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By K. P. Plucknett, Z. Memarrashidi

WC-Co ‘hard metals’ are widely used in a variety of industrial applications due to their resistance to abrasive wear, in addition to their high hardness and toughness. However, in contrast to their mechanical properties, the corrosion response of these materials is relatively poor. In the current work the corrosion mechanisms of two WC-Co cermets are analysed, with 10 and 30 vol. % of the Co metal binder, in a 3.5 wt.% NaCl aqueous solution. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential, potentiodynamic polarisation and cyclic polarisation, together with systematic analysis of the post-corrosion solution chemistries using inductively coupled plasma optical emission spectroscopy. The corrosion potential and current density were determined, following Tafel extrapolation, allowing the calculation of the corrosion rates. It is demonstrated that continuous dissolution of the cobalt phase occurs during corrosion, which is a result of poor cermet passivation behaviour, and this response increases with the amount of binder in the cermet.

Jan 1, 2015

By Louise Grondin

Laronde Mine has been working for a number of years to identify substances that could contribute to process water toxicity and to find an effective way of removing these contaminants from the water. Initial studies have identified ammonia, nitrite, cyanide, thiocyanate, cyanate, dissolved organic carbon, copper and zinc as potential toxicants. Bench-scale tests were carried out with Lakefield Research to find a water treatment process that could effectively remove the suspected toxicants. Nine treatment processes were evaluated: 1) granular activated carbon (GAC) filtration followed by zeolite, 2) zeolite filtration followed by GAC filtration, 3) aeration followed by GAC filtration, 4) multi-stage GAC filtration, 5) chlorination followed by dechlorination, 6) addition of clay based polymer, 7) treatment with peroxide and ultra-violet light, 8) bulk addition of GAC and zeolite powder, 9) treatment with bacteria. This article presents a summary of the test results and of the problems associated with the evaluation of technologies for the treatment of toxicity.

Nov 1, 2002

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

For developing new technologies, it is important to characterize the microstructure of materials with high spatial resolution at the nanoscale. To achieve high resolution, field emission scanning electron microscopes (FE-SEM) were developed. These microscopes allow working at low accelerating voltage, below 5 kV, to take advantage of the reduction of the interaction volume with accelerating voltage. Furthermore, their higher gun brightness compared to conventional thermo-electronic emitters, allow a probe size at the nanoscale. At low accelerating voltage, the emission volume of backscatter and secondary electron (SE) of the type II signals approach that of SEI signals. However, it is not enough to reach the highest resolution. A magnetic field above the sample improves the spatial resolution by collecting mostly high-resolution signals. In addition, the energy-filtration of the electron signals allows selecting the type of contrast detected: topographic, compositional, or crystallographic. The development of these new technologies permits to extend the imaging capabilities of the SEM towards new nanoscale applications.

Jan 1, 2014

By A. Probst, J. A. Finch

"Solids concentration (weight % solids) profiles and the clear liquid/slurry interface level (mud-line) were determined from conductivity measurements in thickeners at Falconbridge's Strathcona mill (Ni concentrate and non-mag thickeners) and Kidd Creek Division (Cu, Zn concentrates and final tails in the concentrator and a jarosite thickener in the Zn plant).The conductivity measurement system consisted of a probe 1.5 m in length with 23 electrode cells, a 24-channel relay, a conductivity meter and a computer. A conductivity profile is collected which locates the mud-line by a sharp change in conductivity. The conductivity measurements are readily converted to solids concentration profiles using a model due to Maxwell.The results from conductivity measurements were compared with direct measurements on local samples obtained using a modified Noranda sampler.It is concluded that the conductivity technique is applicable to locate the mud-line and to estimate the solids concentration profiles in thickeners. This on-line informnation could improve the operational efficiency of industrial thickeners."

Jan 1, 1994

By D. T. Smith, S. J. Strohmayr

Originally developed as a step change in ultrafine grinding efficiency, the IsaMill™ has made inroads into conventional ball mill and tower mill mainstream grinding duties during the last 5 years - beginning with the Anglo Platinum mainstream grinding projects in South Africa. At the 2006 SAG Conference, plant testwork on the incorporation of IsaMill™ technology into the McArthur River (Northern Territory, Australia) Pb/Zn primary grinding circuit was reported. The IsaMill™ has now become an integral component of that circuit, treating up to 1mm top size feed and directly producing P80 45 µm rougher flotation feed. Two 1.1 MW IsaMills™ are now used in this duty contributing to a 27% increase in overall plant throughput and a reduction in rougher feed size distribution. In this paper, we report on the current state of development and performance of the IsaMill™ in the primary grinding duty at McArthur River and also consider future directions.

Jan 1, 2012

Introduction Gold Mining is an Important Economic Activity in Canada n Total value added during 1990-99 was $15.5 bn n The gold price is an important factor in the value added process n The gold price affects gold mining output, profits, exploration expenditures, employment, etc. Some Factors that Affect the Gold Price n The value of the US Dollar affects the US Dollar price of gold: a weaker US$ correlates with a higher gold price n Supply affects the gold price: the higher the supply on the market each year, the lower the average gold price that year Central Bank Gold Sales n Yearly central bank gold sales add to supply, and affect the price of gold negatively n The negative impact on the price of gold reverberates through the Canadian gold mining industry n Despite the modest amounts, even Bank of Canada gold sales affect the Canadian gold mining industry

May 1, 2003

By Michael Jerome Wallace

"This paper refers to the wet open circuit ball mil ls in operation at Sidbec-Normines'5 pelletizing plant at Port-Cartier, Quebec, which commenced operations in late November· 1977. Prior to detailing our experiences in the grinding area at Port-Cartier, a general description of the total Sidbec-Normines project is outlined.HI STORYSidbec-Normines was incorporated in 1976 to develop the Fire-Lake - Port-Cartier iron ore mining, concentrating and pelletizing project. The primary objective of Sidbec-Normines is to produce 6mi11 ion tons per year of oxide pellets, of which 3 mi 11 ion tons per year are of a low silica grade suitable for direct reduction purposes. The participants in the project are Sidbec, the Quebec Government steel producer, British Steel Corporation (lnt'l) and the Quebec Cartier Mining Company. Equity interest is held in the company by the participants in the proportions of 50.1%, 41.6:7% and 8.23%, respectively."

Jan 1, 1979

By A. M. L. Cushing, S. Kelebek, A. Ghahreman

Iron sulfides are part of many ore deposits affecting flotation separation of non-ferrous base metals from them. Open-circuit potential (OCP), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) measurements were carried out with pyrite and pyrrhotite electrodes to investigate their reactivity under various flotation conditions, which involved the use of TETA, SMBS, and their combination. TETA was found to adsorb on the electrode surfaces causing a significant increase in charge transfer resistance of the product formed, which was most significant at OCP. This effect is much less with SMBS, indicating its greater surface reactivity compared to TETA. The combined use of these reagents decreases charge transfer resistance to a greater degree than that experienced with their individual uses. Addition of Cu2+ as a potential activator to this system nearly eliminates the action of TETA on the electrode surface, which can be attributed to sequestration/chelate formation in liquid phase. The relative effects of these reagents on pyrrhotite electrode are similar to that of pyrite. The main difference between the pyrite and pyrrhotite electrodes is that the observed charge transfer resistance on the pyrrhotite surface with each reagent case is significantly lower by 3 to 4 fold. This is compatible with its anodic nature and ease of oxidation since the OCP value of pyrrhotite is lower than that of pyrite. Results are discussed in relation to flotation/depression behavior of these iron sulfide minerals in mineral separation processes.

Jan 1, 2017

By Y. Kocaefe, D. Bhattacharyay, D. Kocaefe

The carbon anodes used in the electrolytic production of aluminum are made of petroleum coke, recycled anodes and butts, and coal tar pitch. Due to technological advances in the aluminum production technology, aimed at increasing production and decreasing energy consumption and greenhouse gas emissions, better quality anodes are required. Presently, the anode quality is evaluated by visual inspection and the analysis of a small core taken from 1.5-2% of the anodes produced. The visual inspection is susceptible to human error and limited to surface imperfections. The analysis of cores takes time, and therefore, it is difficult to determine the existence of a problem and intervene at the right time. In addition, the core does not represent the whole anode due to the non-homogeneity of anodes. A validated online anode quality control system can highly improve the situation. In this article, an electrical resistivity measurement method developed for this purpose is presented.

Jan 1, 2014

By R. A. L. Drew, J. P. Immarigeon, F. Jalilian, M. Jahazi

In the present work TLP bonding of Inconel 617 is investigated. The influence of the main processing parameters i.e. time and thickness of the interlayer were studied with optical and scanning electron microscopy. Boron containing interlayers with two different thicknesses were used and the influence of various holding times from 5 min to 24 hours on the microstructure of the bond region was investigated. The results indicated that, for the testing temperature of 1065°C and holding times above 2 hours with an interlayer of 25.4 microns thick no liquid phase was observed. The same phenomenon occurred only after 6 hours for a 76.2 microns thick interlayer. Precipitate growth started at grain boundaries and continued inside the grains. The composition, size and morphology of the precipitates were studied using electron microprobe analysis. No noticeable changes were observed in the grain size of the base metal with increasing holding times.

Jan 1, 2004

CFD (Computational Fluid Dynamic) models have been developed and validated for a pulsed column with disk-doughnut internals, as used for solvent extraction. First a single phase model was developed to simulate the turbulent oscillating flow around the internals of the column. This model was successfully validated using detailed PIV measurements of velocity taken at eight different phases through the pulse cycle. Second, the CFD model was extended to allow for a continuous aqueous phase and a dispersed organic phase (kerosene) flowing counter-currently. The model was a two-fluid model that accounts for droplet breakup and coalescence, and solves for droplet size distribution using a population balance model incorporated into the CFX4 package. PDIA (Particle Droplet Image Analysis) measurements were taken on a pilot scale solvent extraction pulsed column to determine droplet size distribution for calibration and validation of the CFD model. The measurements were made under pulsing intensities ranging from 10 mm/s to 32.5 mm/s.

Jan 1, 2007

By L. Voisin, E. Díaz, V. Montenegro, W. Kracht

Grinding media is of great concern in the mining industry mainly because its consumption represents an important part of the costs during mineral processing and consequently, of the total mining business OPEX. In addition, grinding media consumption impacts directly on flotation performance through negative contamination by corrosion, affecting the pulp chemical potential, complicating the understanding and control of the process, as galvanic interactions between mineral species also occur. In addition, during the process there is also a physical consumption of the grinding media through erosion and impact. In both cases, mineralogy has an important role because pulp abrasion power, chemical reactivity, rheology, hardness and other variables depend on the minerals contained in the pulp and their interactions. In the present study, a geometallurgical and phenomenological model, which describes the grinding media consumption and its relationship with mineral hardness expressed by Bond Work Index, was obtained based on advanced mineral characterization techniques such as Hylogger3TM, X-ray diffraction, X-ray fluorescence and experimental grinding tests using a laboratory mill applied on Chilean copper pulps. The results obtained show that pH has an important effect on grinding media consumption, because corrosion varies with hydrogen ions availability. Also, mineral hardness depends on mineralogical composition, but textural analysis must be performed to have a better description of this property. Finally, minerals present in a sample define the grinding media consumption mechanism, because a sample with harder minerals and a greater value of Bond Work index is capable of protecting grinding media from impact wear, while a sample with lower hardness but with a big sulfide minerals content would be more aggressive with grinding media because corrosion is more important in this case. The geometallurgical model obtained is capable to relate the grinding time, mineral hardness, content of sulfide minerals and grinding pH to estimate the grinding media consumption.

Jan 1, 2017

By Raj Thamburaj

"Over the last few decades, the emphasis on affordability and reduced cost of ownership has necessitated the development of innovative processes to carry out repairs in aero engine components. Conventional weld and braze repairs have evolved into advanced, sophisticated processes using state of the art knowledge in lasers, robotics and materials technology. This paper illustrates past and present scenarios in an attempt to illustrate progress that has been made in this area. The problems encountered in the past have been detailed along with the solutions that have been developed and commercially implemented to address these issues. Apart from technical progress, this presentation also addresses the progress made in business approaches and in Certification/Regulatory issues surrounding aero engine repair. Progress in Technology Repair technologies have also been the embryo from which new and revolutionary manufacturing technologies have evolved as well. Electron Beam Free Forming and LENS are examples of how a completely new manufacturing concept can evolve what was originally only a process to join metals. The current and future potential of these spin offs is discussed providing examples of application. While several problems have been solved over time with the implementation of advanced repair technologies, the demands of the industry have created new challenges. The paper describes these issues, outlines potential solutions and discusses the future of repair technologies in terms of the far reaching influence it is sure to have in design, manufacturing, maintenance management and life extension. Progress in Business Trends.Business approaches to repair and maintenance have also gone through considerable change with the introduction of ""Power by the Hour"" and other similar arrangements between the companies responsible for engine overhaul and the end-users. Program Based Logistics (PBL) is yet another innovation to provide a win-win situation for the repair service provider and the end user. This paper traces the development of these business initiatives and highlights successful applications. Progress in Repair Certification, Regulatory Issues.Understanding of the issues surrounding certification of repairs has also evolved with time and regulatory issues have been clarified considerably. Procedures for analysis and testing are much clearer and ""Check Lists"" are being drafted for certifying repairs on various engine components. The PMA phenomenon has added yet another dimension to the issues regarding certification and these are discussed as well."

Jan 1, 2010

By Larry B. Smith

"Feasibility studies are the means by which mineral reserves are established prior to financing a project. However, guidelines are generally lacking for the content, data quality and accuracy of these studies. Regulators take a principle-based rather than prescriptive approach to the content of studies and look to the industry to define study content. Professional organizations, engineering firms and mining companies must eventually establish guidelines and best practices for this work. Most likely these will draw on standards or “stage gates” that have been developed by major mining houses and engineering firms. Engineering studies must: 1.,Define optimal mining and processing methods, production rates, infrastructure, product sales, environmental management and risk mitigation. 2.,Increase confidence in resources, reserves, production plans, processing performance, infrastructure design, environmental management, permitting, capital and operating costs, and financial performance to support financing. 3.,Provide engineering designs suitable for accurate cost estimates. 4.,Develop project execution plans with sufficient confidence that project delays and cost overruns will not occur. Conceptual (scoping, preliminary assessment) Establish the principal characteristics of the project from the geology, resources, metallurgy and development constraints. Assess different approaches to mining and processing. Identify project execution requirements. Test project viability with economic analyses. Recommend additional work to increase the confidence in geology, resources, metallurgical performance, infrastructure, operating and capital costs, environmental conditions and permitting to allow selection of the best development options."

Jan 1, 2003

By Victor F. Hollister

Although none of the deposits discovered to date are of commercial interest, significant Frasch or sedimentary sulphur deposits occur in Nova Scotia in Upper Mississippian Windsor Group evaporites. The evaporite sequence contains anyhdrite and is overlain by impervious shales. It also is •mderlain by locally petrolijerous formations that are potential hydrocarbon sources for reaction with anhydrite to produce sulphur. As well, stratigraphic and structural traps are known to exist in the Mississippian beds. Thus, all requisites for sedimentary sulphur genesis are present. Available hydrocarbon sources are numerous but small; resultant sulphur deposits therefore are probably also small. Evidence suggests, however, that sulphur deposition is not yet complete.

Jan 1, 1984

By Bradley Stoughton

The magnetic oxide of iron, F eO4 , contains a theoretically larger amount of iron ( 72.4 per cent.) than any other commercial ore. It is probable that it has originated in many cases by the prolonged exposure of the hydrated oxide, ZF e20 a + 3H20 to heat and pressure which converts it first into hematite, F e20 3, and then into magnetite. It would thus appear as if nature had already done part of the work of removing all the oxygen and that magnetite should be relatively easy to reduce. That it is, in fact, less reducible than either limonite or hematite, is due chiefly to its dense and compact physical structure, which makes it less pervious to the furnace gases, and also to its characteristic action in resisting crushing to a uniform size, with consequent irregularity in reducing conditions within the furnace. The net result is that the magnetic oxide requires more fuel and more time for its reduction in the blast-furnace than any other iron ore of similar iron content and physical condition. There is another very important reason why the smelting of magnetite is more costly than that of hematite, and its treatment viewed with a great deal of adverse prejudice by blast furnace operators, namely, that magnetite decreases the proportion of heat developed by the fuel in the stack of the furnace, and increases the already excessive heat requirements of the heart.

Jan 1, 1924

By Serge Perreault

Le cuivre est un métal fascinant qui joue un rôle essentiel dans le développement des différentes civilisations depuis 7000 ans. Le cuivre est aussi un métal polyvalent et essentiel qui est très présent dans notre vie quotidienne. L’un des premiers métaux utilisés par les humains, il est un élément chimique qui se trouve à l’état natif, ce qui est rare pour les métaux. Il apparaît principalement dans des minéraux, notamment sous forme de sulfures, en raison de son caractère chalcophile (c’est-à-dire son attraction pour l’élément soufre). Le cuivre se trouve dans la croûte terrestre sous forme de minéraux de cuivre, tels que dans les sulfures dont la chalcopyrite, la bornite, la covellite et la chalcocite. Il est également présent sous sa forme native ou dans des minéraux oxydés comme la cuprite et dans des carbonates hydratés, comme la malachite et l’azurite. La formation de gisements de minerai de cuivre implique des processus géologiques complexes, notamment l’activité hydrothermale, les intrusions magmatiques et l’altération des roches. Les gisements de minerai de cuivre se trouvent dans divers types d’environnements géologiques, dont les gisements porphyriques, les gisements de cuivre encaissés dans des roches sédimentaires, les gisements de type skarn, les gisements de sulfures massifs volcanogènes, les gisements magmatiques de type nickel-cuivre, les gisements de cuivre oxydé, et d’autres [1].

May 2, 2024

By Warnett Kennedy

"GENUINE CONCERN for the environment is a built-in attitude of mind. If you do not have it by age 40 you probably never will. Some people speak the jargon of 'environment' and 'ecology' for political reasons, others because it feeds their need and bias toward attitudes of moral indignation or dissent. Others pay lip-service for purely business reasons. Complete reactionaries equate conservationists, ecologists and environmentalists as either 'commies' or 'pinkos'. Their real credo is the old saying, ""Where there's muck there's brass."" Those who have genuine concern for good environment are not only romantics like Thoreau but realists who sense the danger to our planet if human greed is rampant and unchallenged. The cities are in real trouble. Almost 75 per cent of the population already live in and around cities. Even mining men live in cities or bring up their children in the new 'instant' towns. The ecology of cities is the concern of all. Our distinguished guest Stewart Udall, in his book ""The-Quiet Crisis,"" quoted Thoreau in 1859 as having written ""each town should have a miniature wilderness park, a primitive forest of five hundred or a thousand acres where a stick should never be cut for fuel, a common possession forever."" Mr. Udall will be glad to know that this advice was taken in at least one instance known to me. I refer to Stanley Park in Vancouver. It is a primitive forest of 1000 acres right inside our small downtown peninsula. It remains unmanicured. This month we celebrated the completion of a seawall of 4%, miles along its perimeter. The construction of this wonderful walkway started in 1910. We are very, very proud of our park."

Jan 1, 1972

By Y. Chunhua, L. Chunsheng, W. Sheng

"Countercurrent solvent extraction is the dominant industrial rare earth separation method. For the rare earth separation, with low separation factors and multiple components, designing and optimization plays an important role in reaching product quality and reducing separation plant costs. Based on the theory of countercurrent extraction, cost-efficient methods, such as third-outlet separation and hyperlinked extraction processing, have been introduced following computer simulation. The consumption and fixed investment of industrial practice are compared, by which advantages of the optimized rare earth separation process are indicated. INTRODUCTIONThe rare earths (RE) have outstanding optical, magnetic and electric properties in advanced material applications and have therefore received much international attention in recent years. Liquid-liquid extraction is the major industrial RE separation method and is widely used in the industry. Supported by the government and with collaboration from the institutions and enterprises, China has made great progress in RE separation, and has become the dominant supplier of separated RE products. Complicated by multiple elements and low separation factors, careful design of RE separation processes is vital for the quality and cost of production. The theory of separation is the key to basic of flowsheet design and industrial applications.BASIC SEPARATION PROCESS AND THEORYGeneral ProcessAcidic extractants such as P507, P204 and naphthenic acid, are the most popular extractants in modern RE separation industry. In the general separating process, the extractant is saponified with a base, then ion-exchanged with RE solutions, thereby to provide stable and high RE loading in the extractant to fulfill the requirement of production quantity and quality. The RE-loaded extractant is then countercurrently extracted and scrubbed with RE solutions and the RE element thereby is purified. After the countercurrent extraction process, the RE-loaded extractant is stripped with acid to obtain an aqueous RE product, and prepare the extractant for recycling (Xu, 1995)."

Jan 1, 2012

By J. E. Gill

"THE YEAR 1959 appeared to be a good one in which to attempt a summary of progress in the location and study of sulphide deposits in Canada because a temporary surplus of metals caused prices to fall and many geologists who had been working like beavers were suddenly not so hard pressed. So it was •decided to arrange a Symposium. The response to the call for contributions was excellent and the result is the interesting collection of papers that follow.Activity in the search for massive sulphide deposits has never been as intense as in Canada since 1954. That was the year when the airborne electro-magnetometer first became generally available on a contract basis. These instruments work best on massive sulphide bodies, as do most of the ground electrical survey devices, so much of the new information relates to these. It was decided, therefore, to focus attention in the preparation of symposium papers on such masses. This served also to keep the survey within reasonable limits."

Jan 1, 1960