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By J. F. Vynne

ABSTRACT This paper examines several of the systems and processes that have been developed over the past few years and are now being utilized by major mining companies on draglines in North America, Australia and South Africa. These technologies include production monitors and reporting systems, GPS navigation systems, structural integrity monitoring systems, structural analysis studies to increase the dragline rated suspended loads (RSLs) and inspection and response strategies. The use of these technologies provides significant increases in dragline production and reduces maintenance costs, downtime and the chance of a catastrophic failure.

Jan 1, 2010

By D. MOORE, A. REINSBAKKEN, A. J. Sinclair

The Gypo quartz vein lies near Oliver, British Columbia, and was quarried between 1955 and 1968 for decorative chips. The vein is one of many quartz veins hosted by the Late Jurassic Oliver Plutonic Complex, specifically by the porphyritic quartz monzonite phase of the pluton. The vein has a known length of 155m and a thickness of 46m. It strikes east-west and dips at 60 degrees to the south. Mineralogy is predominantly quartz with minor pyrite, muscovite, fluorite, calcite, apatite and manganese; trace amounts of chalcopyrite, pyrrh otite, marcasite and molybdenite also are present. Quartz in the vein is zoned. A thin grey quartz zone found near the margins of the vein fades gradually into white quartz, which comprises over 95% of the vein. Late-stage boxworks cut earlier mineralization, particularly fluorite, which occurs as pods in a zone fairly close to the hanging wall. Sulphide minerals are found in a centrally located zone in the quartz vein. The hanging wall of the Gypo veins is altered only slightly, but thefootwall is altered extensively to a greisen of muscovite and grey quartz. Evidence suggests that early in rhe vein development, the adjoining country rock was feldspathized. As grey quartz and muscovite was deposited, a period of intensive greisenization and fracturing occurred which so weakened the rock that a central block of greisenized country rock foundered. This provided the open space in which the vein was deposited.

Jan 1, 1984

By R. P. Smith

PRIOR to June, 1937, the employees of Hollinger Consolidated Gold Mines, Ltd., at Timmins, Ontario, received medical care for themselves under a contract system developed through an agreement between the employer, employee, and a contract physician. This form of practice is common to the mining industry in Ontario. But with the improvement in mining methods and conditions of living, and through an increasing demand for provision of a complete medical care, it was not any surprise when the employees of the Hollinger mine approached organized medicine and indicated their desire for a plan to provide their families with a more or less complete medical service in addition to that supplied for themselves. In April, 1937, this approach was made, and on June 18th, 1937, the Hollinger Employees' Medical Services Association was formed and started to provide medical services. A review of five years' experience is now presented. The Association provides complete medical service for the employee, his wife and family, as well as those dependents who are the total responsibility of the employee. The employee membership is limited to employees at the Hollinger mine in Timmins who reside in the immediate vicinity. The employee is examined by a Company doctor on application for employment and is subject to further examination by a specialise in chest diseases under the direction of the Workmen's Compensation Board of Ontario. The wife and family are not subject to examination but have to be registered when the employee is accepted for employment. The dependents, other than the immediate family, are subject to medical examination and approval after the employee has applied for such dependent or dependents to be admitted. Membership in the Association is obligatory when the employee is hired, but at the end of any Association year he may drop out if he so wishes.

Jan 1, 1943

By Bevan. P. A.

The general location, topography and climate are discussed briefly, together with an historical record of the deposit. General geology, grade control and ore reserves are covered at some length, and reasons are given for the operation being placed on a salvage basis.

Jan 1, 1973

By G. Simard, D. Boudeville, A. Leclerc, A. Boivin

"The objective of this work is to study the various parameters that affect the overflow clarity of gravity settlers used in the precipitation circuit of alumina hydrate from the Bayer process. A mathematical model incorporating the size distribution of the feed suspension (Multi Size Group model), its diphasic nature (Schiller Naumann model) and the presence of turbulence (Shear Stress Transport model) has been solved numerically using ANSYS-CFX software. Preliminary results indicate that the overflow clarity is mainly controlled by lateral diffusion of fine particles (~20µm) from the exit of the feed well and by their upward transport from the sediment bed interface. Also the turbulence pattern in the settling zone seems to play a significant role in this vertical transportation. The validity of the model has been verified by comparing the measured solid concentrations from a pilot classifier with the calculated ones. This model could provide mineral processing plant operators and designers with a tool to optimize the configuration of classifiers with respect to the overflow clarity.INTRODUCTIONProblemIn the Bayer process, alumina hydrate precipitation from the saturated liquor is initiated in settler by adding crystallization seeds. Most of the precipitated alumina settles to the bottom of the tank while the liquor and the remaining alumina rise to the top, where they are removed at the overflow. Ideally the overflow clarity, which depends on the operational mode of the classifier, should be controlled within targeted limits."

Jan 1, 2016

By Kwang-Hyun Jeon

Recently, 3D printing technology in the manufacturing field is in the spotlight. In the construction industry, similar rapid prototyping technology that does not use conventional form can be applied to meet the demand on free formed structure that can provide aesthetic value and functionality. Conventional formwork can increase construction cost and period for various structure with complex shapes while it has numerous advantages such as high strength, convenience, accuracy and good quality of surface roughness. To meet the demand on free formed structure, automated freeform construction systems such as Contour Crafting and Concrete Printing have been developed with active collaboration between university and industry in USA and England. However, details on the system have not been fully released in public, so the possibility of its fusion and spin-off technology cannot be expected. In this paper, cost-effective solution for mechanical and control system for constructing a free curved structure without mold are described. As an appropriate material for the system, fiber reinforced mortar was selected by experiments on compressive strength, setting time and fluidity. After performing G-code simulation, transfer and extrusion experiments with the selected mortar mix were performed and the possibility of the development of automated freeform construction system was demonstrated. Based on this research results, it is required to keep the automated freeform construction system improve and extend it into the new application area in construction industry.

Aug 1, 2013

By P. Hale

"The trend to drives of more than 10,000 hp on large-capacity ball and autogenous mills for increased operating efficiency has been limited by factors in the conventional drive system. A solution to this problem, using modern developments in static converter technology, is the concept of driving the mill directly without gearing using a low-speed, low-frequency synchronous motor with a cyclo-converter power supply.This paper presents various practical arrangements of mill and low-speed motors giving the specific advantages of each system. The means of controlling inrush currents on starting and of spotting by the use of variable-frequency control are outlined in general form. Several gearless ball mill drives are scheduled for start-up in European cement plants and further orders have been placed."

Jan 1, 1970

By M. Knot

Fans delivered to the Russian Federation, and eventually to countries of the former U.S.S.R., for mine ventilation must meet the legislative requirements of local jurisdictions. This paper presents a discussion of these legislative requirements and presents examples of fan equipment designed to meet the requirements. The legislative obligations discussed include four (4) separate requirements, including: ?Technical design requirements ? The Federal Agency for Technical Regulation and Metrology is responsible to issue a GOST R certification declaring conformance to the requirements ?Operational requirements ? A ?License for Application? must be obtained prior to operation ?Explosion risk requirements ? If the area of operation includes potential for explosion a special certificate must be obtained ?Technical condition requirements ? Market segments within the mining industry require special conditions that must be satisfied Examples of fans designed specifically for use in the Russian Federation are also discussed and examples provided. Designs for fan volume flow control will be highlighted.

Aug 1, 2013

By K. Kim

"All milling operations would like to achieve the best possible recovery in combination with the highest achievable throughput. Unfortunately, many operations have problems with low recovery, low throughput or both. In the majority of these cases investigated by the author, the solutions to improve recovery and throughput were simple. The solutions did not include implementation of new technology or major capital, but rather a return to fundamentals. In most cases, problems occurred because the operation was not following their own operating procedures, because the design of the circuit was changed without adequate change management or understanding of the implications of changes, or because basic metallurgical measurements and control were not taken or ignored. In this paper, examples of these problems and their solutions derived from long and varied experience will be discussed. The objective of this presentation is to provide the milling operator with practical and readily implementable solutions to common milling issues to improve throughput and recovery.INTRODUCTION Mill operations can be evaluated by many operating parameters, but the two best indicators are recovery and throughput. These two parameters summarize the wellbeing of an operation. The grade to the mill is also a good indicator, but this is usually controlled by the mine. The best recovery and throughput are achieved through a team work involving operators, maintenance workers and metallurgical staff. The milling operations include many unit operations, such as crushing, grinding, flotation, leaching, carbon in leach, Merrill Crowe, roaster, autoclave and refinery. The tools available to the operations are plant design, process measurements, assays, metallurgical balance, and operating strategy. Twelve real life examples of improvements of recovery and throughput are presented in this paper. EXAMPLE 1: CRUSHING CIRCUIT WITHOUT FINE ORE BIN At this operation plant throughput could not be maintained at a high rate because feed to the mill became coarse during the day. The cone crusher was feeding the ball mill directly. As the day wore on, the gap on the cone crusher would slowly increase, which would cause the product size to increase. This would increase the re-circulating load on the ball mill. The throughput would decrease accordingly. Furthermore, the throughput would decrease more with high frequency of maintenance on the cone crusher."

Jan 1, 2019

By C. C. Li

Traditionally, strong and stiff devices, such as fully encapsulated rebar bolts and concrete lining and arches, are preferred for underground rock support. The attention is paid to the strength of the devices in such support designs. It has been observed in engineering practice that support systems composed of stiff devices are often subjected to premature failure in high stress rock conditions. In the past decade, yield support devices have been employed to improve the performance of rock support systems. A rock support system usually consists of both internal and external devices that are installed within the rock mass and on the free surface of the rock, respectively. Great efforts have been made to make support devices yieldable in the past years, but the efforts are focused on different aspects in the tunneling and mining branches. In the tunneling branch, the focus has been put on the development of external yield devices, such as Lining Stress Controller (LSC), Honeycomb element and compressible concrete, which are embedded in shotcrete liners, while in the mining industry the efforts has been on the development of yield rockbolts, such as the cone bolt and the D-Bolt. The internal and external support devices are not compatible in their deformation capacities in the current rock support systems even though yield devices have been employed. All the devices in a support system should be deformable and compatible in deformation capacity. With such a support system, premature failure of individual support devices could be avoided and the service life of the support system is prolonged. It is a trend at present to take into account the energy absorption capacity, instead of simply the strength, of support devices in rock support design.

Jan 1, 2015

By L. A. Nazarova, M. Vandamme, L. A. Nazarov, R. I. Rodin

"The paper describes a new method of interpreting the “canister test” data for the quantitative estimation of gas-kinetic parameters of coal bed based on the developed model of gas emission from coal sample placed in a sealed container. The model accounts for grain-size composition of the sample, initial gas content S, as well as coefficients of diffusion D and mass transfer ?. The inverse coefficient problem is formulated to find S, D and ??from the data of pressure measurements in the sealed container. It is shown that the inverse problem is uniquely solvable if the pressure is dropped during the experiment. The method has been tested using the data from an underground coal mine in the Kuznetsk Basin.Based on the poroelastic model of a coal bed and Khristianovich’s concept about origination and evolution of the filtration zone F in the neighborhood of a degassing borehole the authors considered the corresponding direct problem on rock mass geomechanical state. It was offered interpretation method for data on pressure measurements in a plugged degassing borehole allows evaluation of the diffusion coefficient, the horizontal component of natural stress field and parameters of F. The related inverse problem of the mixed type is formulated, and the cost function is constructed. The analysis using synthetic input data has shown that the cost function has a number of local minimums arranged on the same straight line, one of the minimums being the inverse problem solution. INTRODUCTIONPre-mine degassing is an integral part of coal mining. It allows mitigation of induced accidents in mines (coal and gas outbursts, rock bursts) (Guide, 1990; Malyshev & Airuni, 1999; Seidle, 2011) and also furnishes an alternative and ecology-friendly energy source—methane (Rice, 1997; Nambo, 2001). Choosing an optimized pattern of degassing boreholes, as well as estimating degassing time and amount of gas recovered requires data on gas-kinetics indices of coal beds out of which the key parameter is a gas content S. According to the latest guidelines for coal mines in Russia (Ruban et al, 2012), mining is allowed if S in a coal bed section is under 7 kg/m3."

Jan 1, 2015

By N. Depountis, Th. Rondoyanni, N. Sabtakakis, K. Kavoura, G. Tsiambaos

"Some typical landslide phenomena in Western Greece, in terms of the geological composition and structure of the affected materials, induced by heavy rainfalls are thoroughly studied and analyzed. The studied cases involved composite landslides on Flysch and Neogene weak rock materials that constitute the most critical landslide prone geological formations in Greece. The studied cases named Platanos, Platanitis and Karya include representative landslide sites as regards to the geological composition and structure of the displaced formations. Thus: (a) flysch formation includes different lithological units as shales, marls, siltstones, sandstones and conglomerates and is closely related to the Alpine orogenesis, suffering intense past tectonic movements and (b) the Plio-Pleistocene sediments include clayey marls, marlstones and siltstones. The investigated landslides , affecting mainly transportation routes, are closely related to heavy rainfalls induced by extreme meteorological events and are controlled by active fault tectonics. Long term movement monitoring using borehole inclinometers and surface benchmarks showed that landslides control was effective only when the proper stabilization measures were taken.INTRODUCTIONLandslides represent a major threat to human life, property, infrastructure and natural environment in most regions of the world. They are recognized by the scientific and politic authorities as having a major socio-economic impact and they represent a significant hazard for the population and the properties in particular locations. Landslide hazard expressed as the probability of occurrence within a reference time period and is a function of the spatial and temporal probability (Varnes, 1984; Guzzetti et al. 1999; Lee and Jones, 2004). The spatial probability of landslide initiation (susceptibility) is mainly related to static causal factors (slope inclination, material properties, etc.), while temporal probability is mainly related to dynamic causal factors such as rain input, increased groundwater levels and drainage, earthquakes, etc. (Van Westen et al. 2005)."

Jan 1, 2015

By Chen Feng

Compared to widespread successful deployment of robotic manipulators for repetitive and hazardous tasks in related industries such as manufacturing, the construction industry has achieved relatively limited benefits from robotics and soft automation. Unlike manufacturing, where robotic solutions benefit from the structured layout of the environment (e.g., factory assembly line), construction robots face unique challenges that arise from the rugged, dynamic, and unstructured environment of the work site, as well as the uncertainty and evolving sequence of occurring on-site events. This challenges any intended construction robots to not only replicate basic human motion, but also be capable of sensing and adapting to environmental changes, and making decisions based on the evolving state of the environment. Building upon recent advancements in robotic mapping, computer vision, and object recognition, the authors propose to introduce autonomous behavior at the basic task level for on-site construction robots to address these challenges in a flexible and extensible manner. This paper reports the outcome of the first phase of this research - a structured methodology for improved design and development of basic task automations - and focuses on algorithms developed for mobile robot navigation and relative pose estimation. The algorithms are implemented on a prototype mobile robotic platform, and evaluated in several experimental scenarios.

Aug 1, 2013

By Fathi Habashi, Ahmet Deniz Bas

"The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgy researchers in the early 1950s who assumed the formation of intermediate surface complexes that could be neither separated nor identified by physicochemical techniques. The electrochemical theory of leaching introduced in the late 1960s resolved this problem by comparing the leaching process to a corrosion phenomenon similar to the corrosion of metals. Few years later, experimental evidence showed that anodic and cathodic zones are formed on the dissolving mineral although no electric current is imposed on the mineral during dissolution. A discussion of these findings is outlined.INTRODUCTIONIn the early 1950s researchers realized that kinetic studies for leaching ores are as important as thermodynamic calculations. It was also during this period that the concept of species adsorption on mineral surfaces has dominated the interpretation of the mechanisms of most reactions. This may have been due to the fact that many researchers of this period came from the mineral dressing sector and were influenced by flotation theories. However, when the knowledge of lattice defects and the semiconductivity of minerals became known and their importance in extractive metallurgy was realized, there was a need to explain the leaching reactions in light of these modern theories (Habashi, 1969, 1970). Semiconducting minerals of importance in metallurgy are two categories: the sulfides such as those of copper, lead, zinc, and the oxides such as those of uranium."

Jan 1, 2016

By K. Chomyn, R. Veenstra, P. Zangeneh, Hatch Ltd., C. Van der Woude, H. Ghorbani

"The furnace is the heart of smelting operations, and therefore the performance, reliability, and campaign life of the furnace are critical considerations. Furnace refractory is exposed to high temperatures and other harsh operating conditions causing brick erosion, crushing, and cracking, typically limiting the furnace campaign life and requiring costly furnace shut-downs for refractory re-lining. Despite extensive study, the in-service thermal / mechanical stresses in these complex refractory systems are not generally well understood. Hatch has developed a thermal-mechanical finite element analysis (FEA) based furnace refractory modeling approach that allows for the quantification of refractory movements, load distribution, and thermal / mechanical stresses.Due to the complexity of the refractory system, a range of models are used to identify and assess damage mechanisms and design improvements, including: 2D models, to capture expansion and movement of individual bricks, changes to load paths, and thermal stresses; and 3D models, to include the effect of differential expansion between bricks in each course, and assess overall load distributions. The 2D and 3D analyses include the effect of nonlinear temperature-dependent properties, thermal expansion, movement of individual bricks with frictional contacts (i.e., gaps can open, bricks can slide), and brick tensile or compressive failure. Both as-built and damaged conditions can be investigated (e.g., after bath zone brick erosion), for circular and rectangular furnaces. 3D models also include papering and brick joint & interface action.Analyses using these models have shown the importance of thermal stresses, papering, and geometry / arrangement of individual bricks. Results have been used to identify and assess damage mechanisms, showing good alignment with furnace autopsy observations. By using this FEA-based approach to quantify the refractory design, the risk of damage can be significantly reduced, low-cost design changes can be identified, and the furnace campaign life can be extended.INTRODUCTIONThe furnace is the heart of smelting operations and therefore the performance, reliability, and campaign life of the furnace are critical to the success of the smelting operation. Furnaces are inherently exposed to high temperatures, often in excess of 1600°C (Holappa, 2004), and furnace operating power has progressively increased over time (Voermann, Gerritsen, Candy, Stober, & Matyas, 2004). The refractory system must withstand high temperature, high heat flux, and other harsh operating conditions. These conditions are particularly significant for the furnace hearth, and can lead to damage including brick erosion due to molten material flows, crushing due to thermal expansion loads, and cracking due to severe thermal gradients within the bricks. Refractory damage typically limits the furnace campaign life, requiring costly furnace shut-downs for refractory re-lining (repair or replacement). In some cases the refractory may lose integrity causing damage to nearby equipment and harm to personnel."

Jan 1, 2016

By R. Druffel, P. Wittke-Gattermann, M. Wittke

"The two tubes of tunnel Hirschhagen along the highway A44 in Germany, underpass the federal road B7, a railway line and the valley of the river Losse close to the city of Hessisch Lichtenau. The ground in the area consists of Triassic sand- and siltstones (""Buntsandstein"") as well as tertiary clays. Prior to tunneling, the groundwater in the area is planned to be lowered by means of a gallery of deep wells. As a basis for the design of this dewatering gallery, two large pumping tests have been carried out. The results of these tests have been evaluated by means of 3D-Finite Element analyses. By means of the large-scale model, the influence of the anisotropy resulting from jointing and bedding and the influence of fault zones in the area have been taken into account, which lead to a thorough basis for the design of the dewatering gallery.INTRODUCTIONThe 4.2 km long Tunnel Hirschhagen of the highway A 44 crosses below the federal road B7, a railway line and the river Losse close to the city of Hessisch-Lichtenau in central Germany. Both tunnel tubes are located in a subrosion depression in which Triassic sandstone and tertiary clay prevail. It is planned to lower the groundwater table in the area of the meadow of the Losse prior to tunnel heading [1]. Groundwater lowering is planned to be achieved by means of a series of large pumping wells. The bottom of the river Losse will be sealed in order to avoid direct inflow of water from the river into the ground (Fig. 1 and 2)."

Jan 1, 2015

By Troy Boisjoli

Since its discovery in February 2014, the Arrow Uranium Deposit has undergone rapid development through aggressive and systematic drilling programs and is now being progressed through advanced engineering and permitting. Based on the 2018 NI 43-101 Technical Report, the Probable Mineral Reserve estimate totals 234.1 million (“M”) pounds (“lbs”) triuranium octoxide (“U3O8”), contained in 3.43 M tonnes at an average grade of 3.09% U3O8. The proposed processing plant at the Rook I Project (the “Project”) will be capable of producing up to 31 M lbs of U3O8 per year, with a projected mine life of nine years based on the Probable Mineral Reserve estimate, although NexGen is permitting a 24-year operating life at the Project assuming the majority of Inferred Mineral Resources are upgraded to Indicated Mineral Resources with continued mineral resource development drilling. The Project will be developed through transverse and longitudinal longhole mining methods, pairing primary and secondary stoping techniques with a high degree of equipment mechanization which will provide a combination of good productivity, high extraction, and stable back support. This next generation of uranium operations combines the use of advanced tele-remote equipment and instrumentation with a low-cost bulk mining method and a best-in-class tailings management practice, effectively reducing operating costs and setting a new standard for elite environmental and social practices.

Jan 1, 2020

The mining industry has generally been slow to apply ion exchange processes to hydrometallurgical applications even if ion exchange offers an ideal solution for a particular problem. Two notable exceptions are in gold and uranium recovery. The largest application of ion exchange in the metals processing industry has been the use of resin-in-pulp (RIP) for gold recovery as an alternative to activated carbon. Iron is a ubiquitous impurity in hydrometallurgical solutions. In many cases, bulk removal of iron from the process solutions is accomplished by precipitation. However, precipitation for iron control is often accompanied by losses of base metals by co-precipitation. Increasingly, the option of ion exchange for removal of smaller amounts of iron from process solutions has been favoured. A number of applications have been developed and proven at the commercial scale for the removal/control of iron from a range of metal processing solutions. This paper provides an overview of the application of ion exchange for iron removal from a range of metal processing operations, including Cu, Ni and Co solutions. A number of case studies are provided which review operational and resin regeneration strategies and the impact upon the commercial operation of metal processing with improved iron control.

Jan 1, 2006

By Phillip J. Mackey, Susumu Okabe

Copper mining and smelting has been carried out in Japan for over 13 centuries and in fact stretching back into antiquity. In 1889, the first electrolytic copper refinery in Japan based on Elkington’s principles was started by Furukawa Mining at Honjyo in downtown Tokyo based on the multiple or parallel system. Within two decades, a number of other copper refineries had begun operation. Interestingly, but perhaps not surprising given Japan’s long history of copper production, this first refinery in Japan commenced just ten years after the first refinery in the USA (1879), and not long after the first plants in Europe. By 1935, as a result of growth in copper demand, there were six domestic copper electro-refineries in Japan with an installed capacity of 97,800 tonnes/a, while actual production was 71,200 tonnes/a. Since about 1932, the majority of these plants were based on the more common parallel or multiple system. In 1946, just after World War II, domestic production capacity had dropped considerably to 29,000 tonnes/a, however with reconstruction, capacity and production expanded rapidly, with production reaching 81,000 tonnes/a in 1955, 187,000 tonnes/a in 1960 and 307,000 tonnes/a in 1965. The introduction of the first refinery and the early ones that followed and subsequent developments are discussed in this paper. The major technical achievements during the high growth period from 1945 to 1963 included: the use of fire- refined anodes; the introduction of newly-developed rectifiers; the introduction of lead-lined or vinyl-lined concrete cells; improvements in the electrolyte heating system; application of improved anti-corrosion materials and the introduction of heat-insulating surface coverings. In 2018, Japan’s refined copper production totaled 1,595,000 tonnes of copper, with Japan ranking third in the world after China and Chile. INTRODUCTION In 2018, Japan’s refined copper production totalled 1,595,000 tonnes of copper and Japan ranked third in the world for refined copper after China and Chile (Wood Mackenzie, 2019). There are now eight copper refineries in Japan which provide Japan’s production of refined copper. These plants are listed in Table 1 (Wood Mackenzie, 2019), also showing the production trend since 2013; in general, production over this period has been relatively steady. The Toyo plant is now the 7th largest copper refinery in the world after several large plants as rated by capacity in China, Russia and India (ICSG, 2019).

Jan 1, 2019

By M. Fafard, F. Chevarin, D. Ziegler, H. Alamdari, M Kavand

"Carbon anodes, used in the Hall-Heroult process, are consumed by the electrochemical reaction to produce metallic aluminum. It is also consumed by parasitic reactions with air and CO2. The carbon anode is made of petroleum coke with different particle sizes, butts (recycled anodes) and coal tar pitch. The mixture of fine particles (less than 150 µm) of coke together with the pitch material forms a matrix, binding the large coke particles together. It is generally thought that the binder matrix is more reactive than the other anode constituents. This conjecture was not clearly proved in the literature. The present study is focused on the CO2 reactivity of binder matrix and anode constituents at 960°C, both under chemical regime (100% of CO2) and under a concentration gradient (diffusion). The apparent reaction rates of these materials were measured. The role of the binder matrix in anode consumption and its disintegration (dusting phenomenon) was discussed.INTRODUCTIONThe metallic aluminum production is one of the most important industries in Canada. The Al metal is obtained by the Hall-Héroult process. The principle of this process is the electrochemical reduction of alumina in molten cryolite carried out by an electrical current between carbon anodes and cathode at 960°C (Equation 1). The carbon anode is typically composed of calcined petroleum coke (65 wt.%) and recycled anode (called also butt, 20 wt.%) with coal tar pitch (15 wt.%), playing the role of cement to ensure the cohesion of the anode block."

Jan 1, 2016