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By M. C. Villeneuve, P. A. Siratovich

We present an integrated analysis of laboratory-based thermally induced fracturing and results of numerical models to give insight to the role of thermal shock fracture on geothermal reservoir rocks. Thermal stimulation is a reservoir permeability enhancement technique applied to commercial geothermal reservoir rocks to enhance fluid injection capabilities for spent power plant working fluids. The process is well known to enhance permeability but the thermodynamic and physical constraints of the process are less certain. In an attempt to constrain the interaction and the ideal conditions that lead to permeability enhancement, experimental procedures were carried out to mimic the conditions that a reservoir rock would experience during a thermal stimulation using temperature differentials ranging from 50-300°C. Samples underwent such thermal gradients under controlled laboratory conditions and were characterized for the changes to permeability, porosity, ultrasonic velocities, dynamic elastic moduli and petrological changes. The thermal stimulation was simulated in a FLAC2D thermal numerical model to investigate the nature of the thermally induced changes in the sample. The development of this model also allows us to investigate the relationship between geological characteristics and the ability to thermally stimulate any type of rock. The results indicate that numerical thermal shocking experiments are corroborated by laboratory-based results. The implication of this study is that the refined numerical models present an insight to the conditions and constraints under which thermal stimulation can prove to enhance permeability that could not be gained through purely laboratory-based studies.

Jan 1, 2015

By S. Wood

"Plastic Filled Valley (PFV) wire rope represents a significant development over the design of conventional wire rope. A sealing thermoplastic is impregnated under controlled conditions of temperature and pressure into a conventional lubricated wire rope to produce a lattice of plastic which surrounds and separates the strands from each other and from the core. Metal-to-metal contact is thereby alleviated and the lubricant is sealed in. The wear resistance, rope breaking load, fatigue resistance and crushing resistance are all increased. The result is a rope which offers exceptional service life.Laboratory tests carried out in Canada and at the University of Stuttgart, in West Germany, confirm the increase in fatigue life. The field trials conducted so far have indicated that the results obtained in the laboratory can be duplicated in the field.IntroductionIn times of double -digit inflation, the consideration given to operating costs throughout industry commands considerable attention. The same can be said of the mining industry. A set of large-diameter wire ropes used on the huge draglines in strip mining can cost in excess of $100,000. Because a machine may use three sets of rope s each year, it is clear that the costs of wire rope can contribute a considerable percentage to any operating budget. As wire rope is a product which is used extensively throughout the mining industry, it would appear timely to turn our attention to any ""Method of Extending Wire Rope Service Life"" in order that wire rope life can be optimized and wire rope costs can be minimized."

Jan 1, 1982

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005

By F. Habashi

"Extractive metallurgy was divided into the three sectors pyro-, hydro-, and electrometallurgy in 1959 when Professor Joseph Newton at the Idaho School of Mines in Moscow mentioned this in his book Extractive Metallurgy. Pioneer hydrometallurgists who built this discipline can be traced to the alchemists in the ninth century. It is now a mature subject of great importance in which pressure plays a vital role. Short biographies of some hydrometallurgists and the processes they invented are briefly outlined.INTRODUCTIONHydrometallurgy is the use of aqueous solutions to recover metals from ores. It is a relatively new discipline when compared with pyrometallurgy the use of fire to melt ores and recover metals which was practiced in ancient times. Hydrometallurgy can be traced to the time of alchemists whose concern was the transmutation of base metals into gold. Although alchemists did not succeed in their venture yet they described many reagents that are useful today. For example, they prepared sulfuric acid by distillation of iron vitriol, muriatic acid by distillation of sulfuric acid with salt, and nitric acid by reaction of sulfuric acid by reaction of sulfuric acid with salpeter. Jabir Ibn Hayyan the Muslim alchemist who lived in the ninth century (Figure 1) described aqua regia a mixture of nitric and hydrochloric acid that can dissolve gold although either acid has no action on gold. THE MIDDLE AGESIn the Middle Ages, it was reported that copper was recovered at Rio Tinto in Spain by allowing copper-containing pyrite to be exposed in piles to the action of air and rain. Copper sulfate solution obtained was treated with pieces of iron to precipitate metallic copper—a process that was called cementation. Georgius Agricola (1494–1555) (Figure 2) a medical doctor in Saxony who used to visit mines and smelters to examine miners and metal workers, described in his book De Re Metallica the parting of gold, i.e., separating of silver from gold by acids."

Jan 1, 2016

By P. Garritsen, J .. A. Blanco, M. C. Bell

"By 1994, Inco Limited will lower sulphur dioxide emissions from the Copper Cliffsmelter by 60% to 265 000 tonnes/year, primarily through implementing two key process changes. First, new milling technology will permit economic rejection of additonal pyrrhotite prior to smelting. Second, a bulk coppernickel concentrate will be oxygen flash-smelted, thereby eliminating the existing multi-hearth roasters and reverberatory furnaces . All copper will be recovered in the matte separation plant as a nickeliferous chalcocite, and will be oxygen flash-smelted for blister production. This paper outlines the development of the project and describes the process, including the flash furnaces, new sulphuric acid plant and additional oxygen plant.IntroductionInco 's SO2 Abatement Program will lower sulphur dioxide emissions at Sudbury from the current levels of 685 000 tonnes per year to 265 000 tonnes per year by 1994 as required by Ontario' s countdown on acid rain regulations.It is the high tonnage of sulphur mined that creates the magnitude of the SO2 emission problem at Sudbury. At a production rate of 240 million pounds of nickel per year, Inco mines 12 million tonnes of ore. At 10% sulphur it mines 1.2 million tonnes per year of sulphur. If Inco did not fix any of this sulphur it would be emitting 2.4 million tonnes per year of sulphur dioxide-about as much as all other Canadian emissions. Today, however, Inco is already fixing 70% of the SO2 in ore, in several ways : mostly as sulphur in pyrrhotite rejected to tailings in the milling operations; as acid from the roasting of pyrrhotite and some nickel concentrate at the Iron Ore Recovery Plant (lORP) and some as liquid S02 from the copper flash smelting furnace. By fixing 70% of the sulphur the current allowable SO2 emission levels of 685 000 tonnes per year is met. Total sulphuric acid production is currently 450 000 tonnes per year and in fact, the 10RP operation is being continued only to maintain established acid markets.Historically emissions have been reduced from the 2 000 000 tonne per year level to the current level of 685 000 tonnes per year by rejecting pyrrhotite from the smelter feed, and 70% of the SO2 containment problem at Sudbury has already been addressed.While Inco's profits are large at current nickel prices, most people have forgotten that back in 1982 Inco was losing a million dollars a day. Inco did make a dramatic response to this economic stimulus. The Ontario Division increased productivity by 65% and lowered costs to become the lowest cost nickel producer."

Jan 1, 1990

By J. G. Whellock, R. J. Phillips, J. W. Matousek, P. J. Marcantonio

"Stillwater Mining Company (SMC), a partnership of Chevron Resources and Manville Corporation, produces a copper-nickel, platinum-palladium flotation concentrate at its Nye, Montana mine. The concentrate is then toll processed in Europe. Recognizing the economic advantage of treating the concentrates at the mine site and of retaining this strategic resource in the United States, the Company commissioned Tolltreck International Limited and International Process Research Corporation to conduct pilot scale smelting tests with a flowsheet that would maximize metal recoveries while satisfying the environmental requirements of operations at Stillwater.Primary smelting was conducted in a single phase, 50 k W, submerged-arc, electric furnace. Refining the product mattes to copper-nickel ""white-metal""; containing approximately 2% iron, was accomplished in a Tolltreck, IV-litre, top blown rotary converter. Over-all platinum and palladium recoveries were approximately 99%; copper and nickel recoveries averaged 94%. INTRODUCTION(l-4)Stillwater Mining Company (SMC) a partnership of Chevron Resources and Manville, operates a copper-nickel, platinum palladium mine and concentrator at Nye, Montana, located in the valley of the Stillwater River, approximately, 100 km southwest of Billings. It is North America's only primary producer of these precious metals. The Stillwater area was mined for chrome ore during World War U and the Korean War, but it was not until 1961 that attention was drawn to the similarities between the Stillwater Complex and the Bushveld Complex of South Africa with its deposits of platinum group metals.A concentrated search for platinum was begun by Manville Corporation in 1967. Its presence, together with palladium, in mineable quantities was confirmed in the period 1976-1978, and the first partnership to develop the deposits was formed by Manville and Chevron in 1979. Anaconda joined the group in 1983, and in 1985 its share was purchased by Lac Minerals. In 1988 the interests of Lac Minerals were purchased by Chevron and Manville.The decision to develop the mine and build a concentrator was made in 1986. Construction began in the fall of that year, and the first concentrate was produced six months later, in March 1987. Underground mining is done in a two-shift, five day- week operation. Since startup, the concentrator has operated on a 24 hour/day, 7 day/week schedule, treating an average of 635 tonnes of ore per day and producing approximately 10 tonnes of concentrate."

Jan 1, 1989

By M. M. Papic

"This paper describes the Sasol coal liquefaction process, as used in South Africa. It covers coal supply, coal gasification, gas purification, Fischer-Tropsch synthesis, the major utility systems involved and the economics of the process.IntroductionThe Sasol coal liquefaction process is based on Fischer-Tropsch synthesis of liquid fuels from carbon monoxide and hydrogen, which are in turn obtained by gasification of coal with steam and oxygen. The process is shown schematically in Figure I.The first step in the process is coal preparation, in which the coal is crushed and screened to a 3-50 mm size for gasification on one side and to -3 mm size for steam and power production on the other. Oxygen needed for coal gasificatoin is produced in the air separation plant.Coal is gasified under pressure by steam and oxygen in the Lurgi gasification plant, where raw, impure gas is produced . The raw gas is first washed in a scrubber with a circulating gas liquor, heat is then recovered from it in a waste heat recovery boiler and the gas is further cooled for purification. Water-insoluble materials (tar oils) in the gas liquor are separated from aqueous solution and sent to tar refining for the recovery of tar products. The aqueous portion of the gas liquor goes to a Phenosolvan solvent extraction process, where phenols and ammonia are recovered. Water then proceeds to the effluent treatment plant.The scrubbed and cooled raw gas goes to a Rectisol gas purification plant, where all components other than hydrogen, carbon monoxide and methane are removed as completely as possible by absorption in refrigerated methanol. The acid gases (CO2, H2S) stripped from the methanol in the Rectisol unit are processed in a Stretford plant for recovery of sulphur. Regenerated methanol is returned to the process. The purified synthesis gas is passed to the fluidized-bed Synthol reactors, where Fischer-Tropsch synthesis reactions take place.The synthesis products are recovered in a product recovery unit as separate streams of decant oil containing higher-molecular- weight hydrocarbons, light oil comprised of lower-molecular- weight species, the aqueous stream containing water solubles, a C3/C4 stream, a C2 stream , a methane stream and a hydrogen-rich stream. Most of the hydrogen is recycled to the Synthol reactors; a major portion of the methane is reformed to hydrogen and carbon monoxide for recycle; the C2 fraction goes to an ethylene plant; and liquid streams proceed to the product refinery.The product refinery is used to upgrade and purify the Synthol products to specification fuels and chemicals.Sasol l, the first coal liquefaction plant in South Africa , was built in 1955. It is still operating and has a product output of about half a million tonnes per year. The Sasol II plant is in a commissioning stage and will be in full operation in 1981. It is about five times the size of Sasoll. It uses over 12 million tonnes of coal and produces more than 2 million tonnes of saleable products annually (1,2,3). The Sasol llI plant, which is a mirror image of Sasol II, is under construction and scheduled for completion in 1983."

Jan 1, 1981

By Henry Smith, Stu Brown

"The Williams Mine is Canada's largest gold producer, with annual production of some 500 000 ounces of gold from two million tonnes of ore. Highly mechanized and automated underground mining practices are utilized at the property in order to help achieve high levels of productivity and the most cost-effective mining possible.Planning and design parameters for the underground ore handling system at the Williams Mine are described in this paper. Particular reference is made to the considerations that were built into the system to provide maximum operating flexibility through the use of multiple orepass systems, portable low profile jaw crushers, underground conveyors and automated hoisting equipment.IntroductionThe Williams Mine is situated in the Hernlo area of northwestern Ontario, approximately 40 Ian east of the town of Marathon (Fig. I). It is operated by the Williams Operating Corporation, which is owned equally by Teck Corporation and Corona Corporation, and is one of three adjacent properties forming the HernIo gold camp.The mine commenced operation in October 1985 at a nominal production rate of 3000 tpcd. Through an ongoing capital development program, winch was completed in late 1989, the production rate at the property was increased to its current level of 6000 tpcd. This paper describes the mine planning process and the evolution of current mining strategies with particular reference to the underground ore handling system .HistoryGold mineralization was discovered in 1944 in the Hemlo area of Northern Ontario, near the north shore of Lake Superior. A year later, 11 claims were staked over the showing and subsequently patented by the late Dr. Jack Kerr Williams.Over the next 35 years, other claims were subsequently staked, explored and abandoned in the immediate area of the 11 patented claims . In 1980 a predecessor of the Corona Corporation acquired claims adjoining the Williams property to the east. Drilling on this claim group started early in 1981 and intersected the Hemlo orebody in May of that year. In December 1981, Corona Corporation entered into an option agreement with Teck Corporation to explore and develop the property.A drilling program by LAC Minerals on the II patented claims discovered the Williams orebody in March 1982. The mine started production in 1985, pouring its first official bar of gold on December 6 of that year. Corona Corporation was awarded ownership of the Williams Mine conclusively by a decision of the Supreme Court of Canada on August 11, 1989. The court's ruling ended a legal dispute with LAC Minerals over the property initiated eight years earlier."

Jan 1, 1991

The paper will cover the basic reasons for alkaline leaching, a brief description of the circuit and the reasons for the flowsheet used. Changes made to the flowsheet, including the use of mechanical agitation of pachuca slurry, the use of oxygen and its effect on extraction, the use of lime and its effect on process economy, and the environment, will be described. A brief description of a unique semi-autogenous mill and future circuit changes will be included.

Jan 1, 1979

By F. Weinberg

"The recent development of the continuous casting process for steel has required basic understanding in a number of areas in the metallurgcal sciences. In some areas, information is still lacking. The success of the application of basic knowledge and research to the process is evidenced by the fact that a large percentage of the steel now produced in the world is produced by continuous casting.A number of areas in which metallurgical science has contributed and is currently contributing to better design and control of the continuous casting process and leading to a better quality product will be considered. These include:(a) heat transfer studies of the entire casting process;(b) fluid flow in the tundish, strand and liquid metal stream;(c) solidification structure and segregation;(d) strength and ductility of steel at high temperatures related to bulging and cracking; and(e) problems related to horizontal casting developments.IntroductionThe continuous casting of steel is a relatively new technology in steelmaking. It is now used extensively throughout the industry. In Japan, for example, continuous casting accounts for approximately 40010 of steel production, and this value is expected to increase to over 50% in the near future . New steel plants are now designed to use continuous casting exclusively. This means the process must work well and be completely reliable, because all the steel produced must go through the caster.The development of the continuous casting process in a short period of time has required concerted research and development in many areas . I shall cite a number of examples of these developments and refer to work done in Canada when applicable. No attempt will be made to review all of the research in continuous casting, nor refer to all of the workers in the field.The developments in continuous casting are based in many cases on metallurgical science, as described below. The use of metallurgical science in these developments is qualitative, in that concepts and idea s are used, as opposed to quantitative values calculated from fundamental equations. In general, most metallurgical problems are too complicated to enable fundamental equations to be used without the introduction of uncertain approximations and boundary conditions in the calculations.Starting at the beginning of the steelmaking process, very extensive research and development has been carried out to produce liquid steel of the required composition and temperature. The replacement of open hearth furnaces with BOF furnaces reduced refining time from many hours to roughly 30 minutes for 250 tons of steel. Two BOF furnaces effectively enable a continuous flow of steel to be available in a plant, essential for the introduction of the continuous casting process. This area of research will not be considered here."

Jan 1, 1981

By A. A. Shirzadi, E. R. Wallach

"Liquid gallium has been used successfully to modify/remove the surface oxides prior to diffusion bonding similar and dissimilar nickel-base superalloys. Using this approach, bonds in nickel-base superalloys with ""virtually invisible interfaces"" were produced, and the compositions in the bond region were very close to those of the bulk alloys. Room temperature tensile and bend tests showed no preferentially failure at the bond lines. Creep tests on samples made between two different Inconel alloys also showed failure away from the joint, i.e. in the parent metal of the Inconel alloy with lower creep resistance. The high temperature lifetimes of these samples were as long as those of the unbounded Inconel, confirming that the joining approach has no adverse effect on the nickel-base superalloys being joined."

Jan 1, 2006

By A. Dolatmoradi

Nanocrystalline structure formations produced by severe plastic deformation in Fe-0.15C with initial ferritic-pearlitic and IF steel with ferritic microstructures have been studied through microstructural observation and microhardness measurements. It was found that the nanocrystalline region first forms near the surface of samples due to localized severe deformation. It was also observed that the nanocrystallization rate of Fe-0.15C and IF steels and the deformed layer thickness in these two materials are different with similar milling conditions. The crystallite size and structural evolution of the samples during milling was studied by employing XRD and SEM.

Jan 1, 2010

By Bong Sun You

AZ31 magnesium plate of 300mm in width and 40mm in thickness was produced by horizontal continuous casting machine, and its microstructures were analyzed on the surface and in the plate interior. The defect formation on the surface and subsurface, such as side cracks, buckling, pores and segregation, was very sensitive to the casting condition and processing parameters. Especially, casting speed and secondary cooling were the most dominant parameters to control the solidification behavior of magnesium melt, for example the position and shape of the solid/liquid interface in the mould. The cyclic marks on the surface were obvious because the plate were drawn by 4-step cycle and can not be removed. The average grain size of as cast plate measured as 50-65µm at the near surface and 300-400µm in the center of the plate was relatively small because secondary cooling water was applied to control the surface quality resulting in rapid solidification of the melt in the mould.

Jan 1, 2006

By H. Vermette, J. Demers, R. Leclerc, P. Bergeron, P. Hudon, A. Lessard

The Arvida Smelter marked its 80th anniversary in 2006. Arvida currently operates 6 potrooms equipped with prebaked side-feeding pots producing 160 000t of aluminum per year, requiring the supply of 300 000t of alumina per year. In the past, to ensure reliable alumina supplies to the pots, especially in winter, a safety stock of alumina was kept inside the plant. The improved reliability of shipping on the Saguenay River has cut the need for such a stock. However, the stoppage of 8 Soderbergtechnology potrooms, starting in the 1980s up to 2003, generated alumina from the cleaning of pot pits, totaling 18000t and leading to the building-up of a significant alumina stock again. Concerns over working conditions, effect on potroom operations, and dust emissions prevented Arvida from tackling effectively this impressive alumina stock. Yet the increasing cost of alumina has created a strong motivation to use the stored alumina. In 2004 Arvida launched a project to recycle the stored alumina. This 4-year project aimed at clearing the alumina stock without affecting the operation of the smelter. It involved changing work organization, improving equipment and controlling the effect of the recycled alumina on the smelting process and working conditions.

Jan 1, 2006

By Brennan Lang

Why Seal Tunnels? ?Restore groundwater levels to pre-mining conditions. ?Saturate rock mass to reduce acid rock drainage. ?Reduce discharge flow to the environment. ?Reduce or regulate flows to a water treatment plant.

May 1, 2002

By Blair Hrabi

Introduction; ?Risks Associated with the Resource Estimation Process; ?Limitations of Available Data; ?Geological and Structural Control of Mineralization Trends; ?Recognizing Multiple Mineralization Controls and Complex Trends; ?Accurate Geodomaining; ?Conclusions.

May 1, 2013

By M. Tanaka, Y. Sato, H. Narita, S. Alam, T. Ogata

To ensure a stable supply of rare earth elements (REEs), it is highly necessary to establish the corresponding recycling technologies for RE magnets and phosphors in inplant wastes and endoflife products. Solvent extraction using 2ethylhexylphosphonic acid mono2ethylhexyl ester (EHPNA) is often applied in the separation and purification of REEs. In this study, the equilibrium distribution ratios of neodymium and dysprosium between 1 mol/L nitrate solution and the EHPNA in an alkane diluent were measured at 298K. The experimental data were analyzed by correcting the nonideal behavior of the organic phase using the Alstad empirical equation under the assumption that a complex with a molar ratio of 1:6 (REE:extractant monomer) was formed. The model correlated well with the experimental data and the extraction equilibrium constants were obtained. The extractant equilibrium constants obtained by this methodology would be useful in the design of REE recycling processes using solvent extraction.

Jan 1, 2014

By E. A. Hart, J. E. Gill

"The property of Arntfield Mining Corporation, formerly Arntfield Gold Mines, Limited, covers an area of 2,110 acres and lies in Beauchastel township, western Quebec. The Francoeur mine lies to the west, and to the east are the West Wasa and Wasa Lake properties.The property was staked in September, 1923, by the late F. S. Arntfield. The early surface work was concentrated in the west part of the property along the Francoeur-Arntfield shear zone. The zone was opened by No. 1 shaft, which was sunk for an inclined depth of 250 feet. A series of silicified lenses were discovered farther east, where No. 2 shaft was later raised to the surface. A third shaft explored a shear zone about 1,900 feet to the east, where No. 3 shaft orebodies were developed.The mill was built at No. 3 shaft and production commenced in July, 1935, at 125 tons a day. This was increased to 280 tons by 1938, and later to 350 tons. The mine continued operations on this scale until April, 1942, when the exigencies of war necessitated closing. The Company was reorganized in 1944 and underground development was resumed in June, 1945. The total value of gold and silver produced to April, 1942, was $2,011, 755 from 529,987 tons of ore.ROCK TYPESThe area is underlain by highly deformed and altered Keewatin volcanics overlain by little deformed Cobalt sediments along the south boundary. The lavas in the vicinity of the mine workings are rhyolite, trachyte, andesite, and a flow breccia of intermediate composition. The fragmentals range from fine, well-bedded tuffs to coarse agglomerate in which acidic and basic horizons can be distinguished.The intrusive rocks are diorite and quartz-feldspar porphyry in the form of stock and sills, and narrow dykes of mica lamprophyre and syenite porphyry."

Jan 1, 1954

By O. Lashkari

Swirled Enthalpy Equilibration Device (SEED) is a new patented Slurry-on-Demand, SoD, processing route. The semi-solid slug preparation is carried out by off-center swirling of aluminum melt in a metallic mould. As part of the current research program on the semi¬solid processing of aluminum alloys, the morphological evolution of 356 aluminum foundry alloy microstructure is reported here. Semi-solid slugs were prepared using two different pouring temperatures of 645°C and 695°C respectively. Morphological evolution of the semi-solid microstructure was characterized using image analysis through measuring of primary a-Al particle size, number density, aspect ratio and sphericity. The possible relationships between microstructural features and process parameters were also investigated. The current report covers the effect of pouring temperature on the morphology of primary a-Al dendrites and attempts are made to explain the differences between the predicted percentage primary a-Al phase and those of the actual values in the as-cast slugs.

Jan 1, 2004

By J. Ipinza, J. P. Ibáñez, Casas J., S. Cortés

Copper powder generated during the treatment of electro-metallurgical bleeds by reactive electro- dialysis (RED) had totally reduced the content of ferric ions in acidic synthetic electrolytes (Cu (II)- Fe (III) – H2SO4). In batch and columnar experiments 100% of the ferric ions were reduced to ferrous ions with an extremely high kinetics. A preliminary conceptual design for reducing ferric ions based on an integrate RED- Column for treatment of electro-winning bleed system is discussed. This system is able to recover simultaneously sulfuric acid and copper powder, which will reduce ferric ions. INTRODUCTION It is well known the negative effect of ferric ions in the copper electro-winning process. The increase of ferric content in the electrolyte reduces the current efficiency, i.e., there is an increase in the energy consumption, and changes the surface morphology of the copper deposit (Das, Gopala & Krishna, 1996; Vargas & Parra, 2013). The increase of the specific energy consumption due to the loss of current efficiency occurs by the reduction reaction of ferric to ferrous ions in the cathode, at the anode the ferrous ions are slowly oxidized to ferric ions (Shaw, Dreisinger, Lancaster, Richmond & Tomlinson, 2004). To control the level of iron in the electrolyte, bleeds are needed; this bleed electrolyte containing copper, sulfuric acid, cobalt, iron and other impurities normally is waster, which increased the production cost of the plant (Milbourne, 2002; Mckevitt & Dreisinger, 2009). Then, permanent efforts oriented to treat those bleeds to avoid losses of valuables components are made; among them are use ion exchange resins (Shaw et al., 2004; Mackevitt et al., 2009), chemical precipitation (Izadi, Mohebbi, Amiri & Izadi, 2017) and electrodialysis (Cortés, Ipinza & Ibáñez, 2013). The last one allows to the simultaneous recovery of sulfuric acid and copper powder. If one of the valuables obtained by treating the bleed can be used to reduce ferric ion concentration in the electrolyte could be an important asset. This issue at laboratory scale is reported in this work, the use of copper powder, generated by reactive electro-dialysis when treating synthetic acidic electro-metallurgical bleeds, for reducing ferric ions in acidic electrolytes.

Jan 1, 2019