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By H. K. Shearer

Oil production in north Louisianat in 1939 was 25,249,640 bbl., a decrease of 11.2 per cent from 1938. The only important increases in production were in the Cotton Valley and Shreveport fields, but Caddo, Homer, Sligo and Zwolle also made slight gains. Greatest decreases were in the Lisbon and Rodessa fields. Xatural gas production of 313,333 million cu. ft. was an increase of 5.6 per cent over 1938. The increase was accounted for in the Monroe field, while all other fields showed only minor variations from the production of the previous year. Well completions in 1939, as compared with 1938, were as follows: The decline in number of completions was due entirely to lack of proved areas for drilling, and would have been greater except for a revival of interest in the old Caddo shallow field. A majority of the wells completed during the year were in various old, shallow fields, so the average depth of drilling was much less than in several preceding years, notwithstanding a few very deep tests. No new fields were discovered, the only wildcat well reported as a producer being a very small oil well in northwestern De Soto Parish, which is of no apparent commercial importance. Deep gas-distillate production in the Cotton Valley formation was opened at Lake Bistineau and Lisbon, and oil at Shongaloo, but all these wells were too small to encourage additional drilling. Extensions and Developments Caddo Field.—More active drilling was donc in the 36-year old Caddo field in 1939 than in any of the newer fields, with completion of 133 oil

Jan 1, 1940

By E. W. Schilling

THE-separation of hematite by hysteretic repulsion was first brought to the attention of the public in 1922, by W. M. Mordey1. Three-years later another paper2 was published and after another four years a third paper3 appeared in the South African publications. Certain data were lacking in these papers. In order to continue the work intelligently a knowledge of the shapes of the hysteresis curves for certain minerals was very necessary. This information was not available until the present year4. It was known that reduction of certain ores rendered them amenable to this process of separation but definite data in. the form of curves showing exactly the effect of such treatment were lacking. Prob-ably our best source of information on the separation of minerals by the use of alternating-current magnetic fields today is the reports from the U. S. Bureau of Mines 5-7. It is not the purpose of this paper to tell the reader in detail how to make a commercial separator. Experimental models have recently been made7 and the results obtained have been so good that it is the opinion of the authors that the public will soon take an active interest in the subject and its development. The writers have constructed a separator that is considerably different in construction and operation from the two types described by Mr. Davis. This will be described; but the real purpose of this paper is to outline certain experiments and give curves showing data that have a fundamental bearing upon the practical construction of a separator of this type.

Jan 1, 1936

By H. K. Shearer

Oil production in north Louisianat in 1939 was 25,249,640 bbl., a decrease of 11.2 per cent from 1938. The only important increases in production were in the Cotton Valley and Shreveport fields, but Caddo, Homer, Sligo and Zwolle also made slight gains. Greatest decreases were in the Lisbon and Rodessa fields. Xatural gas production of 313,333 million cu. ft. was an increase of 5.6 per cent over 1938. The increase was accounted for in the Monroe field, while all other fields showed only minor variations from the production of the previous year. Well completions in 1939, as compared with 1938, were as follows: The decline in number of completions was due entirely to lack of proved areas for drilling, and would have been greater except for a revival of interest in the old Caddo shallow field. A majority of the wells completed during the year were in various old, shallow fields, so the average depth of drilling was much less than in several preceding years, notwithstanding a few very deep tests. No new fields were discovered, the only wildcat well reported as a producer being a very small oil well in northwestern De Soto Parish, which is of no apparent commercial importance. Deep gas-distillate production in the Cotton Valley formation was opened at Lake Bistineau and Lisbon, and oil at Shongaloo, but all these wells were too small to encourage additional drilling. Extensions and Developments Caddo Field.—More active drilling was donc in the 36-year old Caddo field in 1939 than in any of the newer fields, with completion of 133 oil

Jan 1, 1940

By Alfred Wandke

The problem of vein formation has been of particular interest to the writer for years. As his work for a long time was confined largely to districts showing large deposits of copper ore, it was natural that the efficiency of replacement, as one if not the chief control of the emplacement of the ore, seemed a particularly attractive hypothesis. Of late years, in almost daily underground work in the Guanajuato district, he has collected evidence which makes it certain that in a number of cases the ore solutions were under sufficient pressure to force the rock walls apart and to hold them apart, thus offering an open space for the deposition of vein and ore-bearing material. This paper will concern itself with conditions frequently met with in hypogene ore deposits of the vein type, and will deal in particular with ore occurrence in precious-metal veins of the type classified by Lindgrenl as epithermal deposits, or metalliferous deposits formed near the surface by ascending thermal waters2 and in genetic connection with igneous rocks. To account for the emplacement of this type of ore deposit various writers have suggested the following agencies: 1. Shattering of the wall rocks. 2. Pressure of growing crystals. 3. Magmation, as treated at length by Spurr3. 4. Replacement. 5. Openings produced by folding. 6. Shearing due to gravity. 7. Shrinkage produced by the passage of pre-ore solutions. 8. Contraction joints produced by lateral secretion. To this list there may be added another agency, a discussion of which forms the basis of this paper: 9. Pressure of the ore-bearing solutions.

Jan 1, 1931

By N. P. Pinto

Compacting below the recrystallization temperature was studied. Ideal density was attained at 550° to 600°C using 25 tsi. Compacts have strength and hardness higher than cold worked beryllium. The recrystallization temperature of this highly stressed metal is that of cast, cold worked beryllium and appears independent of pressing temperature. THE process metallurgy of beryllium is beset by many difficulties that hinder the production of sound beryllium shapes of controlled properties. Most of these obstacles are traceable directly to the low density, low ductility, and high affinity for oxygen of the metal. Castings are susceptible to cracking and porosity, and controlled grain size is not easily attained, yet is critical to further working. Any process must carefully avoid oxygen pickup. Conventional metallurgical processes, including melting, casting, forging, rolling, and extruding have been treated previously,'" as have the conventional powder metallurgical methods.' More recently, a method has been advanced for producing powder compacts of high density by hot pressing at 1000" to 1100°C, using pressures of 0.25 to 0.5 tons per sq in. (tsi).3 Here, Seybolt and coworkers attained theoretical density of 1.85 grams per cc using pres-sure-temperature combinations of 500 psi-1100°C, 750 psi-1075"C, and higher. The warm pressing of beryllium is a practical method for producing bars of controlled properties and appears to have certain advantages, particularly when high strength and hardness are required. Other investigators have studied the hot pressing of various pure metals, such as copper,"-" gold," iron,10-11 and aluminum." Their results indicate that ideal densities may be attained by compacting at temperatures less than 50 pct of the absolute melt-

Jan 1, 1955

By Arthur Phillips

THE progress made in recent years in the art of dispersion-hardening has naturally led to an intensive study of alloy systems capable of yield-ing supersaturated solid solutions at ordinary temperatures. In general, the investigations have been confined to rather precise determinations of solubility limits and to experimental approaches designed to furnish more complete information regarding the rate and nature of precipitation under appropriate thermal conditions. Efforts are being made to focus more sharply on the atomic changes that are a direct consequence of the instability of the supersaturated solution. Here precision X-ray methods have come to be of considerable importance because lattice parameter measurements indicate very precisely the concentration of solute atoms in the solvent lattice. In spite of the general acceptance of parameter values as a criterion for the placing of solubility limits, it may be suggested that no thorough appraisal has been made of the several factors that conceivably may affect such measurements. More specifically, little attention has been devoted to the significance of surface energy conditions, specimen size and method of preparation, with par-ticular regard to the genesis of the grains and the surface concentration changes as a consequence of heat treatment and etching. Stenzel and Weerts1 recently published the results of a detailed study of precipitation reactions in aluminum-rich copper alloys. They found that, although copper lowers the lattice constant of aluminum, a 5 per cent copper alloy quenched from 150° and 225° C. had parameter values unquestionably higher than that of pure aluminum. Their results seem to substantiate, at least qualitatively, the earlier work of von Göler

Jan 1, 1934

By H. R. Hose

Total crude fluorspar reserves in western Europe, containing more than 35 pct CaF*, are estimated at 12 million metric tons, while reserves in the USSR and Soviet sphere may exceed 5 million metric tons. The bulk of these reserves are concentrated in the USSR, Spain, United Kingdom, Western Germany, and Italy. Since published estimates of the tonnages of individual mines and explored deposits are not available for most countries in Europe, the estimates given in Table I for individual countries are necessarily approximate, as they have been compiled from various sources and modified and combined according to the author's judgment. The majority of fluorspar deposits in Europe belong to the late Paleozoic metallogenetic epochs and have been found within or along the borders of the Hercynian massifs. Deposits in the Central and Esterel massifs of France, those of Western and Eastern Germany, Sardinia, the Catalonian coastal range and the Sierra de 10s Santos in Spain, and those of Devonshire and Cornwall belong to the Hercynian metallogenetic epochs. The deposits in southern Norway and Sweden belong to the middle Paleozoic or later, those of northern England to the late Paleozoic or later, those of northern Spain and Greece to the late Mesozoic, and those of northern and probably central Italy and Switzerland to the early Tertiary. Fluorspar occurs typically in veins, lenses, and stringers, but also in bedded replacement deposits and pockets, and may be colorless to white, yellow, green, pink, brown, blue, or purple to almost black. Except for the colorless variety, the only kind which can be used for the optical industry, the color of the fluorspar does not affect its ultimate use,

Jan 4, 1955

By C. A. Stetefeldt

In May and June, 1885, I was engaged in examining the goldores of Las Minas, in the State of Vera Cruz, Mexico, with a view of finding a cheap and efficient method for extracting the gold. The following minerals could be plainly seen in the ore : magnetite, pyrites of iron, pyrites of' copper, quartz, and garnet. Neither galena nor zinc-hlende mere visible, but the ore contained a trace of lead, and in some samples of ore from the Muertos mine, 1.19 per cent. of zinc mas found. Antimony and arsenic were not present. Native gold could scarcely be seen in specimens of' the ore, and it only appeared—mainly in extremely fine particles—after pulverizing and washing. Magnetite was in every instance the most prominent mineral, its quantity varying between 43 and 67 per cent. Determinations of copper and sulphur showed that from 3.5 to 7 per cent. pyrites of copper, and from 3 to 22 per cent. pyrites of iron were present. The gold-value of the ore varied between 0.3 oz. and 0.8 oz. per ton. I do not speak of specimens, but of average samples of large quantities of ore put through the battery. In ore that had been crushed through a No. 40 screen, the gold appeared, in part, as free gold, the rest being thoroughly mixed with the magnetite and pyrites, both minerals containing about the same percentage of gold. If this free gold was brought in contact with pure quicksilver it (lid not amalgamate readily, even if the quicksilver was charged with sodium amalgam.

Jan 1, 1886

By Magnus Troilius

The method of using the bromine process of determining sulphur in steel, described below, is in successful use at the Midvale Steel Works. Ten grams of drillings are weighed out and put into the 1/2-liter flask A, with long neck. The flask is connected with a wide glass tube C', which, in its turn, is connected with the absorption bulbs B, containing HCI, 1.12 specific gravity, and ahout 5 C.C. of bromine. The wide tnbe C causes the vapor to condense and flow back into the flask A during boiling. The bulbs B connect with a long glass tnbe, which may be made to carry off the bromine fumes through a hole in a window, or, better still, through a flue with powerful draught. The connections being made, 100 C.C. of boiling water are run in through the thistle tube T. The air is thus completely driven out of the flask. 100 C.C. of HC1 (about 1.19 specific gravity) are then run in. When the gas begins to run rattler slowly through B, heat is applied until boiling gradually ensues. The steel being completely dissolved, the apparatus is disconnected, and the contents of B rinsed out into a beaker of 100 C.C. capacity, into which a few C.C. of a concentrated solution of BaCI, have been previously introduced. Heat is then applied (best by means of the hot iron plate) until the bromine is completely driven off and the BaSO, has settled nicely to the bottom. The BaSO4, is then filtered off on a small

Jan 1, 1884

By Rossiter W. Raymond

The manufacture of ferromanganese in the blast furnace having been the subject of considerable attention in the Institute, I beg to put on record a contribution to the discussion from a quarter hitherto not directly represented, namely, the St. Louis furnaces, near Marseilles in France, belonging to a company of which M. Jordan, a member of the Institute, is Managing Director. These furnaces commenced in 1862 to manufacture specular pig (fontes facettes) containing from three to six per cent. of manganese. In 1864 the regular production of spiegeleisen (fontes miroitantes), containing seven to ten per cent. of manganese, was inaugurated. At that time the Rhine was the only locality of this manufacture, and the Bessemer works of England and France obtained from Gernlany all their spiegel. From 1864 to the present time, the St. Louis furnaces have been advancing steadily the percentage of manganese in their product. From ferromanganese of thirty per cent. they had arrived, about two years ago, at a product containing seventy to seventy-five per cent., and for some time past they have been turning out what, as M. Jordan remarks, may fairly be Termed fonte de manganese, or manganese pig, instead of iron, since the percentage of iron it contains is not more than 8.5, while the percentage of manganese is 85, or ten times as great. This very high grade material has a peculiar appearance, entirely different from that of ordinary cast iron or spiegel. It is granular, and steely gray in color. The following analyses, communicated to the Sociètè des Ingenieurs Civils, by M. Jordan, show the composition of various products of the St. Louis furnaces:

Jan 1, 1879

By Sir John Cadman

Since my previous review of the Persian fields, presented in 1929,' considerable progress has been made. The main feature of drilling development has been the delimitation of the Haft Kel field and its extensions. Although the limits have not yet been reached, a productive area of about 40 square miles has already been proved and it is now certain that the field will be of the same order of importance as the Masjid-i-Sulaiman field. Production to main pipe line from Haft Kel was begun in November, 1929, and to date about 4,500,000 tons have been produced. Normal production has continued from the Masjid-i-Sulaiman and Naft Khaneh fields. The search for oil in horizons below the main producing limestone is perhaps the most interesting and important exploratory drilling work in progress. Promising results have been obtained in the first well deepened in the Masjid-i-Sulaiman field with this objective, and the exploration of these lower formations is being continued. In this connection an allied program of geochemical research work on the nature of the oils and oil-bearing rocks of different horizons is at, present being undertaken. Masjid-i-Sulaiman Field Since the Haft Kel field was brought into production in 1929, production from Masjid-i-Sulaiman has been reduced in order to equalize to some extent the producing lives of the two fields. The production for the last four years has been as follows: m Approximate Equivalent in TonB Barrels 1929 5,434,071 38,038,497 1930 4,925,869 34,481,083 1931 4,248,086 29,736,602 1932 Approximately 4,500,000 31,500,000

Jan 1, 1933

By R. H. Richards

In October, 1891,I read a paper before the Institute on a "A HandTelescope for Stadia-Work" (Bans., xx., 732), and promised to report at an early date some results showing the degree of accuracy attained with the instrument. I am now able to report on these results and also on certain improvements that I have made in the target since the first paper was read. I may say that I prefer the title, "Prismatic Stadia-Telescope," to that used in my earlier paper, for while the instrument can be used with perfect satisfaction for short sights up to, say, 300 to 600 feet when held in the hand, it is impossible to read milch longer distances without the use of a tripod, as a steady support for the instrument. Results are here given upon four combinations of prism and telescope. No. 1. A telescope made by Alvan Clark & Sons, 3-inch objective, 28 inches focal length, magnifying 60 diameters, the prism covering half the objective: Feet measured Reading of Distance reduced Reeding of rod pro by tape. the rod. to feet. portional to 100 ft. 127.66 1.1825 100 .92629 211.35 1.9585 100 .92666 326.59 3.0265 100 .92669 484.88 4.4925 100 ,92652 606.91 5.6225 100 .92641 Average,,92651 The value of this prism therefore is .92651 feet on the rod for 100 feet of distance, or 1 foot on the rod corresponds to 107.931 feet of distance. No. 2. A Bardou telescope having a 1-inch objective, magnifying 20 diameters, and a prism covering half the objective:

Jan 1, 1893

By Colin M. Sargent

ALTHOUGH annealing twins are frequently observed in many fcc metals, their occurrence in aluminum is relatively rare. ~ahn' in his review of twinning has listed only a few references to observations of twins in aluminum, e.g., Refs. 2 and 3. They have also been shown to occur in evaporated aluminum layers.4 During the present work, several annealing twins were studied in aluminum. The specimens of 1099-grade aluminum had the following thermomechanical treatment: deformed 90 pct by rolling, partially re-crystallized, further deformed 60 pct to a final thickness of 100 p, then annealed for 24 hr at 120°C. This treatment produced several annealing twins—-about ten per electron microscope specimen. The specimens were produced by the window technique and examined in a Phillips E.M. 200 operating at 100 kv. A typical twin boundary is shown in Fig. 1. For several of the twins studied the twin plane could be tilted so that it was parallel to the electron beam, e.g., Fig. 2. The associated diffraction pattern, Fig. 3, shows the twinned relationship between the grains. The twinning plane in each case was (111). Use of a reflection common to both the twin and the matrix,* i.e., using reflecting planes parallel in the twin and the matrix, the coherent twin boundary becomes invisible and only the noncoherent segments of the stepped boundary are seen, e.g., Fig. 4. Trace analysis of the boundaries showed that the long straight portions were invariably the twin plane; i.e., these portions are coherent. The planes of the shorter segments are shown by Fig. 5 to be (551 1, (7111, and {211).

Jan 1, 1969

By H. S. Gieser

THE flotation of oxidized silver, ores offers an interesting problem to the operating metallurgist, who has to treat this material. The advances made in the art of selective flotation by the use of newer collectors with accelerating and inhibiting reagents suggests that there should be something to help to decrease tailing losses. For many years there was no working hypothesis, so the subject was approached more or less in the dark, but with the publication of a paper by Taggart, Taylor and Ince1 giving results of flotation tests with many organic compounds and presenting a tentative theory, a better foundation has been laid and henceforth progress should be more rapid. Over a period of one and one-half years there was much experimentation with flotation of oxidized silver ores at El Tigre, Sonora, Mexico. The material coming to the mill was straight sulfide ore in a silicified rhyolite gangue, the ore minerals being sphalerite, galena, pyrite and tetrahedrite. This came largely from the lower levels of the mine. With the approaching exhaustion of these orebodies, attention was turned to oxidized ores left behind during higher prices of silver. Of late oxidized ore has been at times 25 per cent. of mill tonnage. Aerofloat 25, in considerable quantity, together with ethyl xanthate, has been used in the mill. The former raises large quantities of "insoluble" or gangue, which is difficult to reject when the density of the tailing pulp approaches 33 per cent. solids, as it did during periods of water scarcity. The mill tailing at times contained as much as 5 oz. of silver on a 32-oz. mill head.

Jan 1, 1931

By F. C. Miller

THE metallurgical fuel of Colorado, Utah, and New Mexico has been a very tardy member in the caravan of western industrial progress. The history of western coke has naturally been closely related to the development of the metallurgy of iron and steel and the precious metals, in the State of Colorado. It was at Leadville, with a population of 300 in 1877, that the Sentinel was published by Richard S. Allen. The Sentinel gave very full accounts of the various mineral discoveries at the new town of Leadville, which found their, way to the more widely circulated journals of the East, and attracted the attention of many people. At the close of 1878, a census showed a total of 5040 persons. The first smelter was established in 1877, at Malta, two miles from Leadville, by A. R. Meyer, but was not successful. It was succeeded by the Harrison Reduction Works, in 1878. The La Plata began with one furnace in June, 1878, and in 1879 had four furnaces in active operation. These furnaces used charcoal for fuel, and, because of hot tops, suffered a tremendous loss in lead and silver. This difficulty was overcome by the erection of 50 single-bank 10-ft. beehive ovens at Crested Butte, Colo., in 1880. The slack coal sent to these ovens was very pure, and yielded a coke carrying as little as 4.5 per cent. ash. Among the pioneers in the Leadville district were Grant, Eddy, James, Billings, Eiler, and Dickson. To these men the West owes the present expansion of its mining industry, and the erection of metallurgical processes for the treatment of precious metals.

Jan 8, 1918

By R. P. Agarwala, M. S. Anand, S. P. Murarka

Using the residual radioactivity technique, grain boundary diffusion of chromium in the a phase and lattice diffusion in the a and the ß phases of zirconiuttz have heen studied. The diffusivities (in units of square centiwzeters per second) have heen expressed as THE rate of diffusion of atoms along surfaces and grain boundaries is much greater than that through the bulk of metals. These processes dominate over volume diffusion at lower temperatures and can be isolated from it by virtue of the fact they yield high diffusion coefficients and low activation energies. In zirconium, however, it has been difficult to identify the volume-diffusion parameters separately. The values of diffusivities in a and ß phases yield activation energies which are much lower than those for volume diffusion calculated from semiempirical or empirical relations.1-3 Diffusion frequencies (Do) are also low, especially in the a phase, and they yield negative entropies of activation.4 Similar results have been obtained for the diffusion studies in titanium.5 It is yet to be investigated whether in these cases diffusion is controlled by some extraneous factor like high reactivity of these metals, or some different mechanism is operative as suggested by Pound et a1.6 However, Federer and Lundy,7 in a recent study of the diffusion of zir-conium-95 and columbium-95 in zirconium, and Gibbs et al.,8 in the study of impurity diffusion in titanium, found a temperature dependence of D, Do, and Q. Their study yielded low values of Do and Q at low temperatures, as has been found by other workers, and fairly high values at high tempera-

Jan 1, 1965

By Edward B. Dismukes, Walter R. Dickson

Measurements of current efficiency at an iron anode during the electrolysis of FeO-CaO-SiO2 melts contained in an iron crucible indicate that compositions of high SiO5 content conduct current almost entirely by ionic mechanisms. Hozueuer, compositions of high metal oxide content give euidence for considerable nonionic conduction that can be attributed to p-type semicon-duction. Measurements of transference numbers in a Hittorf-type cell show that both calcium and iron ions are important contributors to ionic conduction. ELECTROCHEMICAL properties such as conductance, transference numbers. and oxidation or reduction at an electrode have been studied as means of delineating the structure of simple silicate melts that are related to the more complex slags encountered ir steelmaking processes.' Measurement of these properties has strengthened the concept that molten silicates are constituted of metal ions and of silicate networks. Typically, the magnitude of electrical conductivity and the extent of agreement with Faraday's law have given evidence for ionic structures, and transference numbers have shown cations to be the exclusive carriers of electrical charge. However, melts containing oxides of iron, FeO in particular, have been found to exhibit nonionic conduction of curx,ent. The work by Inouye, Tomlinson, and chipman' demonstrated semiconduction, presumably of the p-type, in molten wüstite. Simnad, Derge, and George3 and Dukelow and Derge,4 in studying the electrolysis of FeO-SiO2 and FeO-MnO-SiO2 melts, concluded that p-type semi-conduction occurs in these systems, although ionic conduction is generally favored by increased percentages of MnO or SIO2. Previous research on the electrochemistry of

Jan 1, 1962

By George J. Bancroft

At the New York meeting of the Institute, April, 1907, I presented a paper entitled, The Formation and Enrichment of Ore-Bearing Veins,' in which paper I advanced the following propositions: (1) That the majority of mineralized veins are the product of expiring vulcanism; (2) that most of these veins were primarily mineralized by comparatively rich solutions in comparatively short periods of time; (3) that the solutions gained their metal-values from a comparatively rich source; (4) that there is a bary-sphere containing large amounts of the useful metals; (5) that eruptions spring from various depths and bring various kinds of magmas towards the surface; and (6) that only those eruptions which disturb the barysphere and bring a magma rich in metals sufficiently near the surface to be leached by vein-making solutions are productive of valuable ore-deposits, other eruptions producing barren veins. Ore-deposits due to magmatic segregation were not included in this general survey. As a result of considerable further study I have modified my views in some respects, while in others I feel more sure than ever of the ground taken at that time. That ore-bodies are infrequent occurrences and born of extraordinary conditions I think is now generally accepted. The theory that persisted for a time—namely, that ore-bodies were formed by the ordinary ground-water, which consists of extremely dilute solutions, derived from leaching extremely lean surface-rocks, and which must occupy enormously long periods of time in concentrating the values so leached, is, I think, now pretty generally regarded as not applicable to the great majority

Jan 1, 1910

By A. D. Hoagland

The Flat Gap mine is located on Copper Ridge in the Appalachian Valley of East Tennessee. Large zinc orebodies occupy zones of solution and collapse breccias in Lower Ordovician Kingsport limestone and dolomite. The principal ore mineral is sphalerite and the principal gangue is dolomite. The ore-bearing horizons are considerably more than 95% covered by thick residual clay. Geochemical prospecting under these conditions is an effective exploration technique which played an important role in the discovery and exploration of the Flat Gap mine. The Flat Gap mine, an important zinc deposit of the Appalachian type, is located in the Copper Ridge Belt in the Valley of Tennessee approximately 30 miles northeast of the Mascot-Jefferson City zinc district (Fig. 1). The ore is found in large stratigraphically linked deposits in solution and collapse breccias of the Kingsport, Longview and, to a minor extent, Mascot formations of Lower Ordovician age. The principal ore mineral is sphalerite and the principal gangue minerals are dolcrmite and accessory pyrite. There is local minor galena and very rare barite and fluorite. The ore-bearing horizons are covered by about 20 to 100 ft or more of residual clay except where active streams have exposed bedrock. Considerably less than 5% of the favorable host rocks are exposed in outcrop, and this nearly complete soil cover creates a serious obstacle to exploration. Comprehensive surveys of the base metal content of soils furnish a useful substitute for outcrop geology, and under favorable conditions, this technique is a very valuable prospecting tool. The analysis is carried out by a titrametric dithizone method modified after the procedure described by E. B. Sandell.' This method detects

Jan 1, 1962

By William Schriever

The flow of a gas-free liquid through a spherical-grain sand has been investigated by S1ichter.l By theoretical considerations involving a rather large number of approximations he arrives at the following flow-formula: V = CPd2At NLB{1 - m) where V is the volume of liquid delivered in time t through a cylindrical column of sand of length L and cross-sectional area A by a pressure-drop P when the sand grains of diameter d are packed to a porosity m and the coefficient of viscosity of the liquid is n. C and B are constants which were determined from geometrical relations; B was in reality a function of . Values of B(l — m) for various values of m were given in a table. In the same Annual Report of the U. S. Geological Survey, King reported the results of his experiments on the flow of water through porous media. He found that there was a departure of about 86 per cent. from a linear relationship between rate of flow and pressure, for a specimen of Dunnville sandstone for pressure drops not exceeding 60 cm. of mercury. The specimen was approximately 4 cm. in diameter and 5.1 cm. in length. Over the same range of pressure he found a departure of 45 per cent. for a specimen of Madison sandstone. For unconsolidated sands he found departures as great as 49 per cent. for pressure drops of 70 cm. of mercury; for pressure drops not exceeding a few inches of water he obtained a close approximation to a linear relation. He also investi-

Jan 1, 1930