Search Documents

By N. K. Jaber

The "Pidgeon Process" for the extraction of magnesium from dolomite ore utilizing ferrosilicon as the reducing agent has been studied extensively by active metallurgists such Mr L,M, Pidgeon the father of this process, Most of the work sited so far has focused on heating the (FeSi/MgO,CaO) briquette mix under vacuum in stainless steel retorts by external fuel hydrocarbon heating, In this work Electrical Induction Heating was employed as the heating method whereby the briquette mix was placed in a steel crucible around which an Induction Heating copper coil was wound and placed inside in a stainless steel vacuum tank, It was observed that by virtue of the fast Induction Heating method utilized in the silicothermic extraction process higher reduction temperatures were reached in shorter periods of time due to fast heat transport into the ore charge mix, This facilitated shorter metal reduction times as compared to the conventional fuel heating methods.

Jan 1, 2006

By K. E. Waters, E. R. L. Espiritu, G. R. da Silva

"Rare earth (RE) elements are essential components of emerging green technologies. The increase in demand for these applications have driven the search and development of new rare earth deposits such as the Niobec project in Quebec, Canada. This deposit consists primarily of dolomite with significant amount of RE minerals bastnäsite and monazite, the primary sources of RE elements. Due to the minerals’ fine liberation sizes, flotation is commonly used as a concentration method. To develop an efficient process, the electrokinetic properties of the minerals must be understood. In this study, the surface properties of bastnäsite, monazite (RE minerals) and dolomite (a common gangue mineral) were investigated by zeta potential measurements. These measurements are affected by various ions present in solution; for bastnäsite, monazite and dolomite, some of these ions are H+, OH-, PO43- and CO32-. Dolomite, being a sparingly soluble mineral and a primary component of the ore, may be the greatest contributor of these ions in solution in the form of CO32- ions. Thus, different sources of CO32- ions (from dolomite dissolution and from Na2CO3) were investigated. The research work aims at elucidating how these reagents may influence the minerals’ surfaces. The results have shown that dolomite supernatant and sodium carbonate greatly affect the electrokinetic properties of each minerals. The addition of dolomite supernatant have resulted to relatively similar zeta potential of the minerals; while, sodium carbonate have affected them differently. These observations could be useful in efficient flotation of bastnäsite and/or monazite from bastnäsite-monazite-dolomite system.INTRODUCTIONThe increase in the demand for rare earth (RE) elements has driven the search and development of new deposits. Out of 53 rare earth projects in the world, 19 can be found in Canada (Hatch, 2015). These include the Niobec project of Magris Resources Company in Quebec. This deposit contains a significant amount of rare earth minerals (such as bastnäsite and monazite), with carbonates (such as dolomite) as the primary gangue minerals."

Jan 1, 2016

By Jin Li

The tensile properties and microstructure of AZ91 Mg alloy before and after equal channel angular extrusion (ECAE), and the fracture behavior during tensile testing for as-extrusion and ECAE AZ91 were investigated. The alloy was performed ECAE from one to eight passes at 498K. The elongation decreased with the pass number increasing after ECAE. Grains were refined, partial coarse ß-Mg17Al12 phase fell to pieces, fine ß-Mg17Al12 precipitated in the AZ91 Mg alloy after ECAE. During tensile test the a-Mg/ ß-Mg17Al12, a-Mg/Al8Mn5 interface and the grain boundaries in a-Mg matrix acted as the crack initiation sources. The frequency of micro-cracks at the a-Mg/ß-Mg17Al12 interfaces and grain boundaries increased after ECAE, which accelerated the growth and coalescence of the micro-cracks during tensile test and resulted in the decrease of elongation of AZ91 Mg alloy by ECAE.

Jan 1, 2006

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By B. S. W. Buffam

"The property of Aunor Gold Mines, Limited, is in Deloro township, Ontario, about 3 miles southeast of Timmins. It consists of a group of eleven claims between the Buffalo Ankerite and Delnite mines.In the autumn of 1909, two brothers, John A. and W. S. Mitchell, joined the 'gold rush' to Porcupine. By the time they arrived the township of Tisdale, in which the Hollinger and Dome discoveries had been made, was staked solid but they managed to locate four claims in the northern part of Deloro township. Sufficient surface work was performed to bring the claims to patent in 1915. Following the Porcupine fire the Mitchells left the north to follow the oil developments in southwestern United States. In 1935 because of the rise in the price of gold and the successful development of the l3uffalo Ankerite and Delnite mines, they returned to Timmins and organized Augite Porcupine Mines, Limited, which combined the original four claims in Deloro and two adjoining claims controlled by Montreal River International Silver Mines, Limited. There were few rock exposures on the property, and as the overburden was generally deep surface exploration was impracticable. A programme of diamond drilling was, there; fore, undertaken in an endeavour to locate the western extension of the orebearing formation of the Buffalo Ankerite mine. This drilling was started in August 1936, and 5 months later ore was intersected at a depth of 500 feet on the south boundary of the property."

Jan 1, 1954

By Michael McClintock, Bern Klein

"The high pressure grinding roll (HPGR) is a relatively new comminution technology that is gaining popularity for providing energy efficient solution to hard rock mining operations. A significant barrier to increased adoption of HPGRs is the present requirement for large amounts (excess of 2 tonnes) of sample for pilot testing, which may not be possible for most early stage projects. Three methodologies have been developed at NBK Institute of Mining Engineering at the University of British Columbia that may be used for sizing design optimization of HPGR circuits. All three methodologies use a MTS pistonpress to simulate HPGR comminution. These tests are capable of providing information regarding energy consumption, energy breakage relationship, reduction ratio, and product size distributions. In a period of slow economic development, these methodologies are critical to allow the industry to cost effectively understand the operational benefits of HPGR implementation. This paper examines previous test work done at UBC, as well as the development of an HPGR and piston press database for use in sizing and budgeting of HPGR circuits.INTRODUCTIONCurrently, the mining industry faces several challenges due to falling commodity prices and escalating costs. This has applied pressure for operations and projects to reduce costs and improve project economics. In addition engineering and metallurgical budgets have shrunk as companies try to conserve cash. Improvements and optimization of milling and comminution circuits is one area project economics may be significantly improved. By considering alternative comminution technologies such as the high pressure grinding roll (HPGR), energy operating costs may be greatly lowered. Many have begun to implement HPGR crushing as an alternative to semi-autogenous grinding (SAG) mills, including KGHM and, Sierra Gorda, and Freeport Mc-MoRan’s Cerro Verde operation. However, implementing new technology for companies with little or no HPGR experience may not be practical. An operator must consider both feasibility and economics of a circuit. Currently, consideration of the HPGR requires expensive pilot scale testing for which large sample sizes are needed. In addition, few laboratories are equipped for running pilot scale HPGR test programs. Furthermore, the results of pilot HPGR testing are dependent on the quality of the sample, which cannot represent variations across a deposit. In contrast, ball mills and SAG mills can be sized using the Bond Mill Work Indexes that require a small amount of sample which enable a number of different geological blocks to be tested to allow engineers to have a complete understanding of how the comminution circuit will perform for the life of mine."

Jan 1, 2016

By J. P. Messervey

THE story of the efforts made by the Department of Mines of Nova Scotia in the search for and investigation of mineral resources for the Canadian war effort began in the spring of 1937. During the past five years, however, heavy enlistments in the Active Service Forces by employees of the mining industry of the Province caused a recession in the production of coal, salt, and other essential minerals required to keep industry rolling on a wartime basis. A marked increase was shown during the period in prospecting for 'strategic' minerals, not only by individuals but also by some of the foremost mining companies. The Provincial Government offered encouragement in this field of endeavour by the enactment of legislation whereby the prospector was enabled to secure the maximum area of ground in a prospecting license at a minimum of cost. The labour requirements on the ground staked, however, remained unchanged. The Nova Scotia Department of Mines continued active investigation of minerals vital to the war effort. These included fluorspar, barytes, diatomite, limestone, and coal. Fundamental knowledge concerning the geology and mode of occurrence of these minerals was accumulated and extensive diamond drilling was carried out on the promising occurrences. Work in these fields is being continued.

Jan 1, 1945

By Andrew Dobson

The assessment and control of environmental noise from mines has become increasingly important in recent years, due to urbanization and population growth, increased regulation of environmental factors, and overall awareness and sensitivities to noise exposure. Minimizing adverse effects on communities and achieving compliance with local ordinances is now commonplace, and consideration of noise during the design and/or operation of a mine cannot be ignored. Ventilation equipment can represent the loudest and most bothersome equpiment at mines, however there are complexities when attempting to control the assocaited noise, due to the acoustical nature of mine vent fans. In fact, the utilization of traditional and/or industry standard methods can intensify the noise impact, or simply not work as intended. This paper provides recommendations on specific noise control methods that are suitable for mine ventilation equipment, based on recent assessment work and field experience.

Oct 1, 2024

By Tyler Roberts

New Afton mine is an 11,000 tonne per day block caving operation, located 8 km west of the city of Kamloops, British Columbia. Due to the nature of block caving and the weak rock mass at New Afton, the mine has faced and overcome many blasting challenges during its ramp-up to commercial production. As New Afton Mine continues to grow the demand for drill and blast precision has continued to grow as well; any misstep incurs delays in achieving full production capacity. The block cave mining method used at New Afton employs single-shot draw-bells, fired with very little void and blind undercutting, allowing little margin for error. New Afton has made continuous improvements to its blasting strategy by reacting quickly to real-time problems and employing sustainable, repeatable solutions to overcome its unique blasting requirements. Examples of these solutions include: increasing blast hole diameter, casing production drill holes, developing pre-loading procedures and developing strategies for remotely blasting under-broken remnants in both draw-bells and undercutting. Increasing the blast hole diameter has alleviated initial problems with hole plugging in the highly jointed rock mass at New Afton. This has reduced drill-cleaning time significantly and enabled New Afton to meet blasting targets. PVC hole casing was trialed when blasting in extremely fractured ground, where drill holes continually plugged. The casing allowed the drill holes to remain open long enough to load and blast. Calculations were carried out in order to achieve the same explosive energy in the cased holes as a typical blast. Results were generally positive, but more testing is required. Production flexibility and scheduling reliability have been maintained at New Afton by developing a pre-loading procedure for the production undercutting. In doing so, New Afton has been able to keep productivity high by having a flexible production schedule that is not reliant on a specific piece of equipment or production drive to remain productive; this flexibility is because the mucking of undercut material can occur at any stage of the drill/blast/muck cycle. New Afton has developed a strategy for blasting remnant under-break in its draw-bells and undercutting by remotely drilling holes near to the under-broken section and then loading the toes of these holes with emulsion, the remainder of the hole is then filled with grout. The holes are grouted in order to prevent damage to permanent pillars between draw-bells (where the majority of the recovery holes need to be located). Several critical areas were recovered using this technique with little to no damage to the remaining permanent pillars. Innovative blasting solutions have allowed New Afton to overcome obstacles in order to become a producing operation. Moving forward, New Afton looks to continue its trend of innovative drilling and blasting techniques when faced with out of the ordinary situations.

Aug 1, 2013

By Kuwauchi. Y., M. Barati

Recycling of dust using a rotary hearth furnace (RHF) has gained considerable attention in the past two decades for the sustainable production of steel with less environmental impact. In order to further promote the recycling of electric arc furnace dust and carbonaceous wastes using the RHF process, a mathematical model was developed to predict the reaction behaviour of dust-reductant composites. The reduction kinetics of zinc and iron oxides as well as the volatilization behaviour of volatile matter in the reluctant were considered. The modeling approach and some preliminary results are presented in this article.

Jan 1, 2011

By E. Thune, F. Stålesen, E. O. Stensholt, O. M. Dotterud, E. E. Henriksen, P. O. Ramsdal

"The development and commercial operation of the Falconbridge chlorine leach process have been described in papers in 1985 and 1987. Since this time, various process improvements have been implemented and the capacity of the Kristiansand refinery has been increased to 85 000 t/y Ni, 40 0000 t/y Cu and 4500 t/y Co. The focus has been on continuous improvements in productivity, the use of energy and other costs. Several environmental issues have also been eliminated or reduced since 1987. IntroductionThe first nickel refining operation in Kristiansand, Norway, started in 1910 based upon raw materials from Norwegian mines. In 1929, Falconbridge Nickel mines purchased the refinery to acquire information and the patent rights to the Hybinette refining process that was practised at the small Kristiansand refinery. Falconbridge ownership has now, for more than 70 years, provided a strong base regarding raw material supply, financial resources and technical support for further expansions and major technical improvements at the refinery.The main concepts of the new chlorine leach process were developed in the laboratories from 1966 to 1969 and the process was piloted from 1970 to 1972. The main stages in the commercial plant were started in the 1975 to 1981 period. After 1981, there have been a number of process modifications, plant expansions and improvements to operating practices. The developments up to 1988 have been described in previous publications (Stensholt et al., 1986, 1988).This paper presents an overview of the process and how it is practised at Falconbridge Nikkelverk AS (FNA) today and describes some of the main changes that have been implemented since 1988. During this time, the nickel capacity has been expanded from 54 000 t/y to 85 000 t/y and the cobalt capacity from 2000 t/y to 4500 t/y. The paper describes how these expansions were achieved together with continuous improvements in operating efficiency and also gives an overview of the main environmental concerns at the refinery."

Jan 1, 2001

By China University of Mining & Technology, Yuemin Zhao, Bo Zhang, Liang Dong, Zhenfu Luo, Chenlong Duan

"In China, approximately 65% of coal reserves are in the west region, where water shortage is a serious problem: high-efficiency dry coal beneficiation technology is desired. Using magnetic powder and fine coal as heavy medium, and using air as the fluidizing agent, a novel air dense medium fluidized bed separator is proposed for coal preparation. Coal can be efficiently separated according to density in the fluidized bed, where bed density is steady. The separator is highly reliable, the circulation quantity of heavy medium is low, and the gas distributor cannot be easily easily. The world’s first industrial modularized dry coal preparation plant was built by China University of Mining and Technology. Dry coal beneficiation technology was first used to produce low-ash coal. Results of industrial production show that the ash content of clean coal is 3.46%, the probable error E value is 0.055 g/cm3, and the organic efficiency is over 90%. The advantages of the modularized dry coal beneficiation system are the high separation accuracy, the simple process flow, the low operation cost, low energy consumption, and so on. This technology provides a new effective method for coal separation in acid region and coal tending to sliming.INTRODUCTIONCoal is the most important primary energy source in China, where coal output reached 3.68 billion tons in 2013 and represents approximately 68% of the primary energy consumption. Coal has made a great contribution to the development of the Chinese national economy, but it also brings serious environmental pollution. However, approximately 65% of coal reserves are in the arid west region in China where water shortages present a challenge for wet coal preparation technology. In addition, the abundant lignite resource, because it is easy to mud in the water, should not be treated with the wet separation method. Therefore, it is critical to develop highly efficient dry coal preparation technology to meet the demand in arid areas. Further, water resource shortages are a global problem, thus the development of efficient dry coal preparation technology in has potential application in other water-short countries like South Africa, Brazil, India and Turkey."

Jan 1, 2016

Applying DEM to prediction of tumbling mill performance is challenging because several different modes of breakage are active in the process. As our knowledge of breakage and computational capacity improve, it is worth revisiting previous simulation tasks which did not produce a satisfactorily realistic description of a measured process. At SAG 2006, we reported the simulated and measured outcomes of treating a well characterised ore in a 1.2 m diameter mill. This well instrumented, pilot scale mill at the University of KwaZulu-Natal has been combined with some new approaches to ore testing to allow different modes of breakage to be tested. The mill design allows the rate of generation of fine material to be measured in close to real time for autogenous and SAG mill charges. The updated simulation model estimates mass loss with particle evolution and embeds the cumulative damage and breakage. The simulated results are compared with the measured results. Issues such as relating modelling inputs to particle breakage characterisation data and the accuracy of the predictions of the models are discussed.

Jan 1, 2012

By M. S. Millman

Close monitoring of performance at each process stage, from raw material through to finished product, is vital for operational consistency and the production of high quality steel. However, many of the integrated iron and steelmaking process route stages operate under such severe conditions of temperature, dust, water, thermal radiation, vibration, pressure, vacuum, extreme dynamic events, high material flows, corrosion, erosion, electrical-noise, electromagnetic-noise, or audio-noise that, in general, it is a very difficult challenge to obtain useful information for control. Thus, state-of-the-art non-contact and remote sensors are applied to help monitor and control specific process operations. Often, these sensor systems have been developed especially for the steel industry and they are based on four principal technologies: Laser, Microwave, Electro-Magnetics and Thermal Imaging with supporting technologies such as: X-ray Fluorescence, Audiometry, Digital Image Processing, Radio Telemetry, GPS and many others. These advanced sensor technologies are reviewed with respect to their application at various stages along the integrated process route.

Jan 1, 2004

By Barry D. Simmons

"A well-defined approach is essential to ensure the long-term success of a regional exploration program. Teck's approach in eastern Canada is designed to fulfill corporate objectives while recognizing certain unique parameters for exploration in the area. The elements of this approach include clearly defined objectives, technical considerations and personnel policies, all of which are equally important. The goal is a significant discovery before the mid-l990s and the company is confident that this target will be achieved.IntroductionAs one of Canada's oldest continuously operating mining companies, Teck Corporation traces its roots to Kirkland Lake, Ontario, with the development of the Teck-Hughes gold mine in 1913, later supplemented by production from the Lamaque gold mine in Val d'Or, Quebec. Control of the company was acquired by Temagami Mining Company, part of the Keevil Mining Group, in 1959. Credited as one of the first discoveries made using airborne geophysics, the Keevil Group had recently found the small but very high-grade copper deposits at Temagami, Ontario. These developments in eastern Canada formed a foundation for remarkable growth and Teck's present status as one of Canada's most successful and respected mining companies.Teck currently operates successful mining ventures across Canada and has international exposure through its association with Cominco Ltd., M.I.M. Holdings Limited and Metallgesellschaft AG. Operations in eastern Canada, however, remain an important component of Teck's ongoing success. The David Bell and Williams mines at Hernlo, Ontario, are Canada's lowest cost and largest gold operations, respectively. The Niobec Mine at Chicoutimi, Quebec, is North America's only significant producer of niobium. Teck maintains a 45070 interest in Golden Knight Resources Inc., part owner of the successful gold mining operation in the Casa Berardi area of northwestern Quebec. As a significant shareholder in Aur Resources Inc. and as a part owner, Teck is participating in the development of the Louvicourt deposit, a major base metal discovery at Val d'Or, Quebec."

Jan 1, 1992

By Z. Farhat

In spite of advances in cutting tool technology, the understanding of the basic wear behavior and failure mechanisms needs further study. Tool wear is the main factor contributing to geometrical error and thermal damage in machined components. Manifested as a reduction in tool life, it also affects the workpiece surface finish, increases cutting forces and induces residual stresses. Furthermore, the emergence of high and ultra-high speed machining processes necessitates the investigation of tool wear under these severe working conditions. Tungsten carbide-cobalt composite material has been used traditionally as wear resistant materials for many years. One main application of this material is in cutting tools. WC-Co tools consist of hard WC particles imbedded in a tough Co matrix, which functions as a binder phase. More recently, Cubic boron nitride (CBN) tool material have attracted special attention due to its high hardness and excellent wear resistance. Boron nitride in its cubic form is known to be the hardest material next only to diamond. In this paper microstructural and tribological properties of commercial grade WC-Co and CBN cutting tool materials are investigated under high speed cutting conditions. The CBN cutting tools were found to be superior to tungsten carbide (WC) tools. Four-fold increase in productivity and significant reduction in chipping and cratering was achieved for CBN as compared to WC. Wear mechanisms are proposed and are related to the observed wear characteristics in the cutting zone.

Jan 1, 2006

By F. Czerwinski

Mechanically fragmented chips of an AZ91D magnesium alloy were transformed into a semisolid slurry within the Thixomolding® system. Microstructural analysis of a material at various processing stages revealed that the cold deformation of the alloy, experienced during chipping, led to the recrystallization and growth of equiaxed grains which were subsequently converted to the globular structures by melting the grain-boundary network.

Jan 1, 2004

By T. T. Wang, T. H. Huang, S. S. Zhan

"Fractures with diverse features dominate the hydraulic behavior of fractured rocks and are one of the major subjects for hydrogeological characterization of a site. This study investigates curve patterns obtained by packed tests, and as well the influence of fracture features based on 59 sets of in situ packer tests with different fracture combinations and fracture features. The result shows that, in the example of Heshe site, neat and tidy fractures usually provide stable channel for water flow during testing, and the hydraulic properties of fractures infilled with breccia and mud may change during testing because of leaching and/or washed out of infilling breccia and mud. Different combinations of fractures with diverse features in packed test sections lead to different curve patterns for in situ hydrogeological tests. For groundwater flowing predominately through neat and tidy fractures, the pressure-discharge curve of modified Lugeon tests are usually linear curve pattern, and the pressure decrease while the discharge increase in pressure-discharge-time curves of single-hole double packer tests, which benefit statistically determining the transmissivity of dominant fracture sets. INTRODUCTIONFractures interlaced in rock masses are major channels for groundwater flow and generally account for the anisotropic and heterogeneous characteristics of permeability for fracture rocks. To describe reasonably the permeability of a fracture rock, the Discrete Fracture Network (DFN) approach and others with similar ideals have been developed. Many methodologies and associate equipment, for instance, the televiewer and the in situ hydrogeological test, have been proposed to investigate the spatial distribution and the transmissivity for different fracture sets, which are two main parameters necessary for the DFN or similar model simulation (Pearson & Money, 1977; Barker & Black, 1983; Hsieh et al., 1985; Bernard et al., 2006; Quinn et al., 2012). However, diverse outlooks for the pressure-discharge curves and the temporal pressure and associate temporal discharge curves often confuse the investigation results by significant deviations on derived permeability (Houlsby, 1976; Zlotnik, 1994; Royle, 2009; Camilo, 2010).Aiming on technical development for in situ hydrogeological tests and fracture investigation, an experimental well site with 10 wells has been established in Heshe in central Taiwan since 2011 (Wang et al., 2011; Song, 2012; Zhan et al., 2013). Extensive geological survey and well-hole scanning by a televiewer provide spatial distributions and outlooks of fractures in detail. Additionally, a series of Lugeon tests, double packer injection tests and pumping tests have been performed to investigate the permeability of fracture rocks, and dominate fracture sets as well. Based on the results obtained from the Heshe site, this study classifies the curve patterns of hydraulic packer tests. The features of fractures involved in packed sections for packer tests are then inspected in detail. Relationship between the curve patterns of hydraulic packer tests and associated features of corresponding fractures in rock are discussed and addressed accordingly."

Jan 1, 2015

By H. R. Stockford

"A pyroxenite-carbonatite complex containing extensive pyrochlore mineralization was discovered during January, 1966, within an exploratory license area held by Consolidated Morrison Explorations Limited. Located 32 miles south of Moosonee, Ontario, the deposit was found under 100 feet of glacial till and Paleozoic sedimentary cover using airborne and ground magnetometer surveys. Exploratory and detailed drilling, totalling 47,625 feet in 85 holes, was completed in outlining the deposit to a maximum depth of 900 feet. Pyrochlore reserves are estimated at 62,000,000 tons averaging 0.52 per cent Cb,05 to a depth of 825 feet. Included in this tonnage is a high-grade section containing 10,000 tons per vertical foot grading 0.82 per cent Cb20 5• The deposit is still open at depth and the intrusive complex has by no means been fully explored.The columbium (niobium) mineralization occurs in a lineated calcite-dolomite host rock which has been intruded along a fault zone within a northeast-trending granulite belt. Potassium-argon dating indicates an age of 1655 million years.Preliminary studies suggest that the complex was intruded in a series of pulses in the form of a partially crystallized mush. The James Bay intrusive is unusual in that it is linear in form and contains only two main rock types - p•yroxenite and carbonatite. Nepheline-bearing syenites and associated rocks are notably absent. Moreover, the pyrochlore is essentially non-radioactive and free from many of the impurities generally associated with other pyrochlores. A test shaft to investigate soil conditions and to provide a 250-ton bulk sample was completed during 1968. Subsequent pilot-plant operations indicate that good quality pyrochlore concelttrates can be produced from this deposit."

Jan 1, 1972

By Hong Zhong, Shuai Wang, Fangxu Li, Guangyi Liu

"The flotation performances and adsorption mechanisms of a-hydroxyoctyl phosphinic acid (HPA) to malachite, cassiterite and wolframite were investigated by micro-flotation tests and X-ray photoelectron spectroscopy (XPS) analyses. The micro-flotation results indicated that compared with styrene phosphonic acid (SPA), diphosphonic acid (DPA), benzohydroxamic acid (BHA) and salicylhydroxamic acid (SHA), HPA exhibited excellent collecting power to the three oxide ores. In addition, HPA showed superior selectivity against hematite, tourmaline, feldspar and quartz. The results of XPS analysis demonstrated that HPA reacts with active species (M) on metal oxide by formation of P-O-M or P-M bonds.INTRODUCTIONIn mineral processing, flotation has been the main process for separation and recovery of valuable minerals from complex ores (Mei, 2013; Zhou, 2014). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by surfactant (known as collector in flotation) adsorption so that these mineral particles can preferably attach air bubbles in a slurry or pulp (Bai, 2004; Hankins, 2004). To anchor a solid surface selectively, special functional group are designed to adjust the interaction between the surfactant and the active sites of solid surfaces (Wu, 2006; Huang, 2014).Organic phosphorous compounds have strong affinity toward metals or metal oxides because they form more stable metal complexes than metal carboxylates (Pazik, 2001; Zheng, 1998). In mineral engineering, phosphorous compounds have been exploited as metal extractants and flotation collectors (Alguacil, 2002; Sun, 2008). Ni (2012) and Zhang (1998) introduced diphosphonic acid (DPA) as an effective collector for flotation of fersmite and niobite. Liu (1999) found styryl phosphonic acid (SPA) was a superior collector for flotation recovery of finely disseminated rutile ores. Gruner and Bilsing (1992) thought SPA was one of the best collectors for flotation recovery of cassiterite which could obtain a high-grade concentrates of more than 40% with high recovery values. Bulatovic (1999) investigated the flotation performances of phosphoric acid ester (PAE) to perovskite, ilmenite and rutile and found that PAE was an impactful collector for selective flotation of titanium minerals from complex ores in the presence of petroleum sulfate. However, a-hydroxyoctyl phosphinic acid (HPA) as a flotation collector for recovery of titanium ores were hardly reported in the previous literatures."

Jan 1, 2016