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By P. R. A. Andrews

"The sillimanite group minerals, kyanite, sillimanite and andalusite are identified as alumino-silicate minerals with the common chemical composition AIP3.Si02' so that each possesses similar physical properties. Kyanite is the most abundant mineral and mainly occurs in Quebec, Ontario and British Columbia; sillimanite occurs in Ontario and Manitoba; and andalusite in Nova Scotia. The main use for the sillimanite-group minerals is in refractory applications for the production of refractory bricks and shapes. In refractory applications, the main performance criterion is the relative percentage of mullite formed within the material during firing. This phase gives a greater degree of resistance to creep deformation and slag attack, and improves the ability of the refractory to withstand high temperatures under load. The beneficiation of refractory silicate minerals has been the subject of many investigations at CANMET, and the former Mines Branch. Eighteen kyanite, two sillimanite, and three andalusite evaluation studies were conducted between 1933 and 1987. A review of some of the more important studies is presented, which includes information concerning mineralogy, beneficiation methods and flotation data."

Jan 1, 1995

By M. Timberlake, A. J. Jonaitis

"The DENVER Tube Press is a simple, high pressure (1500 PSI (100 bar)) filtration unit, developed for processing difficult-to-dewater materials and to produce a handleable filter cake and clear filtrate product.Lab and Pilot testwork conducted in Australia on coal fines (55-70% -35 micron (400 mesh)) have shown that total moisture contents of less than 20% are consistently achieved in the final cake products from the Tube Press.currently, these coal super fines are sent to waste due to uneconomical mechanical dewatering methods, which were only able to reduce total moisture levels in excess of 30%. Calculated, throughput rates for the 500 series Tube Press exceeded 1700 kg/hr (3750 lbs/hr). Feed solids concentration requirements are between 45 and 50% to achieve these results.INTRODUCTIONThe DENVER Tube Press is an automatic membrane high pressure filter press, which operates at hydraulic water pressures up to 1500 PSI (100 bar). The Tube Press was developed in the late 1960's by Charlestown Engineering, st. Austell, Cornwall, England, formerly a division of English China Clays, Ltd., to address more effective methods of moisture reduction of micron-size china clays. The Tube Press reduced moisture sufficiently to produce a hard surface-dry, handleable cake and clear filtrate discharge, which was recycled into the process. This development work was conducted using a 200 Series Tube Press (200 mm diameter x 2500 mm long filter surface)."

Jan 1, 1993

By Franco Oboni

Numerous voices are raising around the world to show how misleading and fuzzy commonly used risk assessments methods are. These criticisms come at a time when public trust in ?proponents of new projects?, operators, private or governmental, seems to have hit a low and the legal system ?targets? public officers. It is common that technical experts and the public strongly disagree in their analysis of risks. Risk definition requires the evaluation of probability and consequences and those words are oftentimes enough to stir great worry to the public. Thus it is nowadays commonly understood that ?reality? is not scientific, but resides in public opinion, hence urging technical people to communicate better, more transparently. Blatant failures on both counts have lead to the emergence of ?new myths? used to justify complacency using ?complexity? and other buzz words as an alibi. This paper (together with its companion presented elsewhere) explores how poor ?common practices? in Risk Assessment contribute to biasing project team, design teams opinions, skew decision-making process and finally misrepresent reality to the public resulting precisely in the raise of public distrust, legal implication witnessed around the world. The discussion first reviews the pitfalls of common approaches (FMEA, Probability Impact Graphs) pinpointing them as possible causes of future legal liabilities. An alarming disconnect also comes from various codes, ISO 31000 itself has this flaw, invoking the term ?acceptable?/?tolerable? without defining it or giving any guidance for its determination. Wide-spectrum public consultation could be developed to define a ?modern? social acceptability criteria helping all the stakeholders making/understanding decisions. Another alarming disconnect comes from the poor definition of consequences of mishaps and their societal ripple effects. This aspect is indeed mostly ignored in codes, leaving ample room to biases and censoring applied to potential losses. In our society no one seems to have anymore the possibility of hiding behind a shroud of ?carefully maintained? misrepresentation. It is time to act and ?write the book? for proper risk assessments avoiding misrepresentations.

May 1, 2013

By D. R. Griffiths

"Oxidation of pyrrhotite prcxiuces sulphuric acid which in turn leaches out heavy metals, resulting in acidic contaminated seepages. The establishment of a marsh on top of the pyrrhotite would result in an anaerobic sediment, which should prevent further oxidation of the pyrrhotite. Initial data indicates that concentrations of sulphates and heavy metals in the seepage water are greatly reduced. Further hydrogeological studies are required however, to determine if metal and acidic loadings to the environment have increased.L'oxidation du sulfure de fer produit de l'acide sulfurique qui a son tour attaque les métaux ayant pour resultat une contamination d'acide et de métal des eaux d'infiltration. L'etablissement d'une couverture faite de boue et de vase au-dessus du depot du sulfure de fer réduit les effets de l'oxidation.Les données initiales indiquent que les concentrations de souffre et de métaux dans les eaux d'infiltration sent grandernent réduites.Des études plus poussées sent nécessaires pour déterminer si les quantités de souffre et de métaux dans les eaux d'infiltration ont augmentées.INTRODUCITONPyrrhotite tailings are readily oxidized through a combination of precipitation and atmospheric oxygen causing acidification of the unsaturated zone above the water table. This reaction is usually catalyzed by the bacteria, Thiobacillus ferooxidans. As the pH decreases, heavy metals become more soluble resulting in contaminated seepages to ground and surface waters.By creating a marshland on top of the pyrrhotite, an anaerobic intermediate layer should form between the organic covering and the tailings, preventing the oxidation process from progressing.In September 1986, Falconbridge Limited implemented a tailing reclamation project that involved creating a marshland on top of pyrrhotite tailings. The following paper will discuss and illustrate the preliminary results obtained during the sampling period of May to September 1987."

Jan 1, 1988

By Anne-Laure Bonnet

Les connaissances acquises au cours des dernières décennies sur les gîtes de métaux de base et précieux intensément métamorphisés (p. ex. Vokes, 1991; Cornell et al., 1992; Zaleski et Peterson, 1995) ont permis d?élaborer des guides d?exploration pour de tels gisements dans les terrains de haut-grade métamorphique (Spry et Scott, 1986; Rubin et al., 1993; Hand et al., 1994; Spry, 2000; Spry et al., 2000). Un transfert de ces connaissances à la cartographie des vastes terrains gneissiques non différentiés de la province de Grenville permet d?affiner l?approche cartographique nécessaire pour reconnaître les systèmes hydrothermaux métamorphisés en terrains vierges et peu diagnostiques puis d?en discriminer les divers halos d?altération (Corriveau et al.,1996, 1997, 1998, 2003; Williamson et al., ce volume). Cette approche prend en compte les « empreintes métamorphiques » observées sur le terrain, telles que les variations des assemblages minéralogiques, du mode et de la composition des minéraux métamorphiques, pour reconnaître des roches présentant une composition inhabituelle caractéristiques de protolites altérés par hydrothermalisme. Ces empreintes citées cidessus sont facilement reconnaissables dans les terrains de haut-grade où la recristallisation induit un grossissement des grains qui permet de déterminer la nature et le mode des minéraux dès les levés de terrain. Cette approche raffine la compréhension des terrains de haut-grade métamorphique et illustre que leur complexité (i.e. polyphasage de la déformation et du métamorphisme) n?est pas forcément une limite à leur exploration. Elle a donc été utilisée systématiquement lors des levés de terrain réalisés dans le cadre d?un projet de l?Initiative géoscientifique ciblée de RNCan. La zone cartographiée se situe le long de la marge sudest du Groupe de Wakeham dans le secteur est de la Province de Grenville. Deux régions ont été plus particulièrement étudiées, celle du lac Musquaro (SNRC 12K10, 11 et 14) et la région côtière comprise entre Kégashka, La Romaine et Baie des Loups (SNRC 12K1, 2, 3 et 7) (fig. 1).

May 1, 2003

By Li Xibing

The In order to mine safely with reasonable cost, it is necessary to research the fracture characters of backfill and its matches with rock mass. Four kinds backfill with cement-tailing ratio of 0.250, 0.125, 0.100 and 0.083 respectively were tested, and basing on stress-strain curves tested, the deformation characters and fracture laws as well as the damage constitutive equations investigated with damage mechanics whose calculating results are coincided with experiment results well were proposed. The results of damage analysis show that there have different damage characters in different backfill, e. g. the lower the ratio of cement to tailings the lower the damage values when stresses reach to peak value; the lower the content of cement the more rapid in damage and the more abrupt in breakage process. In addition, using catastrophe theory, an energy model was proposed for backfill and rock mass acted each other in mechanics, and the unstable condition of the system was obtained. Research results show that the higher is the stiffness of rock mass the more stable the system, and the lower is the ratio of cement to tailings, the more unstable the system will be. Further more, according to the catastrophe model proposed, the reasonable matches between backfill and rock mass were researched, and a calculation formula that designs reasonable strength of backfill during mining was put forward. It has been proved by practice that the model and theory researched in this paper can guide filling design in mining. Keywords: Cemented tailings backfill, constitutive equation, catastrophe theory, match of backfill and rock mass

May 1, 2007

By Miguel A. Cuba

Resource models are generally constructed using data of different types and/or from different sources. A common issue is the consistency of scale in the information that often leads to a requirement to composite the data prior to model construction. For the purposes of mine planning, development and/or resource assessment, this model may then be upscaled to a relevant selective mining unit. It is well established that the geostatistical parameters for resource model construction is scale dependent. In particular, the volume variance of integrating these various scales has a direct impact on the variogram that should be used in model construction and/or the assessment of volume variance relations as it affects resource estimation. The scaling laws are a set of guidelines that detail how the variogram should change as a result of a change in the volume; these laws are empirically derived and involve some simplifying assumptions, not the least of which is an assumption of shape invariance in the variogram structure. An alternative approach was proposed to directly upscale the variogram via numerical integration, which demonstrates that the assumption of shape invariance is not required and we can directly access the new variogram shape given any volume of interest. This paper compares these two different approaches to variogram upscaling by considering two applications: the first corresponds to a 2D synthetic case and the second looks at a 3D case with data from a porphyry copper deposit. The simulation studies in these cases show that the direct upscaling approach performs better than the scaling laws in fitting the average experimental variogram values at any block size. This is based on a mean absolute error criterion. Moreover, it is also shown that with an increase in the block size, direct variogram upscaling significantly outperforms the scaling laws approach.

Oct 1, 2009

By Sammy Bansah, Komla Dzigbodi-Adjimah

Abstract-Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized ("Banka") drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi- Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration programs for use in similar settings.

Jan 1, 1995

By P. Mottahed, J. Ran

Mining practice and research have shown that the jointed roof in stratified rock behaves like a voussoir beam structure with strength greater than that determined by the continuous beam theory. Previous studies have demonstrated the voussoir beam mechanism and developed methods to estimate the crushing and buckling strength of voussoir beams. However, research on voussoir beams with multiple mid joints has not been suffICient and problems such as the voussoir beam support and applications of the voussoir beam mechanism to the mining environment have not been addressed. In this paper, mechanism of voussoir beams containing multiple mid joints and truss support are studied and applications of the voussoir beam mechanism to underground mine openings are discussed based on the numerical and experimental results.

Jan 1, 1995

By Karim Ramji

The extractive sector today faces growing social, legal and political risks (SLPs) from so many different stakeholders including national and local governments, name and shame groups, civil society and environmental groups, and the ?Occupy? movement. Beyond these stakeholders, there are the indigenous peoples who have growing legal, social, political and economic influence which can often determine the outcome of the Project. The development curve in the extractive sector from initial exploration to mine start-up has become longer, steeper and more risky and expensive as these SLPs have grown in scope and complexity. Even if a project is permitted or starts commercial production, its ongoing development and operations are also facing these SLPs. The continuous assessment of these SLPs and the strategy to mitigate for them has now become critical for every project in the extractive sector. A project will only be successful if it is able to obtain the legal permits to operate, then withstand any judicial reviews, and then also to be able to gain and maintain the Social License to Operate (SLO). Stakeholder identification, management and engagement are key risk-mitigation tools. This paper focuses on the growing influence that indigenous peoples are now enjoying and the impacts on the extractive sector. Indigenous peoples are a unique stakeholder group because their legal rights and interests to lands and resources, their aboriginal title and rights, are gaining more recognition. When indigenous peoples form alliances with other stakeholders, this simply adds to their growing momentum and leverage, and this can become a daunting challenge for the extractive sector. More due diligence is required by companies to understand and assess the challenges posed by operating in areas claimed by indigenous peoples. There is a real need for mining companies to develop an effective indigenous engagement strategy to address these challenges in order to successfully convert risks into opportunities. Early identification and engagement with the indigenous peoples is required and the goal should be to conclude an Impact Benefits Agreement (IBA) with the affected indigenous peoples. The real objective must be to develop a real and transparent relationship between the company and the indigenous peoples so as to gain and maintain the SLO.

Aug 1, 2013

By John C. Loretto

"Answers to some of the problems ofRecovery and Metallurgical AccountingIn Gold and Silver Hydrometallurgical PlantsThe start-up over the last few years of new hydrometallurgical plants for the recovery of gold and silver has brought to the surface again a number of problems. Most of the problems have existed for some time and they manifest themselves mainly in two ways. Firstly, the plant results do not agree with the Metallurgical Test work figures and secondly, the Metallurgical Accounting figures do not balance.The plant results not agreeing with testwork figures are mainly due to:a) The testwork samples were not representative of the eventual plantfeed;b) Misinterpretation or misunderstanding of testwork;c) Plant losses;d) Plant design not allowing testwork results to be achieved;e) Operating deficiencies.a} The testwork samples being dissimilar to the plant feed occurs on a very high proportion of projects. The effects of this can beccr.ie exaggerated because the upper levels of the mining company often regard the original testwork figures as sacred and therefore base their judgement of current plant performance on these figures.Frequently the test work samples represent only a minor part of the orebody or alternatively a single composite of the whole ore body is used for the testwork long before it has been determined that all of the potentially different ore zones behave in the same manner. These errors can be compensated for by repeating the ""testwork tests 11 on current plant feed on a routine basis and using these tests to determine whether or not the plant is operating satisfactorily."

Jan 1, 1982

By Sammy Bansah, Komla Dzigbodi-Adjimah

Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized (“Banka”) drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi-Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration pro-grams for use in similar settings.

Jan 1, 1995

By A. P. E. Dirige

In order to maximize the recovery of ore in variably dipping ore zones of moderate width, cemented backfill is normally placed to serve as structural support. With the intention of saving on costs, backfill of low cement content can be used, which are often supported by a sillmat of higher strength. The stability of the low cement backfill face, exposed during adjacent mining, must be carefully studied to provide very effective, safe and economic mining operations. Improper design of these stope support structures may result in fill mass failure resulting in relaxation and failure of the stope walls, with consequent losses of production, ore dilution, and in safety problems. This paper presents a study conducted to assess fill performance during adjacent pillar mining and to provide a comprehensive understanding of backfill behaviour, the failure modes that may occur and the consequences to production, ore dilution and to safety problems, and accurately predict their stability. The design study investigated the effects of stope width and height, orebody geometry and inclination, and wall roughness on the stability of cemented backfill during adjacent pillar mining. Fill properties used were based on paste fill specimens cured for 28 days. Paste fill performances were assessed based on analytical and numerical modeling studies for the different mining conditions. Analytical modeling was carried out using limiting equilibrium analysis and numerical modeling was carried out using FLAC3D. The modeling results suggested that, for stopes that are inclined with smooth wall rock conditions, backfill failure, driven by the fill self-weight, has minimum dependency on the binder content and is reduced by resisting forces developed on the footwall-fill contact. For inclined stopes with rough wall rock conditions, wall roughness contributes significantly to the stability of the backfill during adjacent pillar mining. The analytical modeling approach was demonstrated to be useful in providing some approximate parameters for predicting the behaviour of paste fill exposed faces during adjacent mining, but cannot predict the mode or mechanisms of failure. Numerical modeling not only assess the stability behaviour of paste fill free faces, but also is able to provide a better idea of paste fill failure modes and possible failure mechanisms. The depth of failure and the potential for instability for a simulated stope filled with paste fill can be predicted, and may be useful in estimating the mass of material that could possibly fail and ore dilution levels.

May 1, 2009

By Walter Valery, Lauren Hafla, Megan Tibbals, Adrian Dance, Jeff Snyder

"Newmont Mining Corporation’s Carlin (“Carlin”) operation processes roaster feed through a double rotator, dry grinding mill following secondary crushing. Metso Process Technology & Innovation (“PTI”) was involved in a review of crushing and dry grinding circuit operations in August 2009. A number of opportunities for increased throughput were identified in the PTI study.Extended plant trials were conducted in July 2010 to provide justification for possible circuit modifications and if needed, additional equipment. The trials confirmed that a finer crusher product would reduce the build-up of material ahead of the coarse grinding chamber in the double-rotator. Also revealed were material transport and airflow restrictions in the dry grinding circuit that resulted in a high circulating load.The secondary crushing plant demonstrated it was capable of reducing the amount of +¾” material in the mill feed thus increasing dry grinding throughput. However, wet and sticky feed affected screening efficiency resulting in low utilisation of the existing crusher capacity. The open circuit configuration also made it difficult to control crushing circuit product size.For the dry grinding circuit, changes in grinding media size, transfer grate design and increased airflow were recommended to reduce circulating load issues and increase circuit capacity. This paper summarises the crushing and grinding circuit review, the extended site trials performed by PTI and the improvements in dry grinding operation that resulted from this study."

Jan 1, 2012

By D. Mark Richards

Highland Valley Copper is a large open pit copper mine in the southern interior of British Columbia. Machine guidance technology using the Global Positioning System (GPS), was first implemented at the mine in late 1996 for blast hole drill navigation. The purchase of a third BE49R drill in 1998 completed the change to GPS navigation for all the mine?s drilling. The acceptance of this technology was almost immediate at both the operator and management levels. With the purchase of a new P&H 2800 shovel in 1997, the opportunity was taken to extend GPS navigation to a shovel. Due to communication restrictions, this was not as successful as envisaged. In late 1999, following a cost benefit analysis, a three-shovel trial of Caterpillar?s Computer Aided Earthmoving System (CAES), was initiated. The trial was successfully concluded in June 2000 and a further two shovels were equipped. Acceptance of this system has been very good at all levels, which has undoubtedly contributed to its success. In September 2000, CAES was extended to the dozer fleet with the purchase of a new track dozer. The CAES equipped dozer is used for pit production and project work. It is planned to extend CAES to the rest of the shovel fleet in 2001, along with a production front-end loader and one or two more track dozers.

May 1, 2001

By Emmanuel Henry

The Kiruna Mine, operated by Luossavaara-Kiirunavaara AB (LKAB), is a large-scale sublevel caving operation located in Arctic Sweden. Iron ore is extracted at a rate of 60 000 tpd from a four-kilometre long, 80-100 m thick and 60-degree dipping orebody. Actual production depth is 800 m under the top of the footwall and about 550 m under the average regional ground level. Because no support is left between the footwall and the hanging wall and despite the relatively low mining depth, extraction results in the formation of a huge stress shield modifying the original stress field and concentrating it just beneath the mining level. Effects of stress concentration on the rock mass are monitored through field observations and a seismic system. Severe stress-induced deterioration of openings is visible to a certain radial distance from the mining level: pillar crushing and fault slips are more and more common and extended. The seismic system, installed in collaboration with CANMET, confirms the field observations and completes them in the rock mass: fault slips and major seismic events are recorded. The system proves its effectiveness to outline the extension of the dynamic response of the rock mass, which actually seems much larger than field observations let think.

May 1, 2001

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By Michael K. Watkeys, Jacobus E. Potgieter, E. Guy Charlesworth, Carl R. Anhaeusser, Roger L. Gibson, Alexander F. M. Kisters

Intrusive features of cupriferous noritoids from the deeply eroded Proterozoic granite-gneiss terrane of the Okiep Copper District in South Africa illustrate the emplacement of basic magmas into a mid- to lower-erustal environment. The small, easterly trending intermediate to basic intrusions of the so-called Koperberg Suite display a wide variety of geometries, occurrence and emplacement modes, including dike-, sill- and plug-like bodies. Coeval granulite-facies metamorphism, partial melting and ductile deformation of country rock gneisses during intrusion of the basic magmas led to emplacement and dilation processes of the intrusions which differ significantly from those described for dikes and sills at shallow crustal levels. Regional tectonic stresses are largely negligible due to very low differential stress [( )] during deformation and intrusion, which permits emplacement at high angles to the principal compressive stress and which follows favorably inclined structural anisotropies. Dilation of the basic intrusions is largely determined by compositional differences of host rocks and occurs by thermal erosion, i.e., assimilation of wall rock gneisses. Low length-to-width ratios of basic to ultrabasic dikes and predominantly diapir-like outlines of mesocratic bodies are indicative of low viscosity contrasts between the mafic magmas and high-grade metamorphic host-rock gneisses. Buoyancy-controlled ascent of the basic to intermediate intrusions is expressed by a broad compositional zoning of basic bodies with respect to the granite-gneiss stratigraphy. Various intrusion modes within the stratigraphic column of the granite-gneiss sequence reflect a lithological and structural stratification of the seemingly homogeneous granite-gneiss terrane.

Jan 1, 1994

By T. Hidayat

The distributions of minor elements between slag/metal and slag/matte in equilibrium with tridymite in the Cu-Fe-O-S-Si-Al-Ca system have been investigated in the range of conditions of interest to the high- temperature copper production, refining, and recycling processes. An improved experimental methodology has been used involving high temperature equilibration in controlled gas atmospheres, rapid quenching, and quantitative microanalysis techniques using Electron Probe X-ray Microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrum (LAICPMS). The effect of oxygen partial pressure on the distributions of minor elements between slag/metal and slag/matte has been accurately measured. The effects of slagging components (Al2O3 and CaO) on the distributions of minor elements between slag/metal have also been experimentally determined. The present study is a part of a larger integrated experimental and thermodynamic modelling research program in the systems relevant to high-temperature copper processing. INTRODUCTION In the high temperature processing of copper, minor elements are distributed between different phases, i.e. liquid slag, liquid matte, and liquid metal. From a processing perspective, it is desired to have the valuable minor elements distribute predominantly in the metal and matte phases rather than in the slag phase, and to have the non-valuable minor elements distribute predominantly in the slag phase rather than in the metal and matte phases. Knowledge of the distributions of minor elements between phases in the smelting, converting, and refining processes is required if the distributions of minor elements between phases in these processes are to be optimized.

Jan 1, 2019

By S. Suzuki, C. Tokoro, S. Owada, T. Sakakibara

Acid mine drainage (AMD) has been actively treated by neutralization from about 80 abandoned or closed mines in Japan. More efficient and cost effective treatment processes has been demanded for AMD due to the government investment of billions of yen every year to protect the environment from these discharges. In this study, quantitative modeling was conducted for actual AMD to predict pH or residual concentration of toxic elements after neutralization/co-precipitation process. Simple chemical equilibrium calculation was not adequate for quantitative prediction of pH after neutralization, because residual concentration of major elements of AMD, such as Fe or Si, could not be quantitatively calculated. When oxidation rate of Fe(II) to Fe(III) and precipitation rate of kaolinite were added to the model, quantitative prediction of pH and Fe or Si concentration was achieved. Surface complexation at the interface between hydroxide such as ferrihydrite or aluminum hydroxide and AMD was the most important mechanism for removal of dilute toxic ions. When surface complexation model at the interface of ferrihydrite was added to the model, residual As (V) and Pb (II) concentration after neutralization/coprecipitation process was successfully calculated. On the other hand, surface complezation model of aluminum hydroxide was also necessary for quantitative prediction of residual Zn(II) concentration after neutralization/co-precipitation process.

Jan 1, 2014