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By J. M. Stuve

Calorimetric data for the dissolution of scandium sesquioxide and scandium trichloride in 4.360 molal hydrochloric acid were used to evaluate the standard heat of formation of ScCl3(c). The heat of reaction for Sc(c) + 1.5Cl2(g) = ScCl3(c) at 298.15° K was computed as -225,440 ±340 cal/mole.

Jan 1, 1965

By R. V. Ramani, A. S. C. Owili-eger

Mathematical modeling is a scientific exercise with the objective of developing simplified mathematical statements that relate to one another the same way as the processes that are being modeled. The utility value of the model is dependent on the ability of the model to closely approximate prototype behavior. Development of a perfect model, therefore, is an unrealistic objective because of the simpli¬fying assumptions made in building it. However, for a model to be acceptable for application, its operating characteristics or data generated from it should, within reasonable accuracy, duplicate proto¬performance. The validity and accuracy of a model depends on the mathematical constraints presupposed in model formulation. The final model must be tested for mathematical validity and for closeness of representation of the prototype. Mathematical validity, does not, however, imply that the model is accurate and correct but is prerequisite. Model testing and verification for the steady state model are given in Owili-Eger et al (1973). The unsteady state model has been tested for mathematical validity and found to be correct but has not yet been applied to a field condition for lack of data. However, in the application discussed below, the unsteady state model results are compared with pressure curves reported in literature and also with results from the steady state model. Coal seam characteristics and gas reservoir pressure used in this application are extracted from Kissell (1972). These characteristics are for the Pittsburgh seam, Federal No. 2 Mine, Fairview, West Virginia.

Jan 1, 1974

By W. R. Reed

A computer model named the "Dynamic Component Program" (DCP) was specifically designed for predicting the dispersion off dust from haul trucks at surface mines. Validation of the DCP was completed by comparing its results with the results of the 1SC3 model and with actual dust measurements taken front two operating mine sires. Comparisons of the field measurements, predictions of the ISC3 model and the predictions of the DCP demonstrate that the results from the DCP represent, on average, an 85% improvement truer the ISC3 dust dispersion model results.

Jan 1, 2008

By D. T. Hahn

Adequate and cost effective erosion control is an important component in most plans for reclamation of surface mined land. Despite the fact that much is known about erosion of agricultural lands, insufficient conclusive knowledge is available about erosion of reclaimed surface mined land. Our study was conducted to characterize the erodibility of reclaimed surface mine land relative to unmined cropped land, and to evaluate the accuracy of the universal soil loss equation (USLE) in estimating erosion from reclaimed soils. A rainfall simulator was used to measure runoff and erosion rates from plots at three Indiana surface mines. The relation of erosion of the reclaimed soils was not completely constant with that from the cropped soils. Significant differences in erodibility were observed between reclaimed and nonreclaimed top soils, as well as reclaimed topsoils and reclaimed subsoils.

Jan 1, 2011

By Stephen A. Swan

Bureau of Mines research has not included analyses of mining dredge safety since 1948. Because of the increasing use of dredges, 63 fatal accidents and several hundred nonfatal injury accidents involving dredges were examined. Also, 31 working dredges and 3 dredge manufacturers were visited to acquire qualitative information. Drowning accidents represented 59 pct of the fatalities and are delineated in detail. Also, countermeasures against other hazards are discussed.

Jan 1, 1985

By Greenwald, H. P

The Bureau of Mines has been conducting experiments on the explosibility of coal-dust in the experimental mine for more than 17 years. The results have been published from time to time3, and a forthcoming technical paper4 will summarize the results and discuss them in some detail. The present paper will be limited to a statement of the more important facts that these researches have discovered.

Apr 1, 1929

By R. Hogg, E. Kaya

"The presence of agglomerated particles in airborne dust in coal mines has been confirmed by SEM examination of static samples collected on substrates. In addition, the effect of agglomerated particles on the performance of cascade impactors and cyclone-type personal samplers has been studied. Simple procedures have been developed for evaluating the extent of agglomeration in air-borne dust by comparing the observed size-selectivity of the sampling devices with that expected under idealized conditions. Applications of these techniques in the laboratory and in underground mines are discussed.INTRODUCTIONAirborne dust is invariably present in mine atmospheres. Particle size is a primary factor in determining the behavior of the dust, its effects on miners' health and the effectiveness of dust control measures. Obviously, agglomeration of the dust particles can have important effects on: ""natural"" dust removal processes such as settling• the use of water sprays etc., for dust control• pulmonary deposition characteristicsIn addition, the presence of agglomerates could influence the effective toxicity of the dust. For example, ultrafine particles are often thought to be relatively unimportant in the development of respiratory ailments because of their low deposition efficiency. However, the latter could be substantially increased if such particles were present in larger agglomerates. It is by no means obvious that there should be significant agglomeration of the airborne dust in a mine atmosphere. In fact, calculations based on the classical coagulation theories indicate that, at the kinds of dust concentrations that exist even in what would be regarded as “very dusty"" atmospheres, the coagulation half-time* .should be of the order of weeks or even months. On this basis, agglomeration would be expected to be essentially negligible. On the other hand, laboratory experiments (Polat et al., 1991) have revealed very extensive agglomeration in the airborne dust released during the crushing of individual coal and mineral particles. It is postulated that such agglomeration occurs immediately at the point of dust generation. In other words, many of the fine fragments produced on fracture are never completely separated from their neighbors."

Mar 1, 1992

By Phillip W. Holland

The U.S. Bureau of Mines has developed a mass spectrometer method for determining helium in the parts-per-million to 10% range to an accuracy of ± 1%. The method employs a mass spectrometer, an inlet system utilizing a chromatographic gas-sampling valve, and an activated coconut charcoal trap cooled with liquid nitrogen. Gravimetrically prepared standards of helium in nitrogen were used to demonstrate the linearity of the method over the concentration range of 10 ppm to 10.66% helium.

Jan 1, 2010

By Philip W. Holland

This U.S. Bureau of Mines (USBM) report describes a chromatographic method that is used for rapid field determinations of carbon dioxide in natural gas streams at a USBM helium production facility. The method employs a commercially available portable gas chromatograph that is equipped with a 10-m fused-silica capillary column coated with a porous polymer. The instrument operating parameters permit determinations to be performed over a concentration range of 10 ppm to 10 pct with a frequency of 20 samples/h. The speed at which determinations can be performed is an important factor when evaluating efficiency or troubleshooting processes at the helium facility.

Jan 1, 1994

By H. V. Makar

An aluminizing dross which is accumulating as a waste material in substantial quantities was tested for possible use as a steel deoxidizer. This material, consisting mainly of aluminum, silicon, and iron, was used to deoxidize laboratory-scale melts ranging from 7 to 100 pounds. Oxygen analysis showed that the aluminizing dross was effective in reducing oxygen levels in steel. A direct comparison with aluminum wire showed the dross material to be at least as effective. Under similar test conditions with 7-pound melts, 3 grams of aluminum reduced the oxygen concentration from 210 to 175 ppm, while 4 grams of aluminizing dross (equivalent to approximately 2 grams aluminum) reduced the oxygen concentration from 250 to 170 ppm. An additional 4 grams of aluminizing dross produced a final oxygen concentration of 140 ppm.

Jan 1, 1972

By L. H. Adami

This paper reports the results of solution calorimetry conducted to obtain the heats of formation of crystalline FeS04?6.952H20 and FeS04?1.008H20, from. which values were derived for the stoichiometric compounds FeS04?H20 and FeS04?H20. Also included are derived values of the free energies of formation and dehydration. This work was undertaken primarily to fill a need for data for pure, easily obtainable ferrous compounds that are suitable for use as calorimetric intermediates, The ferrous sulfate hydrates meet the essential requirements for this use.

Jan 1, 1963

By R. H. King

A very simple cold-bend test was devised and tested for evaluating thermoplastic jackets used on mine-power-feeder cables. A test sample is bent into a semi-circle whose radius is equal to the minimum bend radius recommended by IPCEA and then cooled to the, desired test temperature (-35°C). While at temperature, the sample is straightened by pulling the cable ends with a winch arrangement. The results show that of the jackets tested, those which cannot withstand the test literally burst when the sample is straightened.

Jan 1, 1978

By S. R. Wilson

[The Anniversary-Bucky pegmatite is one of the largest, dikes in the Quartz Creek district, 21 miles east of Gunnison, Colo. The major dike consists of quartz-albite pear pagmatite and graphic granite with many quartz masses as individual cores occurring within the dike. A mining operation on one of the largest core areas has exposed several mineralogic cones directly associate with the core. These zones, including the large- units of the dike, are quartz pegmatitc, quartz-perthite pegmatite, perthite pegmatite, muscovite-feldspar -quartz pegmatite, quartz-albite pegmatite, and perthite-quartz (graphic granite) pegmatite. Muscovite and beryl are found in the muscovite-feldspar-quartz zone and are the only two products that have been marketed. Other potential products are perthite, graphic granite, and possibly small quantities of columbite-tantalite, monazite, and related radioactive minerals. The Bureau of Mines drilled two diamond-drill holes during April 1950 to investigate the largest and cost promising core area. This, report describes the results of this drilling.]

Jan 1, 1953

By R. Hogg

"Agglomeration processes and agglomerate characteristics are largely controlled by the forces of interaction between particles. The nature and typical magnitude of these interaction forces are evaluated relative to the external forces commonly present in agglomeration systems. The specific roles of the interaction forces in the various stages of agglomerate formation and growth and their effects on the integrity and mechanical strength of agglomerates are briefly reviewed. Because the interaction forces affect different aspects of agglomerate development in different ways, conflicting requirements can arise. Examples of such conflicts are given and used to demonstrate the importance of evaluating the effects of interaction forces etc., in the context of the overall agglomeration process and its ultimate objectives.INTRODUCTIONThe term agglomeration is generally used to refer to processes whereby discrete particles are caused, or allowed, to associate into clumps in which the individual particles retain their identity but are held together by relatively weak, usually physical forces. Various other designations are given to these processes, depending on the specific circumstances under which agglomeration occurs. The terms balling and pelletizing are often used to describe agglomeration in dry or semi-dry powders; coagulation and flocculation are used to refer to agglomeration of particles dispersed in fluids. Common to all of these cases is the fact that the formation, growth and integrity of the agglomerates depend primarily on the forces acting on and between particles. The same forces are, of course, responsible for manyaspects of the behavior of colloidal systems and their study and evaluation constitute the,basis for colloid and interface science.FORCES ACTING ON FINE PARTICLES AND AGGLOMERATES It is convenient to classify the forces acting on and between particles into two general types: external forces and interaction forces. It should he recognized, however, that a sharp distinction is not always possible.External Forces Gravity and inertial forces act on all particles and their magnitude is proportional to particle mass, i.e. they vary with the cube of particle size. Such forces are oftensignificant for large agglomerates but may be negligible for individual, fine particles.Hydrodynamic (""drag"") forces are important, for particles suspended in fluids. For very small particles, the drag force is directly proportional to size (Stokes' Law) while for very large particles or agglomerates it varies with approximately the square of size (Newton's Law). A useful procedure for estimating drag forces over a broad range of particle sizes and physical conditions has been given by Concha (1)."

Jan 1, 1989

By W. E. Wallace, V. Robinson, M. F. Keane, V. Vallyathan

"An in vitro study of the biologic responses of surface-modified and native silica and kaolin was made to provide comparative information on the supression of cytotoxicity by pulmonary surfactant. The release of alveolar macrophage cytoplasmic enzyme, lactate dehydrogenase (IDH), and lysosomal enzymes B-N-acetylglocosaminidase (B-NAG) and B-ghucuronidase (B-GLUC) and sheep blood-cell hemolysis were moni¬tored as indicators of cell membrane damage and cytutoxicity. Surface modification of silica and kaolin with dipalmitoyl lecithin (UPI) resulted in complete abrogation of cytotoxicity of both minerals. These findings indicate that surface modification of minerals with different adsorption properties by pulmonary surfactant generally lessens their prompt adverse effects.INTRODUCTIONAcute and chronic silicosis are well-characterized clinical and pathologic entities resulting from the inhalation of crystalline silica (Morgan and Seaton, 1984). Kaolin, a layered aluminosilicate clay frequently mined and used in manufacturing, contains tetrahedral silica alternately layered with alumina octahedra. Kaolin is relatively .inert biologically, and distinctly greater pulmonary burdens are seen in patients with kaolinosis than are seen in patients with silicosis. Crystalline siliea (quartz) induces a significantly greater degree of fibrosis in exposed animals in vivo than does kaolin (Hamilton and Hardy, 1974; Parkes, 1982; Hunter, 1976; Sheers, 1964; Warraki and t-lerant, 1963; Lynch and Mciver, 1954; Lapenas et al., 1984).This difference in pulmonary disease associated with the two types of dust is not reflected by in vitro cytotoxicity as Jetermined by pulmonary macrophage bioassays or erythrocyte hemolysis. Cytotoxicity studies using crystalline silica and kaolin of similar size fractions show comparable bioassay response on a mass basis. These cellular bioassays, therefore, do not correlate with the relative in vivo pathogenicity of silicates."

Jun 1, 1988

By C. W. JEFFERS

During the past few years the use of mechanical equipment for the loading and transportation of coal at the working face has rapidly increased . Many mining officials are of the opinion that mechanical methods have tended to reduce the hazards of mining, and a number of statements have been made to this effect . Little actual data upon which to base conclusions in regard to the relative safety of various methods of mining have been made available . While it may be possible that these systems of mechanical mining are inherently less hazardous , obvious dangers should not be disregarded in the belief that the mere act of installing mechanical loading equipment automatically brings about better accident records . The same rules and regulations , modified to meet the new regime must be applied with the same discipline as heretofore . By diligent study and application there is reason to believe that new methods of concentrated mining can be utilized with at least a possibility of increased accident performance . With the idea of preventing accidents by taking available precautions against their occurrence , attention should be directed to the dangers that exist where room and face conveyors are in operation . Due to the cost pressure prevalent in the mining industry at the present time mechanical means are often used in an attempt to decrease cost of production. The management , after having spent considerable sums of money for new equipment , is expected by stockholders and investors to show results by increasing tonnage and reducing operating costs . Consequently the operating officials apply the same pressure to local mine officials to obtain results . The natural reaction of the superintendent and mine foreman is to secure the maximum production from the new method , and unfortunately safety is frequently , if not generally , sacrificed to this end . In many instances , operators of new types of mechanical loaders are difficult to secure and after being obtained are difficult to hold , especially if the new equipment is more or less in the experimental stage . The tendency is to handle the machine operators with " gloved hands " and to permit many unsafe practices which ordinarily would not be allowed, in order to keep from antagonizing them and losing their services . Although these unsafe practices become habitual and even uneconomical , conditions thus established are difficult , sometimes impossible , to change .

Jul 1, 1930

By George McCaa, H. C. Howarth

"During recovery operations following a recent coal-mine explosion, 12 small fires were encountered near the break line of pillar extraction in a large panel. All of the fires except one were quickly extinguished by the rescue and recovery parties. This fire had found its way into a large quantity of loose material at a corner of the cut-through between two rooms, about 100 to 150 feet from the break line of an extensive goaf; had it been necessary to seal the fire, the inclusion of this break line not only would have made the work difficult but would have made the section hazardous as it probably would have given off gas. The fire covered a floor space of about 100 square feet and when discovered was burning briskly, with the flame extending to the roof at a height of 3 or 4 feet; it was the cause of much apprehension on the part of those in charge of the recovery operations and resulted in delaying the work considerablyThe object of this article is to describe in detail the method by which the fire was brought under control and finally extinguished, so that other persons encountering similar conditions may have the benefit of the experience.When the fire was discovered a request for rock-dust, fire extinguishers, and other fire fighting equipment was telephoned to headquarters on the surface. The promptness with which fire fighting equipment and material was provided was a big factor in finally extinguishing the fire and illustrates one of the many advantages of a good organization for fire-fighting. Material was transported in mine cars to a point on the main hauling road about 1,200 feet from the fire. It was then carried to the scene of activity by workmen. The first material to be delivered at the fire was a number of fire extinguishers of various types. The contents of 30 to 35 of these were discharged on the fire and with the aid of a small quantity of rock-dust were sufficient to smother the flame temporarily. It was the opinion of several persons who were present when the fire extinguishers were used that the acid-soda type of extinguisher gave more effective results than the two or three other types used.When the contents of all of the fire extinguishers had been exhausted the fire was temporarily smothered, but as there appeared to be danger that the flame would burst forth again, means for completely extinguishing the fire were"

Feb 1, 1929

By Daryl E. Radcliffe

The Bureau of Mines studied the displacement of the roof in a portion of the Bear coal mine near Somerset, Colo, Horizontal-and vertical-displacement gages were installed in a five-entry section during normal room-and-pillar mining procedures. Monitoring of the roof continued until this section was mined out. Displacement measurements in combination with known time lapses between mining and bolting operations indicate that once support is achieved, the length of unsupported time does not appear to affect long-term roof stability in the mine under investigation.

Jan 1, 1978

By R. R. Schehl

The Bureau of Mines has developed a quantitative Analysis for pyrite in coal by X-ray diffraction that can be accomplished in little more than 1 hour. To minimize the sample analysis time, data processing has been completely computerized with pertinent output information displayed on a VR12 cathode-ray tube display. Use of this computerized system is not only advantageous during the experimental stages of the pyrite analysis project but would also be essential if the X-ray diffraction procedure is accepted as a standard method of analysis.

Jan 1, 1973

By K. C. Dean

A semiquantitative test for the presence and identification of cesium and rubidium in rocks, clays, and mineral waters has been developed by the Bureau of Mines. The test can be used in the field, as a guide for the prospector, geologist, or mining engineer engaged in location or development [w]ork. It comprises two simple spot tests of a solution prepared from the [m]ineral sample. Phosphomolybdic acid, added to a drop of the test solution, [d]etects cesium, rubidium, and potassium in quantities as low as 60 parts per [m]illion. Silicomolybdic acid, added to a second drop of test solution, enables the operator to distinguish between cesium and/or rubidium and potassium. Test procedures, equipment requirements, and limitations of the method are described in this report. Cesium and rubidium were discovered in 1860 and 1861 by Bunsen and Kirchhoff with a spectroscope. The elements usually occur together, particularly in granite and granitic pegmatites. Rubidium does not occur as an essential constituent of any known mineral, yet it is found as a minor element in so many minerals that rubidium is 16th in abundance in the earth's crust. Cesium, which ranks as the 37th most abundant element, is the principal component of pollucite and a minor element in a wide variety of minerals.

Jan 1, 1960