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By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By R. J. McLeod

"A new backfill plant was constructed in 1966 adjacent to the mill of Giant Yellowknife Mines. The reasons for the addition were to increase the storage capacity for sand fill, provide facilities for mixing cement with the fill for mine stope floors and provide a system for pumping fill to B -3 raise, a horizontal distance of 4700 feet from the mill. At the same time it was hoped to increase the density of the fill pumped underground.The plant consists of two only steel storage tanks of approximately 400 tons capacity of sand fill each. They are 17 feet in diameter and have conical bottoms. The cylindrical section is 28 feet high and the conical section 14 feet high. Each tank is fitted with water nozzles around the conical sections to remove solids at the required density. The water pressure on the nozzles is 150 lbs per square inch. The cyclones used to produce the sand back fill are located on top of the storage tanks. Five model Dl0B Kreb cyclones are used for this purpose. The vortex finders are 2 1/ 4 inch and the apex 1 1/4 inch. The cement silo or storage tank is located in the same building. It is a steel tank 17 feet diameter by 41 feet high with a conical bottom. The silo holds 250 tons of bulk cement, which is unloaded by air from a bulk highway carrier using 12 to 15 lbs air pressure. The cement is conveyed to the top of the silo, a distance of 70 feet from the ground by 450 lbs. of air.The mixing tank is a rubber lined steel tank 14 feet in diameter by 14 feet high. It is equipped with a Lightning Mixer supplied by Greey Mixing Equipment Ltd. The mechanism is driven by a 40 HP motor. The lower shaft is unsupported and is equipped with two 36 inch diameter axial flow turbine type rubber covered impellers. The backfill is discharged from the storage tank into the mixing tank by a 5"" x 4"" SRL-C pump powered by a 20 HP motor. A level control in the mixing tank regulates the rate of discharge of this pump through a Grinnell-Saunders automatic control valve. The cement silo is situated at such a height above the mixing tank to allow for a Rota-Lock, a small hopper and a cement feeder. The feeder is an Omega gravimetric belt type dry feeder with a Sensogram controller. The capacity of the cement feeder is 20 tons of cement per hour. The cement and backfill are mixed in the mixing tank at whatever ratio is required for the mine stope floors."

Jan 1, 1968

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Grégoire

Abstract -A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (2:3 cm thick), which seems to have been developed over the entire sedimentary basin of >80 km2, consists of pyrite, vaesite (NiSi), and sphalerite. The average grade of the mineralization is about 5.3% Ni, 0.73% Zn, ?770 ppb (PGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE +Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrient­ rich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic­ matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained S04 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich 1arninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesite­ pyrite assemblage crystallized at approximately 138°C. The ?34:S values range from -14.7 o/oo to-10.0 o/oo and are up to 34 o/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The ?13:C values of calcite in the footwall of the mineralized unit ( -12 o/00 to -6 o/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

By Gary Walters, Matthew White, Thomas W. Gonzales

The copper smelting industry has transitioned into the 21st century compliant with environmental regulations, new smelter installations and brown field expansions. The industry faces new challenges as copper in concentrate grades have decreased while contained impurities have increased. A new benchmarking survey was undertaken to update the last survey of 2016 for operating copper smelters in the world. The information collected was separated based on primary smelting technology rather than by geographical location and supplemented from published literature. Each smelting technology’s unique use of specialized process equipment, concentrate smelting capacity, and impurity flexibility are discussed INTRODUCTION The 20th century was a remarkable time for the growth of copper smelting. Electric, blast and reverberator furnaces dominated the smelting technology well past WWII. In the 1970s, SO2 regulations and high energy cost drove the development of new primary smelting technology. Technological advancements decreased energy consumption and enriched sulfur dioxide concentrations of the process off-gas to levels where sulfur capture in sulfuric acid plants was economically viable. The new smelting technologies began to replace reverberatory and electric furnaces starting in the late 1940s. A new paradigm in copper smelting was established and the enabler was then Outkumpu’s® flash smelting technology from the 1940s through to today. Now, Outotec had become the dominant primary smelting technology with over 44 copper flash smelting furnace installations world-wide. Figure 1 shows the historical installation statistics of primary smelting technologies over the last 70 years (ICSG 2018). The dominance and acceptance of the Outotec® smelting technology from the 1940s to current can be seen. Isasmelt® technology for copper was introduced in the 1970s and did not see advancement in new installations until the 1990s through today. Isasmelt® has 12 world-wide copper furnace installations to date. Mitsubishi® also introduced continuous smelting and converting technology in the 1970s, but had no new installations until the 1990s with a total of 5 copper smelters. Outotec Ausmelt® smelting technology had 3 installations in the 1990s and totals 10 furnaces. Most recently the Chinese technology of Bottom Blown and Submerged Lance Smelting began commercial operations in 2005 for total installations of 11, mostly in China. Other technologies, such as, El Teniente, Noranda, Inco, and Vanyukov furnaces have contributed to the overall global smelting capacity, but have not penetrated the smelting industry to challenge the existing dominant smelting technologies. The technology distribution in Figure 1 also shows flash smelting technology for sulfide concentrate domination untill 2000, bottom blow technology has become the preference in China. Currently, China is the only country building new smelting capacity. Isasmelt® technology also seen a large increase in installations in the current decade.

Jan 1, 2019

By Javier Ramirez

"Recent R&D pilot plant testing was done to validate a full industrial scale system for recovering residual magnetite from the tails of an iron ore concentration plant. The recovery system is based on an autogenous heavy media separator treating a tailings slurry at 0.45% solids by weight. A 3,100 m3/h capacity concentrator was installed based on the testing findings. Excellent metallurgical results have been observed in two years of continuous operation. This experience is the basis for the proposal of a novel process consisting of the preconcentration of base metals ores; the idea being to obtain a heavy bulk concentrate of the polymetallic minerals and discarding in one step the light gangue mineral components. The bulk concentrate then proceeds to conventional froth flotation. The reduced volumetric flow of the bulk concentrate allows a reduction in the size of the subsequent flotation circuit. A prerequisite for the heavy media separation is a fine size grinding of the ore and a correspondingly high degree of liberation of the mineral species to be recovered. A process scheme is also presented in which the gravity concentrator works in conjunction with a companion tailings thickener for process water recovery. The underflow from this thickener, having paste consistency, can be sent to a tailings dam or mixed with Portland cement for mine backfill. The process water in the system is managed at an estimated recovery in excess of 98%. Additional R&D work using this novel approach is being considered by a large iron ore concentrator for removal of liberated silica from the final concentrate; and for upgrading 3.5 million tons of a marginal hematite reserve owned by the mining company.INTRODUCTIONGravity preconcentration (static and dynamic) of sulphides prior to froth flotation has been and is being practiced at various concentrator plants (Asarco´s Young Mill: heavy media cone; Mount Isa: DSM cyclone; Afton Mines: Denver jigs; Tsumeb Mine: Reichert cone) (Burt, 1984). The idea behind installing preconcentration equipment is to reduce the volume of feed processed on flotation, thus requiring smaller flotation plants although other advantages may be of importance, such as obtaining richer concentrates due to higher grade feed, better process water and energy management, and reduced flotation reagent consumption.The SedconTM solid/liquid separator is a versatile process unit patented in Mexico (MX/u/2007/000305). As a gravity device, it may be classified as an autogenous heavy media dynamic concentrator. Figure 1 depicts the Sedcon (Sedimentador de conos) separator. The four main components are as follows: the feedwell for efficient mixing of the pulp with dilution water and flocculant (and coagulant for water clarification); the inner cones (passive elements for solid/liquid separation); the discharge underflow cone; and the scraper mechanism. The standard discharge cone is a 60° inclined cone for general applications. For paste tailings thickening applications, a deep cone with a 69° inclined cone is used."

Jan 1, 2016

By X. J. Guo, H. X. Li

The biological heap leaching at Zijin copper mine is currently the largest industrial application of biohydrometallurgy and one of the earliest mines to develop biological metallurgy technology in China. Since 2001, through demonstration plant and different expansion stages, it has been developed to produce 20,000 tons cathode copper annually. However the ore grade of heap leaching gradually decline year by year with copper grade average at around 0.23% now. The copper mineral is mainly the secondary copper sulfide, and symbiosis with higher content pyrite, the sulfur and iron contents is about 15 times as copper in the ore (S/Cu>15), so the acid and iron treatment of leachate, extractant and acid mine waste water is a great challenge. Combined with located in the rainy area of southern China, huge amounts of over 10 million cubic meters acid drainage need to be treated every year, so the recovery of copper from waste water as well as low grade ore is one of the characteristics of this process. This paper in general introduced the operation of heap leaching, solvent extraction, stripping and electrowinning process in Zijin mine, summarized the experience of production and technical practice, and discussed the methods of heap construction, leaching rate enhancement, third phase formation and treatment, mine effluent treatment, resource recovery and heap slope reclamation. INTRODUCTION The Zijinshan gold and copper mine is located in southeast China, Fujian province, and the typical distribution characteristics of gold and copper deposit are "upper gold and lower copper", both are large porphyry deposits. By the end of 2017, the accumulated proven reserves of available gold resources were 318 tons, copper are 2.15 million tons, and the prospective reserves of copper are more than 5 million tons. The gold mining is open pit while the copper mining is open pit and underground. The cut-off grade of gold mining is 0.15 g/t, and that of copper mining is 0.15%. A large number of very low-grade gold ores (grade <0.30 g/t) adopt a combined ore-dressing process of “partial crushing/ore washing/reprocessing/heap leaching (overlying)/ carbon slurry" independently developed, while flotation and bio-heap leaching are adopted for copper mine. Among them, copper ore with more than 0.25% copper content enters the flotation system to produce copper concentrate, while that of less than 0.25% copper content is processed by bio-heap leaching, solvent extraction and electrowinning. Zijin biological heap leaching plant is the first mine in China to achieve the scale of annual output of ten thousand tons of cathode copper since 2006. In 2008, the solvent extraction and electrowinning system were expanded, now with a daily processing capacity of 20,000 tons of ores, an annual output of 20,000 tons of cathode copper, the expanded plant is the largest biohydrometallurgy plant in China.

Jan 1, 2019

By G. D. Hibbard

New regions of material property space can be accessed by combining microstructural design at the nm-scale with architectural design at the µm- or mm-scale. In the first case, large strength increases associated with grain size reduction to below 50 nm have driven extensive research efforts into the development of nanocrystalline materials [e.g. 1-3]. For many potential structural applications, however, the density of a nanocrystalline material is just as important as its strength. In fact, reducing the density is more important than increasing the strength for certain weight specific materials performance indices, and it is especially critical for applying structural nanomaterials in the aerospace and automotive sectors. We have developed a new type of structural nanomaterial wherein the effective density of the parent metal is reduced by more than an order of magnitude by incorporating an internal periodic cellular architecture of open space. In one example a low density cellular nanocrystalline material was created by electroforming nanocrystalline Ni around a rapid-prototyped acrylic photopolymer microtruss, Figure 1 [4]. Microtruss materials have periodic cellular architectures that are specifically designed to undergo stretching-dominated deformation as opposed to the bending-dominated deformation in conventional open cell metal foams [5,6]. This new cellular nanocrystalline hybrid material combined the structural efficiency of microtruss architectures with the ultra-high strength that can be achieved by grain size reduction to the nm-scale. Although it played a critical role as a cathode support during the initial stages of nanocrystalline electrodeposition, the polymer core did not contribute significantly to the inelastic buckling resistance of the composite metal/polymer struts and it may therefore be desirable to remove it post deposition by means of chemical dissolution or thermal decomposition [4]. Nanocrystalline electrodeposition can also be used to reinforce conventional cellular metals (Figure 2), creating new types of cellular composites such as metal/metal microtruss hybrids [7-10] and metal/metal foam hybrids [11,12]. For example, nanocrystalline Ni-Fe alloy sleeve thicknesses of up to 400 µm were used to reinforce an aluminum alloy microtruss that had been fabricated using a stretch-bend approach; the nanocrystalline sleeves had the effect of increasing the microtruss strength by up to a factor of twelve and the specific strength by a factor of three [8]. Alternatively, much thinner sleeves can be electroplated to produce structural coatings. In one example, a nanocrystalline Ni coating was designed to provide both corrosion protection and inelastic buckling resistance [10]. Because the ultra-high strength material was optimally located at the furthest distance from the neutral bending axis, only a thin coating of 50 µm was needed to double the inelastic buckling resistance of the 1.13 mm x 0.63 mm cross-section plain carbon steel struts [10]. Overall, the mechanical performance increase that can be obtained through electrodeposition depends on a complex interaction between the starting cellular architecture and the nanocrystalline sleeves.

Jan 1, 2010

By Virginia Lawson, Adam Price

The rougher flotation stage is used to reject liberated gangue at a coarse size. Base and precious metals due to their high specific gravity tend to recycle in the grinding circuit and report to the flotation circuit at a finer size than the gangue from which it is being separated. Generally liberation levels of greater than 50% are achieved in roughing and thus a portion of the feed can be immediately upgraded to final concentrate. The proportion increasing as the amount of liberated mineral in the feed increases. Scalping out concentrate from the rougher can reduce the size of the subsequent regrind and cleaner circuits. Examples of alternative process design for circuits demonstrates that you don’t need large volumes to effectively recover all of the minerals – you need smart flotation. Several case studies will be presented where circuits can be significantly reduced in size by designing smarter – not larger. This paper describes case studies to test the amenability of the Jameson Cell to produce final concentrate from rougher feed. Metallurgical performance and plant design implications are discussed. Froth flotation has been used extensively for mineral concentration for over 100 years. Although the flotation cell design has changed, it has generally simply increased in capacity rather than increase in efficiency. Cell capacities of over 600 m3 are now being used in rougher flotation particularly for the lower grade ores where the amount of surface area for flotation is deemed less significant than the required volume. The plant design volume in rougher flotation comes from laboratory batch flotation tests and/or pilot plants. The volume required for the plant is calculated based on the laboratory residence time multiplied by a scale- up factor. Examples of laboratory to plant scale-up design are given in Dunne et al. (2010 part 2). The factors are usually between 2 and 3. A laboratory residence time of 10 minutes would equate to a plant design residence time of 25 minutes using a 2.5 factor. The volume of the required flotation cells can then be calculated using the design tonnage and volumetric throughput. This scale-up factor takes into account the differences in performance between batch flotation efficiency and full scale plant. The differences are likely related to inefficiencies of bubble particle contact in large cells as well as froth recovery, which is essentially complete in a batch cell. Flotation cells, such as the Jameson Cells, are smarter designs that improve bubble/particle collection, bubble/pulp separation efficiency and operate with high froth recovery rather than simply getting bigger. The Jameson Cell was designed on the principal of improving the collection efficiency of fine particles by separating the contact zone from the separation zone and having the bubbles generated by the plunging jet shearing and entraining air. This means the method of bubble generation is not impacted by the wear of mechanical equipment as it the case in other flotation devices. Jameson Cells make bubbles less than 600 micron in size under most operating conditions (Ding, 2016).

Jan 1, 2019

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By Adrianus (Adrian) Halim, Tomas Bolsöy, Stina Klemo

"This paper describes the ventilation system used in underground hard rock mines in Sweden and Finland, which is very different than the system used in other major mining countries such as Australia, Canada, South Africa, and USA. The system utilizes auxiliary fans with Variable Speed Drive to distribute primary airflow to working levels instead of regulators that are commonly used in other countries. Descriptions about Ventilation on Demand in this system and ventilation regulations in Sweden and Finland are presented in this paper. This paper also quantifies a comparison between the Nordic and the system used in other countries. KEYWORDS Auxiliary fan, Regulation, Ventilation on demand (VOD), Variable speed drive (VSD) INTRODUCTION The primary objective of an underground mine ventilation system is to provide sufficient airflow to dilute atmospheric contaminants that are produced by mining activities. Typically, a mine ventilation system consists of one to four primary fans, regulators to control primary airflow distribution to levels or panels, and auxiliary fans that distribute airflow to dead-end workings via ducts. Depending on circuit geometry, underground booster fans are sometimes used. This system is widely employed in many countries such as Australia, Canada, USA, United Kingdom, and South Africa. However, mines in Nordic countries such as in Sweden and Finland employ a different system, in which auxiliary fans instead of regulators are used to control primary airflow distribution, as well as distributing airflow to dead-end workings. This paper describes the general layout of Nordic ventilation system, its VOD and heating system, its comparison with the system that is widely used in other countries which is referred as “Non-Nordic ventilation system” in this paper, and the current ventilation regulations in Sweden and Finland. The comparison was quantified by doing simulations using Ventsim Design 5 software. DESCRIPTION OF NORDIC VENTILATION SYSTEM General System Layout Figure 1 shows a schematic of typical ventilation system used in Swedish and Finnish mines. The schematic was drawn by Franzen, Myran, Larsson, and Rustan from Stiftelsen bergteknik forskning (Swedish Rock Engineering Research Foundation) and the English translation is written next to the Swedish terminologies. The system is generally a push-pull system. None of Swedish and Finnish mines use exhaust system. As shown in Figure 1, the primary airflow is distributed to levels by auxiliary fans that are bolted to a bulkhead located in the access to intake raise/shaft. These intake fans are attached to ventilation ducts that distribute airflow to all working faces. The exhaust auxiliary fans, which are not attached to any ducts and also are bolted to a bulkhead located in the access to exhaust raise/shaft, then flow the exhaust airflow into the exhaust shaft. A small quantity of this exhaust air is directed into the ramp, which acts as another main exhaust airway. The deepest level is also equipped with booster fan(s) that draw air from the intake shaft/raise and direct it into the ramp to provide fresh air in the ramp. There is no free split in this system. Figure 2 shows a schematic of a level ventilation layout in the Nordic system. Figure 3 shows a photo of these auxiliary fans."

Jan 1, 2019

By F. F. Roberto

Sulfuric acid has been demonstrated to be an efficient lixiviant for in situ extraction of copper in the past. It has also been proposed that microbial production (by iron-oxidizing acidophilic bacteria) of acidic ferric solution either in situ or ex situ could provide an economic strategy to generate an effective lixiviant for secondary copper sulfides like chalcocite and covellite. Copper heap bioleaching also takes advantage of this approach. One of the major environmental challenges for in situ copper recovery projects is the containment of acidic solution within the ore deposit, and ultimate restoration of the depleted ore body to its original state. A perhaps overlooked aspect of projected site operations is the possibility that transient acidic conditions and pumping of solutions from surface reservoirs into the subsurface could stimulate the growth of iron- or sulfur-oxidizing species of acidophilic microbes in the ore body, leading to additional generation of sulfate, acid, and ferric iron. This outcome would benefit extraction of copper in mixed oxide/sulfide deposits in the near term, but could complicate restoration activities. Possible impacts of pumping acidic solutions into the subsurface on microbes resident in, or introduced into the extraction zone will be discussed in the context of our understanding of copper heap bioleaching and acid rock drainage. INTRODUCTION As high-grade deposits of metals such as copper continue to decline, conventional mining methods have evolved to mine and process larger and larger quantities of ore. What is currently defined as ore today often contains less metal than the tailings of past operations. The throughput of current-day mines also leads to tremendous amounts of waste rock and tailings that may threaten the environment and communities around the mines, as has recently been experienced by 3 major tailings disposal facility (TSF) dam failures in the past 5 years. Community acceptance of large mine operations thus becomes more difficult to achieve—loss of the social license to operate. In response, the mining industry urgently pursues innovations that can fundamentally change the way in which metals are mined. In situ recovery (ISR) of metals represents one approach to a more sustainable mining industry, by virtually eliminating the need for a pit or underground excavation, eliminating the excavation and transportation of ore to a process plant and the ensuing noise and dust that is generated, and any need for waste rock dumps or TSFs. An ISR mine could have very little visible footprint beyond a network of wells, pumps, and piping to transport pregnant solution to a recovery facility, such as a solvent extraction- electrowinning (SX-EW) plant for copper. Some solid waste streams and/or storage ponds may still be necessary to treat and store bleed streams, PLS and raffinate, or as part of groundwater restoration activities. Thus capital and operating investments would be potentially much lower than that required for a conventional mine. In theory production could also be controlled to adjust to subsurface ore grade and match market demand. A not insignificant challenge of in situ recovery is the requirement for an efficient, low-toxicity, and ideally selective lixiviant for the metal that is targeted.

Jan 1, 2019

By H. Kalsi

"IntroductionRoyal Oak Mines Inc. is currently operating the Parnour No.1 mine located 10.5 miles east of Tinunins, adjacent to Highway No. 101. The operation produces gold ore at a rate of 3300 tpd. A variety of mining methods including bulk open stopes with ITH drilling, narrow vein panel, longhole and open pits contribute to produce 1.2 rnillion ore tons annually. The milling process requires water at an average rate of 1 rnillion gallons per day (700 U.S. gpm). The Pamour No.1 mine has historically had two major problems with regard to water control. The flfSt is the underground pumping system&apos;s inability to handle excess inflows of water generated from spring thaws. When the thaw takes place over a short period of time, large inflows of water are created which quickly migrate underground and sometimes result in the loss of the lower loading pocket. During the spring runoff the pumps at Parnour No.1 work continuously for 24 hours at a rate of 1200 U.S. gpm. The system was further taxed in 1991 when the Hoyle mine was connected to the Parnour No. 1 mine and whatever excess capacity the pumping system had for the spring runoff was taken up handling the inflow of mine water generated by the Hoyle.The second problem facing the mine was the lack of water for the mill during the severe cold winter months and dry summer months. At those periods inflows of water into the mine decline and the underground water normally pumped to the mill is severely decreased. In times of dry spells mill personnel increase the water diversion from the Three Nations Lake in order to meet water demands and maintain tonnage throughout. In essence, the mine was going through an annual ""feast or famine"" situation and a solution was needed.A number of options were considered but were narrowed down to the two most practical. The first was to modify the existing pumping system and increase its capacity in order to handle the excessive runoff during spring thaw. This involved a heavy capital expenditure and would have caused additional operating costs (i.e. increased hydro). The option chosen by the management was to divert the spring runoff into an unused section of the mine called The West End. A bulkhead placed at the 2400 level would provide an ultimate underground water storage potential of 150 million gallons. This would also cut down the load on the existing pumping system, save electric consumption in pumping and provide water storage which could be used for milling during the two dry spells. Pumping stored water from the mine could be scheduled for off peak hours to take advantage of lower power rates. To meet these objectives an underground bulkhead capable of withstanding high water pressure up to 2000 ft head (866 psi) was constructed in the spring of 1992. The bulkhead site was at the 2400 level at the Pamour No.1 mine. A major consideration was the requirement to construct a safe bulkhead and to minimize water leakage from the bulkhead.Figure 1 shows the bulkhead location."

Jan 1, 1994

By C. B. Ndimande, C. Ntsele, M. Lisso, L. Arlow

"In the processing of UG2 platinum ore, stirred milling technologies are dominating regrind applications that require grinding the particles to P80s’ in the region of 45 µm. For this application stirred mills are 30–40% more energy efficient and require a smaller foot print compared to traditional tumbling mills. In this work a study was carried out using a batch pin mill and three scales of Stirred Media Detritors. A laboratory scale pin mill, a pilot scale Stirred Media Detritor with an installed power of 18.5 KW and two industrial scale Stirred Media Detritors in continuous operation, with an installed power of 355 KW and 1,100 KW were used. The industrial scale SMDs were in the secondary grinding section of a mill floatmill float (MF2) UG2 processing plants. The tests were focused on assessing the effect of feed rate and percent solids on power consumption and product fineness at lab scale, floatation response of the SMD product at pilot scale and on an industrial scale, the effect of feed rate on energy consumption and product fineness. The measurements obtained were feed flow rates, mill power and from the samples cut, particle size distribution of both feed and product. Specific energy was observed to increase with increasing percent solids over the 30wt% to 80wt% studied. Floatation response tests of the pilot scale SMD products show improvement in grade. Specific energy and reduction rations are observed to decrease with an increase in feed rate.INTRODUCTIONThe purpose of comminution in most mineral processing applications is to liberate the valuable minerals from gangue so that they can be recovered in subsequent separation stages. Most precious and base metal plants treat low grade fine-grained ores which require a higher degree of size reduction to yield the necessary degree of liberation (Partyka & Yan, 2007). Many authors have shown that the relationship between product size and grinding energy consumption is exponential, the finer the product from the comminution device, the higher the energy consumption (Gao & Weller 1993; Napier-Munn, Morell, Morrison & Kojovic, 1996; Jankovic, Valery & La Rosa, 2003). The suggested reason for this kind of relationship is that smaller particles have fewer flaws and higher strength than larger particles. Particles with fewer flaws and higher strength require higher energy for breakage to occur. One of the challenges most plants face is that of efficient energy utilisation in the liberation of the mineral from these complex ores. Conventional tumbling mills are not energy efficient in fine and ultra-fine grinding applications because some of the energy is spent on moving the charge and does not go directly into breakage. Stirred mills have been found to be about 30% to 40% more efficient and require a smaller foot print compared to traditional tumbling mills for regrind applications that require product size with P80s’ in the sub 45 µm regions (Radziszewski & Allen, 2013). Stirred mills are able to produce fine product because they can achieve a high number of stress events per unit time and volume compared to tumbling mills (Kwade, 1999a). To minimise energy usage without compromising product quality, the mining industry has adopted stirred milling technologies for fine and ultra-fine grinding (Radziszewski & Allen 2014; Kwade, 1999b). The south Africa platinum group metal (PGM) industry alone had over 40 stirred media mills installed by 2011 (Rule, 2011). Of that 40, 13 were in the ultra-fine grinding (UFG) application and the rest in main stream inert grinding (MIG)."

Jan 1, 2016

By Denni Nikols

"Planning for coal beneficiation in the electric utility industry is relatively complex, involving the coordination of experts and specialists in a broad range of fields, as well as compliance with a wide variety of government regulations.This paper examines the role of the planner, reviews possible benefits of coal beneficiation, identifies potential problems and illustrates a typical planning schedule.The steps involved in the planning process are:Step I-Bench- and pilot- washability studyStep 2- Wash plant designStep 3- Power plant and boiler designStep 4-Mine designStep 5-Major environmental and technical problems to address.IntroductionElectrical utilities and coal have a long and intimate relationship . Cleaned coal is becoming an increasingly popular fuel with the utilities for a variety of reasons. Generally, the greatest impetus to burn a cleaned or prepared coal fuel comes from the need to control airborne pollutants.Long-range planning is a standard practice for electric utilities, forecasts of demand must be made well into the future. Since the lead time required to provide new facilities is often as long as 10 years and the cost very high , planning becomes an important task.For a utility that owns and directs the operation of its coal mines, the mine planning or fuel acquisition planning takes on the magnitude of other corporate planning functions. It is from this perspective that a utility would view coal preparation. Except for the interaction of a coal-fi red plant on the actual mine design the planning considerations o f a beneficiating facility for a captive mine or a contract raw coal supply are about the same. Because TransAlta Utilities is currently supplied from captive mines, this discussion will tend to focus in that direction.It is the role of a planner to plan. This is easy to say but it is not always easy to do. Often we are working within a context that resembles the geological time scale. Frequently the objectives are not clearly defined when we begin and ultimately our plans are tested in the waters of government regulations and cost benefit analyses .Planning for beneficiation of Plains coal, or any coal, provides just such a test. The planner&apos;s role in this endeavour requires a wide vision. While parts of the process may be amenable to classical methods of project scheduling, the broad range of subjects and interaction of seemingly unrelated tasks is sure to obscure some of the considerations that must be made. Therefore, the planner&apos;s chief role is coordinating the work of many experts and specialists toward the final objective.Among the specialists are combustion , geo technical, mining, civil , and mineral processing engineers , geologists, hydrogeologists, soil, and reclamation experts to list a few.When one considers coal beneficiation, the planning part o f that consideration is probably more complex than any other single engineering function. Due to the company&apos;s location in the Alberta Plains and the proximity o f the mine to the thermal generating station, this paper will tend to emphasize that situation.Beneficiation may offer some advantages over run-of-mine coal to the power plant opeator. Some of these advantages are: removal of a contaminant, power plant efficiency gains , lower plant capital costs (for new plants), possible lower mining costs."

Jan 1, 1984

By M. M. Papic, G. M. Kimber

"Hat Creek coal was treated by the liquid solvent extraction process in a continuous plant at the U.K. National Coal Board Coal Research Establishment.Extraction levels of over 80 per cent dry-mineral-matter-free (dmmf) coal were achieved.Total light oil yield was around 47 per cent of the dmmf coal. The light oil was shown to be a good feedstock for secondary refining into gasoline, jet fuel and diesel fuel.In spite of the high mineral matter content of the coal the solid residue was successfully removed from the coal extract by filtration.IntroductionBritish Columbia Hydro (BCH) and the National Coal Board of Great Britain (NCB) undertook a joint project to test the Hat Creek coal from British Columbia in the NCB&apos;s coal liquefaction process designed to produce transport fuels and feedstocks for the chemical industry by the liquid solvent extraction of coal(1), In this process most of the coal is dissolved in an aromatic solvent and the residual solids consisting of mineral matter and undissolved coal are removed by filtration. The resultant coal extract solution is fed to a hydrocracker for conversion to light liquid products and a fraction suitable for recycling as solvent. The light liquid products can be converted to gasoline and diesel fuel in a secondary refining stage.The dissolution of the coal is effected by heat-treating a slurry at a temperature in the region of 400°C which causes some bonds in the coal to rupture with the formation of radicals(2,3). These radicals are stabilized by hydrogen transfer from the hydroaromatic groups in the solvent, resulting in a reduction in the molecular weight of the coal. In the absence of donor groups the radicals combine to form an insoluble high molecular weight product(4). From studies of the kinetics of these reactions it has been shown that the formation and stabilization of the radicals is rapid at temperatures around 400°C(2,3). The dissolution of the depolymerizing coal is, however, relatively slow and the need to ensure complete dissolution in order to achieve a high extraction restricts the selection of digestion time(5). Further, it is important that digests do not contain depolymerizing coal as it may re-form under the applied stress in the filter cake inhibiting flow through the bed and resulting in low filtration rates(6).Thus, in practice relatively long digestion times are generally required in order to ensure complete dissolution of the depolymerizing coal, while it is also important to avoid depletion of the hydrogen donor groups in the solvent which would lower the rate of hydrogen donation to the coal and thus reduce the extraction yield and adversely affect the filtration(7). Clearly it is desirable to optimize the digestion time and temperature with regard to the extraction yield and filtration properties.The precise control of the distribution of products from the hydro-cracker is important for the composition of the recycle process solvent. The principal functions of the solvent are to provide a source of donatable hydrogen and a vehicle for the dissolution of the depolymerizing coal. Hydrogen transfer from the solvent, achieved by the conversion of hydroaromatic to aromatic groups, stabilizes the radicals formed by thermal cleavage of some of the bonds in the coal resulting in a progressive reduction in the size of the coal molecules(8,9) and dissolution in the solvent. The combination of radicals would result in the formation of insoluble material and a reduced extraction yield of the coal(4). Thus to achieve a high extraction yield the solvent should contain sufficient hydrogen donor groups to prevent extensive radical combination. The composition of the solvent should also be controlled to allow dissolution of the depolymerizing coal and to prevent precipitation of this material during the subsequent processing of the coal digest and extract solution. The formation of a precipitate not only reduces the extraction yield of the coal and adve"

Jan 1, 1985

By Mohammed Rachek

Résumé : la mine d?Elhammam, opération du groupe minier Marocain Managem, est située au sud de la ville de Meknes à 63 km, elle exploite un gisement de fluorine depuis 1974. La minéralisation se présente sous forme de deux filons principaux orientés N45° avec un pendage variant de 65 à 90° NW, entre ces deux filons on note la présence d?une succession de filons satellites sécants. La méthode d?exploitation pratiquée depuis le démarrage de la mine est celle des chambres magasins, elle assure une cadence d?extraction annuelle de 250000 tonnes. Cette méthode favorisée par une très bonne compétence mécanique des épontes de la minéralisation a offert à l?exploitation une rentabilité très satisfaisante grâce à son faible coût mine. Les travaux de recherche géologique menés en parallèle à l?exploitation ont permis la découverte d?un nouveau secteur ?K-Est Gouaïda? (KEG) qui fait l?extension nord-est du gisement principal, la minéralisation de ce secteur se présente sous forme de deux filons très étendus latéralement (900 m d?extension) et présentant une puissance minéralisée irrégulière et très faible 1.2 m en moyenne, les épontes de la minéralisation sont constituées de schistes de qualité mécanique très faible. Vers la fin des années 1990, l?exploitation s?est orientée vers le développement minier du secteur KEG. Ce développement consiste à faire le choix adéquat de la méthode et de l?infrastructure minière pour l?exploitation de ce nouveau secteur, KEG. La méthode des chambres magasins, pratiquée dans le gisement principal avec un faible coût mine, n?est pas praticable dans le nouveau secteur à cause de la qualité de ses terrains, l?irrégularité de la morphologie de sa minéralisation et de la faible puissance des ses filons. Seule la méthode des tranches montantes remblayées (TMR) peut être applicable techniquement vu les spécifications suscitées de la nouvelle minéralisation, la TMR doit être appliquée sous sa variante mécanisée pour faire face au niveau exigé de la production. Après le pilotage de l?exploitation par TMR mécanisée dans le secteur KEG, il a été confirmé que cette méthode donne une grande satisfaction en matière de stabilité des terrains, sécurité, sélectivité, productivité et récupération du gisement, néanmoins elle reste pénalisée par un coût mine trop élevé pour garder le niveau de rentabilité recherché par l?exploitation d?un produit de faible valeur marchande telle que la fluorine. Dans l?objectif de rentabiliser l?exploitation du secteur KEG qui représente en réserves l?équivalent d?une durée de vie de 4 à 5 ans et d?assurer la pérennité de l?activité, l?exploitation en collaboration avec Reminex, la filiale d?ingénierie de Managem, a adapté une nouvelle variante de la TMR mécanisée dite TMR avec plan incliné sur remblai. Cette nouvelle variante de la TMR consiste à réduire au maximum les travaux dans le stérile en reconstituant un plan incliné sur le remblai à l?intérieur des filons pour faire évoluer en vertical l?exploitation des tranches en montant vers la tête d?un panneau de minerai. La variante des tranches montantes remblayées mécanisées avec plan incliné sur remblai a été imaginée et appliquer en 1978 dans la mine de fluorine de Burc située au Sud-Ouest de la France (Sicard et Mailloux, 1983). Imaginée pour une cadence annuelle de 30000 tonnes et une mécanisation très modérée cette variante a été adaptée par l?exploitation de la mine d?Elhammam en 2002 pour un haut degré de mécanisation et une cadence d?extraction annuelle de 250000 tonnes de minerai. Cette variante de la TMR est appliquée depuis le début de 2003 dans les chantiers du secteur KEG, elle présente les mêmes avantages techniques que la TMR mécanisée classique et elle a permis la réduction du volume des travaux d?infrastructure de 17.65 m à 6.25 m de travaux par 1000 tonnes de minerai. Ceci s?est traduit par une baisse du coût technique de la mine de 34% ce qui a donné un nouveau souffle à la mine pour assurer sa production et pour poursuivre la recherche géologique d?éventuelles zones à mettre en valeur.

Oct 1, 2004

This paper examines the latest advances in mine hoist motor and drives systems. The technology employed for large hoists has migrated from the traditional DC technology to AC motors with cyclo convertor drives, and more recently, advances in pulse width modulation (PWM) drives have resulted in these being applied to large hoist drives. When combined with PWM drive technology, the induction motor presents the ideal solution for hoist applications This paper examines the factors in choosing a suitable PWM drive and motor for a hoist installation. Factors under consideration include: ? hoist duty cycle, ? drive rating restrictions, ? choice of power semiconductor device,, ? low speed operation, ? maintenance ? reliability The cage induction motor and synchronous motor are compared and it is shown that the induction motor is the motor of choice for large hoists.

May 1, 2010

By K. Ghyselbrecht, R. Swennen, Y. W. Chiang, V. Cappuyns, R. M. Santos, T. Van Gerven, B. Meesschaert

Heavy metal contamination from mining and metallurgical activities of aquatic systems poses significant risk to the environment and human populations. The investigation of the distribution and immobilization mechanisms of heavy metals in sediments and soils has recently attained high priority. Different remediation methods can be employed to suppress or eliminate these contaminants. A tailored approach using both commercially available and in-house made adsorbents to rem ediate a heavy metal contamination site due to historical metallurgical activities in north Belgium is studied in this paper.

Jan 1, 2011

By K. Poorhaydari, B. M. Patchett, D. G. Ivey

In this paper, some applications of carbon extraction replicas, as samples for transmission electron microscopy (TEM), are discussed. Modern high strength microalloyed (HSMA) steels, used as structural or pipeline materials, have very small grains with substructures. Replicas used in TEM can resolve the grain boundaries and can be used for grain size measurements in cases where the small size of the grains pushes the resolution of conventional optical microscopes. The grain size variations obtained from replicas correlated very well with mechanical property variations, indicated by hardness, in the fine-grained heat-affected zone and base metal of some welded HSMA steels. Replicas are also very suitable samples for precipitate examination with analytical TEM. Advantages and limitations of the application of replicas, as well as some corrections for the estimation of the volume fraction of fine precipitates, are discussed.

Jan 1, 2005

By E. Poiate, P. A. L. P. Firme, D. Roehl, M. A. Carrion, A. M. Costa

Drilling high-pressure/high-temperature wells in salt rock formations is still a challenge for the energy industry. Creep and solubility is part of the salt rock physical-chemical behaviour, which must be considered in the design of the wells. The stress redistribution caused by drilling, in addition to thermallyactivated processes, triggers creep deformation, leading to borehole closure and the imposition of loads on the casing. The drilling fluid is designed by computer modeling in order to control the creep strain rate to a limit which allows the drilling operations and the casing setting. Depending upon the composition of the drilling fluid, chemical reactions on the salt wall may occur, especially in case of water-based fluids in highly soluble salt rocks. In those cases, cavities by dissolution (washouts) can be generated and the casing column remains uncovered by the cementation and laterally unconfined along the cavity length. This scenario is propitious to the loss of integrity of the casing due to phenomena such as plastic collapse, buckling and non-uniform loading on the casing provoked by the closure of salt formation around it. The casing should remain intact during the wellbore life-time. In this work, a section of a typical well crossing salt formation composed by halite and carnallite is considered. An idealized-cylindrical washout cavity inside a highly soluble salt layer is assumed. The purpose here is to evaluate the effect of the dimensions of the cavity on the integrity of the casing. Several typical diameters and lengths of the cavity are adopted. Numerical analyses are carried out with an in-house finite-element system composed by the pre-processor MTOOL 3D®, the simulator ANVEC 3D® and the post-processor POS 3D®. Salt rocks are modeled as visco-elastic materials. Creep is simulated by the Double Mechanism Creep Law, widely employed in Brazilian salt rock mechanics research. Cement and casing (steel) are modeled as elasto-plastic materials described by the Mohr-Coulomb and the von Mises criteria, respectively. Casing integrity is evaluated with respect to vertical and horizontal displacements. Vertical displacements imposed to the casing can provoke the failure of the column by plastic collapse or by buckling. Besides that, horizontal displacements of salt due to creep closure shall lead to the undesirable contact with the casing. Failure envelopes based on displacements are generated. The results of the simulations have shown that the casing failure by plastic collapse occurs preferentially in short columns, as well as buckling occurs in long and slender columns. The occurrence of both failure modes is more frequent in large-diameter cavities. Additionally, failure caused by contact between salt and casing occurs preferentially in short-diameter cavities.

Jan 1, 2015