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By C. E. Coleman, Joseph D. Davis

During some distillation experiments conducted by the Bureau of Mines in cooperation with the Trent Process Corporation it was observed that amalgams of heavy petroleum oils and finely pulverized coal tended to produce a denser coke than that obtainable from the coal when retorted alone . Even anthracite coal when retorted with oil yielded a coke . This led the writers to believe that by mixing a lowrank coal ( sub-bituminous or even lignite ) - with asphaltic oil and retorting it, a coke suitable for domestic fuel could be made . Thus there was contemplated the production of domestic coke and the utilization of a low- grade oil in one operation . - In order to decide on the practicability of this process , it was necessary to know the value of products obtainable by such a method , as compared with those obtained by separate distillation . A laboratory method was therefore devised , and while it was realized that no small - scale testing apparatus for destructive distillation gives results that are directly applicable to commercial - scale operations , by keeping distillation conditions uniform for comparative tests , results were obtained valuable for purposes of comparison . The plan was to distill mixtures of coal and oil in a laboratory retort , and then distill the constituents separately under the same conditions . The comparative quantities of products yielded were thus directly obtained , and their quality was determined by analysis . The following are the main points investigated : ( 1 ) Quantity and quality of coke ; ( 2 ) Quantity of oils boiling below 221 °C . ( gasoline stock) and oils boiling at 221 to 300° C . ( kerosene stock) ; and ( 3) Quantity and quality of gases .

Jan 1, 1922

By A. C. Rice

Investigation of a variety of mines to determine efficiency for rare- earth extraction has resulted in a solvent extraction technique wherein Primene 81-R,4 N-benzylheptadeeylamine (BHDA), and Primene JM-T give favorable extraction from sulfate solutions. Extraction from chloride, nitrate, and perchlorate solutions is negligible. Distribution coefficients for 10 rare-earth elements with Primene 81-R establish an extraction sequence beginning with lanthanum and proceeding through lutetium according to atomic number. Yttrium and ytterbium are exceptions in the extract ion sequence.

Jan 1, 1962

By E. A. Pelczarski

Initially, the objective of this contract was to develop a PWSCSR that could meet proposed criteria (that were different from 30 CFR 11(Title 30 of the Code of Federal Regulation part II) and that would be less than twice the size and weight of a filter self rescuer. This objective was met. Consequently, the original contract was extended to develop a PWSCSR that would meet existing CFR-30 criteria within the same size and weight constraints. This resulted in the development of a PWSCSR (the SR-100) that received NIOSH/MSHA approval (TC-239). This report presents a historical discussion of the design and development of the SR-100 as developed by CSE Corporation under Bureau of Mines contract number H0368013. The technical parameters and the test results of NIOSH/MSHA 30 CFR 11 certification are also presented.

Jan 1, 1990

By L. B. Pankratzt

The heat capacity of dimo1ybdenum carbide (Mo2C) was measured from 51° to 298° K, and the entropy at 298.15° K was evaluated. Heat content measurements above 298.15° It were conducted for dimolybdenum carbide (M0caY) and monotantalum carbide (TaC). The results were combined with known heats of formation and the 298.15° K entropy for TaC to obtain values of the heat and free energy of formation from 298.15° K to 1,400° K for MoaC and from 298.15°K to 1,800° K for TaC.

Jan 1, 1966

By R. V. Lundquist, H. Leitch

Two hydrated calcium aluminates , formed by side reactions in the leaching step and desilication step of the lime- soda sinter process , were investigated to better define their influence on alumina recovery . The two calcium aluminates , Caз [ Al ( OH) 6 ]₂ and зCa0.Al½ 03 · ( 8-12 ) H₂ ) , were prepared and identified by chemical and X- ray analysis . The relative proportions of each of these compounds formed in typical leach solutions at several temperatures were determined . The influence of free lime as a promoter of calcium aluminate formation was also investigated . The formation and precipitation from leach liquors of calcium aluminates contributes to the low alumina recoveries in the process . The presence of carbonate ion in the leach solution suppresses calcium aluminate formation and precipitation and results in higher alumina recovery . Hydrated calcium aluminates are formed in the aging of lime - soda sinters in the normal atmosphere .

Jan 1, 1963

By L. H. Adami

The heats of formation of anhydrous cadmium sulfate, cobalt sulfate, copper sulfate, nickel sulfate, and zinc sulfate were determined by hydrochloric acid solution calorimetry. The values at 298.15° K for formation from the metal, rhombic sulfur, and oxygen gas follow (cal/mole): CdS04J -222.0 ± 0.3; CoS04, -212.0 ± 0.4; CuS04) -183.4 ± 0.6; NiS04, -208.1 ± 0.2; and ZnS04, -233.1 ± 0.2. Corresponding heats of decomposition to form the metal oxide, sulfur dioxide, and oxygen were derived from these results; heats of decomposition to form the metal oxide and sulfur trioxide were also derived.

Jan 1, 1965

By Fred D. DeVaney

The Mesabi iron district of Minnesota has a potential production of over 50 million tons of iron are annually. The large shipments of ore each year are gradually depleting the reserves, and if the present rate of production is to be maintained there must be a growth in the present available ore supply. Growth is a natural course. The growth of a city may be affected by the addition of city blocks or by the improvement of utilities necessary for its betterment. These may go on in the order named or concurrently. The city-block type of growth of the Mesabi has been tremendous, and the "betterment" type has followed in due course. Probably the former has reached its limit, and if so, more time will be allotted to the latter. It is not the in¬tent of this paper to present either a eulogy of the wonderful mining methods or a history of the milling, but it is pertinent to say that if the lean-ore area continues to produce, the continuance will be more the result of further improvement of milling methods non well under way than of extension of boundaries by the city block plan of growth.

Jan 1, 1932

By Zsuzsanna Zborovszky

Experimental study directed toward gaining improved understanding of the exact mechanisms causing ignition in the PTB breakflash. Investigation and comparison of tungsten and copper wires as to their ability to cause hot wire ignition. Evaluation of the importance of discharge duration in the ignition process. Study of the parameters influencing the duration of a discharge (minimum discharge voltage, purity of electrode materials, purity and properties of the gaseous atmosphere contaminations, deposits on the electrode surface).

Jan 1, 1976

By Harold L. Rhodes

The Bureau of Mines has developed a quantitative method to determine water vapor in helium in the range of 0.1 to 15 ppm by volume. This method uses the quantitative chemical reaction of H20 with CaH2, which produces 1 mole of hydrogen for each mole of H20 in the sample. A gas chromatograph is then used to determine the concentration of hydrogen in the product. The precision of the H20 analysis is ±0.05 ppm at a concentration of 1 ppm. This method is used to calibrate a commercial platinum-phosphorus pentoxide (Pt-P205) electrolytic water vapor analyzer that has an improved inlet system and digital voltmeter readout.

Jan 1, 1981

By Heinz W. Sternberg

The literature on electrochemical treatment of coal is reviewed, and possible avenues of further research in this field are discussed in this report. Electrolytic reduction of finely distributed coal resulted in the addition of as many as 9 atoms of hydrogen to 100 atoms of carbon. Reduction of coal extracts at controlled potentials indicated the presence of condensed aromatic hydrocarbons and reducible quinones in coal. As much as 65 percent of low-rank coal can be made alkali soluble by electrochemical treatment. Higher rank coals gave smaller yields of alkali-soluble products. However, the nature of this reaction is not clear. The difficulty of reducing coal electrolytically is probably due to the insolubility of coal and not to any structural peculiarity. Reduction of coal by electrolytically generated radical anions appears to be a promising approach for further research.

Jan 1, 1962

By W. F. Dietrich

1. On St. Thomas and St. Croix, and possibly also on St. John, low-quality red-burning clays probably can be developed to provide the major part of the raw materials for structural clay products and earthenware pottery. 2. The potential sales volume for structural clay products is too small to sustain a plant in the Virgin Islands to manufacture such products in competition with Puerto Rico; however, handmade patio tile might be produced successfully. 3. The market for pottery utility wares in the Virgin Islands is too small to justify a plant devoted solely to the production of such wares; but it may be feasible to evolve a diversified community activity to make jugs, pots, casseroles, bowls, charcoal burners, patio tile, and other items.

Jan 1, 1955

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By T. A. Henrie, E. K. Kleespies

Electrolytic studies were conducted to determine the transfer rates of the alloying constituents from molten titanium anodes to solid titanium cathodes in molten salt systems . The metals , nickel , tin , copper , bismuth , and manganese , were selected on the basis of thermodynamic data and the melting point of the alloy system . The transfer of nickel , tin , and bismuth was very low . The content of these elements in the cathode was in the range of less than 0.01 to 0.001 percent . The copper transfer was 0.6 to 0.8 weight - percent in electrolytes containing titanium chlorides and 0.12 weight - percent in titanium fluoride salt systems . The manganese transferred at rates comparable to that of titanium . Highpurity titanium and titanium- manganese alloys of uniform composition were produced by electrorefining molten titanium alloys in chloride electrolytes . Comparisons are made between the calculated and the actual quantities of metal transfer .

Jan 1, 1964

By D. A. Reynolds, L. P. Rockenbach

"The method of analyzing light oil for benzene is fully described by Fieldner and others 4/ and Kester and Kolmes 5/. In this procedure, benzene is determined by shaking 20 cc. of the 79º to 81º C. boiling point cut from the fractionation of the refined light oil with 3 volumes of 98—percent sulfuric acid in an A. S. T. M. separator funnel of the type used for determining water in bitumi¬nous materials. After the mixture has been shaken 5 minutes it is allowed to settle at least half an hour and the acid is drawn off; the residual oil is reported as paraffins and the decrease in volume as benzene. The method has been found satisfactory for light oils from coals carbonized at 5000, 600°, and 7000 C. but does not give accurate, reproducible results for oils from the 800° C. tests.The content of benzene of the 790 to 81° C. cut is high, 90 to 95 percent, for 800° C. light oils, whereas for lower—temperature light oils it is considerably less. Benzene is the most difficult of the aromatics to sulfonate, hence the acid concentration must be maintained above 95 percent to insure complete sulfonation. Sulfuric acid (98 percent) reacts with benzene, but its reaction with paraffins at ordinary temperatures is negligible; however, more concentrated acid will attack paraffins and give erroneous yields of benzene. The reaction between benzene and sulfuric acid forms water that will dilute the acid. The effect of this dilution may be overcome by increasing the acid-to-oil ratio or increasing the strength of the acid. The latter, however, must not be used, because the stronger acid reacts with paraffins."

Mar 1, 1942

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By J. A. Eisele

The Bureau of Mines has reviewed the literature related to the recovery of A1203 (alumina) from coal ash. A small amount of unpublished data is also reported. Of the processes studied, the alkaline-sinter process is the most promising from a technical standpoint. However, owing to the high cost of processing coal ash, the dispersed location of powerplants, and the domestic availability of higher grade alternate materials, coal ash does not rank as a primary source material for replacing imported bauxite.

Jan 1, 1979

By L. L. Brown

As part of the Federal effort to help maintain an adequate supply of fertilizer materials, the Bureau of Mines conducted research to characterize complex low-grade Michigan phosphate materials and to devise methods for recovering fertilizer-grade phosphate concentrates. The rock is from middle Precambrian sedimentary formations in the Marquette Range located in the central part of the Upper Peninsula of Michigan. Occurrence of phosphate-bearing sediments in Precambrian rocks is rare. This deposit, containing 12 to 15 pct P205, is believed to be the richest Precambrian phosphate deposit in the United States. Petrographic examination showed that the conglomeritic rock contains crystalline apatite both in "black pebbles" and in quartz matrix. Attrition scrubbing and sizing tests showed that there is no tendency for phosphate to concentrate in any of the sized fractions. In beneficiation tests, which included grinding to minus 325 mesh followed by phosphate mineral flotation using a fatty acid-fuel oil collector, a phosphate concentrate was obtained that had a grade of 30 pct P205 and a P205 recovery of 72 pct. This concentrate should be suitable for fertilizer manufacture.

Jan 1, 1981

By M. Hayashi

The Bureau of Mines conducted laboratory studies on low-grade vanadiferous silicates from the Pumpkin Buttes and Nine Mile Lake deposits of Wyoming to examine techniques for extracting vanadium and uranium. Recovery from low-grade sources such as these could contribute to future vanadium production and reduce reliance on vanadium imports. The Pumpkin Buttes samples contained 0.03 to 0.04 pct V205 and 0.06 to 0.12 pct U308; the Nine Mile Lake samples contained 0.02 to 1.0 pct V205 and 0.06 to 0.19 pct U308" Leaching the Pumpkin Buttes samples for 18 h at 800 C with addition of 200 lb/ton H2S04 resulted in recoverey of 80 pct of the vanadium contained in the samples. The Nine Mile Lake samples were readily leached, yielding 78 to 94 pct of the vanadium after 3 h at 800 C with addition of 100 lb/ton H2S04, A solvent extraction procedure was used to selectively recover urani-um from Pumpkin Buttes and Nine Mile Lake leach solutions and to recover vanadium from the raffinates. In batch shakeout tests, Alamine 336 recovered over 95 pct of the uranium from leach solution adjusted to pH 1. Di-2-ethylhexyl phosphoric acid and Cyanex 272 recovered vanadium from the uranium raffinate after reduction and adjustment to pH 2; vanadium extractions of up to 96 pet and 92 pct, respectively, were achieved.

Jan 1, 1985

By Edward F. Courtney

Loss of life, loss of sight, crippling injuries, and property damage nearly always result from accidents involving explosives. The severity of such accidents has prompted lawmaking bodies to pass laws concerning the transportation, handling, and use of explosives; manufacturers of explosives publish manuals 'describing explosives and practical methods of handling then; and mining companies and others who use large quantities of explosives publish rules based on actual experience for the guidance of their employees. Careless storage of explosives by thoughtless or incompetent persons, particularly if they are left where children or saboteurs have access 'to them, has led to many serious accidents. Many contractors and mining operators who use explosives are extremely careless about storing them. It is the purpose of this paper to discuss the explosive-handling practices of a large western mining company, which are considered better than most.

Jan 1, 1946

By P. A. Wasson

The investigation described in this publication was conducted by the Bureau of Mines to determine the effectiveness of the anionic silica flotation method on goethitic iron-bearing materials from the Cuyuna Range, Minn. Samples used in this investigation were a composite of drill core from 13 holes, and 3 samples from lean ore stockpiles. These samples are believed to be typical of the mineralization occurring in an area with a potential reserve of several million tans of submarginal iron ore. Results from batch tests showed that the iron-bearing minerals could be effectively concentrated by flotation removal of the siliceous gangue. The drill hole composite yielded laboratory flotation concentrates from locked tests containing 56.8 percent Fe and 6.1 percent silica, with an accompanying iron unit recovery of 94.2 percent. Concentrates containing 52.4 to 53.7 percent Fe also were produced from the lean ore stockpile materials; corresponging iron recoveries ranged from 71 to 79 percent in the batch tests, with the possibility remaining for additional recovery of iron from the middlings.

Jan 1, 1963