Search Documents

By R. Le Houillier, M. Nagamori, A. J. Plumpton

"Asbestos tailings are a typical serpentine, hydrated magnesium silicate, consisting primarily of antigorite and a few per cent of unrecovered fibrous chrysotile. Serpentine has unique thermal properties in that dehydroxylating calcination at 600 to 700°C can yield an amorphous structure in which most of the magnesia is liberated from the original bond with silica and thereby rendered chemically active. The amount of activated magnesia can be quantified by selective leaching with a weak acid such as acetic acid. Many wet processes have been proposed to extract magnesium values from calcined or natural serpentine by means of various acids and their ammonium salts. However, the only commercial utilization of serpentine today is found in dry processes such as the production of fused magnesium phosphate fertilizer .The present paper reviews the physical chemistry of the dehydroxylation of serpentine and also various wet and dry processes in order to provide a general view regarding the chemical transformation of asbestos tailings.IntroductionAsbestos fibers occur as chrysotile, a serpentine polymorph. More than nine tenths of mined asbestos ores consist of massive non-fibrous serpentine, primarily the polymorph antigorite, which is discarded as tailings after fiber extraction. For many decades, Quebec has been a world leader in the production of asbestos fibers. As a result, colossal tonnages of serpentine have accumulated in the Eastern Townships'!'. Serpentine minerals are found in large deposit s throughout the world, and significant research efforts have been made, particularly in Japan and the USSR, mostly in attempts to extract magnesia or silica values therefrom.The chemical composition of serpentine (chrysotile and antigorite) may be ideally expressed as Mg3Si2Os(OH). which corresponds to 43.7% MgO and 43.3% SiO2. Natural serpentines often contain a few per cent of Ni-bearing magnetite and other impurities, and therefore the contents of MgO and Si02are both about 40% or lower.Serpentine (hydrated magnesium silicate) is virtually insoluble in weak acids. However, when dehydroxylated under controlled conditions, ' it decomposes to an amorphous state in which magnesia and silica are isolated and chemically active. The magnesia so activated is readily soluble in weak acids. This unique characteristic of calcined serpentine, first discovered in 1942,, has since attracted the attention of innumerable researchers, whence many processes have been proposed."

Jan 1, 1980

By E. Bongajum

We present results from petrophysical studies to characterize a Zn-Pb-Ag deposit in Nash Creek, New Brunswick. The measurements are part of an integrated study that includes geological and geophysical data acquired on the property. In order to successfully characterize the ore body, an understanding of the relevant physical parameters and their change with vertical and lateral variations of the target lithology is necessary. The quality of the estimated 3D variation in the physical properties is supported by the presence of several boreholes that randomly span the survey region. Density was measured from cores of thirty-two boreholes across the area. Seventeen of these boreholes constitute two intersecting borehole profiles, which is ideal for locally modeling the 3D distribution of the ore deposit. High densities (>3.2g/cm3) correlate strongly with Zn-rich mineralization zones (low resistivity). Compression and shear wave velocity measurements made from representative core samples of the regional geology range from ~2.91 to ~6.41 km/s for P-waves and from ~1.41 to ~4.20 km/s for S-waves. The lower bounds of these velocity values correspond to regions with a high degree of alteration. Moreover, porosity estimates from rocks on the property suggest that porosities range from 0.35% to 11.79%. Induced polarization (IP) measurements confirm that mineralized samples show a significant chargeability and resistivity contrast with respect to the host rock. Thus, chargeability and resistivity information can be combined to adequately identify conductors associated with mineralization in electrical survey data. Information on these physical parameters and their 3D statistical distribution have serious implications on various aspects of mineral exploration that include: resource estimation, choice of geophysical data acquisition and interpretation, and information for preliminary rock stability assessment.

May 1, 2009

By J. D. Nye, I. A. Farr, W. J. D. Stone

"A unique deposit of barite exists near Brookfield, Nova Scotia. The crystals are extremely fine and the whole deposit virtually free of heavy metals. The deposit size was not large enough for conventional uses, such as the production of barium carbonate and drilling mud. In an effort to obtain maximum utilization, a program was begun to determine if U.S.P.-grade pharmaceutical barium sulphate for X-ray diagnosis could be produced. Early work was sufficiently encouraging to institute a development program under the federal Program for Advancement of Industrial Technology. This has been very successfully completed. Canadian and U.S. process patents have been issued, clinical trials have been successful, a production plant has been designed and the plant’s production sold. The processing plant will include magnetic separation for the removal of iron minerals, fine grinding by paddle milling to minus one micron and acid leaching. The process is unique in that at no time is the barium taken into solution.Information is given on the deposit, process, markets, use, plant capital and operating costs, and projected profits. The initial production plant will have an annual capacity of 2,000 tons per year of end product. Capital cost is $850,000 and annual turnover more than $1.5 million. As this capacity only represents approximately 15% of the North American market, rapid plant expansion is foreseen."

Jan 1, 1980

By Chris Larsen, Carole Fortin, Dave Scott, Curtis Deredin, Ian Orford, Jean Guy Gauthier, Andy Trusiak, Lyne Côté, Mike Cooper

"Upon successful commissioning of the Stage Grinding Project (Cormier et. al., 2002), process improvements predicted through pilot plant testing were obtained in several flotation circuits, resulting in higher grades and recoveries for zinc and lead concentrates. Subsequent to establishing new baseline operating conditions from the Stage Grind Project implementation, additional opportunities were identified, and through the application of Six Sigma methodologies further gains were made. Six Sigma improvement projects were carried out in the copper-lead, zinc, lead upgrading and bulk flotation circuits. The overall performance increase resulting from incremental improvement projects has been substantial.Most remarkably, given the operational maturity up to the late 1980’s, the Brunswick concentrator team has continued to deliver a steady stream of major improvements over the past fifteen years. While senior managers and their programs have changed several times, there have been some critical constants over the long run. Common elements have been a commitment to team work, a commitment to recruit and maintain technical personnel, a structured business improvement framework supported organizationally by senior management, and focus on a few priority initiatives rather than trying to fix everything at once.The paper briefly discusses the longer term setting and then endeavors to illustrate, with examples, how improvements are presently achieved by applying the Six Sigma quality program.INTRODUCTIONThe Noranda Inc. Brunswick Mine, located near Bathurst, New Brunswick, is one of the world’s larger lead/zinc mines. Milling of ore began in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore from the No. 6 mine. In excess of 100 million tonnes have been milled to date. The concentrator employs differential flotation to produce lead, zinc, copper, and lead/zinc bulk concentrates. The ore is massive sulphide, with approximately 20% valuable minerals, 60% pyrite and 20% silicates."

Jan 1, 2005

By J. R. Goode

"Coarse ore sorting is here defined as the physical separation of a mixture of coarse (+3/8 inch) ore particles into two or more separate groups of total value greater than that of the unsorted ore. An ore will probably be sortable if the geology of the orebody and the mining practices employed meet conditions outlined in this paper.The paper points out how sorting can substantially reduce tonnage variable operating costs because sorting can double the mill head grade of amenable ores by rejecting waste rock from the mine output. The effect of sorting on ore reserves is outlined. It is also suggested that sorting is a low cost alternative to conventional expansion.The mode of operation of the Ore Sorters Kadel 13 Photometric and MK VI A Radiometric sorters is detailed. The report concludes with detailed descriptions of the photometric sorting plant operated by the Doornfontein Gold Mining Company is South Africa and the Radiometric Sorting Plant presently under construction at the Schwartzwalder mine of Cotter Corporation in Colorado."

Jan 1, 1975

By Erin Legault Seguin, Mike Rylatt, Curtis Mohns

"With energy costs increasing and ore grades diminishing, the role of pre-concentration in hard rock mining operations has been gaining greater interest. To maximize energy conservation, the pre-concentration process should be conducted at as coarse a crush size as possible while minimizing losses of pay metals. Dense medium separation (DMS) is a robust process that can be conducted at particle sizes as coarse as 300 mm and as fine as 500 µm with high separation efficiency, depending on liberation characteristics of the value minerals. The DMS process involves three steps: feed preparation, dense medium separation, and ferrous-based media recovery. This paper discusses each of these processing steps, but focus will be given to the dense medium separation stage. Various types of DMS equipment are reviewed. Pilot plant campaign case studies conducted at the SGS Lakefield site are presented, which have included a variety of mineral systems such as spodumene, sulphide-bearing gold ores, and complex sulphide ores. These case studies demonstrate that for amenable ores, mass rejection of 20-60% is possible while maintaining recoveries of greater than 90% in most cases.IntroductionPre-concentration is a process of rejecting mass of gangue while ensuring recovery of valuable minerals prior to more intensive, downstream processing. Pre-concentration has been practiced in industry for many years, and is gaining greater interest as the industry copes with processing lower grade, more difficult ores, typically requiring finer grind sizes and higher energy costs."

Jan 1, 2016

By Bruno Lemelin

Falconbridge Ltd Raglan Mine has been in production since 1998 and has produced annually some 900 000T of ore grading 3.1% nickel, 0.9% copper and 0.06% cobalt. The mine is located in Nunavik, Northern Quebec. The current mine life is estimated at approximately 20 years. Reserves are composed of numerous small ore bodies situated across a 65 km strike length. Planning the extraction of the ten small mineralized zones represents a great challenge to optimize. The overall objective is to maximize the company?s return on net assets. Actual planning uses computerized technology tools like Automod and Mine2-4D, and a conventional discounted cash flow method (DCF) of calculating net present value (NPV). The complex setting of Raglan could benefit from advance valuation techniques such as the real options method (RO). This paper will present the characteristics if the mines that make it a good candidate to use RO to gain further insight.

May 1, 2004

By Martin Kesting

The world wide growth dynamics and the continuously growing demand for energy, results in increasing energy prices. Looking from this point, the efficient exploitation of fossil fuel deposits has become a more important factor to the production of energy raw materials than ever before. This shall be reached by an increase of the automation degree of the bucket wheel excavator in the open pit mining as well as a quality increase of the entire mining process chain. A further optimization of this operation can only be achieved by gathering additional information about the input parameters. The earlier and more exact the description of the input parameter, the greater the effectiveness of the entire process chain. To address this major issue, the RWE Power AG assigned the Institute for Transportation and Automation Technology with the research project "SIMT, Sensory Identification of Material Type and Detection of the Interfaces" [Kes07]. Presently, the control of the bucket wheel excavator is carried out manually by the operator, as well as the visual identification of the different geological layers and the energy raw materials. In this paper, a sensor-system is introduced, which was developed in order to transfer the manual material identification and detection of interfaces into an automatic online procedure. A special challenge and the main focus of this contribution is the integration of this sensor system into a bucket of the bucket wheel excavator. For measuring procedures where direct contact with the in situ material is necessary, the sensor has to be integrated into the bucket. Since direct contact with the material is not necessary, it can be integrated next to the bucket wheel. The results of a preliminary study show that although there is a broad spectrum of sensor technologies for material and interface identification, only a few are suitable for an application in on-line measuring at the bucket wheel excavator. Taking into consideration the demands on the sensor technology, the studies carried out and comparable applications of individual sensor technologies which have already taken place in practice, the integration of the following measuring systems have been realized: ground penetrating radar / reflection measurements, geo electric, resistance geo electric technology. The solution developed in the research project offers for the first time the direct integration of sensor systems into the bucket of a bucket wheel excavator. It will now be possible to test other measurement methods and sensors, not only for the ones already mentioned. As an example the integration of a triaxial accelerometer to measure the solid borne sound and vibrations concerning the cutting of different materials will be shown.

Oct 1, 2009

By E. V. Manlapig, K. R. Rahal, J-P Franzidis

"The Floatability Characterisation Test Rig or FCTR is a highly instrumented, mobile flotation pilot plant built by Baker Process (now EIMCO) for the AMIRA P9 Project for use in flotation plant modelling and simulation studies. With the Mintek Floatstar system controlling the level in every cell, and the facility for full stream sampling on all streams, the FCTR is a unique tool for producing data of sufficient quality for flotation plant modelling. The plant was commissioned at Lonmin's Karee and Eastern Platinum concentrators in 1999/2000, and completed a number of test work programs to investigate the effect of power input and regrinding on metallurgical performance. Lonmin's experience with the FCTR has caused it to build two of its own to undertake further projects on its various mines. This paper describes the design of the FCTR and the features that make it a unique research tool, and the benefits derived by Lonmin through their experience with the unit.INTRODUCTIONAs part of the Australian Mineral Industries Research Association (AMIRA) P9 project, a new model for flotation has been developed, in which the overall recovery, R, of the jth floatability class of the ith size class of a particular mineral, is given as (Savassi, 1998):"

Jan 1, 2002

By Pierre Lacoste-Bouchet, Ian Orford, Mike Cooper

"The Brunswick Mine ore requires fine grinding to achieve liberation of minerals. With 25mm slugs as the grinding media in the ball mill, there was a limitation of a P80 of 25 microns on the CuPb regrind circuit. Results from pilot plant testing showed that the separation efficiency could be increased through fine grinding with a P80 of 15 microns.Options considered were the capital expenditure for new fine grinding equipment such as a vertimill or the use of the present ball mill equipment with smaller media. The Wheelabrator Allevard Enterprise (WAE) millpebs product was chosen because it was a smaller media with a distribution of steel pellets between 5 to 12 mm.With millpebs the grinding product was reduced in size from a P80 of 25 microns to a P80 of less than 19 microns. The power draw to achieve the finer grind was 13% lower while the media consumption was 57% higher.The millpebs grinding media was also tested on the zinc regrind mill. The purpose of the trial was to understand what the media consumption and power draw would be with the charge lowered to achieve an equivalent grind as obtained with the slugs. The media consumption was approximately the same and the power draw was reduced by 30%.INTRODUCTIONThe Brunswick Mine ore is a complex Pb-Zn-Cu-Ag sulphide ore with the grain size of the minerals varying from submicron blebs to particles up to several mm in size. The ore is ground progressively finer in stages. The first step of grinding occurs in the SAG mill circuit. The product sizing 80% passing 95 microns is fed to the CuPb prefloat stage (Cormier et al 2002). The tails from the prefloat is then further ground to a P80 of 35 microns for the CuPb rougher flotation. The final liberation for the CuPb circuit takes place in the CuPb regrind circuit. The regrinding mill further liberates the cleaner scavenger concentrate, second cleaner tails and third cleaner tails. The reasoning for the progressive grinding is to achieve fine grinding without having galena over ground due to its high specific gravity that preferentially sends it to the cyclone underflow."

Jan 1, 2006

By E. C. Morton

The Western Australian School of Mines (WASM) has developed a facility for the static testing of large scale ground support elements. The samples are loaded using a mechanical screw feed jack. Instruments measure the displacement and the load being applied. Methods have been developed for testing of mesh, shotcrete and membranes. Mesh samples are restrained on all sides and loaded centrally. A new large scale punch test method has been developed to evaluate shotcrete and membranes. These products are sprayed on to a sandstone substrate containing a centrally located isolated disc. The sprayed product is loaded by displacing the disk. The different test methods are described in detail. The test program involved two types of mesh, several shotcrete mix designs with different curing times and one membrane product. The force-displacement responses are used to directly compare the products. The implications for implementation of the different ground support products are discussed.

May 1, 2009

By Robert J. Maron, Mark Fernald, Alex Van der Spek, O’Keefe. Christian, Tim Bailey

"Sonar array-based non-invasive flow measurement technology is becoming an accepted and many times a preferred method of measuring challenging single and multi-phase flows in the mineral processing industry. This fundamental sensor and measurement technology has been extended to two developments that provide new measurement capabilities useful for monitoring and managing slurry flows and pipes.The first development is the non-invasive measurement of real-time velocity profile of slurry flow in horizontal pipes. Multiple non-invasive passive sensors measure localized velocities and are combined to provide a velocity profile measurement. This information can be used to determine the approach and onset of solid deposition on the bottom of the pipe. Having this information in real time can enable operation at lower velocities and/or higher solids concentration while avoiding solids deposition or plugging and its associated operational costs.The second development is the non-invasive measurement of pipe wear on slurry lines. Presently, such measurements are made by hand-held portable ultrasonic thickness gages. The numerous shortfalls associated with the manual method are overcome with a set of permanently or semi-permanently installed transducers clamped onto the outside of the pipe. This ring of sensors contains a series of conformable ultrasonic transducers spaced around the circumference, which are used to measure the thickness of the pipe under their respective locations. Compared to manual methods, this system and approach results in better repeatability and accuracy. It also decreases inspection labor costs and pipe access requirements. The minimal accuracy variations in the presence of varying environmental temperatures will be shown. Trending of pipe wall thicknesses in high wear pipelines will be illustrated. The benefits of significantly improved pipe wear monitoring in hydrotransport lines with abrasive solids, and associated improvement in the ability to insure safe operation and avoidance of costly environmental damage due to leaks caused by pipe wear will be discussed."

Jan 1, 2009

By R. G. Hamm

A brief outline covering the shovels and draglines in use in the open-pit mines of Western Canada, including British Columbia, Alberta and the Yukon, is given, followed by the procedure for the selection of the correct wire rope for each application. Such fa ctors as wire rope constructions, lay directions and types of cores are mentioned. Once the correct wire rope has been selected, there are variousfactors that can affect the service fife ofthe rope and the reduction ofdown-time during rope change-overs. Factors such as hairpin winding, types of Becket loops, and shovel drum and bail adaptors are described.

Jan 1, 1979

By Mike Turner

The Otter-Juan mine was closed by WMC Resources? Kambalda Nickel Operations (WMC-KNO) in 1999 due to the combined effects of low Nickel prices and high mining costs. GBF Mining Pty Ltd purchased Otter-Juan Mine from WMC in early 2001 as part of WMC?s disinvestment from the nickel mines in the Kambalda area. Goldfields Mine Management (GMM), (a wholly owned subsidiary of GBF Pty Ltd) re-opened Otter-Juan in May 2001. The Otter-Juan mine is one of the oldest mines in the Kambalda region and is now mining at depths below 1160mbs. Stresses are very high, rock mass deformation considerable, and the mine has a history of serious seismic activity. Orebody widths in the current mining area range from 2 to 2.5m, with dips from 25° to 40°. On taking over the operation, GMM converted the mining method from the previous mechanised drift and fill method to a slot-rise and strip method using hand held airlegs. During the latter years of production under the control of WMC, production averaged around 12000 tonnes per month, with grades of 2.7% and orebody extraction of only 55 to 60%. In the last three years of operation under the control of GMM the mine has produced an average of 12000 tonnes per month of ore at an average grade of 4.2% and with an orebody extraction of 70 to 75%. The mine is now highly profitable with at least another 3 years of reserves remaining at depth. The main benefits of the current method include reduced dilution and increased extraction. In the relatively poor ground conditions experienced this has only been possible using airleg mining, with excavations designed to suit conditions, support to suit rockmass deformations, and with improved extraction sequencing. Other benefits have included improved operating conditions, reduced falls of ground incidents and a dramatic reduction in seismic activity. These achievements have only been possible by stepping back in time and using traditional airleg stoping methods to extract the maximum amount of the orebody with minimum dilution. This paper includes details of the mine history, geology, mining method, seismicity, and support.

May 1, 2004

By Claude MacDonald, John H. Ashburn

"IntroductionIndustrial growth and technological change over recent years had been accompanied by two major sources of concern to management and employees: (a) increase in occupational injury and illness and the resultant costs involved; and (b) equipment damage and breakdowns in concentrated production lines causing more extensive loss potential.Due to economic factors, management attention has focussed more on production and quality than on safety, health and related loss potential sources. As a result , occupational safety and health activism has grown, government legislation of compensation and occupational safety and health standards have progressively developed and stronger liability attitudes have been taken by courts of law.To improve efficiency and allow development in more competitive markets, rising labour costs, equipment costs and safety related financial losses have dictated that attention be given to conservation of all resources. Conservation of resources, people, equipment, material and environment, can no longer be addressed in isolation but must be managed integrally with production and quality. To this end, systems have developed utilizing sound management principles applied with equal intensity to production, quality and loss potential"

Jan 1, 1987

By Michael Li, Arie Moerman

"Paste backfill as a means of supporting underground mining is gaining popularity. Despite this trend, engineering and design of mine paste backfill systems are still largely based on empirical methods rather than established scientific principles. Because of a lack of sound understanding of mineral paste flow, some degree of trial and error is often involved during commissioning and operating of new paste fill systems. New operations often have to be built with flexibilities and contingencies, escalating the overall project costs.Disciplines that can lend some science to mineral paste flow include slurry transport, fresh concrete rheology, and soil mechanics. This paper reviews the applicability of some scientific and engineering principles found in those related disciplines to mineral paste flows. Examples are given to illustrate important points. The phenomenon of mineral paste flow is examined from new perspectives. Gaps in our understanding of mineral paste rheology are identified and from those some future research directions naturally emerge. Status and problems of the current engineering and design practice are also briefly discussed.INTRODUCTIONPaste backfill as a means of supporting underground mining is gaining popularity. Despite this trend, engineering and design of paste fill production and distribution systems today are still largely based on empirical methods rather than established science. One of the weaknesses of such empirical methods is the lack of scalability and transferability of rheological data from pre-engineering test phases to production phases. It is not uncommon that flow fiction data generated from expensive loop pumping tests turn out to be uncharacteristic of the paste in fullscale production. In such a case the operators have to re-climb the learning curve, sometimes with expensive disruptions to the mining operation."

Jan 1, 2002

By Jack Zhang, Yunguo Tang, Baodong Zhao

"Rare earth elements (REEs) have numerous key applications in both traditional and advanced technologies. A shortage of some critical REEs is expected due to the discrepancy between the REE abundance in REE deposits and the REE demand from the market. For example, Neodymium, Europium, Terbium, Dysprosium, Erbium and Yttrium are expected to be in short supply. REE recovery and separation from secondary resources such as uranium wastes, heavy mineral sands, and recycled materials can balance the shortfall in a cost effective way.The Saskatchewan Research Council (SRC) is engaged in the development and commercialization of complete REE recovery and separation technologies in Canada. One of SRC’s newest developments is the design and commissioning of a heavy rare earth (HREE) separation pilot plant. The pilot plant uses hundreds of stages of solvent extraction (SX) to produce high purity individual HREEs from both primary and secondary resources.This paper presents the design of an HREE recovery process for the particular case of uranium processing wastes. The separation results of a group separation are reported and discussed, as well as the issues and the challenges of the development, commissioning and operation of the continuous SX pilot plant.IntroductionSignificant amounts of strategic specialty heavy rare earth elements (HREEs) are found in uranium wastes in Saskatchewan. It estimated that about 47 tonne/a of heavy rare earth element oxides (HREO) including 27 tonne/a of Y2O3, plus 6 tonne/a of Sc2O3 are in the raffinate of every uranium mill for potential recovery. Since the HREEs are already in the raffinate, cost effective HREE production is promising in Saskatchewan.Selective precipitation including nutraulization, oxalate and double-salts precipitation, as well as sulfide precipitation, ion exchange (IX) and SX are commonly used technologies for the recovery and purification of REE solution. REE oxalate precipitation is an effective technology to remove Fe, Al, Ca, Si and other impurities by taking the advantages of the solubility difference between oxalates of REEs and impurities in acidic solution (Xu, 2005)."

Jan 1, 2017

By D. Richardson

Presentation Objectives ?Demonstrate the utility of 3D modelling for visualizing exploration data ?Demonstrate the target generation ability of 3D model query methods Exploration Criteria -Example Given the Geology of Sudbury What Are Our Exploration Criteria? (selected examples) ?Geometry ?Trends ?Lithology ?Proximity to Sulphides ?Length and Grade of Anomalous Mineralization ?Distance from Footwall In Addition ?Geophysical Criteria ?Economic Criteria ?Amount of Available Space ? Depth

May 1, 2006

By R. Ramírez, N. Aslin, G. Ríos, T. Bravo, A. R. Almansa

Lacy copper has been an on-going concern at Atlantic Copper for at least 10 years and was first reported to Glencore Technology in mid-2010. Over the past 12 years, many of the plates were replaced due to age and general deterioration however; plate passivation and lacy copper issues have persisted. After analyzing all the possible causes of this phenomena, it was found that the problem is caused by a degradation of stainless steel as a consequence of the deposition of Sb oxides. These deposits act as passivating agents of stainless steel, which reduces the density of copper nuclei, causing defective copper deposit, with low thickness and ductility. After doing several tests for reducing/removing the phenomena, the over-riding factor was found to be the anode-cathode overlap. An adequate overlap eliminates the problem of "lacy copper". This was verified during an eight month trial with anodes extended 2.5cm in length. Longer anode not only avoids the appearance of lacy copper, but also recovers cathodes that already have lacy copper. On the other hand polishing of plates only gives rise to a temporary solution that requires on-going polishing, to avoid the re-appearance of lacy copper. INTRODUCTION The electrolytic copper refinery of Atlantic Copper in Huelva (Spain) was commissioned in 1970 with an initial capacity of 40,000 t of cathodes per year. In 1975 the copper refinery was expanded to 108,000 t/year. From 1994 to 1996, a new expansion together with the implementation of ISA permanent cathode technology led to a capacity of 215,000 t/y. Since 1995, a progressive increase in the current density up to 350 A/m2 has been accomplished, which together with an increase in the number of cells from 1,120 to 1,204, has led to the present cathode production capacity of 290,000 t/y A lack of copper deposition in the lower part of the steel permanent cathodes was first reported in 2010. This phenomenon is known as “Lacy copper” because of the appearance of the copper deposit as it can be seen in Figure 1. The occurrence of this phenomena was relatively low and was assumed to be originated by an excessive anode scrapping. Nevertheless, in December 2015 Lacy Copper was observed in a significant amount of copper cathodes giving rise to the following issues: Increased tramp copper – housekeeping and maintenance problems Poor appearance of cathode deposit and untidy looking bundles

Jan 1, 2019

By S. Nikolic, G. M. Stieper, D. P. Mallah, B. J. Hogg, P. B. Voigt

Copper feed materials processing is becoming more challenging, due to an incremental increase in the mineralogical and compositional complexity of these feeds. These complex and polymetallic feeds are now becoming more common and many sites have been forced to re-evaluate their operating strategies to process these materials at cost competitive rates, whilst meeting ever more stringent environmental regulations. Most operations must first evaluate the merits of pyrometallurgical and hydrometallurgical treatment routes. Although there are multiple copper smelting technologies available, only top-submerged lance (TSL) technology, supplied by Glencore Technology as ISASMELT™, has been applied in the real world to consistently and successfully smelt complex materials in integrated metallurgical facilities such as Glencore’s Kazzinc Ltd. operation in Kazakhstan, Umicore Precious Metals Refining in Belgium and Aurubis AG in Germany. Glencore Technology also offers hydrometallurgical processing, through the Albion Process™ technology, opening up viable flowsheet options previously not possible for these complex feeds. This paper describes a number of real world process flowsheets at global operations and Glencore’s own operations at Mount Isa and Kazzinc Ltd., which process complex feeds. These flowsheets integrate the ISASMELT™, Albion Process™, ISACONVERT™, ISAKIDD™ Tank house, and bottom blown oxygen cupel (BBOC™) technologies to provide an effective process solution for the treatment of complex polymetallic feeds to produce metallic copper and associated by-products. INTRODUCTION Traditional smelters and those built in recent times within the bulk smelting hubs of the world have been designed to treat standard/clean concentrates. In recent years the processing of complex polymetallic sulfide concentrates and the recycling of secondary copper and derivatives of waste electrical and electronic equipment, such as e-scrap, have become a focus for numerous companies (Alvear & Nikolic, 2013). Processing of these complex feeds, characterized by relatively high levels of minor elements (over 5% of elements such as arsenic, antimony, bismuth, lead and zinc) is more challenging. Facilities not designed for these types of materials may require significant modifications or a change in smelting technology to treat them. Often operations find themselves re-evaluating the merits of pyrometallurgical and hydrometallurgical treatment routes for their sites through a number of factors:

Jan 1, 2019