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By Irving Wender

This report describes Bureau of Mines experiments and reviews the work of others on the exposure of coal and coal-derived products to gamma rays and some other types of radiation. Results are presented on tests of three bituminous coals and a lignite that had been pulverized to minus 200-mesh particles and exposed to 1,000 megaroentgens of gamma irradiation from spent-fuel elements of a nuclear reactor. Of about 20 chemical and physical tests in Bureau work, only mass spectrometry of gases evolved during vacuum pyrolysis of the coals to 450° C gave results indicating differences in the irradiated and unirradiated samples. Mass-spectral distribution curves for CO and CO2 evolution showed fewer irregularities (reversals of curvature) for irradiated coals; thus, mass spectrometry appears to be the most sensitive method for determining radio-induced changes in coal. It is concluded that coal is not significantly altered by gamma irradiation owing to the resistivity of its highly condensed ring structure. High-level gamma irradiation, therefore, is unlikely to prove advantageous in coal processing and utilization. Specially treated coals, because of resistivity of coal to radiation damage, may be useful as an absorbent in processing radioactive wastes.

Jan 1, 1968

By Paul T. Allsman

The vanadiferous deposits of the Sublette Ridge and Salt River Range, 2 miles east of Raymond, Idaho, in western Lincoln County, Wyo., were examined August 24 to August 30, 1942, by an engineer of the Bureau of Mines, who was shown these properties by W. W. Rubey of the Geological Survey, Washington, D. C. The Sublette Ridge deposits are owned by the former U. S. Phosphate Co. H. F. Chaney, Portland, Oreg., is the representative for the company. The following report covers the history of the district, outlines the physical features and communications, mentions the property, and notes the ownership. The deposits and ore are described, and work performed by the Bureau of Mines is explained in detail. Ore-dressing tests and methods are explained.

Jan 1, 1949

By A. J. Kraemer

The twenty-fourth of a series of semiannual surveys pertaining to motor gasoline marketed in the United States was made by the Bureau of Mines in August, 1931. The first part of a report giving the results of that survey as they pertain to specification data is given in this paper. A companion report, Part II, is in preparation and will discuss the results of other determinations made on the samples, including octane number ratings on the individual samples (to be made by the Bureau of Standards) and results of the determination of gravity, color, doctor test, and "gum" content by the copper dish method and the Bureau of Mines steam-oven method. The retail price and the tax at the time each sample was taken will also be reported.

Jan 1, 1932

By Donald E. Redmon

This Bureau of Mines report reviews injury experience in the metallic mineral industries for 1966-67. For each of the years, 27 tables summarize disabling work injuries by department, source of injury, extent of disability, part of body injured, and nature of injury. Correlative information on employment, worktime, and operating activity is also presented.

Jan 1, 1973

By E. L. Litchfield

Four short-term studies of practical ignition problems were undertaken and completed during the course of the Bureau of Mines project "Development of Specifications for Intrinsically Safe Equipment." Conclusions were as follows: (1) the most easily ignitible mixture of propane-air in a PTB break flash apparatus is approximately 5.2 percent propane; (2) miniature lamp bulbs to be used in intrinsically safe circuits are about as incendive to coal dust-air as to methane-air and should be tested in gas mixtures containing about 7.0 to 7.5 percent methane; (3) the sodium amalgam contained in high-pressure sodium lamps does not present an ignition hazard for coal dust or methane, where the lamps contain no more than 30 milligrams of amal-gam; (4) the maximum allowable surface temperature of permissible electrical enclosures should remain at 150° C despite efforts by industry groups to raise the value to 200° C.

Jan 1, 1980

By H. W. St. Clair

In about 1930, Degussa applied for a patent on a process for the of oxides, carbides, sulfides, and other nonmetallic impurities by filtration in the molter state. The filtering media listed were wire screen, coke, and ceramic materials, and quartz. It was also suggested that filtration might be combined with chemical reaction between the metal and the filter medium or that might be added to the system. No patent was granted on the general scheme, but several years later a patent was granted on a continuous process purification of crude light metals, especially or alkali earth and their alloys. The melt was stirred at 1 temperature at which the impurities (such as oxides and salts) remained solid and the metal was drawn through a filter tube. The impurities collected under the filter and were removed by a screw conveyor. Crude sodium was purified by this process in Degussa's Knapsack plant. During the last war, when the refining of scrap became a very urgent Problem in Germany, experimental investigations were extended to separation of other metals and metallic compounds by filtration. Preliminary experiments seemed to confirm the opinion of Dr. L. Weiss that the principles of wet chemical filtration might be applied to a great extent in the purification of metal and alloys.

Jan 1, 1949

By J. Owens

Advanced materials development ranks as one of the most important high-tech industries of the future in the United States. Recent breakthroughs can be attributed to advanced computer technology, powerful mathematical models, and more precise analytical tools that enable scientists to examine and control properties of materials as never before. Discoveries now being made are providing many industries with opportunities to improve product lines, fabrication techniques, product reliability, and so forth. More¬over, industries, such as space, medicine, and defense, which require stringent: design and perfomance specifications in highly competitive world markets, increasingly demand these new materials. The definition of advanced materials used here is one that has been adopted by the U. S. Bureau of Mines: Those materials which have been developed over the past 30 years or so, and which are being developed at present, that exhibit greater strength, higher strength-density ratios, greater hardness, and/or one or more superior thermal, electrical, optical, or chemical properties, when compared with traditional materials.

Jan 1, 1991

By W. C. Holliman

This report is one of a series of reports on the characteristics of commercial aviation gasolines, It presents compilations of inspection test data on their products furnished by 16 manufacturers of commercial grades of aviation and special date obtained in Bureau of Mines laboratories on 66 samples of these gasolines, Data are presented for 19 samples of grade SO, 17 of grade 91/98, 22 of grade 100/130, and 8 of grade 115/145 aviation fuels. These gasolines are designated July 1948 production, although some of the samples may have been produced a month earlier or later.

Jan 1, 1948

By E. C. Lane

This paper is the first part of a report giving the results of the Bureau of Mines' twenty-third semiannual survey of motor gasoline marketed in the United States. A companion report, Part II, is in preparation and will give a more detailed discussion of the whole survey. Results of the determination of copper-strip corrosion, color, sulphur content, copper-dish evaporation residue, and gum content as given by the Bureau of Mines steam-oven method will be presented in the second paper, which will also include the prevailing retail price and the tax at the time the sample was taken. This paper deals specifically with data relative to gravity, Reid vapor pressure,5 and distillation (method 100.13).6 The samples tested were divided into "competitive-price gasolines" and "premium-price motor fuels," a method of presentation that was begun with the twenty-second semiannual survey.7 A total of 312 samples were collected from service station pumps in 20 cities throughout the United States. Of this number of samples, 207 were "competitive-price gasolines" and 105 were "premium-price motor fuels." All of the samples were collected in March, 1931, and analyzed at the Petroleum Experiment Station of the United States Bureau of Miner at Bartlesville, Okla.

Jan 1, 1931

By H. G. Iverson

Solid state reactions of manganese with silica were investigated in high-temperature tests. Reactions of 0.5 to 4.0 moles manganese (Mn) with 1 mole silica (SiO2) at 1,100° C and of 2.0 Mn:SiO2 mole-ratio mixtures at 1,000° to 1,150° C yielded products consisting of a slag phase and a metallic phase. At 1,100° C, the slag phase from reactions of the low Mn:SiO2 mole-ratio mixtures was composed of SiO2 and rhodonite (MnSiO3), and the slag phase from the high Mn:SiO2 mixtures was composed of MnSiOs and tephroite (Mn2SiO4). The metallic phase from the corresponding low Mn:SiO2 mole-ratio reactants consisted of two manganese silicides, Mn5Si3 and Mn3Si; from the high Mn:SiOg mixtures, it was Mn and the manganese silicide (Mn5Si). For the higher mole ratios of MnSiO2 the manganese content in the metallic phase increased, while the manganese and silica contents of the slag phase remained nearly constant. The slags did not contain free or uncombined manganese oxide (MuO). For the 2.5 to 4.0 Mn:SiO2 mole-ratio mixtures reacted at 1,100° C, the maximum quantities of silica reduced and of the manganese in the slag appeared to become asymptotical at about 41 and 48 percent, respectively. A brominating procedure was developed that was highly selective in removing the metallic constituents from the reaction product, leaving the slag phase as residue. X-ray diffraction patterns were obtained on prepared silicides Mn5Si, Mn3Si, and MnSi.

Jan 1, 1967

By Charles A. Seitz

This Bureau of Mines report describes a chromatographic method for analyzing impurities in helium that utilizes a helium carrier gas contain-ing 25 to 30 ppm Ne. An example of the effect of trace amounts of nitrogen, methane, and moisture on the detector's response is shown. The added neon in the carrier does away with irregularities of the analysis which were experienced when the carrier contained up to 3 ppm Ne. The addition of 25 to 30 ppm Ne causes a loss of sensitivity, but the re-maining sensitivity is adequate for routine analyses. The high-neon carrier allows positive and more linear responses for eight impurities: neon, hydrogen, argon, oxygen, nitrogen, methane, carbon dioxide, and ethane. Neon concentration levels of 0.02 to 125 ppm in helium carrier gases were studied. The high-neon carrier has been in successful rou-tine use in Bureau of Mines helium facilities since October 1981.

Jan 1, 1985

By D. Harrington

Part III-B, presented in this circular, completes the series reviewing the literature on effects of breathing dusts with special reference to silicosis; it includes data on the status and cost of compensation for silicosis in the United States and several foreign countries and a summary and general conclusions covering the whole series. Parts I, II, and III-A of the series have been issued as Information Circulars 6935, 6840, 6948 , and 6957; Part I defines and classifies dusts, indicates sources of exposure, and describes the physiological effects of breathing dusts; Part II-A discusses the principal dust factors producing pulmonary pathology and methods of determination of dust in air; Part II-B presents data on the engineering and medical control in the prevention of dust diseases and general recommendations for their control in industry; and Part III-A deals with the economic and legal aspects of dust diseases in industry.

Jan 1, 1936

By Roy L. Soderberg

Ground support for metal, nonmetal, and coal mines was examined through fill placement with a pneumatic stower to increase extraction, reduce ground pressures, and improve general mine safety. Several pneumatically stowed stope-fill products were tested to determine the effects of specific gravity, gradation, moisture, and impact velocity on the in-place density of the stowed fill. Hydraulic sand filling has now served the mining industry for several decades but because of the low density does not always provide ample support to the hanging wall; therefore, the sill and crown pillars sometimes build up excessive stresses that are detrimental to mining. Cementation of a dense fill adjacent to a pillar to allow 100-pct extraction of the pillar, or a fill that can be placed without the use of water and where water is a detriment to rubber-tired mining equipment, was found to be a possible use of pneumatic fill. Placing of coal mine washery products into abandoned underground workings is another possibility in order to completely eliminate surface impoundments.

Jan 1, 1976

By Kenneth H. Johnston

This report describes an in situ combustion project and three waterflood projects in Allen, Anderson, and Wilson Counties, Kansas, that will be visited during the 1964 annual tour of the Kansas-Oklahoma Waterflood Association. Among the unique features of the projects are the movement of heavy crude oil through the reservoir and into the wellbore with energy furnished by burning s portion of the crude oil therein. Another feature is the simultaneous injection of C02 and water, through separate tubing into input wells during early development, to increase injectivity at moderate pressures, Discussion of individual projects includes information on their early history, source and treatment of injection fluids, oil production-decline curves, and the results of water injection on oil production.

Jan 1, 1964

By Harold Bailie

The purpose of this Bureau of Mines report is to furnish information on mining practices applied to flat-bedded fluorspar deposits in southern Illinois. It presents new and improved operating procedures and specialized techniques applicable to deposits of this type. All of the operating mines of the Ozark-Mahoning Co. in this area have been opened by vertical shafts which connect with levels consisting of haul-age ways, stopes, and loading stations. The stoping practice used locally called room and pillar, is open stoping with pillars left at different distances and diameters. To facilitate haulage and drainage, the mines are worked from openings turned off the main haulage drift on a grade to conform with the dip of the ore beds. The ore is predominantly fluorspar with smaller amounts of galena and sphalerite that contain traces of cadmium and germanium. The principal gangue minerals are limestone, calcite, shale, barite, and sandstone. The rock hardness ranges from relatively soft shale to hard, abrasive sandstone.

Jan 1, 1960

By Larman J. Heath

Preliminary results of an explosive fracturing-solvent injection heavy oil recovery experiment conducted by the Bureau of Mines at a shallow oil reservoir near Bartlett, Kans., are given. Three wells 35 to 50 feet apart were drilled to a depth of 360 feet, and an open hole interval from 300 to 350 feet in the Bartlesville Sandstone Formation was explosively fractured with 3,000 pounds of pelletized TNT in each well. Laboratory tests were made on cores obtained from these wells to confirm the suitability of using an aromatic-type solvent. Injection of a 74-percent aromatic solvent was begun into one well and continued intermittently for approximately 2 months. Crude oil production amounted to 29.6 bbl, or 11.7 percent of the total oil con¬tained within the three-well interwell zone.

Jan 1, 1972

By Sidney Katell

This report is the fourth in the series, Bibliography of Investment and Operating Costs for Chemical and Petroleum Plants. The initial work, Bureau of Mines In- formation Circular 7516, was published in October 1949 in conjunction with the synthetic liquid fuels program authorized by Public Law 290, 78th Congress. It included references to and abstracts of publications appearing from 1930 to September 1948 on all processes in general use in the petroleum refining and chemical industries. A supplemental bibliography, Bureau of Mines Information Circular 7705, was published in January 1955 to cover the period September 1948 through June 1952; and Supplement 2, Information Circular 7751, published in September 1956, covered the period June 1952 through June 1954. The present supplement covers the period July 1954 through December 1956.21 The information in this paper was obtained from the following sources: 1. Bureau of Mines Information Circulars. 2. Bureau of Mines Reports of Investigations. 3. Chemical Engineering. 4. Chemical Engineering Progress. 5. Chemical Engineering Costs Quarterly (Cost Engineering).

Jan 1, 1958

By G. G. Campbell

Bureau of Mines research to develop an in situ retorting recovery method for oil shale has involved field testing of fracturing techniques for creating fluid-flow paths in impermeable oil shale. Electrolinking, hydraulic fracturing without and with sand propping, and explosive fracturing with a liquid explosive were tested in a 25-ft-square, five-spot pattern. These wells were drilled into oil shale at 50-to 88-ft depths near Rock Springs, Wyo. Results of the fracturing tests were evaluated by injecting air into a test well and measuring flow rates and flow profiles in adjacent test wells before and after each test. To identify points of air entry (location of fractures) in wells, flow profiles were determined by use of inflatable packers and by continuous logging with an airflow probe developed during the fracturing program. Electrolinking and hydraulic fracturing without sand propping were relatively ineffective; hydraulic fracturing with sand propping created horizontal fractures with desirable flow capacity; and fracture flow capacity was significantly increased by detonation of nitro-glycerin displaced in the natural and hydraulically induced fracture systems.

Jan 1, 1970

By James F. Devine

This Bureau of Mines report describes tests conducted at three sites to determine if, and to what extent, a vertical presplit fracture plane placed between a blast point and detection point will reduce vibration levels. Statistical analyses indicate that the presplit fracture plane did not reduce the vibration level.

Jan 1, 1965

"Status of the Mineral Industries" provides a written and graphic view of the Nation's mineral position and its mineral industries. The report, issued annually by the Bureau of Mines, U.S. Department of the Interior, describes recent activities in mineral production, consumption, imports, exports, and uses of significant minerals and mineral raw materials. Charts profile trends for the past 28 years in supplies and uses of iron, steel, major nonferrous metals, primary nonmetallic construction raw materials, fertilizers, and plastics. Also included are current and historical financial data on the mineral industries, such as debt-equity ratios, asset-to-liability ratios, and plant and equipment expenditures.

Jan 1, 1979