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By P. R. Goad

"Kidd Creek is a large volcanogenic base metal sulphide deposit, located near the west end of the Abitibi greenstone belt, 27 km north of Timmins, Ontario. The rhyolite geology is characterized by a NNE-striking and steeply east-dipping package of rhyolite volcaniclastics upon which has been imposed a strong ESE-striking and north-dipping structural fabric . Massive rhyolite units with grey-black. chloritic cores and yellow, sericitic margins intrude as dykes into the stratigraphic footwall and as sills higher in the stratigraphy. Massive rhyolite units positioned near the top of the felsic pile exhibit an extensive marginal development of hydraulic fracturing and are termed crackle-brecciated rhyolite.The stringer sulphide zone is positioned in a lobate blanket of crackle-brecciated rhyolite at the top of the felsic pile. The stringer sulphide zone is characterized by a mature chemical alteration, being specifically depleted in alkalis and enriched in iron-rich chlorite. with accompanying silica, sericite and carbonate alteration. A suite of trace elements characterizes this mature alteration. The massive rhyolite units, which intrude lower in the rhyolite volcaniclastics, exhibit a core of weak chlorite alteration and strong marginal sericite alteration. Tight or unfractured massive rhyolite units are essentially devoid of sulphide mineralization and exhibit a suite of trace elements characteristic of this immature alteration. It is interpreted that the massive rhyolite units intruded into an already evolving system and ""choked-off"" active conduits carrying hydrothermal fluids and subsequently acquired an immature alteration signature. Rhyolite units positioned higher in the pile developed intense hydraulic fracturing and a mature alteration coincident with the formation of the stringer sulphide zone. In summary, a model, based strictly upon the rhyolite geology, is reviewed to assist in the exploration for volcanogenic base metal sulphide deposits."

Jan 1, 1985

By Lloyd A. Clark

"The kuroko deposits, which are extremely variable in size, comprise both stratiform layers of clastic sulphide particles and cross-cutting vein and disseminated components. The ores lie on the flanks of rhyolitic lava domes which have risen from a postulated subvolcanic magma chamber that provided cupriferous hydrothermal solutions and also acted as a heat source driving ground-water convecting cells. The polymetallic sulphides precipitated initially in explosion craters, pipe fillings and feeder veins as rising hydrothermal solutions mixed with sea water. As sulphides clogged the plumbing system, minor phreatomagmatic explosions produced layers of sulphide fragments on the adjacent sea floor. One to ten repetitions of this process produced multiple fragmental sulphide beds. Each deposit formed in a relatively short space of time, because only minor tuff beds are intercalated in spite of active volcanicity in the region. In this model, the heated ground waters convecting through thick piles of acidic pyroclastic rocks leach the zinc, lead and barium later deposited as kuroko ores. As the subvolcanic pluton cools, the supply of silica and copper wanes and the minor counter-circulation cells above the pluton are replaced by main cell fluids bearing zinc, etc. This change in solution flow is abrupt rather than gradual, as the plumbing system is somewhat disrupted by the magmatophreatic explosions that create each ore layer.IntroductionKnowledge of the kuroko deposits ha s greatly expanded during the 25 years since modern recognition of their volcanogenic origin. However, one aspect of the ore s, which may be of unique importance in their genesis, has received little attention. That is the fragmental character of much o f the sulphide ore, which was briefly referred to in a previous publication (Clark, 1971) and is examined in more detail by Barton (1978). Most researcher s have concentrated their attention on or e deposition above and beyond the vent, which is inconsistent with the geology."

Jan 1, 1983

By B. Tougas

Recycling of titanium represents an important economic activity due to high cost of the material and the amount of returns of machined parts which represent the bulk of finished titanium products (typical "buy to fly" of 10 in the aeronautic industry). In the present work, the metallurgical quality of 76 mm in diameter and 20 cm ingots poured in coated graphite mold will be assessed against the nature and condition of application of 4 coatings namely aluminum oxide, yttrium oxide, zirconium oxide and zirconium oxide with 4% aluminum oxide. The metallurgical quality has been evaluated in terms of alpha case thickness, microstructure and composition. Microhardness from surface will be assessed against casting conditions. Least square regression analysis have been use to optimize casting conditions.

Jan 1, 2011

By E. M. De Souza, A. M. Coode

"Since potash was discovered substantial rock mechanics research has been done to develop the technology needed to cope with the unique conditions in Saskatchewan mines, to assure general mine safety and to assess the problems associated with mining potash at depth.The practical result of this research was the development of multiple entry systems incorporating yielding pillars for access ways and the chevron type layouts for production panels. These developments proved the viability of extracting potash from between 950 m and 1100 m depth using a high degree of mechanization. High extraction ratios could not, however, be achieved using the developed technology.The presence of a competent salt back is critical to mining the potash, and underground practice is governed by the presence of anomalous geological zones. These factors may be associated with the occurrence of brine inflows. One potash mine in Saskatchewan ceased its underground operations and was closed due to flooding of the entire mine. Two other potash mines in Saskatchewan had significant brine inflows. The costs involved in brine pumping, equipment relocation, bulkhead construction, grouting, and in auxiliary operations can run into the tens of millions of dollars.At Central Canada Potash, the use of stress relief and yielding pillars in the design of the mining layouts has resulted in over-all stable underground excavations and safe mining practices. There are two types of production room s, the chevron and the hybrid, which result in a planned block average extraction ratio of 35010. Mining activity has resulted in brine ingresses in two areas, and additional operating costs have been incurred over the years. These mining areas have demonstrated abnormally high closure rates, and rapid back deterioration. A program was established in those two areas to ensure the practice of safe mining procedures.The short-term perspectives inherent in the program included the elimination of all uncertainties associated with the possibility of an increase in brine inflow leading to flooding, the elimination of the abnormal ground behaviour and ground deterioration in the inflow areas, and the reduction of the long-term adverse effects of mining on regional mine stability. The program was also designed to provide means for developing alternative safe mine layouts which would improve the exploitation of potash resources. Details of the extensive work performed during the program are found elsewhere (E. De Souza, 1988).Grouting and salt backfilling are viable techniques to control brine inflows in underground excavations in potash mines. Detailed instrumentation of the backfilled test areas provides information on the long-term behaviour and effectiveness of the grout/backfill system, allowing for rational decisions on the complete abandonment of these mined out areas, thus resulting in considerable operational cost savings.This paper is presented in two parts: the first addressed the problems of diamond drilling , grouting and backfilling in Panel 209 and the second, addresses the problems of instrumentation and rock mechanics."

Jan 1, 1990

By L. A. Clark, G. H. R. Burrill

"Most unconformity-type uranium deposits in Saskatchewan occur within a few tens of metres above and/or below the basal unconformity of the 1,45-b.y. Athabasca Sandstone. Graphitic basement rocks coincident with post-Athabasca faulting or brecciation at or near the unconformity are important in localizing uranium deposits which form as tabular, ribbon-like bodies with grades averaging over 2 per cent uranium and containing up to 50,000 tonnes UJOs. Some of these deposits have similar contents of nickel and arsenic.In the genetic model proposed to explain these deposits, traces of uranium were leached from the sandstone and weathered basement rocks by oxidized formation waters sweeping through the sandstone and along brecciated faults. Over basement meta-petites, a thick clay regolith adsorbed uranium from the solution. Thus fixed, the uranium was reduced through an indirect reaction with graphite, possibly involving methane. The clay mineral surfaces were thus continuously cleared to allow further adsorption. Basement faults localized along weak graphitic units were re-activated, offsetting the sandstone formation, probably at the time of an early uranium deposition about 1.2 b.y. ago, and served as vents for spent ore solutions. Fluid convection was induced by topographic relief and/or crustal heating from radioactive decay in basement plutons or mantled Archean domes with uranium and/or thorium contents a few ppm above those of adjacent rocks. Heat from radioactive decay within the incipient uranium deposit would develop in about a million years. The self-generating convection cell would continue uranium deposition until all permeability was plugged by minerals. In some instances, convection was re-initiated after subsequent faulting and brecciation. While some deposits were further enriched, heavy flows of oxidized fluids re-dissolved and partially depleted other uranium deposits.The East Alligator Rivers uranium deposits in Northern Territory, Australia, occur within Middle Proterozoic quartzchlorite and quartz-muscovite schists overlain by sandstone. Highest grades occur in silicified breccias where carbonate beds were leached out. Mineralization ages are both pre- and post-Kombolgie Sandstone, but, to date, no significant uranium mineralization has been encountered in the sandstone. There are many general similarities with Saskatchewan deposits, but important differences in detail."

Jan 1, 1981

By Michael K. O’Leary, William D. Coplin

"Risks from political instability and government policies restricting equity ownership, local operations and transfers of payments affect the profitability of foreign mining ventures. More than seat-of-the-pants judgments and old-boy networks are required to anticipate these risks and to take actions appropriate to offsetting them. A system for making political forecasts, called the Prince System, and a series of charts relaying risk s to a production of key minerals will be presented.IntroductionFirm s with extractive operations outside their home country do not have to be told that political stability and government decisions play a big role in the success o f their operations. The takeover of copper firm s in Chile during the Allende administration in 1971 and the recent decision by Venezuela to reduce Reynolds Metals equity share in a smelting operation from 50% to 28% are two examples of hundreds of events that have determined the profitability of extractive operations over the past decade. Both risks and opportunities for international firms seeking to produce and market raw materials are heavily affected by political conditions. While news of political events travel much faster than in the past and host governments are more clever in shaping the risks as well as the opportunities, politics has always been part of the mining business.What has changed is the need to be more systematic in approaching the assessment of political conditions and how it affects business. The increasing costs of extractive operations, the need for long-range planning, the importance of financial arrangements and the world-wide scope of man y firm s' activities require that the assessment be updated continuously and be comparable across different countries and different types of investments. Political risk analysis, the assessment o f macro-political changes and specific governmental decision s on the operations of extractive industries needs to become as systematic and integrated into corporate decision -making as economic analysis has become over the past two decade s."

Jan 1, 1983

By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

By Michel Gauthier, Jacque Trottier

"ForewordA symposium on base metal deposits was held in Bathurst, New Brunswick, from June 10-13, 1990, sponsored jointly by the Geological Surveys Branch of the New Brunswick Department of Natural Resources and Energy, the New Brunswick Prospectors and Developers Association, and the Geology Division of the Canadian Institute of Mining, Metallurgy and Petroleum. Papers prepared for the symposuim are being published as a series of articles in the CIM Bulletin. This third paper (the first was by Fyffe, et al., in Vol. 83, No. 938, the second is in this issue) in the series presents an overview of the tectonic setting and geochemistry of base metal deposits in the Eastern Townships of Quebec.ABSTRACTIt is well known that the classification system of volcanogenic massive sulphides (VMS) is based upon their metal content. This metal content, the result of hydrothermal solutions circulating within strata underlying the deposits, is generally thought to be related directly to two parameters: (1) the nature of the underlying stratigraphic sequence; and (2) the physico-chemical conditions that existed at the time of the hydrothermal event. Furthermore, these two parameters are, in turn, related to the tectonic setting. One must bear in mind that these parameters are diachronous and evolve with time. These factors are considered in our analysis of the major VMS deposits of the southeastern Quebec Appalachians. This analysis will describe the time and environment of formation of these deposits and integrate them into an evolving paleotectonic model.VMS deposits in the southeastern Quebec Appalachians formed during three distinct metallogenic episodes. During the first episode, which involved early closing of the Iapetus Ocean and associated destruction of oceanic crust by subduction processes(Early Ordovician?), cupriferous VMS deposits hosted by pillowed, mafic (boninitic) lava flows were formed in immature island-arc systems (""Cyprus-type"", e.g. Huntingdon deposit).In the second episode, which also occurred during the closure of Iapetus but at a later stage (Early to Middle Ordovician), mature island-arcs formed and hosted polymetallic VMS deposits (""Kuroko-type"", e.g. Eustis deposit).Finally, during culmination of the Taconic and/or Acadian orogenies (Middle Ordovician and/or Devonian), transtensional basins, associated with tholeitic to transitional mafic volcanism began to develop. Major sedimentation occurred contemporaneous with volcanism, and within this framework polymetallic VMS deposits were formed (""Besshi-type"", e.g. the Memphremagog deposit).Although incomplete, the proposed paleotectonic model represents the sequence of the tectonic settings that prevailed during the formation of the VMS deposits of the southeastern Quebec Appalachians."

Jan 1, 1991

By S. Esmaeili

The yield strength model developed by Esmaeili, Lloyd and Poole [1] has been adapted to model isothermal aging in Cu-containing AA6xxx alloys, with (a) a moderate and (b) a very low Cu content in the solution-treated, as-quenched, condition, Isothermal calorimetry has been used to analyze the kinetics of precipitation in these alloys, While the kinetic parameters for the low Cu alloy has been derived from the present experiments, the previously determined kinetic parameters for the high Cu alloy AA6111 has been used to model the precipitation kinetics in the moderate Cu alloy. The age hardening responses of both alloys have been well predicted by the model.

Jan 1, 2005

By George A. Guess

The making of contracts for the purchase of ores is a business which the metallurgist usually understands better than the miner. Companies in the custom ore business often employ an ore buyer who is aware of the class of ore which the smelter needs, and is thoroughly conversant with the business. The miner on the other hand makes ore contracts but seldom, and it is often only after a settlement has been made that he realizes the meaning of the terms of the contract under which he has sold his ores. He has expectations usually greatly in excess of the amount 'net proceeds' shown at the bottom of the settlement sheet. Seldom does the occasional shipper really know his contract. A somewhat similar parallel is to be found in insurance policies. We all have insurance policies; we never know the conditions contained in them until after the fire. The clauses in the policy are for the protection of the Insurance Company. An Insurance Company has no friends.

Jan 1, 1926

By H. Yasuhara, N. Kinoshita, S. Nakashima, K. Kishida

"In this study, flow-through experiments in fractured rocks have been conducted under different stress, temperature, and pH conditions so as to understand the evolution of permeability induced by these conditions. Throughout the experiments, the confining pressures and temperatures are well-controlled. Effluent concentrations are also measured for the ten elements of Si, Al, K, Fe, Ca, Na, Mg, Ti, S, and Cl that are included mainly in the targeted rocks. In the early stage of the experiments, the fracture permeability measured abruptly decreases with time, and subsequently reaches quasi-steady state within a relatively short period. In contrast, the permeability in the intact rocks monotonically increases with time. The permeability increase and decrease are attributed likely to the relative dominance of mineral dissolution in the pore spaces and to that of mineral dissolution/crushing at the propping asperities within the fracture and/or mineral precipitation onto the free surfaces, respectively. The evolving rates and magnitudes of the permeability are likely to be controlled by the stress exerted over the contacting asperities, temperatures, and pH of the permeant. Thus, this complicated behavior should be attributed to the coupled chemically- and mechanically-induced effects, which should be examined in more detail for longer period to contribute to the safe entombment of radioactive wastes. INTRODUCTIONUnderstanding of the flow and transport characteristics of porous/fractured rocks is required for the safe and long-term geological isolation of energy-related by-products (i.e., high level radioactive wastes and anthropogenic CO2). Notably, under relatively high temperature and stress conditions, mechanically- and chemically-mediated processes may alter the pore structures in rocks, resulting in an irreversible evolution of the flow and transport behavior. Augmentation in permeability may result from mechanical dilation due to shearing and mineral dissolution within the pore spaces, while reduction may result from reversible or irreversible mechanical compaction, mineral dissolution at the contacting areas, and clogging of pore spaces by precipitation of secondary minerals."

Jan 1, 2015

By G. J. Hutchins

Precision surface mining is gaining traction in the iron ore, copper, iodine, limestone, bauxite, coal and gypsum markets. In this paper, we first address the possible improvements of a surface miner control using GPS techniques. An application in an iron ore mine in Western Australia is presented. The second item addressed is improvements of a new drum driving technique for a 100 ton surface miner. This technique involves installing a slow speed hydrostatic motor directly on the cutting drum rather than driving the drum through chain and sprockets. Details of the performance of this direct-drive versus the chain-drive are detailed. In addition to the 100 ton machine, we also present a 200 ton surface miner. This larger machine has 1600 hp (894.8 kg), and has been successfully introduced into a large iron ore mine in Western Australia. Performance of the 200 ton surface mining machine in various rock hardnesses is detailed. Some comments on the cost effectiveness of using a built-in loader versus loading with wheel loaders are included.

Aug 1, 2013

By Deni Côte, Marcel Vallée

"The Guide to the Evaluation of Gold Deposits reviews the successive evaluation steps in the domains of geology, engineering, and economics. The Guide analyzes, in a systemic perspective, the sequence of exploration, development, and evaluation work required to bring a mineral deposit to production. The aim is to identify the metal/mineralization losses and ore dilution that each work step contributes to the evaluation and mining process. The procedure allows one to maximize the income and profits of a mining operation, and to reduce the risks of financial losses tied to investment decisions in the mining sector. For greater efficiency, the criteria of reserve estimation and classification should be integrated with the evaluation steps and methods. At earlier stages of deposit development, when quantitative knowledge is available mainly on the geological axis, the term ""delimited mineral deposit"" should be used. The term ""reserve"" should be used only in an operating mine or in a mining project, when information in the geological, engineering, and economic domains is adequate to ensure technical and financial feasibility. ""Reserves"" are by definition ""mining reserves"". Each category of proven/probable reserves and measured/indicated deposits should be subdivided into two classes to express better the many steps of mineral valuation. The category of ""possible reserves"" shall be replaced by that of ""inferred mineralization"". This system, derived from the Australasian Code, can easily be integrated into current practices of the exploration and mining industry within a short timeframe. The proposal to develop the use of the margins of error of the estimates at a confidence level of90% should be viewed in a longer timeframe. Establishing the precision of the mineral inventories and distinguishing between categories and classes by means of the margin of error will require more work and a longer break-in period.SOMMAIRELe ""Guide d’évaluation des gisements d'or"" analyse, dans une approche systémique, les travaux d'évaluation et de mise en valeur des gisements minéraux dans l'axe de la géologie, dans l'axée l'ingénierie et dans I ‘axe de l'économique. L’objectif est d'identifier la contribution aux pertes de métal et à la dilution du minerai des diverses étapes de l'évaluation et de l'exploitation du gisement. Ceci aid erra à maximiser les revenus et les profits, et ainsi, à réduire les risques départe financière que comportent les décisions d'investissements dans le secteur minier. Pour atteindre ces objectifs, iI est essentiel de relier les critères d'inventorie et de classification des réserves aux méthodes d'évaluation des gisements. Aux stades antérieurs du développement minéral, lorsque les connaissances quantitatives ne s'étendent qu’à l'axe géologique, le terme ""gisement délimite"" sera utilisé. Le terme ""réserve"" ne sera utilisé que dans une mine en exploitation au dans un projet minier, lorsque l'information dans les axes de la géologie, de l'ingénierie et de l'économique sera appropriée pour en garantir la faisabilité technique et économique. Chaque catégories des réserves, prouvée et probable sera subdivisée en deux classes pour mieux qualifier les niveaux d'évaluation du projet. La catégorie actuelle des réserves possibles sera remplacée par celle des ""minéralisations inférées"". Plusieurs essais démontrent que le système propose, qui s'inspire du Code australasien, peut facilement et rapidement s'intégrer dans les pratiques de l'industrie. II pourrait également contribuer à une standardisation des méthodes et des nomenclatures à l'échelle internationale. La proposition d'utiliser les marges d'erreur des estimes au niveau de confiance de90%pour caractériser les estimations se situe dans une plus longue perspective. Cette application demandera des développement méthodologiques additionnels ainsi qu'une période de rodage."

Jan 1, 1992

By Matthew S. Bingham, David H. Searle

"One of the most significant developments in environmental law has been the development of mandatory project review processes, at both the federal and provincial levels.FederalWhile, in the past, project review processes have, f or the most part, been spelled out in guidelines, the guidelines have not had the force of law. All that has changed, particularly at the federal level, with the Federal Court decisions commonly referred to as the Old Man River and Alameda and Rafferty Dam cases. These decisions, taken as a whole, are authority for the proposition that the Environmental Assessment and Review Process Guidelines Order, SOR 82-487 is a law of general application, not a mere guideline which may or may not be applied. This federal environmental assessment process first provides for a screening, and, depending upon the results of the screening process, the possibility of a public review. This federal process only applies, however, when the proposal is being undertaken by a federal department, or where the Government of Canada makes a financial contribution, or where federal lands are involved, or where a federal licence or permit is required.Bill C-78, the Canadian Environmental Assessment Act, will replace the Federal Environmental Assessment and Review Process Guidelines Order once it has been passed by Parliament. Currently the bill is being widely discussed, both between governments as well as public interest groups.ProvincialOn the provincial scene, there are three project review processes, one concerned with new mines, the second with energy projects and the third with all other major projects. The most recent initiatives taken by British Columbia are twofold. First, the Mine Development Review Process which was in the form of a guideline, has been replaced by the Mine Development Assessment Act. Second, the Major Project Review Process has been formulated and is to apply to four main categories of major projects:1. Pulp and paper production;2. Mineral smelting and refining;3. Chemical products; and4. Major ports and marinas.Energy projects are governed by the Energy Project Review Process which is legislatively mandated under the Utilities Commission Act."

Jan 1, 1991

By K. E. Harley, M. J. Whiting, T. J. Sabin, E. M. Ryan, J. F. Watts

"Wire and Arc Additive Manufacturing (WAAM) has the potential to enable a very significant reduction in buy-to-fly ratio compared to conventional manufacturing through the ability to build near-net shape components. Components manufactured from AA 2319 by WAAM can exhibit significant levels of porosity. There is also a variation in the physical appearance of the surface deposit sometimes found on such components. This deposit is similar to those observed on aluminium joined by MIG and TIG welding processes. It has been suggested that both the bulk porosity and the surface deposit are caused by hydrocarbon-based lubricant on the feedstock wire. An established correlation between surface deposit and porosity would offer valuable insight into WAAM products and enable early interventions in quality control or process monitoring based on visual examination. The relationship between the nature of the surface deposit and porosity has been studied for AA 2319 WAAM components manufactured using different wire batches. Evidence is presented to support the assertion that (i) there does not appear to be a relationship between surface deposit coverage and porosity, (ii) batch-to-batch variability in feedstock wire affects porosity. This study has led to a better understanding of the cause of porosity in WAAM components.INTRODUCTION There is a high cost associated with conventional, subtractive manufacturing because of the high ‘buy-to-fly’ ratio, a measure of the initial material bought compared to the material found in the finished part (Allen, 2006; Yilmaz & Ulga, 2016). A typical aerospace product may have up to 90% of the purchased billet of forging machined away which is cost inefficient and high in material waste. Wire and Arc Additive Manufacturing (WAAM) has the potential to reduce costs and lead time. Robotically controlled weld torches rapidly deposit feedstock wire in layers to build large near-net shapes with mechanical properties similar to those of conventional manufactured parts (Sequeira Almedia & Williams, 2010; Martina et al., 2012; Ding et al., 2015; Williams et al., 2015). A high level of porosity variation has been observed in aluminium WAAM parts (Cong, Ding & Williams, 2014; Gu et al, 2016) which can result in a range of material properties (Rudy & Rupert, 1970). This leads to difficulties in regards to standardisation and qualification of process and parts. In order for WAAM to be used commercially, porosity will need to be understood, monitored and reduced to a reproducible acceptable level or eliminated."

Jan 1, 2018

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

By A. Zarei-Hanzaki, O. Golmahalleh, S. M. H. Hosseini, H. Azizi-Alizamini

The main importance of acicular ferrite microstructures arises from their desired combination of mechanical properties in comparison with the bainite and ferrite-pearlite microstructures. Several factors affect the microstructural transition from bainite microstructure into the acicular ferrite one. As is well established any factor corrupting the prior austenitc grain boundaries nucleation potential, such as the thin layer of allotriomorph ferrite and the austenitc deformation inhomogenities may promote the acicular ferrite formation instead of bainite. Accordingly, this study deals with the effects of the aforementioned features on the acicular ferrite formation in low carbon microalloyed steel. The results indicate that the formation of strain-induced ferrite at the prior austenite grain boundaries accompanied by deformation inhomogenities in the austenite grains change the effectiveness of allotriomorph ferrite on acicular ferrite formation from active to inert one.

Jan 1, 2004

By S. Jordanov

The nature of processes that take place on top of copper bearing grains during the suppression of copper acid drainage from mine tailings was studied on a grain model. Cyclic voltammetry (C.V.) was employed as an experimental technique suitable for indirect measuring of copper leaching. Experiments were done in sulfuric acid (pH=2) at electrodes that progressively approach the real situation during acid main drainage, starting with Cu-metal, then with CuO and finally with CuO covered with CaSO4. Oxidation was found to be the only process that takes place on metallic copper electrode anodically polarized up to 2 V vs. Cu/CuSO4 reference electrode. Dissolution is intensive and reaches up to 50 mA.cm-2. When the same was repeated, but on CuO electrode, anodic currents were some 4 times lower than on the bare metallic surface. This indicates that the electrode material is not completely oxidized to copper(II)oxide and the Cu(O) or Cu(I) residues are oxidized during the anodic polarization. This explains the diminished dissolution. Dissolution is further restricted at electrodes covered with CaSO4. It is some 20 times lower than on the bare oxide electrode. When the second layer of CaSO4 was applied, anodic currents were another 15 times lower. Total decrease of anodic currents when transition is made from Cu-metal to CuO covered with 2 layers of CaSO4 reaches up to 7.500 times. C.V. measurements produced a proof that mechanical blockage is the way how lime prevents leaching of copper bearing grains in immobilization experiments referred elsewhere.

Jan 1, 2007

By P. Homola, M. Karlík, M. Slámová

"Aluminum sheets (AA1199, AA8006, and AA5754) were processed by accumulative roll-bonding (ARB) in the temperature range from 20 to 350°C. The microstructure of the sheets was characterized by means of scanning and transmission electron microscopy and electron backscattered diffraction. Mechanical properties were monitored by hardness measurements and tensile tests. Increasing strain (number of ARB cycles) led to incremental development of lamellar microstructure with a decrease of the spacing between high-angle grain boundaries in the normal direction of sheets. ARB process produced an important increase of strength while maintaining thickness and relatively high ductility, without accenting of the anisotropy of mechanical properties of sheets. The level of hardening decreased with the processing temperature and at 300 and 350°C ARB caused even the softening of the material due to the recovery of the deformed microstructure or partial recrystallization during heating to ARB processing temperature.INTRODUCTION Accumulative Roll Bonding (ARB) is a technique of grain refinement by severe plastic deformation (SPD) proposed by Saito et al. (1999). One ARB cycle consists in sheet cutting, surface treatment, stacking of two pieces, heating (optional), and rolling with 50% reduction in thickness. Since the sheet thickness remains unchanged by this cycle, ARB processing can be repeated as many times as desired. The goal of ARB is to impose an extremely high plastic strain on the material, resulting in structural refinement and strength increase without changing specimen dimensions. After several cycles, ultra-fine grained (UFG) materials with high strength and relatively high ductility are produced. An advantage of this method is that it does not require any special equipment as other SPD methods such as equal channel angular pressing (ECAP) (Valiev & Langdon, 2006), high pressure torsion (HPT) (Valiev et al., 2000), or cyclic extrusion and compression (CEC) (Richert et al., 1999), but only a conventional rolling mill and so it is seen as an economically viable and industrially scalable processing route. ARB processing has been successfully applied to various kinds of metallic materials at room or elevated temperatures (Tsuji, 2005). Besides processing single metals and alloys, ARB has also been used for creating ultra-fine grained and nanograined metallic composites (Wu et al., 2010; Qu et al., 2014)."

Jan 1, 2018

By N. D. MacFarlane, D. J. Mossman

"The Nemeiben Lake ultramafic complex, in the Churchill Province of the Canadian Shield in north-central Saskatchewan, is a small I. 6-km circular plug largely composed of high-alumina pyroxene cumulates forming a series of grossly concentric layers of clinopyroxenite, websterite and wehrlite. Minor dunite and gabbro are present in the northwestern part of the pluton.Disseminated primary magmatic pyrrhotite, pentlandite, chalcopyrite, magnetite and chromite occur throughout the intrusion. Sulphides occur in proportions of economic interest in the northern outcrops. A secondary assemblage of fine-grained oxides, sulphides and native metals occurs in serpentinized and uralitized peridotites and pyroxenites. Primary opaque minerals are largely altered to marcasite, violarite and hematite. The ores represent a primary magmatic assemblage extensively modified by metamorphism and, to a lesser extent, by supergene alteration.The complex intruded an Early Aphebian supracrustral succession during the waning stages of the Hudsonian orogeny. The metamorphic peak during Hudsonian time reached middle to upper amphibolite facies, granitized the country rocks and contributed to the partial amphibolitization of the ultramafic pluton.The Nemeiben complex has a number of features in common with the zoned intrusions of southeastern Alaska, including: the diopsidic composition of clinopyroxene, highly magnesian olivines, ubiquitous primary magnetite, relatively high alumina content of clinopyroxenes and the unlikelihood that associated gabbroic rocks are derived from a magma common to the ultramafic rocks. However, at Nemeiben, orthopyroxene occurs as a widespread postcumulus phase and, to a lesser extent, as a cumulus mineral. This fact, together with geochemical data on whole-rock and mineral compositions, indicates a tholeiitic parentage.The nickel-copper deposits of the Nemeiben Lake ultramafic complex are not currently economic, although standard technology for recovery of sulphide minerals in the clinopyroxenite (and websterite) would probably be adequate. Most ore minerals in the altered peridotites belong to the fine-grained secondary assemblage of opaques due to the formation of retrograde hydrous silicates and are probably too fine grained for standard recovery methods."

Jan 1, 1982