Search Documents

By Jamal Asfahani

Abstract - Natural gamma ray well logging, an effective tool in geophysical prospecting, is used to investigate the radioactive and phosphatic layers in the Khneifiss mine in Syria. The interpretation of the gamma ray measurements, using numerical methods of analysis developed previously and applied successfully in some phosphatic areas in Syria, make it possible to define precisely the phosphate thickness from place to place in the study area. This technique has been successfully applied while studying seven boreholes in the area. Sixty-three core samples from phosphatic layers in the boreholes have been analyzed, using gamma ray spectrometry for the determination of P2O5 , U, Th, and K. Good correlation between P2O5 content and U concentration has been found. The total count gamma logs correlate reasonably well with the U core analysis, suggesting that radioactive equilibrium exists in the U decay series. These gamma logs can be therefore used effectively to quantitatively map the distribution of P2O5 and U. The characteristics of both subsurface phosphatic sand and phosphatic rocks have been investigated and outlined using a statistical approach. The affinity of uranium to some trace elements such as V, Sr, Cu, and Ni has been verified using correlation matrices of these elements.

Jan 1, 2002

By B. McFadzean, J. Taguta

In order to recover minerals by flotation, the sub-processes of collector adsorption onto the valuable minerals followed by bubble-particle attachment should occur efficiently. This paper investigates both of these sub-processes for various thiol collectors and their mixtures onto base metal sulfide minerals. The aim of the work was to investigate whether there is a correlation between the strength of the collector interaction with the mineral and the subsequent bubble-particle attachment. The collector-mineral affinity was measured experimentally using an isothermal titration calorimeter in order to determine the molar enthalpy of adsorption for each collector-mineral system. The bubble-particle attachment was measured using a microflotation device which essentially determines the hydrophobicity of the mineral. Sodium ethyl xanthate (SEX) and sodium diethyl dithiocarbamate (DTC) and mixtures thereof were used as collectors with either single minerals or binary mixtures of pyrite and chalcopyrite, respectively. The adsorption enthalpies of the collectors were interpreted with reference to the chemical structure of the collector molecule and showed that the greater the positive inductive effect of the collector, which may be qualitatively related to their pKa, the greater their affinity for the mineral surface. In the microflotation studies, recoveries were strongly related to the alkyl chain length but there was no correlation between the enthalpies of adsorption and the flotation recoveries. When mixtures of collectors were used there was clear evidence of synergistic effects and in the case of DTC/xanthate mixtures it is possible that this synergism is related to a DTC promoted oxidation of xanthate to dixanthogen. When mixtures of pyrite and chalcopyrite were used the flotation recovery and enthalpy of adsorption of SEX onto the individual pyrite particles in the mixture increased substantially compared to the case of pyrite alone. Mechanisms are proposed to interpret these important observations.

Jan 1, 2016

By Farzad Khodabakhshi, Adrian P. Gerlich

"In this article, cold spraying process was utilized to coat the surface of AZ31 magnesium alloy with a layer of AA7075 aluminum alloy. Thereafter, friction-stir processing (FSP) was employed to enhance the microstructure and consolidate the deposited layer. The grain structure and phase morphology were studied along with indentation hardness before and after cold spraying and friction stir processing. The magnesium substrate had an initial hardness of 74 HV which increased to 102 HV after FSP due to refinement of grains to <2 µm. The aluminum coating layer, provided improved surface hardness up to 160 HV, which further increased to 173 HV after FSP was applied.INTRODUCTION Cold spray is a material deposition process which can be used for surface modification, since it deposits material on a metallic substrate with little heating by way of high velocity ballistic impacts. Using cold spray technology, it is possible to deposit a wide range of coatings with various thicknesses by controlling the characteristics of the feeding powder and metal substrate, gas temperature, gas pressure, powder feeding rate, nozzle geometry, and gun traverse velocity. This process has been recently employed for surface modification in various aircraft and automobile structural applications. This has led to a broad range of research using this process for production and modification of different metallic and non-metallic systems. In the present study, cold spray process was used to deposit a uniform layer of aluminum-zinc alloy (AA7075) on the surface of AZ31 magnesium alloy. This coating was subsequently treated by way of friction-stir processing (FSP) as a new post-spraying modification technique to enhance the structural homogeneity and densification of the coated aluminum layer. This method utilizes a non-consumable rotating tool with a specially designed shoulder and pin that is plunged into the surface of metal to be modified and then moved along the direction of interest. The localized frictional heating between the rotating tool and workpiece leads to softening of the materials around the pin, and material extrusion through a complex flow of material from the advancing toward the retreating side the tool. To the author’s best knowledge, only a few reports discuss the modification of a cold sprayed deposit by FSP process. The microstructure and mechanical properties of the cold sprayed layer and substrate before and after FSP modification were examined using optical observations (OM) and indentation hardness testing. Furthermore, the AZ31 alloy substrate alone was treated with FSP as well, for the aim of comparison to the processed coating."

Jan 1, 2017

By S. M. Chentouf, M. Jahazi, N. Bombardier, T. Belhadj

The main limiting factor in the commercial expansion of superplastic forming (SPF) of thin sheet aluminum alloys is the extent of cavitation phenomenon that takes place during the processing. The severity of the cavitation process is mainly dependent on the uniformity of deformation (i.e. level of local thinning) during processing. In the present paper, correlations are made between thickness variations in several formed sheets and the characteristics of the cavities observed in the material. The 1.4 mm thick 5083 aluminum alloy sheets were hot pre-formed at around 450°C for 4 min and then air-cooled. Opto-digital and Scanning Electron Microscopy were used to examine the microstructure and analyse the cavities. Also, grain size measurements were carried out for different location in the SPF formed piece. The surface and volume fractions of the cavities were measured with the aid of metallography image processing (MIPTM) on as-polished samples prior to etching. The results are analyzed in terms of the influence of applied strain and microstructure conditions on the propensity to cavitation of the alloy.

Jan 1, 2015

By H. Stocker, C. E. Makepeace

"This paper presents the statistical analyses of several sets of data acquired in several programs of sampling of radon daughters in uranium mines. The measurements were taken over periods of days or weeks for given locations or location occupations within these mines. Because the sampling applies to specific intervals of time and specific locations, a method is suggested f or the eventual application of a monitoring program which would be suitable on an annual basis for these locations. The present data and analyses thereof are not justifiably applicable to a monitoring regimen on an annualbasis, without a number of additional assumptions.The aim of the present analyses of concentration measurements is the determination of the minimum number of measurements required to achieve an annual radon daughter exposure estimate, for individual workers, having an error no greater than 50% at the 95% confidence level. The criterion of accuracy is taken from a statement in the American National Standard, Radiation Protection in Uranium Mines (ANSI NI3.8-I973), and is currently used, in somewhat modified form, as a guide to uranium mining licensees in Canada. Uncertainties associated with occupancy time are ignored in the present analysis. IntroductionOne of the principal aims of any scheme of radiation protection is that of improving the accuracy of exposure estimation for workers. The example presented here is from the area of radon daughter exposure estimation for uranium miners. The conventional means of estimating workers&apos; exposures is grab sampling of radon daughter concentrations combined with occupancy time weighting in the various work and travel locations. Uncertainties exist in each of these components, and in an environment of highly variable radon daughter concentrations (such as an active uranium mine) one is always uncertain as to the representativeness of the grab sample (compared to the average concentration) unless a sophisticated monitoring scheme has been implemented based on previous experience in such an environment.Improvements in the accuracy and precision of employee radon daughter exposure records depend, primarily, on three factors;"

Jan 1, 1980

By Haibin Ma, Jie Song, Qingyou Han, Xiaoming Wang, Wei Vian

In the grain refinement of aluminum, Al3Ti and TiB2 particles are introduced to reduce the casting grain size down to 200 micrometer level, which makes cold working possible. The particles are brought in by the addition of Al-Ti-B type master alloys. It is generally believed that TiB2 particles are stable and nucleate a-Al grains in solidification in the presence of extra titanium than the stoichiometry of TiB2 from the dissolution of Al3Ti particle in the master alloys. Titanium in solution either form Al3Ti layers on the surface of TiB2 particles or as solute to promote the nucleation and to restrict the growth of a-Al grains. However, a consensus on a grain refinement mechanism is still to be reached due to the lack of direct observation. This paper presents finding on the TiB2/Al3Ti interfaces in an aluminum matrix. It demonstrates a strong epitaxial growth of Al3Ti on the surface of TiB2 particles, a sign of the formation of an Al3Ti layer on the surface of TiB2 particles in grain refinement practice. The Al3Ti layer has a crystal coherency with a-Al and hence offers a substrate for heterogeneous nucleation of a-Al grains.

Jan 1, 2015

By T. Hadley, Northern Minerals Ltd, C. S. Griffith, T. A. Safinski, K. H. Soldenhoff, M. Fainerman-Melnikova, A. Manis

"ANSTO Minerals and Northern Minerals have been working together since 2012 on the process flowsheet development for the Browns Range project for the recovery of the heavy rare earths (Dy – Lu, + Y). Initial efforts were directed toward defining the most efficient and direct flowsheet for the Preliminary Feasibility Study (PFS), issued in June 2014, then towards the Definitive Feasibility Study (DFS), issued in February 2015. These goals were achieved by undertaking comprehensive laboratory and continuous piloting programs. Further improvements to the flowsheet following the DFS have been made. This publication provides an overview of the evolution of the process flowsheet based on these laboratory and piloting programs from the PFS through the DFS and beyond.INTRODUCTIONNorthern Minerals Ltd (Northern) has been working on developing their flagship project at Browns Range for the recovery of the heavy rare earth elements (HRE, Dy – Lu, + Y). The project is located in the north of Western Australia as shown in Figure 1. The Total Mineral Resource at the project is currently estimated at 8.98 Mt @ 0.63% total rare earth oxides (TREO) comprising 56,663 t of contained TREO using a cut-off grade of 0.15% TREO. Of the Total Mineral Resource, 58% is classified as Indicated Resource, with the remainder in the Inferred Resource category.The deposit is characterised by breccia-hosted, hydrothermal, HRE-rich, xenotime mineralisation. The main gangue mineral associated with the xenotime is quartz. The distribution of rare earths (RE) observed for the xenotime mineralisation at Browns Range is presented in Figure 2. Extensive test work has shown that the xenotime can be readily beneficiated to between 20 – 40% rare earth oxide (REO) using a process consisting of crushing and grinding, followed by magnetic separation and flotation steps. Continuous piloting of this process was conducted on ~80 t of trench-sourced ore in late 2013 at SGS Perth, to produce ~2 t of ~20% REO mineral concentrate (MC) for hydrometallurgical testing. The composition of the MC produced during piloting is presented in Table 1."

Jan 1, 2016

By R. F. Favreau, R. A. Morin, G. W. Kuzyk, P. J. Babulic, N. J. Tienkamp

"Atomic Energy of Canada Limited is constructing an Underground Research Laboratory (URL) as part of a comprehensive program to evaluate the concept of nuclear fuel waste disposal deep in crystalline rock formations. Careful blasting methods have been used to minimize damage to the excavation surfaces. Good wall quality is desirable in any excavation. In excavations required for nuclear waste disposal, the objective will be to minimize blast-induced fractures which may complicate the sealing requirements necessary to control subsequent movement of groundwater around a sealed disposal vault. The construction of the URL has provided an opportunity for the development of controlled blasting methods, especially for drilling accuracy and optimization of explosive loads in the perimeter and cushion holes. The work has been assisted by the use of blast simulations with the mathematical model Blaspa.This paper reviews the results of a recent project to develop a controlled method of full-face blasting, and compares the observed field results with the results of a blast simulator called Blaspa. Good agreement is found between the two, and the Blaspa results indicate quantitatively how the blasting may induce damage in the final excavation surface. In particular, the rock in the final wall may be stressed more severely by the cushion holes than by the perimeter holes. Bootleg of the rock between the perimeter and cushion rows occurs when the burst out velocity imparted to it by the explosive loads in the perimeter holes is inadequate. In practice, these findings indicate that quantitative rock stress and rock burst-out velocity criteria can be established to minimize wall damage and bootleg. Thus, blast simulations become an efficient way to design controlled blasting and to optimize quality of the excavation surf ace."

Jan 1, 1989

By Joo Hyun Park, Hyun-Sik Park

"Gold is one of the most valuable and precious metals. But, the extraction efficiency of gold from natural resources is very low and labor-intensive due to very low concentration of gold, i.e.,1–5 ppm, which means that gold extraction processes produce extensive amounts of tailings. The gold content in printed circuit boards (PCB) from waste mobile phones is about 100 to 400 ppm, which is enormously greater than the concentration found in natural ores. Consequently, processes for recycling waste PCB and gold mine tailings become of increasing importance to maintain a sustainable society. As processing these waste materials by pyrometallurgical methods has become more economically attractive, understanding the thermodynamic behavior of gold in smelting slags under oxidizing and reducing conditions has become increasingly important. Therefore, in this study, the effects of slag chemistry, oxygen potential and temperature on gold solubility in smelting slags are discussed. From the results presented, the predominant species of gold is strongly dependent on the basicity of slag. Furthermore, more basic slags showed higher solubility of gold at a given oxygen partial pressure, and more oxidizing atmospheres enhanced the dissolution of gold to the molten slag phase. As a consequence, careful control of the slag composition during pyro-processing of gold-containing waste materials is required to maximize gold recovery. INTRODUCTIONGold has good physicochemical properties. Thus, it plays an increasingly important role in industrial applications. For example, over 300 tons of gold are used annually in electronic components (Hageluken &Corti, 2010).However, 75% of all gold ever produced has been extracted since 1910 and gold reserves in the world are becoming rapidly depleted (Louis & Pluchery, 2012).The cost of gold production and its price in the market have increased rapidly during last 20 years as shown in Figure 1, and interest in the recycling of gold-containing materials has naturally increased.The wastes from electronic equipment (e-wastes) contain large amounts of precious metals compared to their own respective ores, and therefore such wastes may be considered as a secondary source of valuable metals. For instance, the concentration of gold in natural ore is commonly 0.5–15 g/ton-ore (0.5–15 ppm), while its concentration in electronic circuit boards is over 10 times higher, typically being about 150 ppm in expansion cards and over 10,000 ppm in central processing units(Barbieri et al., 2010).Also, gold mine tailings are discharged after the flotation process as slurry form then stored near the operating plants (approx. 100 ton per day in one Korean gold mine). Gold mine tailings contain gold at about 1–2 g/ton. This is the reason why Au-containing materials such as e-wastes and mining wastes are highly important sources of gold (Yamasue et al., 2009)."

Jan 1, 2017

By H. R. Manouchehri

"It is well understood that, apart from particle hydrophobicity, the flotation process is strongly influenced by the cell hydrodynamics. Once the chemical conditions were optimized and fixed, the flotation rate is essentially determined by impeller speed and the air flow rate.The collection efficiency in flotation is a product of collision, attachment and stability/detachment efficiencies. The collision efficiency for a given particle diameter is increased by decreasing the bubble size and bubble velocity as well as increasing the power input to the cell. The attachment efficiency, however, is defined by bubble size and its velocity. The detachment/stability depends on the relative magnitudes of the attachment force between the bubble and particles and the detachment force acting on the bubble-particle aggregates. For the particles having specific contact angle, the stability decreases as the energy input increases. Therefore, there must be an optimum energy dissipation to maximize recover of defined size fraction.A comprehensive laboratory study was devoted to determine the effect of power input in recovery of finely grind Cu-Ni bearing ore. Several flotation tests were conducted to define the hydrodynamic parameters for a laboratory scale Runge cell under different impeller speeds. An increase in flotation recovery of finely ground ore was observed when the impeller speed was increased from 450 to 1,200 rpm. The experimental results have shown increasing in water recovery and improving in flotation kinetics of fines by increasing the power input to the flotation cell. Implementation of the Wark flotation model to the experimental data revealed a good correlation between the experimental data and the model. For the particles having enough hydrophobicity the flotation rate increases by increasing the impeller speed due to a higher value for collision efficiency within the cell."

Jan 1, 2016

By A. R. MacPherson

"This paper considers four aspects of autogenous grinding. Part 1 discusses statements on power efficiency of autogenous grinding compared to conventional crushing and grinding systems. It also demonstrates how high-power efficiency can be obtained from autogenous grinding systems. Part 2 considers a simple method of testing ores to determine the type of autogenous plant which can treat these ores on a commercial basis. A comparison of testing for simple small plants vs large plants or complex ores is included. Part 3 considers important aspects which have to be considered in proper design of an autogenous grinding system. Part 4 discusses problem ores and how they can be treated in an autogenous system. INTRODUCTIONAfter about 35 years of using autogenous grinding plants in the mining industry, it is perhaps time to review where we are with this, by now, relatively old development. Autogenous grinding in this paper means grinding run-of-mine ore by fully autogenous means or by using a ball charge to assist the grinding (semi-autogenous). Also, autogenous grinding can be eitherby dry or wet.The use of autogenous grinding in the fifties was making its slow start, and it was not until the sixties that more of the mining industry would consider its use . By the seventies, most builders of new plants would have considered autogenous grinding, whether they used it or not, in the final design.In the eighties, most large plants use autogenous mills and to reduce over-all operating costs, many older conventional plants are now looking and actually retrofitting these old plants with autogenous grinding mills.It is evident that many misconceptions concerning autogenous grinding are still current. Some come from improperly designed plants which result from poor test work. There are many considerations in the proper design of autogenous plants. Some ores have been found to give problems even in a well designed plant. These ore types are beginning to be classified and recognition in the test stage allows steps to be taken in the design so that these ores can be efficiently handled in autogenous grinding plants.Therefore, this paper will address the following aspects of autogenous grinding:1. Misconceptions regarding autogenous grinding.2. Testing of ores to ensure a well designed commercial plant.3. Important considerations in mill design.4. Difficult ores, their recognition and types of design to handle such ores."

Jan 1, 1989

By Amyn S. Dahya, David J. King

"The object of the paper is to discuss the developments in Carbon-In-Pulp (C.I.P.) technology for gold recovery. The CIP process is comprised of four major operations:(a) adsorption of precious metals onto activated carbon;(b) elution (stripping) of precious metals from the loaded carbon;(c) electrowinning of the precious metals from the concentrated eluate;(d) regeneration of the eluted carbon before recycle to the adsorption process.A detailed review of the technological developments in each of the above operations is presented together with a brief theoretical background of the underlying processes. The advantages and disadvantages of the CIP process are discussed in comparison with conventional zinc precipitation. IntroductionThe carbon-in-pulp (CIP) process involves the use of activated carbon for treatment of pulps containing dissolved precious metals, and provide s an alternative to the conventional gold recover y processes using filtration or counter-current decantation in conjunction with the Merrill-Crowe zinc precipitation process. The commercial application o f the CIP process in gold processing technology is a fairly recent development and it is of growing importance around the world.The fact that activated carbon ha s the property of adsorbing precious metals from solution was first published in 1847. In the following years , a great deal of work was carried out to develop an over-all recover y process using carbon, but all attempts were uneconomical because the loaded carbon had to be smelted to recover the gold.It was not until 1950 that Zadra, at the United States Bureau of Mines Research Centre in Reno, Nevada, developed a technique for stripping the loaded carbon using sodium sulphite-sodium hydroxide mixtures and then recovering the gold from the stripping solution by electrolysis. However, this process was not effective for stripping silver and further testwork was carried out on alternative stripping techniques. In 1952, Zadra published a paper describing the use of a hot sodium hydroxide- sodium cyanide stripping technique, which was effective in stripping both gold and silver. This paper included a description and flowsheet for the CIP process which is essentially the same as we know it today. This technique was used in the first major CIP plant, constructed and commissioned in 1973 by Hornestake Gold Mining Company. Since then there have been numerous CIP plants built in the U.S A., South Africa and Australia."

Jan 1, 1983

By G. Azimi, C. A. Ang, F. Zhang

"Nickel recovery from laterite ores generates large amounts of solid and liquid wastes. This is primarily due to the low concentration of Ni (about 1.4 wt%) in the feed ore to the High-Pressure-Acid-Leaching (HPAL) process. It is known that the HPAL residue contains a high concentration of hematite, a commercially important source of iron in the steelmaking industry. However, the balance is natroalunite, containing sulfur, which is a detrimental element in the steelmaking process. Hence, to make the HPAL residue a suitable feed for steelmaking, natroalunite must be removed. The current work is focused on: 1) a thorough characterization of the HPAL residue obtained from Vale, and 2) a systematic investigation of an alkaline leach process to remove natroalunite. The characterization results indicated that there are about 83 and 12 wt% hematite and natroalunite in the HPAL residue, respectively. The leaching results indicate that sodium hydroxide is the best leaching agent, which results in 55 wt% reduction in the sulfur content. The results of this work enable the conversion of an otherwise waste product into a useful feedstock for steelmaking. Furthermore, this project could potentially have significant environmental benefits by reducing the amount of residue produced during the HPAL process.INTRODUCTION Conventionally, crude steel has been obtained by reducing iron ore containing oxides such as hematite (Fe2O3), magnetite (Fe3O4), and wüstite (FeO) in a blast furnace with coke. The product is then refined in a basic oxygen furnace to produce steel with useful properties (McGannon, 1969; Turkdogan, 1978). Steel has been sought for its desirable properties and its application is widespread throughout modern civilizations. Surpassing the growth rate of other materials, the annual demand of steel has increased at a compound growth rate of 5% over the last 20 years (Baddoo, 2008). The global demand for steel was reported to be 1501 Mt in 2016 and demand is expected to double by 2050 (Cullen, Allwood, & Bambach, 2012; World Steel Association, 2016). In recent years, to meet the rapid growth of demand, secondary resources for iron have been identified as strategic sources of iron (Das, Kumar, & Ramachandrarao, 2000; Li, Sun, Bai, & Li, 2010; Matschullat et al., 2000). The residue produced from high-pressure acid leaching (HPAL) of laterite ore has been identified as one of the important secondary sources of iron (McDonald & Whittington, 2008). Laterite ore represents 60% of the world’s nickel resources and accounts for approximately 40-50% of the world annual nickel production (U.S. Geological Survey, 2016). Therefore, the amount of iron residue produced by the process is substantial and its utilization will produce both economic and environmental benefits."

Jan 1, 2017

By Nessetech Consulting, L. A. Cisternas, E. D. Galvez, S. H. Kuan, L. H. Saw

"In Malaysia, there were two rare earths processing plants namely Asian Rare Earth (ARE) and the Malaysian Rare Earth Corporation Plant (MAREC) in Perak, which were operated until 1992 and were subsequently closed due to problems pertaining to disposal of large amount of radioactive waste. Recently, Lynas Advanced Materials Plant (LAMP) has become one of the largest rare earths processing plant in the world producing rare earth elements (REE) in Gebeng, Pahang. The primary raw material is lanthanide concentrate (LC) which is imported from Mount Weld mine in Australia and shipped to Malaysia. LC is produced from lanthanide ore after mining and mineral processing. The ore has a lower impact than Bayan Obo, Mountain Pass and adsorbed clay deposits, given the small footprint of the mine itself and the remoteness of the location. The type of ore being mined (rare earth phosphates: carbonatite, monazite) may have higher thorium content than bastnasite ore from the Chinese or American mines but still far below radiation concerns. This paper was written to review the processing flowsheet at the Lynas Advanced Materials Plant (LAMP), the environmental impact associated with the processing of the said ores and the sustainability of the operation.INTRODUCTIONRare earth minerals are one of a set of 17 minerals or chemical elements which consists of yttrium and scandium, as well as the 15 lanthanide elements (lanthanum, cerium, praseodymium, neodymium, promethium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). Despite their importance, rare earth minerals rarely exist in economically viable concentrations and they are usually difficult to extract. Rare-earth minerals create strong magnets when added to magnetic elements such as iron, and are useful for the production of electronics systems as well as electric cars. They are also used extensively in automotive catalytic converters, fluid cracking catalysts in petroleum refining, wind turbines, phosphors in colour televisions and flat panel screens, displays for mobile phones and laptops, rechargeable batteries, and various medical devices. The elements are typically split into two subgroups: the cerium sub-group of ‘‘Light’’ rare earth elements (LREEs) which includes La to Eu and the yttrium sub-group of ‘‘Heavy’’ rare earth elements (HREEs) which include the remaining lanthanide elements, Gd to Lu, including yttrium (Gupta and Krishnamurthy, 1992; Jordens et al., 2013; Trifonov, 1963). Scandium, however, when it is classified as a rare earth element, is not included in either the LREE or HREE classifications (Gupta and Krishnamurthy, 1992; Jordens et al, 2013). Half of the world’s 110 million tons of reserves exist in China while other sizable deposits are found in Russia, United States, Brazil, India, Australia, Canada, and Greenland. The countries known to be actively mining REE are China, Russia, India, Brazil and Malaysia (Hao et al., 2015). Among these countries, China has the largest REE production, accounting for more than 93% of global supply (Yap, 2015). The critical metal report (Moss et al. 2011) listed 14 economically vital raw materials that are prone to supply disruption and concluded that supply disruption would threaten the goal for cleaner transport and sustainable energy since rare earth metals are used in products using green technology, such as hybrid/electric vehicles, carbon capture systems, wind power generation, low-energy lighting, and energy efficient flat-screen displays."

Jan 1, 2016

By George H. Bodfish

This paper begins with a short history of air compressors, emphasizing their "roots" in the mining industry. It then describes the types of compressors available, including reciprocal, the various rotary positive-displacement compressors, and the centrifugal. The advantages and disadvantages of selecting a certain type of compressor over another are enumerated, considering customer requirements and operating costs, among other factors. Guidelines to operation and maintenance are discussed, including installation, monitoring and maintenance procedures. Finally, the paper addresses itself to future trends, with special attention being given to the system concept, the increasing use of rotary compressors, power consumption, reliability, packaging and noise attenuation.

Jan 1, 1978

By Tommee Larochelle, Henry Kasaini

"Simulation of rare earth element solvent extraction processes for plant design and optimization is complex, requires extensive bench scale and pilot scale testing, and is traditionally performed using proprietary algorithms. The complexity of simulation is mainly due to traditional simulation software solvent extraction modules not being designed to simulate rare earth separation processes because of the interaction between each element. This paper presents an alternative method for designing and optimizing rare earth element solvent extraction separation processes using METSIM to converge each stage of the battery individually until the full battery reached ultimate convergence. A feed-forward controller is used to control the organic to aqueous flow ratio feeding the solvent extraction modules. This method minimizes the complexity of simulating such processes by using inexpensive batch solvent extraction data, and allowing for rapid theoretical optimization, by varying the process configuration and parameters from a graphic interface instead of the traditional code-based interface of most proprietary models. Comparison of the model predictions to pilot plant data reveals that the method can be used to accurately model rare earth solvent extraction processes, as illustrated by its application in the development of Rare Element Resources innovative process.INTRODUCTIONThe Rare Earth Elements (REEs) consist of 16 metals, specifically the 15 lanthanide elements and yttrium, which is typically found in the same mineral deposits as the lanthanides. Scandium can be associated with the rare earth elements, but is usually only present in trace amounts, and therefore omitted. The term “rare earths” originates from an old term used to designate minerals (earths) and their believed scarcity upon their initial discovery. The rare earths designation is now considered a misnomer because it was demonstrated that the crustal abundance of some rare earth elements, such as cerium, is known to be higher than many common metals, such as copper. However, enriched deposits are fairly uncommon compared to other similarly abundant metals. The REEs are typically divided into groups commonly consisting of light rare earths (LREEs), medium rare earths (MREE), and heavy rare earths (HREEs). Light rare earth elements include lanthanum to neodymium, medium rare earths include samarium to gadolinium and the heavy rare earth elements include terbium to lutetium, and yttrium. The REEs exhibit similar chemical characteristics and are usually extracted from the ore and processed into a mixed rare earth concentrate. The rare earth concentrate requires further processing in order to separate the REEs from each other and produce a series of single element products."

Jan 1, 2016

By I. J. Burgess, B. C. Barlow

"The electrodissolution of nickel pellets with different controlled electrical variables was investigated in an effort to mitigate plating residue in Watts bath based electroplating cells. During galvanostatic dissolution at 0.4 A dm-2, the anode potential was seen to oscillate between passive and pitting potentials. In-situ microscopy and ex-situ characterization has shown that lacy-pit formation and large, partially perforated, pit covers form during the potential decay from pitting potentials. In general, covered pitting at low current density shows increased plating residue. Using potential pulses is one way to maintain greater control over surface pitting by creating a higher density of pit nuclei while at the same time controlling their growth. Pits generated from a series potential pulses were examined ex situ for a range of pulse times and stages of pit growth were identified. An alternative method of anode dissolution was devised using potential pulses and duty cycles that allowed average current densities comparable to industrial plating conditions to be achieved. By restricting the time at pitting potentials to 0.05 s, plating residue was reduced more than six-fold in comparison to an equivalent galvanostatic experiment run at a comparable current density.INTRODUCTIONIn typical galvanostatic (direct current) nickel electroplating cells employing soluble anodes, some amount of plating residue is produced which consists of metallic nickel and impurities that detach from the bulk in the form of small fines. Significant buildup of residue requires plating operations be halted and the anode assembly cleaned of residue before operation can resume. While variables in the refining process have been shown to affect plating residue, more precise control of electrochemical variables may provide an attractive route to mitigation of residue."

Jan 1, 2016

By Rolf Andreas Lauten, Guy Kluck

"Formation of scales may have important detrimental effects in many mineral processing applications. A well-known problem is the need for frequent maintenance to remove scale from processing equipment. Another challenge may relate to encapsulation of valuable minerals in precipitating scale. In this work, we explore the ability of some crystal growth inhibitors to prevent or lower the degree of scale precipitation. In many situations pregnant leach solutions contains substantial concentrations of calcium, magnesium, sulfate and carbonate in addition to dissolved valuable elements, e.g. gold, copper, zinc. Together with non-dissolved gangue minerals, some slurries may also contain particulate gold, copper etc. During normal processing of the pregnant leach solution it may be exposed to temperature gradients or similar promoting precipitation of various scales. Valuable minerals may become entrapped in precipitates and thus become inaccessible to the lixiviant. Use of a crystal growth inhibitor may lower the degree of encapsulation of valuable elements.Using a simple model system, supersaturated with respect to gypsum, the effect of some crystal growth inhibitors on the prevention of scale is evaluated in terms of amount precipitated gypsum, the particle size of the precipitated gypsum and the carbon gold loading capacity.INTRODUCTIONGold bearing sulfide ores are often roasted or pressure oxidised prior to leaching. The purpose of this unit operation is to prevent loading the leaching circuit with sulfides that consume cyanide. Pressure oxidation or roasting chemically converts the sulfides into sulfates and at the same time, the pH of the slurry ends up in the acidic range. Typically, lime addition is the preferred means to raise the pH to around 10 where gold leaching takes place. Combination of large amounts of calcium ions from the lime with sulfate ions from the ore induces precipitation of gypsum. Compounds like calcium carbonate may also precipitate if carbonate ions are present in the slurry. Depending upon the composition of the ore, compounds like calcium carbonate and other types of scale may also precipitate on gold surfaces on the slurry particles. A layer of scale on top of exposed gold surfaces will prevent dissolution in the cyanidation that takes place during leaching. Naturally, such a precipitation may lower the gold recovery."

Jan 1, 2016

By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By R. J. Grant, D. W. Scott, M. A. Cooper, E. R. Shannon

"The Brunswick No.12 site concentrator processes 10,500 tonnes per day of a complex lead, zinc, copper and silver ore producing four concentrates by differential flotation. Research over the years has led to increased understanding about the mineralogical and flotation characteristics of the ore. A pilot plant study conducted at Lakefield Research, primarily designed to investigate the technical feasibility of semi-autogenous grinding, provided an opportunity to test recent theories about grind size,, reagent schedule and flowsheet configuration.A fundamental approach was taken with each of the unit processes involved in grinding and flotation. Basic operating and metallurgical criteria were established in each area and a step-by-step implementation program initiated in the plant.Significant improvements in metallurgical and financial performance have been realized through the application of basic grinding and flotation principles using conventional milling equipment and without major capital expenditure. Current operating practice is detailed and metallurgical advancements cited.INTRODUCTIONBrunswick Mining and Smelting operates one of the world's largest lead and zinc mines near Bathurst, New Brunswick. Brunswick is a publicly traded company with majority ownership held by Noranda Minerals (63%). In addition to the No. 12 underground mine, the company operates a lead smelter and phosphate fertilizer plant in Belledune, N.B. and maintains a 25% interest in a joint venture with Noranda Minerals' Heath Steele mine near Newcastle, N.B. Through the four operations, a total of 2000 people are directly employed with fixed assets totalling Cdn$187 million (BM&S, 1991)."

Jan 1, 1993