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By G. J. Hawkes

"We all know that every man who works for us should have a thorough knowledge and understanding of his responsibilities. But how about ourselves? Du we have a thorough knowledge and understanding of our own responsibilities as Mill Superintendents?I once had an occasion to say to a Manager that I did not know something was my responsibility and he replied with suitable emphasis ""Everything inside those four walls is your responsibility"". That makes the extent of our responsibilities clear but does not give us a check list to keep an eye on as we do our job from day to day.What are our responsibilities? I suggest they are the following:1. Developing and maintaining efficient operating and maintenance crews.2. Milling the required tonnage.3. Recovering the economical maximum amount of gold.4. Keeping costs at the economical minimum.5. Seeing that the figures are reasonably accurate for tonnages, assays, production, losses, and costs.6. Preventing accidents.7. Preventing fires.8. Maintaining the equipment and building and keeping them clean and tidy.9. Enforcing company rules and regulations."

Jan 1, 1965

By A. E. Gillis

"Some or all of the following benefits can be expected following application of automatic control to a grinding circuit:1. Maintenance of Optimum Mill Load Level2. Improved Uniformity of Grind3. Increased Productivity4. Decreased Power Costs per Unit of Product5, Reduced Ball Wear per Unit of Product6. Reduced Labour Costs per Unit of Product7. Reduced Operator SupervisionTo establish an indication of the benefits that could be expected through automation of the grinding circuit at East Malartic Mines Ltd. it was agreed that the Department of Mines and Milltronics Limited should jointly conduct a survey of the existing grinding circuit and operation.Aside from establishing feasibility, an important purpose of this survey was to determine costs of a suggested control system that East Malartic Mines Ltd. management might be in a position to assess the economics of the proposal and justification of the investment.The survey involved the taking of sound recordings of rod and ball mills during manual operations, locating circuit bottlenecks, establishing time constants and determining the number and location of sensors for good automatic control."

Jan 1, 1966

By F. W. Gray

Foreword: It is not my purpose, in this address, to write the history of the Geological Survey of Canada, which has from time to time been reviewed by the officers of the Survey itself, and by men more competent than myself to handle so large a subject, but rather to set out some of the reasons for the regard in which the Survey is held by our Institute, the body best qualified to speak for the mining men of Canada. And, a further purpose is to publish the desire of our Institute that the work of the Survey shall be maintained at the highest pitch of efficiency the resources of our country. will permit, because to scrimp expenses on the Survey is 'to save at the spigot and lose at the bunghole." A historical examination of the grounds on which it may be asserted the Geological Survey has been, and still is, of fundamental economic value to our country, discloses a prescience on the part of the forefathers of Canada, calling for our admiring gratitude, and reveals a unanimity among the real leaders of Canadian thought, on the value of geological knowledge, that is impressive in its continuance dawn to this date. There seems always to have been before our people the realisation that large stretches of Canada are unfitted for agricultural settlement, and that our glaciated areas, the barrens and tundra of the North, and our extensive mountain ranges, had promise of compensating mineral content which the geologist and the prospector, labouring together through the years, would disclose. The Geological Survey is one of Canada's oldest public services, distinguished by an unimpaired tradition of honourable and useful labour. Founded in 1843, under William Edmond Logan, not yet 'Sir William', one year after the Act of Union, it was directed by him until 1869, or into the early years of Confederation, so that the early years .of the Survey were also, politically, the formative years of Canada, as we know her today.

Jan 1, 1932

By G. Chi, W. J. Davis, S. Watters, D. Hoy, S. Castonguay

"The Poplar Mountain gold occurrence in western New Brunswick is hosted in the Poplar Mountain volcanic complex (PMVC), which is located along the southern segment of the regional Woodstock fault zone. The PMVC consists of three principal units including, in ascending order, a porphyritic felsic volcanic unit, a volcaniclastic unit, and a mafic volcanic unit. U-Pb dating of zircon indicates that the age of the volcanic rocks is younger than 459 ± 3 Ma, and 40Ar/39Ar dating of mineralization-associated sericite indicates that the age of mineralization is 411 ± 3.7 Ma. Gold-mineralized zones occur in all the lithologic units but mainly in the porphyritic felsic volcanic unit. Gold zones are not controlled by individual faults but are characterized by high-density brittle fracturing, thin carbonate-quartz veining, and intensive ankerite-sericite alteration, superimposed on an earlier chlorite-calcite- quartz alteration. Gold is associated with arsenopyrite, which mostly occurs as disseminations in the host rocks, and to a lesser extent with quartz-carbonate-sericite veins and quartz-cemented breccias.Geochemical data indicate that mineralization-associated alteration is characterized by enrichment of K, Rb, Cs, Ca, Sr, Ba, As, Sb, W, C, and S. Fluid inclusion data indicate that the mineralizing fluids are composed of H2O, salts, and CO2 with variable amounts of N2 and CH4; salinities range from 2.3 to 10.6 eq. wt.% NaCl, but mainly from 2.3 to 5.6 eq. wt.% NaCl, and homogenization temperatures lie mainly between 220° and 270°C. Fluid pressures at the site of mineralization are estimated to have been 770 to 1200 bars, corresponding to a depth of 2.9 to 4.6 km at lithostatic pressure. The d18OSMOW and d13CPDB values of mineralization-related ankerite range from +14.5‰ to +16.5‰, and -6.8‰ to -8.3‰, respectively. The d18O values of the ore-forming fluids are estimated to be 6.4‰ to 8.3‰ at a temperature of 250°C. These carbon and oxygen isotope data fall in the field of magmatic fluids and in part the field of metamorphic fluids.Considering the geological setting of the region, abundant granitic intrusions, the similarity between the age of mineralization (411 ± 3.7 Ma) and the nearby Pokiok batholith (402-415 Ma), and the enrichment of granophile elements in mineralization-related alteration, the ore-forming fluids were probably derived from a granitic intrusion underneath the PMVC. These fluids were focused along structures related to the Woodstock fault. The Poplar Mountain gold occurrence might be compared to some granitic intrusion-related gold systems based on the geochemical data presented herein. L’indice aurifère de Poplar Mountain dans l’ouest du Nouveau Brunswick est contenu dans le complexe volcanique de Poplar Mountain (CVPM), lequel est situé le long du segment sud de la zone de faille régionale de Woodstock. Les trois unités principales du CVPM sont, de la base au sommet, une unité volcanique felsique porphyrique, une unité volcaniclastique et une unité volcanique mafique. La datation U-Pb de zircons indique que les roches volcaniques sont plus jeunes que 459 ± 3 Ma, et la datation par la méthode 40Ar/39Ar de séricite associée à la minéralisation assigne à la minéralisation un age de 411 ± 3.7 Ma. Bien que les zones minéralisées en or soient présentes dans toutes les unités lithologiques, on les retrouve surtout dans l’unité felsique porphyrique. Les zones aurifères ne sont pas contrôlées par des failles individuelles mais sont caractérisées par une grande densité de fractures cassantes, de minces veines de quartz-carbonate, et par une altération en ankérite-séricite intense qui se superpose à une altération antérieure en chlorite-calcite-quartz. L’or est associé à l’arsénopyrite, laquelle est principalement présente à l’état de disséminations dans la roche hôte, et à un moindre degré avec des veines de quartz-carbonate-séricite et des brèches à ciment de quartz.Les données de géochimie indiquent que l’alté"

Jan 1, 2008

By Michael J. Beare

Requirements of both local permitting and international fundraising are forcing increasing numbers of projects in Russia and CIS to carry out dual technical studies. The principal focus of Russian mining project design is to satisfy local regulatory requirements. However, the technical documents are not generally accepted by international banks for project finance outside Russia. Similarly, international study documents are not accepted for permitting in Russia. The purpose of this paper is to compare and contrast Russian and international approaches to mine technical studies and draw conclusions from this. The Russian design and permitting system is centered around two key statutory technical documents termed the TEO Konditsy and the TEO Project. These documents are subject to regulatory approval and are broadly equivalent to the international prefeasibility study and the feasibility study respectively. A comparison of study criteria suggests similar approaches are used for the main technical disciplines in project design by the time projects are at the point of construction, but there is divergence on environmental matters where the OVOS (Russian ESIA equivalent) differs from an ESIA in some significant areas. The key differences relate to project footprint, level of technical detailed required for baseline studies, level of public consultation, consideration and disclosure of information, labour, coverage of community and social issues and the preparation of a Social and Environmental Management System (SEMS). It has been noted that the Russian Design Institutes often leave the detailed economic analysis until after the TEO Konditsy. A common problem is design teams tend to look for ?technological solutions? without due concern for project economics. The end result of this can be mines that are overcapitalized and hence sub-optimal. It can be concluded that Design Institutes have the monopoly on Russian permitting reports and this is likely to continue. Similarly, Russian institutes generally do not prepare feasibility studies to international standards and this is likely to continue to be the case. Therefore to achieve the requirement of dual technical studies, the international consultants and Russian Design Institutes will need to cooperate on a joint work program. Key issues will be to ensure the most appropriate option studies are carried out at the right stages, that project economics are considered throughout the study, and that the environmental work program covers the additional studies necessary for the ESIA.

May 1, 2009

By Kenneth Williamson

La découverte de nouveaux gisements métallifères constitue le point de départ du développement de l'industrie minérale. Or, au cours de ces dernières années, le nombre de ces découvertes a fortement diminué dans les territoires classiquement explorés, entraînant une recrudescence de l?exploration dans les terrains géologiques de grade métamorphique élevé (e.g., Province de Grenville, Grand Nord du Québec). Ces derniers ont été traditionnellement considérés comme stériles à cause (i) de la monotonie apparente des gneiss qui les composent, (ii) de la difficulté d?identifier leurs protolites, (iii) des changements importants dans l?apparence des gîtes recherchés reliés au fort degré de déformation et de métamorphisme et (iv) des théories qui prônent un lessivage important des cations et des métaux d?intérêt économique par les processus de déshydratation des roches lors du métamorphisme régional (Weaver et Tarney, 1985; Vokes, 2000). Cependant, l?avancée des connaissances dans la compréhension des gîtes métallifères et de leurs terrains hôtes gneissiques intensément métamorphisés, montre que les systèmes géochimiques des roches altérées demeurent robustes (p. ex. ; Trägårdh, 1991; Craig et Vokes, 1993; Geringer et al., 1994; Schandl et al., 1995; Zaleski et Peterson, 1995; Vokes, 2000; Blein et al., 2003, sous presse). Bien sûr, les sulfures peuvent être localement remobilisés et même fondre, mais cette remobilisation n?implique pas forcément la disparition du gîte hôte (Williams, 1990) et peut s?avérer, bien au contraire, bénéfique pour la rentabilité d?un gîte en augmentant sa teneur en minerais (Marshall et al., 2000). Jusqu?à présent, dans les terrains métamorphiques, les contextes sédimentaires et plutoniques ont été reconnus et respectivement explorés pour les gîtes de type SEDEX et les gîtes magmatiques de Ni-Cu. L?étude de gîtes de métaux de base et précieux intensément métamorphisés (faciès des granulites) et leur comparaison avec des gîtes équivalents peu on non métamorphisés a permis d?établir, au cours des dernières décennies, des outils pour l?exploration des terrains de haut-grade métamorphique (Vokes, 1991, 2000; Slack et al., 1993; Spry et al., 2000). Ces outils sont basés sur la reconnaissance de roches diagnostiques d?une circulation ou d?une exhalation de fluides hydrothermaux telles que les méta-exhalites (formation de fer, coticules, tourmalinites, roches riches en quartz-gahnite, en apatite, en barite ou en staurolite zincifère) (Spry, 2000; Spry et al., 2000). Ils sont utilisés constamment dans les ceintures supracrustales riches en roches métasédimentaires.

May 1, 2003

By S. Eckert, M. Reuter, O. Keplinger, D. Obiso, N. Shevchenko, M. Akashi

We report on laboratory experiments focusing on bubbling phenomena arising from gas injection through a top submerged lance (TSL) in a liquid metal layer. The objective of this study is to reveal the characteristics of the formation and behaviour of the particular bubbles at different gas flow rates and submergence depths of lance. Visualization was performed in the eutectic alloy GaInSn using X-ray radiography. Argon bubbles were injected through the injection positions at three different submergence depths. Essential parameters such as the bubble size, bubble shape, detachment frequency and the two- dimensional gas distribution in the flat vessel were obtained by image processing. The results show that the deep position of the submerged lance causes an asymmetric large-scale circulation inside the fluid vessel. Bubble detachment frequencies were calculated by Fast Fourier Transformation from fluctuations of the image intensity in the vicinity of the nozzle injection point. This frequency does not show strong variations with respect to changes of the gas flow rate and the submergence depth of the nozzle. An increasing gas flow rate results in an increasing two-dimensional projected bubble area and the occurrence of a significant number of small bubbles being trapped by the strong fluid flow in the liquid metal layer. INTRODUCTION The Top Submerged Lance (TSL) process has been an essential component of the metallurgical industry since the emergence of first concepts about 50 years ago (Floyd, 2005). The process, which is characterized by blowing reactive gas through the submerged lance into a liquid bath, was developed mainly for improving the tin smelting process and has been applied for waste treatment or the production of several metals such as copper, lead, nickel and zinc. The productivity of the reactor is determined mainly by the efficiency of the chemical reaction between the gas or solid particles and the liquid. To achieve a high efficiency requires good exchange between the gas-liquid phase and therefore a large interface area. The efficiency changes greatly with the number and size of bubbles injected from the nozzle and the extent of splashing on the free surface. The degree of turbulence in the bath plays a decisive role here. For the reason, the design of an efficient TSL process requires a profound knowledge of the fluid dynamics especially for complex multiphase flows.

Jan 1, 2019

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By Michael Sudbury

Introduction The essence of a good presentation is said to be: Outline what you are going to say Say it Summarize what you said This is perhaps especially good advice at 8.30 a.m. So here goes: This is an attempt to put numbers on three inextricably linked subjects: People and the Future Irrigation and Agriculture Mine Water and Mine Waste

May 1, 2013

By Jason Prno

Context ? Climate change an issue of global significance ? Research is lacking ? Study initiated by the David Suzuki Foundation, led by ArcticNorth Consulting Industry Surveying ? 34% and 48% of respondents indicated climate change is already affecting operations ? Majority believed climate change would have negative impacts in the future ? Cost and uncertainty of Future impacts are major barriers to adaptation

May 1, 2010

WMS an Operation Service and Tool WMS is a the new SNC-Lavalin solution to complete and support your site?s operation. It targets phases in the project cycle including mechanical completion, pre operational verification and commissioning. The goal is to track phases completion and electronically deliver a plan with hand over documents.

Aug 1, 2013

By J. H. Hodgson

"Those of us who have been concerned with the problem of geophysical exploration in southwestern Ontario have followed the development of the Poulter method with much interest. I have much appreciated the opportunity of reading an advance copy of Dr. Poulter's clear exposition and of preparing the following brief remarks on the probable applicability of the method to the Palaeozoic area of southwestern Ontario.During the years 1944 to 1946, the Ontario Department of Mines, in co-operation with the Union Gas Company and the Dominion Natural Gas Company, operated an experimental party in the hope of establishing a seismic technique appropriate to the •area. The results were completely negative. During two summers' field work, no reflections whatever were obtained except in one area near Windsor. It is the •purpose of these remarks to inquire whether Dr. Poulter's techniques might yield favourable results.It was the conclusion of the report on our work that two principal causes contributed to the failure of the method. In the first place, the geological column possesses few elastic discontinuities and those that exist appear to have low reflection coefficients. In the second place, the area is drift-covered in general. This drift complicates the situation by absorbing seismic energy and by giving rise to groups of complicating refracted phases which obscure the entire interesting section of the record. The situation is further complicated by the high reflection velocities and the relative shortness of the Palaeozoic section, these factors combining to bring in a reflection from the basement in about half a second."

Jan 1, 1950

By Ian Thomson

OBJECTIVES OF EXPLORATION ? Prove/Disprove presence of potentially economic mineralization ? Keep on budget ? Minimize negative environmental impacts ? Gain a ?Social License to Operate? (SLO) WHAT IS A ?SLO? ? Granted by the local community ? Intangible, informal, non-permanent ? Has to be earned and then maintained ? Defined as ? Ongoing Approval (BSR and AccountAbility) ? Ongoing Approval, broad social Acceptance (Joyce and Thomson) ? Ongoing Acceptance (Nelson, and many others) ?Expression of the quality of a ?relationship?

May 1, 2010

By Angus W. Davis

The case of the P. G. E. railway is a peculiar one. Traversing, as it does, to a large extent, a mineralized country there are as yet no producing mines along its route although I am convinced that mines will be developed in the region tributary to the railway. The Fitzimmons group of claims, a copper property near Mons station, 37 miles from Squamish is now (unless recently relinquished) under bond to the Granby Company. On Cadwallader creek, in the upper Bridge river country, certain gold properties, referred to later, are being developed. Prospectors are fairly active in the Pemberton meadows area. There are also a large number in the Bridge river, Gun creek, and Whitewater districts. East of Marguerite station some development work is being prosecuted on some copper claims located there. In addition here and there throughout the entire route of the railway prospecting is being undertaken. At Hat creek, 15 miles from Pavilion station there is an enormous deposit of lignite. It is by no means certain that this coal can be profitably mined and hauled to the railway, but as a cheap fuel it offers possibilities in the recovery of by-products by destructive distillation. Logical procedure would ? indicate the expenditure of considerable money on development and, if results justify, the construction of a spur from the main line to the deposit.

Jan 1, 1925

By H. M. Roscoe

Fifty per cent. increased lump coal production and at the same time a reduction of from 20 to 40 per cent. in explosive consumption. These results were achieved by the use of the rock-dust cartridge method of stemming shots in the Ruhr coal mines, as announced by Dr. Alfred Stettbacher in the September 1923 number of the Explosive Engineer. Immediately, the explosive and the coal-mining industries on this continent became intensely interested. Considerable experimental work has been carried on in a number of American and Canadian mines during the past year, by which our engineers have become assured that the use of rock-dust cart-ridges for stemming shots increases the efficiency of explosives and promotes safety in coal mines.

Jan 1, 1924

By Barbara A. Filas

The IFC goal is to promote private sector investment in developing countries which will reduce poverty and improve people?s lives. The developing country goal is to promote health, education and employment opportunities that improve their economies and their standard of living. The mining company goal is to Promote successful ?triple bottom line? mining projects that will grow shareholder equity

May 1, 2002

By S. A. Willis

For over 150 years gypsum from Nova Scotia has been shipped via water to the United States east coast. The history of the movement has been one of continual improvements in quarrying, loading, and shipping. At the start, man-size rock quarried by hand auger and black powder was loaded into horse-drawn carts, hauled to the waterfront, and dumped into 100-ton sailing schooners. Last year the Canadian Gypsum Company completed the latest and most modern of these successive installations for the movement of this Nova Scotia product. The new system loads crushed gypsum into 11,600-ton vessels at Hantsport in two hours' time at high tide. At the head of the bay of Fundy are located vast deposits of gypsum. The tidal rise and fall of 45 feet twice a day, with its attendant swift currents, has always presented major navigation and shipping problems. When the tide is low, the Hantsport ship-loading pier is high and dry, with no water within 400 feet. Three hours later a large river has flooded in (running up hill) and large steamers can dock at the wharf. Before high water, the ship has been loaded and -there is a depth of 30 feet or more of water around the wharf. At high water, the ship sails away on the ebbing tide as the river runs in the other direction. Tides are caused by the gravitational attraction of the moon and sun on the ocean. When both celestial bodies are pulling together the 'spring tide' results, which means a 50-foot variation from high to low. This occurs at new and full moon. A week later, when the sun and moon work in opposition, the difference is only 32 feet between high and low water. The bay of Fundy, having a funnel shape (150 miles wide at mouth from Yarmouth to Portland, while the upper estuary at Hantsport is only one mile wide), builds up a tidal influence from 10 feet at the mouth to an average of 45 feet at Hantsport.

Jan 1, 1948

By J. Bourgeault

Modem civilization is indebted to that most ancient of the skilled crafts - the art of stone working, as the one consistent means whereby the dim un-recorded past has conveyed to our modem schools of science volumns of facts, written in characters of imperishable stone. Although left, centuries ago, to ruin and decay, architectural examples of the ancient building crafts still remain to the glory of the old master-builders, whose accomplishments in that remote age continue to influence and inspire their modem successors. Present-day architects and builders will leave to posterity just as faithful a record of our modes of living and of the methods now adopted for protection, as if it had been made by written word; and our craftsmen have profited greatly, in meeting modem requirements, by taking advantage of the indurance and utility of stone. Stone in all ages and stages of the world's civilization and development has been the material chosen by the masterbuilder, the one material possessing qualities that render it most desirable in affecting the artistic ideals of each period. It perfects the science of architecture through its durability and thus renders possible the study of man's workmanship in stone throughout periods of civilization of which we have no specific written account. Other materials have been used for the construction of man's habitations, but none have withstood the test of time, nor have established the credit of designer and builder so well as stone. _All other materials fall into ruin and decay, leaving neither mark nor monument for the enlightenment of mankind.

Jan 1, 1925

By R. F. Errington

"Radioactive minerals are found together with the more familiar ore minerals in veins, gossans, and pegmatites, Since they have a peculiar property, that of giving off penetrating radiation, the simplest means of field detection is by the use of some radiation detector.The two principal radioactive elements one may encounter are uranium and thorium. These may occur separately or together. At present there is very little demand for thorium and hence radioactive occurrences should be examined with some care to determine which element is present. To do this it may be necessary to have a chemical analysis made of samples from the occurrence. Uranium minerals that do not carry appreciable thorium have a conventional occurrence in quartz or carbonate veins. They are distinctive in appearance. Pitchblende, the principal ore, is hard, black, and very heavy. It weathers readily to soft, powdery minerals •brilliantly coloured orange, yellow, and sometimes green. It may be associated with familiar minerals such _as native silver, nickel-cobalt sulphides and arsenides, chalcopyrite, and hematite.It is the purpose of this paper to review very briefly the types of radiation detectors available .and to draw some general conclusions as to the types most suitable for particular applications.The highly penetrating gamma radiation is the most useful for detection of radioactive mineralization. The alpha rays have little or no penetration, and beta rays are stopped by thicknesses of a millimeter or so of material. We shall confine our remarks principally to those instruments intended to detect gamma radiation. These are of three types."

Jan 1, 1950

By C. Sist, J. Shannon, J. Fossenier, J. F. Adams

With the cleanest and easiest to treat copper concentrates dwindling and becoming harder to find, electrorefineries must deal with the reality of higher impurity anodes. There are well-known strategies for managing nickel, bismuth, antimony, etc. using bleeds (Ni, Bi, Sb, As) or arsenic control (Bi, Sb) or hydrometallurgical add-on circuits (IX, MRT, SX for As, Bi, Sb). However, for integrated copper producers and those producing other base metals it is often worth considering a more holistic, global approach. This paper will discuss both the well-known strategies as well as some global strategies and the role that hydrometallurgy can play in them. Examples will include atmospheric and pressure leaching, selective precipitation and impurity recycling or fixation. INTRODUCTION In the electrorefining of copper, impure copper anodes are electrically corroded, and pure copper is deposited on cathodes by passing DC current through an acidic copper sulphate solution. The anode copper impurities either settle to the cell bottom as insoluble components (anode slimes) or remain in solution with minimal deposition at the cathodes when correct operating parameters are maintained. Consideration of impurities is important in all copper electrorefineries. A typical impure anode contains 98.5–99.5% copper (Schlesinger et al., 2011). Table 1 shows the range of impurities reported for all copper anodes in the 2007 survey of operating refineries (Moats et al., 2007). Also shown is an approximate “limit” of anode compositions within which the majority of refineries operate without additional impurity removal capacity (beyond conventional liberator/bleed circuits). The column is somewhat subjective and meant to be an approximation only since there are many factors that influence impurity deportments and refinery impurity tolerances. More recent world survey data from 2013 show the averages for all impurities trending upward from 2003 to 2013 (Moats et al., 2013). With a competitive market for good concentrate and more copper recycling from electronics (which contain high levels of impurities such as nickel, lead and antimony), this trend is expected to continue through the coming years. The traditional primary method of impurity control is refinery bleed through liberator cells which are employed in the vast majority of refineries (Moats et al., 2013). These are used to control copper (primary liberators), nickel, arsenic, antimony and bismuth (secondary and tertiary liberators). Other methods of impurity control include arsenic addition (upstream in the smelter deporting to anode or directly to electrolyte) to control antimony and bismuth (Kamath et al., 2003), ion exchange or molecular recognition technology (Hur et al., 2005; Navarro et al., 2012) for antimony and bismuth. Many refineries also operate nickel evaporators to remove nickel sulphate before recycling back acid. Some use, or are contemplating using, acid purification units to recycle acid and arsenic without nickel and making nickel carbonate (Kamath et al., 2003; Sheedy et al., 2006).

Jan 1, 2019