdox Ltd and Zollern GmbH, and CSIR Miningtek who managed the project. A structured process was followed during the development to minimize the risks involved in using such leading edge technology. The system was rigorously evaluated to ascertain the economic viability of the method and to collect data for the design of a production system.

Sep 1, 2001

By R. Falcon, A. J. Ham

This paper summarizes the characteristics of Southern African coals, presents a fundamental approach to the combustion performance of coal, and reviews some of the recent developments in the fields of technological evaluation and boiler design for coals typical of this region. This includes a summary of the petrographic constituents of coa~ highlighting the differences between the Palaeozoic coals of the northern and southern hemispheres (Laurasia and Gondwana respectively), and the effects of these properties on the combustion performance of coal as seen in terms of laboratory, pilot-scale, and full-scale operating conditions. Recent developments in boiler design linked to advanced characterization studies and commercial experience have led to unprecedented use, with maximum effect, of the low-grade, high-ash, high-inertinite coals typical of some parts of this region. In the light of this success, more adequate understanding and better methods of assessment of the coals typical of the Gondwana region are called for, particularly in the light of the price premium for high-grade coal and the more cost-effective lower grade coals on the international steam markets.

Jan 1, 1988