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By Timothy W. Ellis, Abbas H. Mirza, R. David Prengaman

Recycled lead, i.e. material produced by the recycling of lead-acid batteries, has become the primary source of lead in much of the world. This has been important to the recycled lead industry as other uses have dwindled, e.g. lead based pigments, chemicals, fuel additives, solders and CRT glasses. Presently, battery manufacturing accounts for greater than 85% of lead consumption worldwide while recycled lead accounts for approximately the same market share of lead supply. Battery manufacturing and production of recycled lead are intimately coupled. In 2007, of all the industrial base metals, lead from lead-acid batteries had the highest recycling rate in North America at greater than 95%. In this paper we will review some of the processes and technologies used in a modern lead acid battery recycling facility, and how recycled lead has become the material of choice for battery construction through the development of a recovery and refining process that exceeds the industry requirements. We will also briefly review an advanced air emissions treatment system in a modern lead recycling plant that demonstrates the feasibility of a new maximum available control technology (MACT) for secondary lead smelters.

Jan 1, 2011

By D. M. Morrison

"The most important factor in Canadian mining is not the operating cost of current projects but the availability of capital for future projects. The future of mining at depth will be producing ore from the top of the orebody working downward with very effective, tightly controlled mining methods, i.e. either selective mining or bulk mining with well controlled dilution and fragmentation. The key characteristics of future mines will be smaller access excavations, more effective ground support, very precise blasting techniques and more efficient and reliable materials handling systems. Equipment will be smaller and designed for high efficiency and low maintenance, reducing both the capital and operating cost. This means there will be fewer scoops, more continuous mucking machines and conveyor belts, both lateral and vertical.Orepass failures have become accepted and the resultant redevelopment and retramming has become common. The capital investment in so-called permanent ore passes and crusher stations becomes questionable, particularly when crushers are only necessary for less than 10% of the ore going through the system. The best way to solve the chronic instability of ore passes is, as with all of the stability problems at depth, by reducing the excavation size rather than increasing ground support. Smaller access drifts would reduce the capital cost and increase the rate of development as well as reduce the amount of waste to be handled, reducing the ground support and the ventilation requirements. Large drifts and ore passes are essential only for the equipment needed to handle large pieces of ore and the productivity of scoops is very expensive when the requirements for ventilation and large access drifts are taken into account. The key issue is the fragmentation generated by primary blasting.The future of mining in Canada will depend on simple and robust technology geared to the environment in which it will have to operate. Its survival will depend on some-thing much more fundamental and difficult to accomplish than a technological advance — it will require a dramatic change in the way the mining process is managed, how work is organized, how effort is rewarded and how costs are measured — a complete change in mind-set."

Jan 1, 1996

By C. A. D' Odorico

The zinc pressure leaching (ZPL) plant at Teck Cominco's Trail Operations was started up in 1981 and represented the world's first commercialization of the technology. From the outset, the process was designed to operate using iron-rich Sullivan Mine zinc concentrate. When the Sullivan Mine reached the end of its life in 2002, the ZPL plant underwent a significant process change with the treatment of 100% Red Dog zinc concentrate. Through careful improvements to existing plant processes, controlled changes to plant operating parameters and a rapid adjustment to the modified process by operations personnel, the plant has been successfully converted to processing a feed of 100% Red Dog zinc concentrate. This paper discusses the challenges faced during the conversion and describes the modifications to plant operating procedures, as well as changes to plant processes.

Jan 1, 2004

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By R. P. Viljoen, A. D. Scheglov, A. L. Sokolov

"Abstract -The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth's crust including ancient platforms, mobile belts and zones of tectonic­ magmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonically­ controlled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian plat­ form, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu rnineralization. lt does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By Yves Bellemare

Entre 1983 et 1997, l'exploitation de la pierre de taille au Québec a été marquée par l'émergence et la consolidation de plusieurs nouvelles variétés de granit, provenant exclusivement ou presque de la Province de Grenville. Le Québec demeure toujours le principal expéditeur canadien de granit dimensionnel, avec des expéditions annuelles représentant près de quatre-vingt-dix pour cent des expéditions totales canadiennes de granit brut et transformé. La production annuelle de granit brut oscille, depuis 1994, autour de cent mille tonnes métriques. Cette production a plus que doublé de 63 000 à 140 000 tonnes métriques entre 1981 et 1990, mais elle a connu une chute importante en 1991 (67 000 tonnes métriques); cependant depuis 1994, elle est en forte progression (Ménard, 1998). En 1983, le granit dimensionnel était extrait de plus de vingt-cinq carrières, dont les trois quarts se localisaient dans la Province géologique de Grenville. Comparativement, en 1997, le Québec comptait trente-sept carrières actives, dont trente-cinq dans le Grenville (Gaudreau et al., 1998). Cette concentration des carrières dans la Province de Grenville s'explique par la demande accrue de nouveaux produits au fil des ans et par le potentiel élevé de découvertes de nouvelles variétés dans cette Province géologique. L'accessibilité au territoire, toujours plus grande, a facilité la mise en production de carrières favorisant la diversification des produits. Le ministère des Ressources naturelles du Québec (MRNQ) a consacré depuis 1980, beaucoup d'efforts dans la recherche de nouveaux gisements et de nouvelles variétés. En plus des programmes de subvention destinés aux prospecteurs ou aux compagnies, le ministère a réalisé des campagnes d'inventaire de pierre de taille, de pierre concassée et de pierre d'enrochement pour en connaître le potentiel géologique et à orienter les recherches futures (Nantel, 1983; Nantel et Martignole, 1991; Bellemare, 1995a, b, c, d, e, f, 1997, 1998a and b; Bellemare et Petryk, 1996a, b, c and d). Cette étude donne un aperçu des différentes variétés de pierres extraites dans la Province de Grenville entre 1983 et 1997, les situe dans leur contexte géologique et en localise les principales régions productrices. Elle est une suite à l'article publiée par Nantel (1984).

Jan 1, 2001

By W. M. Williams

"Although manganese is a metal virtually unknown to the layman, it is hardly necessary to point out to the engineer the importance of manganese in modern metallurgy, an importance intimately linked with iron (and steel), the basic materials of engineering construction for hundreds of years and certain to remain so for long into the future. World steel production will approach and perhaps reach 1 billion tons/year in the 1980s; with a manganese content between 0.5% and 1 % in ordinary steels, and more in specialty steels, manganese use worldwide will soon approach 15 million tons annually. Manganese was discovered and isolated in Sweden in 1774 by Karl Wilhelm Scheele (who also discovered molybdenum), but the element was only of scientific interest for several decades. By the early part of the nineteenth century, however, manganese oxide had become commercially available and was in use for colouring glass and for the production of chlorine. Commercial application in metallurgy appears to have been limited to the manufacture of crucible (or ""cast"") steel, a highquality product made by carburizing wrought iron, and melting it in small batches to make ingots which could be rolled and used for special applications, e.g. for the manufacture of fine tools or for ""steeling"" the cutting edges of implements such as wrought iron axes and chisels.* However, it was not until Bessemer's epoch-making invention of cheap steel in 1856, and the dramatic expansion of the steel industry thereafter, that manganese assumed the importance that it holds in modern steelmaking."

Jan 1, 1999

By G. W. Poling

"Construction, equipping and planned operation of a new laboratory for engineering-teaching and research in coal and mineral processing is described. This facility will provide approximately 1860 m2 (20,000 ft. 2 ) of laboratory space with nearly half devoted to a new venture in coal preparation. Two high-bay, overhead crane-accessed areas will accommodate major unit operations for each of the ""coal"" and ""mineral"" laboratories. COAL PREPARATION FACILITIES:The coal facility provides three main functional areas:(1) Sample preparation (drying, blending, crushing, screening) and sink-float washability testing.(2) Unit operations U1igh-bay, serviced by crane).(3) Analytical laboratories.(l) Sample Preparation and Sink-Float TestingBreaking or comminution of coal will be accomplished using a rolls crusher, a hammer mill, a jaw crusher, or a pulverizer. Capacity to prepare coal at rates of up to approximately 4 tph will be provided by some of these units. Large diameter (~0.5m) baths of heavy organic liquids will be available for sink-float washability tests on coal samples of several kg. Particle sizes of up to 25 mm can be tested in these baths. Smaller scale washability tests on finer samples will be accelerated by centrifuges."

Jan 1, 1980

By Richard W. Lawrence, Richard Poulin

"Numerous processes co-exist for metal extraction and for metal removal from effluents of mining operations. Each process enjoys an economic advantage, including environmental cost and benefit, if utilized in a specific situation. This applies equally to biohydrometallurgical processes. This paper will analyze four types of biohydrometallurgical processes for their economic and environmental attributes: biooxidation of refractory gold, extraction of copper from sulfide, metal removal from effluents by active sulfate reduction, and metal removal by the use of wetlands. By examining the economic and environmental advantages of these processes, generalizations can formalized and it becomes possible to define niches of application where biohydrometallurgy can be considered. Our analysis shows that biohydrometallurgy can be efficient at small scale, be more environmentally friendly than conventional technologies and is relatively easier to operate. The higher financial risk associated with unproven technologies at the commercial scale is being eliminated as biotechnology-based plants are put into production.IntroductionBiotechnology can be described as the rational exploitation of the activities of living cells or parts thereof, requiring an integrated multidisciplinary approach between biological and technical disciplines. Microbiology, biochemistry, botany, molecular biology, chemistry and engineering all contribute to practical applications in the extraction, manufacturing and service industries, and in environmental management. Considerable commercial success of biotechnology has been achieved in several sectors, including health care, agriculture, forestry and aquaculture.Over the past 40 years, industry, research organizations, government laboratories, and universities in a large number of countries have participated in investigating the utilization of biotechnology applications in mining. Today, several technologies are used commercially in well understood and engineered systems which can be grouped under the term biohydrometallurgy. Many more technologies have been demonstrated at laboratory or pilot plant scale. Although initial developments and commercial applications were aimed at metal extraction, the dramatic increase in environmental awareness, the practice of sound environmental management demanded by more stringent regulations over the past decade, and the need for low cost treatment in perpetuity, has led to serious investigation of biotechnology for environmental control. In addition, increasing power costs, lowering of ore grades, and decreasing commodity price in real dollar terms require the use of highly efficient and competitive extractive technologies."

Jan 1, 1998

By Gordon T. McKenna

"Syncrude Canada Ltd. is developing new concepts in lease-closure landscape design for its Oil Sands Leases 17 and 22 in northeastern Alberta. Closure planning is becoming an integral part of the planning cycles and of the lease operation. By incorporating closure planning into the day-to-day operation, the company will achieve acceptable lease closure in an economical manner. Ultimately, Syncrude will achieve lower operating costs through innovation in mine planning and a reduction in residual liabilities.New concepts being evaluated for lease-closure landscape design include: designing for closure, use of landforms and natural analogs, self-armouring bouldery ground, robustness in design, landform grading, terrain analysis of reclaimed land, geotechnical hazard assessments, choices in closure design timeframes, passive maintenance, determining post-closure monitoring goals, engineering tailings, engineering other substrates, use of test plots and field demonstrations, geomorphologic monitoring of reclaimed lands, defining closure goals, and visiting other mines. These concepts are being formalized under the new discipline of Landscape Engineering."

Jan 1, 1996

By Barry J. Morash

The over-all slope angle of between 55 and 60 degrees at the Adams Mine necessitates control blasting on the final pit walls. The control blasting techniques used are pre-shearing and buffer blasting. Pre-shearing with 2'I2-inch holes on 5-foot centers is used in areas where jointing and rock type are not conducive to smooth stable walls. Buffer blasting with 12'/4-inch holes is used in areas where the rock is competent. Control blasting adds to the operating costs, but can result in substantial savings in increased slope angle and reduced stripping.

Jan 1, 1978

SOFCs with thin electrolyte of two types: SDC (15um) single-layer and YSZ (5um) + SDC (15um) bi-layer were fabricated by screen printing and co-firing on Ni¬YSZ cermet substrates. Using in-situ sintered Sm0.5Sr0.5CoO3 cathode the SDC-cell shows high performance at low temperature, 1180mW/cm2 peak power density around 650°C, while the YSZ+SDC bi-layer cell generates about 340mW/cm2 at 650°C, and good performance at 700-800°C with almost theoretical OCV value. Many Zr-content micro-islands were found on the SDC electrolyte surface. The influence of co-firing temperature and thin film preparation methods on the Zr-islands' appearance was investigated.

Jan 1, 2005

By J. E. Udd, L. B. Geller

"Mine-shaft wire-rope discard regulations include, among other criteria, a limited amount of permissible loss-of-breaking-strength (LBS). Currently, this parameter is estimated on the basis of non-destrutive-testing (NDT) with electro-magnetic (EM) type instruments. This paper analyses the accuracy with which these estimates have, so far, been obtained in practice.It concludes that while certain types of testers have produced better results than others, the desired accuracy level has not been attained. Also discussed are the putative reasons for this situation, and appropriate actions that the mining industry might wish to take."

Jan 1, 1990

By K. S. Fraser, H. J. H. Pieterse

"A pressure oxidation plant to pretreat refractory sulphide ore at the Goldstrike plant in Nevada, was commissioned in early February 1990. The plant, with a nominal capacity of 1363 t/d, was commissioned over a one-week period and achieved design capacity and availability within ten weeks an unusually short period for a plant of this complexity.The pressure oxidation process is conducted under elevated temperature and pressure conditions, and in a corrosive environment. These conditions demand that the process and engineering design of the plant be carried out in a much more sophisticated and detailed manner than is normally required in a conventional gold plant.This paper provides an account of the process and engineering design of the Goldstrike pressure oxidation plant with special emphasis on the design of the vessels, slurry pumps, piping, valves, and control systems.BackgroundLocationThe Goldstrike property is located in Eureka County in northcentral Nevada on the Carlin geological trend. The mine is approximately 40 km northwest of the town of Carlin which is situated on Interstate Highway 80. The minesite is located 1700 m above sea level in the Tuscarora Mountains.Initial Goldstrike OperationsShallow, low-grade mineralization was discovered by diamond drilling in the Goldstrike area in the 1960s. A heap leach operation was established in the mid-I970s by the previous owners. The Post deposit was discovered in 1982. Gold production by mining and heap leaching reached I t/a (40 000 oz/a). American Barrick purchased the property in 1987 and started an aggressive program of deep drilling. This led to the discovery of the Betze and Deep Post deposits and established sufficient reserves to justify an initial 4100 t/d mill and a 5 500 000 t/a heap leach operation"

Jan 1, 1992

By A. Y. Smith, R. J. Allan, E. H. W. Hornbrook, R. W. Boyle, W. Dyck

"HYDROGEOCHEMICAL METHODS in the Canadian Shield can be based on analyses of the following :(1) spring waters and their precipitates;(2) stream and river waters;(3) lake and muskeg waters;( 4) ground waters from drill holes, wells, faults, etc.;(5) waters issuing from diamond drill holes, faults, shear zones, etc. into mine workings and open pits; also analyses of precipitates associated With these waters.The first four can be utilized in both reconnaissance and detailed surveys. The last is suitable only for detailed work.For hydrogeochemical methods of prospecting to be effective, the following conditions must be present. 1. Natural waters must come into contact with mineral deposits and remain in contact with them long enough for the solution of detectible amounts of ore, gangue or indicator elements. 2. Dispersion patterns must be present in the hydrologic systems in order to trace the elements back to their source. These patterns may take the form of trains (e.g., increasing amounts of elements upstream toward t he source (s), Figure 1 ) or halos (e.g., increasing amounts of elements in bodies of water toward the source (s), F igures 2 and 3)."

Jan 1, 1971

"Projections of demand for Alberta coal indicate a quadrupling of current production rates to some 70 million tonnes/year by the end of the century. About half of this output-comprised of subbituminous coal-will be required within the province, primarily for generation of electric energy. The remainder-roughly 70 per cent high-volatile bituminous (hvb) steam coal and 30 per cent medium- or low-volatile bituminous (mvb/lvb) metallurgical coal-will be exported, principally to Pacific Rim and Western European countries. Direct employment in mining and coal processing is projected to increase from the present ca. 3000 to at least 12,000 persons.This paper presents separate forecasts for subbituminous, hvb and mvb/lvb coal production in the period 1982-2000; notes a number of possible developments that could substantially modify these forecasts; and briefly discusses attendant infrastructure requirements. Attention is drawn to potential shortages of qualified manpower and to threatening inadequacies of transportation facilities.IntroductionDespite the dislocations triggered by the 1973 'oil crisis', energy budgets of Western industrial countries are mostly still in the very early stages of the anticipated transition to greater reliance on coal. Shift s to coal are still more often only talked about than being implemented; and the public policies which are essential for timely development of facilities for producing, transporting and using coal are in many instances not yet even broadly formulated, let alone enunciated.In these circumstances, long-range projections of coal demand and supply-even if restricted to internal requirements- are subject to greater uncertainties than usually afflict such forecasts.On the demand side of the equation, these uncertainties arise ultimately from linkages between a need for coal and the availability and pricing of OPEC oil. The current surplus of oil on world markets, which has recently forced substantial reductions of posted prices, is undoubtedly a transient phenomenon that is unlikely to have any long-term impact."

Jan 1, 1982

By P. Lausch, Z. X. He, J. F. Archibald

"Documented underground fill failures have resulted because of the lack of adequate knowledge concerning fill strength and other physical parameters, as well as to a lack of consistent quality of fill materials being used by operators. On the basis of literature review and correspondence with backfill operators at 18 mines throughout the province of Ontario, non-systematic quality control procedures have been shown to exist, both within different levels of single operations and between separate mining operations, which act to provide inferior engineered fill materials and erratic application response in situ.Assessment of existing procedures set by mine operators for determining backfill physical parameters, and recommendation of optimum fill material testing and manufacturing guidelines are presented in this paper.A series of standard fill characterization test procedures are recommended to provide substantial, though not comprehensive, fill behaviour review. The purpose of these recommendations is to propose industry standards for backfill quality review. Data acquired could be utilized for fill design functions and as a means of comparing fill quality parameters between sites in a regular and more systematic fashion than is presently done."

Jan 1, 1993

By Jean-Loui Frenetie, Françoi Himbeault

"Flow of traffic in the underground mine has been improved through the years with clever use of traffic lights. The evolution is characterized by three major design changes. This paper will scan the basic criteria of these designs.IntroductionMines Gaspe, formerly known as Gaspe Copper Mines Limited, is a member of the Noranda Group of companies. The mine is the ""raison d'etre"" of the town of Murdochville, located 600 m above sea level on the Gaspe Peninsula. Paved highways link the town with Gaspe, 95 km to the east, and with Anse Pleureuse, 400 km to the north, on the Gulf of St. Lawrence.The low-grade copper mineralization was discovered in 1921 at Copper Mountain by local prospectors, the Miller brothers. Noranda Mines Limited obtained an interest in the property in 1937. World War II interrupted exploration work and it was not until 195I that a decision was made to bring the property into production.Initially, operations were confined to the Needle Mountain underground deposits which commenced production in 1955. Between 1968 and 1982, low-grade ore from the Mountain open pit supplemented the production. Due to the depressed market, surface and underground operations were suspended in 1982. Needle Mountain underground mining resumed in the second half of 1984, but the Copper Mountain open-pit operation remained idle. Since 1979, more than 75 km of exploration drilling resulted in the discovery of two new deposits, one which is located under the town of Murdochville . Mines Gaspe's present ore reserve, approximating 8 million tonnes, will be depleted by the end of 1992."

Jan 1, 1988

By Michael Hopp

The beginning of the electroforming technology dates itself on the beginning of the industrial revolution 1800 to 1820 approximately. Basis was the existence of electricity in order to be able to drive the electro-form-process. With the development of the electroforming, big names of the science-history, like Michael Faraday (1791? 1867), Sir Humphry Davy (1778?1829), Max Schlöter (1878?1946), Werner von Siemens (1816?1892), and many others. Already about 1840, the first monograph originated to electroforming (38). While in the first years the electro-forming most extensive only to the coating of art - or other usefulness-objects was used. At the beginning of the 20th century the formation of objects from pure metals became more and more, later also from alloys to application. One of the first bigger electroforming factory, the ?Württembergische Metallwarenfabrik? was working 1894 in Geislingen / Steige, Germany. In the industrial application, the electroforming-technology is to be imagined away for miscellaneous coatingtasks and the form-body-preparation no longer today (18). A little bit confusing is the german name ?galvano-technology?. It based on the Italian physiologist and naturalist Luigi Galvani (1737 ? 1798). This technically seen is however wrong, right, the name is electroforming. The physical bases were founded mainly by Michael Faraday and Sir Humphry Davy.

Oct 1, 2003

By Barry W. Schmitke, J. M. Marino

"Cigar Lake Mining Corporation is presently operating an underground test mine in northern Saskatchewan, with a view to developing a high grade uranium deposit. The mining test is intended to demonstrate that the innovative mining methods designed are safe and economical. Two vertical mining methods are considered for the test:• box hole boring from the lower level;• blind boring from the upper level.In both cases, it is anticipated to freeze the ground before excavation to ensure hole stability and limit the inflow of water. Special care will be taken to minimize radiation exposure of personnel.Remote controlled equipment will be used where applicable.The access to the orebody was an important component of the test. After shaft sinking to a depth of 500 m, development work commenced at the 420 level in fractured sandstone which was grouted to restrict the inflow of formation water. The drifting continued in a section of poorly consolidated sand, clay and sandstone; this area was frozen to allow stabilization prior to excavation. At the 480 level relatively little water was encountered in the altered basement gneiss and grouting was not necessary; however, extensive ground support was required in the soft ground areas."

Jan 1, 1992