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By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By A. L. Mackie

Arsenic is a highly toxic element and a known human carcinogen. It is often a contaminant in mine water discharges, particularly from gold mining and roasting operations, and has been found at concentrations as high as 4 g/L. Increasingly stringent controls on the concentration of arsenic allowed to be discharged into the environment cannot always be met by current treatment processes and thus enhanced technologies are required to achieve low treated effluent concentrations at reasonable costs. A novel two-step physicochemical treatment process was developed and tested at the bench-scale using synthetic mine water solutions (SMWs) in order to reduce arsenic concentrations in treated effluent to exceed current discharge regulations. The process includes chemical coagulation with ferric sulphate and ballasted flocculation for enhanced solid-liquid separation. The SMW contained 59 ± 2 mg/L arsenic with a slightly alkaline pH. The effect of arsenic speciation on the process was tested by using either arsenite, As(III), or arsenate, As(V), in the SMW solutions. Tests were performed at cold temperature (3 ± 1 °C) to ensure the process? efficacy year-round in northern climates. Arsenic in As(V) SMW solutions was removed to a final total concentration of 0.0054 ± 0.002 mg/L, almost half the current recommended allowable drinking water concentration of 0.010 mg/L. As(III) was removed to a concentration below the Metal Mining Effluent Regulations? (MMER) current limit of 0.50 mg/L, to 0.32 ± 0.06 mg/L, with double the coagulant dose used in Stage 1 for As(V) removal. Oxidant addition at a concentration of 5 mg KMnO4/L in Stage 2 resulted in final total arsenic concentrations of 0.017 ± 0.002 mg/L and pH adjustment with lime in Stage 2 resulted in 0.0415 ± 0.0007 mg As/L in treated As(III) SMW. Both of these modifications to the process reduced arsenic concentrations to below proposed new MMER limits (i.e., 0.10 mg/L). This two-stage treatment process was shown to reduce arsenic concentrations to well below current treatment guidelines while reducing or eliminating chemical oxidant demand.

Aug 1, 2013

By L. E. Puddington, A. L. Mular

"Since the inception of spherical agglomeration, few investigations to exploit commercially the technique in the metallurgical field have been conducted. Of these, none appear to have been carried sufficiently far to demonstrate commercial feasibility.This paper describes a continuous agglomeration-separation process that can rapidly handle large tonnages of ore material. A small pilot plant de-signed from information obtained with the semi-batch unit described herein is currently in operation.In the absence of a reagent recovery system or cheap reagents, the process is probably not economically attractive for many common ores. However, for iron ores, the fuel content of the agglomerates can be used in a subsequent step such as direct reduction."

Jan 1, 1968

By D. J. W. Piper, T. Hundert, G. Pe-Piper

"Abstract - Potentially commercial deposits of kaolin are found in the fluvial Lower Cretaceous Chaswood Formation, the sedimentologically proximal equivalent of deltaic sediments of the offshore Scotian basin. The geological setting of the kaolin deposits has been interpreted from high-resolution seismic-reflection profiles and boreholes, and mineralogical studies on one reference borehole. The kaolin is a product of early diagenesis involving meteoric water below the water table. The distribution of kaolin is controlled by the presence of intraformational unconformities that were sites of ground water recharge, and are marked by the development of oxisols above the water table. Such diagenesis was facilitated by interbedded, loosely consolidated, permeable sandstone. The highest-grade kaolin deposits are found in areas close to river belts, where overbank muds were not sufficiently drained to develop paleosols, but where later uplift created intraformational unconformities. In the sandstone, meteoric water flow altered feldspars to kaolin, thus yielding commercial silica sand deposits. It also altered ilmenite to rutile, which is concentrated as secondary placers in modern rivers that have eroded the Chaswood Formation and tills derived therefrom. Sommaire - Des dépôts de kaolin potentiellement économiques ont été notés dans la Formation de Chaswood d'’âge Crétacé Inférieur, laquelle constitue un équivalent latéral en milieu fluviatile aux sédiments deltaïques du bassin de Scotian. Le contexte géologique de ces dépôts de kaolin a été interprété a partir de profils de seismique-réflection à haute résolution, de sondages, et d’études minéralogiques sur un sondage de référence. Ce kaolin est un produit diagénétique précoce formé par de l’eau météorique sous le niveau de la nappe phréatique. La distribution du kaolin est contrôlée par la présence de zones de recharge associées à des discordances intraformationelles marquées par le développement d’oxisols au-dessus du niveau de la nappe phréatique. La présence d’interlits de grès perméables faiblement consolidés a contribué à l’efficacité de ce processus diagénétique. Les dépôts de kaolin les plus riches se trouvent en périphérie des rivières, là ou les boues de la plaine d’inondation n’étaient pas suffisamment bien drainées pour permettre le développement de paléosols, mais où des mouvements verticaux subséquents ont crée des discordances intraformationelles. La circulation d’eau météorique dans les grès a entraîné l’altération des feldspaths en kaolin, générant ainsi des dépôts économiques de sable de silice. Elle a aussi causé l’altération de l’ilménite en rutile, que l’on trouve dans des placers secondaires situés dans des rivières contemporaines qui ont érodé la Formation de Chaswood et les tills qui en sont dérivés."

Jan 1, 2006

By I. V. Kojo

Continuous development of technologies has been self-explanatory for Outokumpu Technology's engineers for decades. The aim in the development has always been the improvement of profitability of the copper production but also the sustainability of the processing i.e. high copper recovery, low external fossil based energy utilization, high emission captures and of course low operation and investment costs. Outokumpu Technology's long-term view of the development is a change towards continuous processes and elimination of number of unit operations in smelting i.e. elimination of possible sources of emissions. Outokumpu blister smelting processes i.e. Outokumpu Direct-to-Blister Flash Smelting and Kennecott-Outokumpu Flash Converting have shown excellent operational results during the years of operation and it is expected that soon more than 10 % of the world primary copper is produced by these technologies. The paper will give some background of this development trend.

Jan 1, 2007

By E. Swartzman

"DURING 1951, experimental cleaning studies on both fines and larger sizes of certain Canadian coals were conducted on a relatively large scale in two pilot plants in the United States, large enough to be considered as small commercial units, and in one commercial plant in Canada.One of the pilot plants was a wet washer of a type which apparently has never been .used in Canada, nor has any Canadian coal been tested in it before. In the other pilot plant and in the commercial plant, dry cleaning equipment was used. The commercial plant is the first of its kind to be employed in Canada, and this type is used only to a limited extent in the United States.Fine-Coal Cleaning ExperimentsTest PlantsHydrotator and Hydrotator-Classifier combination pilot-plant with a capacity of about twenty tons per hour. This is a classifier type washer adapted for cleaning fine coal as well as certain intermediate sizes. The Hydrotator deals with that portion of a coal retained on approximately a 24-mesh Tyler sieve, whereas the Hydrotator-Classifier deals with the minus 24-mesh fines."

Jan 1, 1952

By George W. Bain

The area in Quebec immediately north of the Ottawa river is underlain by a large area of granite gneiss intruded in lit-par-lit fashion into Grenville sediments and low silica intrusives of the Buckingham Series. This complex of metamorphic rocks is intruded by a much later magma found, chiefly, as a very large stock about 20 miles in diameter and extending from Brownsburg to Grenville, and as dykes and small outliers at various places adjacent to its outer margin. 1A similar stock at Rigaud, Quebec, is situated south of the Ottawa river and has been described by O. E. Le Roy. The earliest representatives of the later magma are a series of granodiorite dykes characterized by abundant hornblende, along with primary magnetite and subordinate sulphides scattered as roundish grains through anorthoclase and aligoclase feldspars and subordinate quartz. The rock is found as narrow dykes and shows no prominent secondary structures, either in the field or in thin sections under the microscope.

Jan 1, 1926

By R. D. Corrans

"Abstract - Africa is endowed with a number of the world's giant ore deposits which have contributed significantly to the development of their host countries. Mineral exploration has a long history in the continent, but mining on an unprecedented scale took off during the latter part of the 19th century, accompanied by the development of lines of communication and other infrastructure to service the major mining centres .The ""Winds of Change"" which swept Africa in the 1950s and 1960s brought in new styles of government and economic management to a number of regions, often with demise of economic viability and infrastructure. ln recent years, with the end of the cold war, collapse of communism and changes in South Africa, new opportunities for mineral exploration are opening up rapidly in Africa. However, due to the large cost, long lead-in time, and high risk of developing new mineral ventures in the continent, it is necessary for the host countries to draft realistic and favorable mineral laws and fiscal codes in order to attract, and not deter, potential mineral investors.There will be an on-going role in mineral exploration throughout Africa for the artisanal miner, the smaller entrepreneurs and mining companies, exploration aid programs funded by the developed countries through African governments, as well as the major mining houses who have the resources to develop larger viable mineral deposits."

Jan 1, 1994

By R. J. Enkin

Modern mineral exploration depends on multidisciplinary 3-dimensional integration of geological and geophysical data. Identification of the geological sources of geophysical anomalies requires knowledge of the physical properties fingerprint of rock types, formations and their alteration products. Understanding how and why rock physical properties vary within the Earth's subsurface ensures that appropriate geophysical exploration methods can be chosen, and allows for more efficient and effective surveys to be designed. Physical properties knowledge is integral to geophysical modeling - measured data or values estimated based on geological understanding are used to produce realistic forward calculations and to constrain inversion models. Mira Geoscience and the Geological Survey of Canada, in collaboration with industry and academia, are building a Rock Properties Database System (rpds.mirageoscience.com). It compiles the most valuable physical properties for mineral exploration (density, porosity, magnetic susceptibility and remanence, electrical resistivity and chargeability) linked with location and lithological metadata. A critical knowledge gap, addressed in this study, concerns the dependence of physical properties on alteration and mineralization processes. We report on the results of a collaborative University of British Columbia - Geoscience British Columbia project, ?Integrated Geological & Geophysical Porphyry Models: Adding Value to Geoscience BC Geophysical Data?. As part of the QUEST and QUEST-West geophysical initiatives, Geoscience BC focused detailed geophysical surveys on a suite of six known porphyry deposits: Mount Milligan, Endako, Huckleberry, Bell, Granisle, and Morrison. Physical properties for a set of 269 samples of characteristic host rocks and their altered equivalents were measured. The causes of physical properties variations were investigated through their correlations with ore and alteration mineralogy determined from thin-section observations and X-ray diffraction analyses. Physical properties of variably altered host-rocks and intrusive rocks vary significantly between different BC porphyry deposits. No specific unifying geophysical model exists that can be uniformly applied during exploration. Knowledge of local background geology and local physical properties variations is necessary as host-rocks and intrusive rock compositions vary depending on magmatic affinities, and alteration styles will vary reflecting host-rock compositions, crustal depth and influence of meteoric water. A district-scale exploration strategy requires location of intrusive bodies, which are commonly magnetic, resistive and low in density. Correlations should not be expected between density and magnetic susceptibility, because alteration may lead to magnetite destruction or to secondary magnetite development. Deposit-scale ground geophysics might image potassic alteration zones that can be magnetic in both alkalic and calcalkalic systems. Low magnetic susceptibilities, resistivities and densities might aid in locating the typically more porous phyllic and argillic zones. All geophysical data must be interpreted with background knowledge of local rock types and in light of the expected deposit model and associated magmatic and hydrothermal processes. The most effective means to building physical properties knowledge prior to geophysical investigation remains collecting rock physical properties measurements. The cost of rock properties data collection is low, relative to the overall costs of running a mineral exploration program, and can provide an important framework for design of geophysical surveys, survey method selection, geophysical modelling, and data interpretation.

Aug 1, 2013

By H. J. White

The effect of alloying elements on the mechanical properties and weldability of wrought gamma prime strengthened nickel- base superalloys is well known. An understanding of the basic guidelines concerning alloying additions has led to the invention and development of HAYNES® 282® alloy for applications in aircraft and land base gas turbines and other high-performance high-temperature environments. The alloy combines exceptional high temperature properties with good weldability and fabricability. At high temperatures (~ 900 °C), the alloy is stronger in creep strength than Waspaloy alloy (UNS N07001) and it approaches the creep strength of R-41 alloy (UNS N07041). Because the alloy has better thermal stability, fabricability, and weldability than Waspaloy and R-41 alloys, it is currently being considered as a candidate universal consumable for welding/ repair welding of gamma prime strengthened nickel based superalloys and it is also being considered as a suitable replacement for applications where R- 41, Waspaloy, and 263 (UNS N07263) alloys are currently being used. The alloy was designed to have improved resistance to strain age cracking, a problem common to gamma prime strengthened nickel based superalloys. In this paper, we present (1) results from hot ductility testing of annealed and annealed/aged material; (2) results from Time Resolved X-ray Diffraction (TRXRD) studies during a welding thermal cycle of annealed and annealed/aged material, and (3) gas metal arc (GMA) and gas tungsten arc (GTA) welding of annealed and annealed/aged material.

Jan 1, 2010

By Joseph W. Mills

"The Mic Mac property comprises 994 acres held under mining concession and approximately 2,000 acres held under development licenses in Bousquet township, Abitibi county, western Quebec.Gold was first discovered in this locality by Tom Duval in June, 1936. In February, 1937, Cassels Duval Mines, Limited, was incorporated under Quebec charter to take over the property. In September, 1937, the property was examined by Agaura Explorations, Limited, and an option agreement was signed on October 6th, 1937. In June, 1938, an option for complete ownership was taken on adjoining claims belonging to Norgold Mines, Limited, and in September, 1938, a mining plant was installed and the sinking of a 3-compartment shaft begun. In June, 1939, an option was taken by Mic Mac Explorations, Limited, on seven claims of Mooshla Gold Mines Company, Limited, that adjoined the Norgold block to the east. In December, 1939, a new company, Mic Mac Mines, Limited, was formed, amalgamating the Cassels Duval, Norgold, and Mooshla claims, as well as two claim groups to the west of the mine known as the Vaughan and West Cassels groups."

Jan 1, 1954

By E. J. Wade

The general location, climatic conditions and access of the Tasu mine are covered briefly, with comments on the Jack of conventional transportation and communication facilities. The Haïda story of Tasu and early at-tempts at production are presented, together with a discussion of the government legislation which throttled exploration and production in the late fifties. General and specific details of local geology, mineralogy and current ore reserves are also covered.

Jan 1, 1968

By G. Kipouros, M. Dadvand, A. Dadvand

"A novel methodology was developed to obtain a 3D porous layer with a high aspect ratio of porosity on a titanium electrode. The porous structure allowed more active material such as hydrous ruthenium oxide to be accommodated during the fabrication of the supercapacitor, resulting in an exceptionally high capacitance per surface area. The electrode demonstrated a remarkably high capacitance of 4,800 mF/cm2. The porous layer was composed of functionalized nanoparticles of TiO2 organized in a perfect 3D hexagonal close-packed array that resulted in a highly porous 3D structure. The layer was used as a template to electrolessly deposit a thin layer of silver prior to the electrodeposition of active material. KEYWORDS Capacitance, Porous, Ruthenium, Silver, Supercapacitor, Titanium RÉSUMÉ Une méthodologie innovante a été mise au point afin d’obtenir une couche poreuse tridimensionnelle (3D) affichant un rapport d’aspect élevé en termes de porosité sur une électrode en titane. La structure poreuse permet d’utiliser une matière plus active telle que l’oxyde de ruthénium hydraté durant la fabrication du supercondensateur, ce qui se traduit par une capacité exceptionnellement élevée par surface active. L’électrode affichait une capacité remarquablement élevée de 4 800 mF/cm2. La couche poreuse était composée de nanoparticules fonctionnalisées de dioxyde de titane (TiO2) organisées dans un arrangement regroupé parfaitement hexagonal en 3D, qui a engendré une structure en 3D hautement poreuse. Cette couche a servi de modèle pour le dépôt autocatalytique d’une fine couche d’argent avant l’électrodéposition de la matière active. MOTS CLÉS argent, capacité, poreux, ruthénium, supercondensateur, titaneINTRODUCTION There is a growing demand for integrating compact energy storage elements into electronic circuits due to the miniaturization of electronic circuits, sensors, and actuators, and the increasing importance of portable and wear-able devices incorporating more advanced electronic technologies that operate in controlled or uncontrolled environments to gather, process, store, and communicate information (Deng, Ji, Chen, & Banks, 2011; Beidaghi & Wang, 2012; Chen, Ramachandran, Mani, & Saraswathi, 2014). The manufacturing of compact energy storage elements needs to be compatible with the electronic circuit microfabrication processes. Recently, interest in integrating miniaturized supercapacitors into electronic circuits has increased due to their high charge–discharge rate and long operating life; however, ultra-high power miniaturized supercapacitors suffer from low energy density, hence requiring significant enhancement in their energy density for various applications (Deng et al., 2011; Beidaghi & Wang, 2012; Chen et al., 2014)."

Jan 1, 2019

By Joseph F. Daniels

In recent considerations of the utilization and beneficiation of coal, the chemise and the chemical engineer have been occupying the centre of the stage with their presentation of the picture of new fuel forms. The stage hands and supernumeraries of the cast, the miners and the consumers who carry the brunt of the present-day burdens, are apt to be forgotten in the glorious settings and the climaxes. With no thought of disparaging or of minimizing the efforts of our fellow scientists, let us remember that economic considerations as well as technical difficulties will limit these chemical applications, which must develop and move slowly before reaching the stage of industrial application at some later day. In the meantime, the coal-mining industry must live on hard faces rather than rosy dreams. In these brief notes it is my purpose to call attention to some of the physical advances in the utilization and beneficiation of coal which have been of interest to the industry in the State of Washington.

Jan 1, 1928

By M. J. Latva-Kokko, T. J. Riihimäki

"Oxidation autoclaves are normally operated at elevated temperature and pressure. The improvement in kinetics is due to combined effect of temperature and partial pressure of oxygen. In this paper exclusive effect of pressure has been studied with a low grade sulphide ore at below 100 °C temperature. These studies are related to development of a novel tower-like reactor that utilizes hydrostatic pressure. Technology is designed to generate high amount of effective fluid volume for high solid content slurries with lower energy consumption and improved kinetics compared to normal atmospheric operation.INTRODUCTIONEconomical utilization of low-grade ores requires handling of enormous amount of material. This sets new requirements for process equipment in terms of size and energy efficiency. For example on the field of mineral processing this has lead to a six fold increase in the operating volume of mechanical flotation cells over the past two decades. Ore beneficiation methods like flotation greatly reduce amount of material that needs to be further processed in smelters or hydrometallurgical refineries. However with some ore types, such as nickel laterites and refractory gold ores, traditional concentration technologies cannot be utilized. Thus direct leaching of ground ore could be an attractive option. In many cases normal atmospheric tank leaching has traditionally been a non-feasible option mainly due to high capital and operational expenses induced by large amount of stirred reactors required. Main restriction for increasing reactor size to beyond 500 m3 has been mechanical load and power requirements set by mixing in cases when high dispersion efficiency of gas is required. THEORETICAL BACKGROUNDIn hydrometallurgical industry autoclaves are typically operated at elevated temperature and pressure. In many cases increase in operating temperature is the desired phenomena and improvements in kinetics are strongly related to that. Thus increase in pressure might be induced solely by water vapor pressure. However when gaseous feed is present, pressure itself has a strong effect on leaching kinetics for various reasons and its role should not be neglected."

Jan 1, 2012

By J. A. C. Fortescue

During the past decade, geochemical prospecting methods have become important in Canadian mineral exploration. The object of this paper is to discuss the role of geochemical methods in a typical mineral exploration program involving parallel geological and geophysical methods applied at different degrees of intensity. Particular attention is given to the description of the degree of development of geochemical prospecting under different kinds of local conditions.

Jan 1, 1967

By Robert Halupka

The industrial minerals sector represents a broad range of products involving a variety of technologies serving a diversity of markets and end uses. Unit values of products vary widely, reflecting the peculiarities of each product/market sector. Generalizations are therefore understandably difficult to make and borrowers may need to take extra time to "educate" lenders on the key aspects of their business and industry sub-sector. This paper will examine the factors and the thinking that lenders apply when considering financing proposals to companies in the industrial minerals sector. If you understand the lender's perspective and their concerns, then you can make better use of your own time and resources when arranging financing for your company or project.

Jan 1, 2001

By Y. Chengxian

Many factors about the HIC (hydrogen-induced cracking) resistance of pipelines are discussed in this paper. The main factors that influence the ability of HIC are environmental and material factors. The chemical compositions, non-metal inclusions and microstructure are discussed in detail, while a group of tests on HIC resistance are done according to varying C, S, Mn and P contents in pipeline steels, different experiment time and different strength to the coupon. It is concluded that decreasing the amount of C and S can obtain good HIC resistance; the test time has an effect on the different microstructure of X70; microstructure is the most sensitive factor for the initiation processes of HIC.

Jan 1, 2005

By R. L. Brown

The burning sulphide ores in the Sullivan Mine generate sulphur dioxide gases. This paper is concerned with a description of the environmental impact of SO2 on air quality in the mine and on the surface in the vicinity of the mine. As a result of surface caving, SO2 has been able to vent to surface and winds have carried it into one residential area of Kimberley. Monitoring practices are described.

Jan 1, 1977

By T. Johnson, D. Kelley, J. Graham

"Hydrometallurgical processes can be exceptionally corrosive. Conditions associated with metal extraction and refining require materials of construction that can withstand process acids and acid chlorides at temperatures up to 90°C (194°F). Process vessels, piping, scrubbers and ducting can be rapidly compromised in these aggressive environments if not designed with care. Design engineers are challenged to find materials that can stand up to hydrometallurgical processes especially for copper, zinc, nickel, cobalt and uranium. This paper will evaluate material solutions to determine which provides attractive economics for initial procurement as well as high durability for reasonable life cycle costs.INTRODUCTIONMining activity in a number of metal ores has been running quite high over the last few years. In particular, those metals that employ acid functional extraction processes such as copper, nickel cobalt and uranium have been particularly active.The world’s largest nickel mine – the massive $4.76 billion Ambatovy nickel mine on the African island nation of Madagascar is nearing completion. When it reaches its full production capacity in 2013, the mine will produce 60,000 MT/yr of nickel and 5600 MT/yr of cobalt. Coming on the heels of the Ambatovy project is the Long Harbour Processing Plant in Newfoundland, Canada which will process the ore from Vale’s Voisey Bay mine in Labrador. Voisey’s Bay is expected to generate more than 50,000 MT/yr of nickel ore when it starts up in 2013. Next up will be the Boleo project in Mexico on the Baja peninsula. When commissioned in 2013, the $858 Million Boleo project is expected to produce 60,000 MT/yr copper, 3100 MT/yr cobalt, 36,000 MT/yr zinc and 100,000 – 250,000 MT/yr manganese carbonate.High nickel alloys and rubber lined steel have been used for decades to design corrosion resistant equipment for mineral processing environments. These materials demonstrate reasonable resistance to corrosion for most environments. Unfortunately, higher nickel alloys are quite expensive. Rubber lined steel is a bit more affordable but requires continuing service over time which ultimately drives up its cost as well. FRP (Fiberglass Reinforced Plastic) has also been used extensively in mineral processing for tanks, piping and ducting employed in aggressive environments. Today, more and more design engineers and material specifiers are calling for FRP composites for both new and replacement equipment used in the refining and processing of a variety of metal ores."

Jan 1, 2012