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By Prasad S. Mulukutla

INTRODUCTION The use of specialty chemicals In mining Is an Important consideration In determining the economic efficiency of a floatation plant. The plant metallurgist would like to maximize the recovery of valuable minerals while maintaining an acceptable grade product. The direct cost of the reagents, while significant, Is only a part of their economic effect. Reagents determine the flotation rates and the selectivity of the mineral separation. In flotation practice, mineral selectivity can be achieved through the addition of various reagents that can control the wettablllty of a particular mineral In the flotation pulp. The reagents which will generally optimize the flotation process are commonly classified Into three distinctive categories: collectors frothers and modifiers. Large tonnages of metal sulphide concentrates which are the source of most of the common base metals are produced economically by fairly standard flotation techniques. The advent of modern technology coupled with the necessity of processing finely disseminated and complex ores of low grade has Increased the need for utilization of non traditional and high selective chemicals reagents for the economic recovery of metals and raw materials. Mining operations in developing countries continue to progress at a rapid growth as many countries mine and process both metallic and nonmetallic ores. The total mine production of base metals, precious metals, Iron ores and coal In developing countries In Africa, Asia and South America has been much higher as compared to the western world production In terms of tonnage and dollar value. Global capital Investments In mining during 1991-95 Is $ 55.1 billion and It Is anticipated that the development of new and specialty reagents may be concentrated In the processing of aluminum , copper, precious metals and Industrial minerals with special reference to potash, phosphates, kaolin and silica sands.(1) The challenge for the design and development of new specialty chemicals Is dependent on Its cost performance and environmental acceptability. Information on the theory and application on the development of mining chemicals has been reviewed In several conference proceedlngs,(2-4) publications(5) and also discussed by several Individual authors.(1,6-10) These publications serve as a comprehensive reference source on the reagents used In several flotation processes. This paper discusses the present trend in the use of specialty mining chemicals In diversified mining operations on several mineral systems with particular reference to sulfide ore systems. The necessity to expose these specialty chemicals through aggressive marketing techniques In mining operations In many developing countries Is also presented. SPECIALTY CHEMICALS Specialty mining chemicals, like other specialty chemicals, share common business characteristics that transcend geographic boundaries. They are manufactured 1n a few selected areas, generally expensive relative to commodity chemicals, shipped and compete globally and usually require specialized knowledge for proper use. Specialty mining chemicals are relative newcomers to chemical markets. The vast majority of mining chemicals are derived from products that are less than two decades old. Traditional collectors and frothers have been available for a considerably longer time. The emphasis on adding value to existing products and byproducts Is responsible for several characteristic features of the mining chemicals business. Most raw materials for these chemicals are related to oil and gas byproducts, chemical refineries, pulp and paper mills and all chemical manufacturers. Until the last several years these operations were located In Industrialized countries, while a significant number of mining chemical users were In developing countries. Therefore International trade In mining chemicals developed through agencies or agents in each particular country.

Jan 1, 1993

By S. E. Phifer

The Haile Gold Mine was the largest gold producer east of the Mississippi River prior to 1942. It is currently the only producing gold mine in the Southeastern United States. Current development involves the mining and heap leaching of some 1000 TPD. Carbon is employed as a recovery medium. Due to its clayey nature and excessive fines in the oxide ore, agglomeration using Portland cement is required prior to leaching. The ore ranges in screen size from two inches to -200 mesh. The agglomerating step combined with certain other conditions has enabled Piedmont Mining Company to achieve recoveries of 90%.

Jan 1, 1987

By J. R. J. Edwards

Jaspilite, a mineral consisting of silica and iron oxide in varying proportions, is one of the host rocks of the high grade ore deposits situated in the Middleback Range of South Australia. As a result of laboratory investigations, a flowsheet was postulated for the beneficiation of jaspilite to produce an acceptable grade product for feeding to blast furnaces, The flowsheet involved the reduction of the hematite in the haspilite to magnetite, the grinding of the reduced product to 95 pct minus 325 mesh Tyler followed by wet magnetic separation, hydroseparation and filtration to yield a magnetite concentrate. Agglomeration of the fine concentrate would then be necessary to meet the physical requirements of blast furnace feed. To prove the postulated flowsheet, to obtain a more accurate estimate of costs and to obtain design data for a commercial installation, a pilot plant was constructed at Whyalla, South Australia.

Jan 1, 1960

By Jack V. Hill

A unique type of grinding mill liner has been developed by Waagner-Biro A.G. of Austria. This liner system, termed an angular spiral lining (.ESL), was, successfully tested by Magma Copper Company's San Manuel concentrator in both their 10 Ft x 10 Ft (3.05m x 3.05m) and 12 Ft, 6 In x 14 Ft (3.81m x 4.27m) grate discharge wet grinding ball mills. Magma Copper's savings in power and grinding balls justified conversion of more than half of their twenty-six ball mills to the ESL system.1,2 The ASL system was provided by the Capitol Castings Division of Midland Ross Corporation, the exclusive licensee for such conversions. Capitol Castings proposed the following as expected benefits from installation of an ASL system in an 18 Ft x 21 Ft (5.49m x 6.40m) overflow discharge wet grinding ball mill at the Pinto Valley Operation of Cities Service Company: "(a) Reduction of power consumption per ton of ore milled = 12%, (b) Increased throughput = 6%, (c) Reduction of ball consumption = 6%."

Jan 1, 1982

By F. S. Knoll

The high tension process which separates materials based on relative differences in surface conductivity has been very successful in recovering non-ferrous metals from municipal waste. Aluminum is by far the largest constitutent of the total non-ferrous metal fraction; accounting for >95% in most localities. Wire and insulation mixtures from industrial wastes have been treated commercially for several years by a high tension process initially developed for use in the iron ore industry. The wire and insulation application was a forerunner of municipal waste dry treatment technology. In the past eighteen months the rotating-drum-type electrostatic separator has undergone extensive testing and development in order that the process might be efficiently adapted to the recovery of aluminum from municipal waste.

Jan 1, 1974

By Paul J. A. Lever, Robert H. King

Human operators, geological conditions, equipment changes, mining sequences, and roof conditions are some of the continually changing operating conditions that drive a dynamic mining environment. These dynamic characteristics make it difficult to automatically analyze mining data because attributes change as the mining environment changes. Mine monitoring systems could provide mine managers with much more useful information than they do presently, if automatic analysis were possible. Automatic analysis of sensor data is also key to autonomous mining systems. This paper describes artificial intelligence (AI) and sensor fusion based sensor data analysis techniques developed over the past four years. These techniques were used to classify machine operating events by continuously monitoring machine power usage in a continuous miner section at an under- ground coal mine. The result is a report similar to an industrial engineering time study. First, numerical pattern classification techniques broadly identify operating events. However, domain knowledge about inter-machine and intra-machine interactions is necessary to identify and refine dynamic event boundaries. By implementing AI and sensor fusion based techniques we are able to classify machine events more accurately and recognize more specific events. These techniques could easily be applied to many different mining sensor data applications

Jan 1, 1993

By W. L. Dalke

The Minntac complex is a facility for production of iron ore pellets located on the Mesabi Range at mountain iron, Minnesota. It consists basically of a mine, crushing plant, concentrator, and a pelletizer producing twelve and one-half million tons of pellets annually. This paper deals with some of the aspects of the grinding circuits; but prior to that discussion, it might be well to briefly describe the flow of material in the operation. The crude ore, containing from 20% to 25% magnetic iron, is mined by 14-yard electric shovels. .the blasted ore is loaded directly into 50-yard side dump railroad cars and hauled to the crushing plant. Crushing is done in three stages, originally, two 60" primary crushers; four 7-foot standard secondary crushers; and six 7-foot short head tertiary crushers were installed, when the plant was expanded to double its capacity, five secondary and ten tertiary crushers were added. These were duplicates of the original 7-foot standard and short head crushers used in the original construction, there was no expansion of the primary crushers but a one-half-million-ton surge pile of tertiary crusher feed was added.

Jan 1, 1976

By A. V. Castelli

Since the record year of 1981 through 1985 the tonnage of weighting materials (barite and other heavy minerals) used in drilling fluids has decreased an estimated 49%. As in the past, barite still makes up over 90% of the minerals used for weighting materials in drilling fluid. Domestic production of barite has decreased 69% since 1981 and imported barite has made up over 50% of the total barite consumed since 1982. See Figure 1 for usage of barite. The number of operating grinding plants has decreased from 69 in 1982 to 39 at the end of 1985. With the decrease in demand of weighting materials for drilling fluids and an over capacity of grinding existing, prices for weighting materials have decreased dramatically. Although the American Petroleum Institute has not changed any of the specifications for barite, some users have initiated their own new specifications and have proposed to have them included in the API specifications. The exploration for and development of oil and gas dictates the level of weighting material used in the drilling fluids industry. Most forecasters do not foresee (or predict) increases in the level of drilling until the 90's. The primary or unground barite produced in the U.S. mines has a difficult time competing with imported barite due to the location of the mines. These mines are located in North Central Nevada, with small tonnages being produced in California, Missouri, Illinois, Montana and Washington. The major reason, is the difference in transportation costs from the mines versus ocean freight rates from the foreign ports to the major area of use, the U.S. Gulf. Since 1981, the production of primary barite has decreased from 2,849,000/ST (2,584,596/MT) in 1981 to an estimated 890,000/ ST (807,403/MT) in 1985(1). If it were not for the use of unit trains by some producers the production of primary barite in the U.S. would have probably declined another 20% in 1985. During the same period, of the total amount of barite consumed in the U.S., imported barite ore increased from 417, in 1981 to 65% in 1985. The major exporting countries to the U.S. during this period were China 46.27, Morocco 15.27., Chile 10%, Peru 8.4%, India 7.9%, Mexico 5.4%, Thailand 3.9% and Ireland 2.3%.

Jan 1, 1986

By M. R. Yenchek

Faulty insulators on mine trolley/track haulageways may allow the flow of leakage currents into the mine roof and ultimately result in combustion of the local roof material. The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory (PRL), has devised a passive means to detect overheating insulators on direct current systems. The detector consists of a spring-loaded cartridge that ejects a reflective streamer of white Teflon tape when subjected to elevated temperatures. The cartridge assembly can be easily installed over the outer metallic shell of an existing trolley line insulator. If an insulator overheats due to ground leakage currents, the visible streamer alerts mine personnel traveling on the haulageway.

Jan 1, 1998

By David J. Dunn

Mill liner design is an important factor in grinding. Testing and selection of the optimum liner profile for a given set of mill operating conditions can improve mill capacity, liner life, and liner wear rate At a time when mill avilability is at a premium, production costs are going up, and lead time for mill liner castings is a year or more, the mill liner that grinds best, lasts longest, and costs least is a necessity for economic mill operation. In testing four mill liner profiles for 13' x 12' overflow ball mills, Climax found that an improved design increased mill tonnage by 3 tons per hour while reducing finish grind by 1.7% + 100 mesh, reduced liner wear rate, and almost doubled liner life.

Jan 1, 1976

By N. Gritzuk

The area of Canada with which we are here concerned consists of Yukon Territory and Northern British Columbia. Generally it lies west of the coastal mountain range and access to the sea can be gained at only selected points which are relatively few. It is served by the Alaska Highway as well as a provincial and territorial system of roads permitting transport of mining products to Whitehorse in Yukon Territory. This town it the northern terminus of the White Pass and Yukon Route, which system provides a rail service between Whitehorse and Skagway, Alaska a distance of 110 miles, and thence to Vancouver, British Columbia, by the coastal Motor Vessel C. J. Rogers, a distance of an additional 890 miles. At present the service between Vancouver, B.C. and Whitehorse, Y. T. is on a fourteen day basis. The coastal vessel, capable of carrying 3,200 tons of cargo, was specially designed and built in 1955 for handling containerized cargo and general cargo northbound, and containerized and palletized asbestos fibre, and palletized lead and zinc concentrates southbound.

Jan 1, 1961

By A. J. Richardson

Before the development of the underground stoping and mining costs can be considered, certain facts about the ore body, the proposed mine, markets, etc., must be known or determined. In the case to be studied, the zinc-lead mineralization occurred with a narrow vertically dipping structure of undetermined length and vertical extent. Exploration completed to date has revealed 6.5 mil¬lion st t of proven reserves. A further 820,000 st of in¬dicated reserves has been outlined and this tonnage is considered capable of being expanded by a factor of approximately four after more detailed drilling. After studying the market conditions and completing a very preliminary feasibility study, it was decided that production would be 730,000 stpy (or 2000 stpd) of ore. First year production would be at the rate of 1500 stpd. The main design criteria for the selection of the min¬ing methods are minimizing surface subsidence, maxi¬mum recovery of the ore body, maximum degree of grade control, maximum productivity, and safe working conditions. Two basic extraction systems are considered capable of meeting these requirements: mechanized cut¬and-fill stoping and sublevel long-hole stoping with filling. The primary development system of the mine has been designed to give maximum flexibility in stoping systems and layout and to permit changes if considered necessary as a consequence of actual production ex¬perience. At the present time, access to the mine is by a circu¬lar concrete lined vertical shaft, 16 ft diam, sunk to a depth of 1380 ft. Two exploration levels have been driven within the ore zone at depths of 165 and 1246 ft below the surface outcrop. The development to date had the objective of sampling the mineralization and produc¬ing detailed information on the outline of the ore body and the distribution and controls of zinc and lead values. In an attempt to satisfy the basic design criteria for the mine, it was decided that production would be best achieved by a combination of 40% sublevel long-hole stoping and 60% cut-and-fill mining. Costs of exploration and capital development of per¬manent underground facilities are normally written off over the life of a mine. Production expenditures, on the other hand, are of a temporary nature and are normally charged as and when incurred as an operating expense. Reasonably accurate predictions of mine production costs can be built up from engineering design and estimates of individual mine activities for ultimate inclusion in the comprehen¬sive data required for financial decision making. The simulated operations can be costed on a detailed basis in the form of a monthly operating budget. The budget format can be generalized or detailed, depending upon the scope of the project. However, ex¬perience suggests that a fairly detailed format has the advantage of assuring that all significant cost items are included. For underground costing it is suggested that the budget structure include five major cost centers (i.e. development, diamond drilling, ore extraction, hoisting/ transportation, and general mine expense). These in turn are detailed under numerous subheadings. The mechanism for compiling an operating budget will be illustrated. Because of its relative simplicity, ore extraction under sublevel long-hole stoping has been chosen for illustration. All other activities, simple or complex, can be estimated in similar fashion. BLOCK AND STOPE DEVELOPMENT Long-hole blocks, used where advantageous, will be up to 250 ft in height, depending upon the vertical con¬tinuity of the mineralization, and approximately 300 ft long. Drawpoints will be at 36-ft intervals and serviced by loading crosscuts driven from a footwall drift parallel to and close to the ore zone. Pillars between the stopes will be 50 ft wide. Stopes will be drilled off with vertical rings of blastholes drilled from sublevels approximately 60 ft apart vertically. This drilling will be done by percussion drilling machines (31/2 in.) mounted on a trackless drilling rig. Load¬haul-dump (LHD) equipment will be used to move broken ore from the drawpoints to the orepass connecting to rail haulage systems. On completion, long-hole stopes will be backfilled to prevent caving and to facili¬tate later pillar removal. From a planned stope layout, a forecast of produc¬tion and development is made in Table 1. Table 1. Block Tonnage and Stope Development Quantity Ore Waste Total ore block 375,000 st 2 stopes 310,000 st 1 pillar 65,000 st Access crosscuts, 4 at 100 ft 400 ft Drill sublevel drifts, 6 at 300 ft 1800 ft Stope raises, 3 at 250 ft 750 ft Undercut sublevel drifts, 2 at 300 ft 600 ft Loadout crosscuts at 35-ft intervals 550 ft 100 ft 3300 ft 500 ft Total development footage 3800 ft Tons per ft of development 987 st

Jan 1, 1982

By Harry R. Dahlberg

Heap leaching is discussed as a unit process. Five factors are identified as the principal elements that can be measured and/or controlled. These are: 1. Material Size 2. Volume of solution 3. Tonnage of heap 4. Time 5. Solution concentretion. The Rate of Extraction Curves obtained from an actual heap or column tests describes the economic viability of the unit process. By analysis of these curves and the five factors end their inter-relationship it is possible to determine how the extraction rate can be increased. The practice of leach and rest used by many operators is analyzed and shown on a hypothetical rate of extraction curve. The influence of the driving force of the hydrogen ion and ferric Lon as Lixivants and its effect on the rate of extraction curve is discussed.

Jan 1, 1979

By Shane Yanagisawa

The Mineral Creek Diversion Project is at the Asarco Ray Mine Complex, about128 km (80 miles) east of Phoenix, Arizona. The new tunnel will intercept the waters of Mineral Creek about 2,134 m (7,000 ft) upstream from an existing tunnel. The 5.74 m(18.83 ft) hard rock TBM will break into the old tunnel about 2,162 m (7,090 ft) in from the old portal after mining 3,888 m (12,753 ft). The TBM will mine through a series of igneous and metamorphic formations including volcanic tuff, soft volcanic ash, massive diabase, fractured quartzite, and schist. The TBM will hole through into the existing 4.88 m (16 ft) dia. horseshoe tunnel where the TBM will be disassembled and removed from the tunnel.

Jan 1, 2001

By C. S. Boland

The Copper Range Company's mining properties are located in the Upper Penisula of Michigan. (Fig.). Early work indicated the presence of copper ore in a bedded deposit, confined to the base of the Upper Keweenawan Nonesuch shale, and exploitation of this deposit on a portion of the Company's property was undertaken by White Pine Copper Company. Diamond drilling of the White Pine orebody indicated that a major fault pattern terminated the values to the South-west. Further drilling Southwest of the fault zone proved a downward displacement of the ore bearing horizon some 1,500 feet and a lateral displacement of approximately 4,000 feet; and in this area an ore deposit was outlined in a large asymmetrical syncline locally plunging to the South-west. (Figs. 2 and 3)

Jan 1, 1962

A linear programming model with integer sequencing variables is developed to schedule limestone production for a quarry in Central Japan. The model is used to optimize raw material production from the quarry supplying limestone to cement, quick lime and aggregate plants. Typically, the mining in the quarry takes place in four to six different areas each area having 3 or 4 mining increments. Each mining increment contains different quality of limestone. The limestone production from the quarry is transported to the plants byway of 3 ore passes. Each plant requires a given quantity of limestone per period meeting certain quality constraints. This paper will describe development of the scheduling optimization model and how it is used to schedule production by period within the quarry to meet the capacity and blending requirements of the plants.

Jan 1, 2003

By G. E. Jones, G. K. Hoffman

Two Sun Juan Basin studies were completed through the USGS National Coal Availability program. The study areas are in the northwest Bisti field (Fruitland Formation) and in the eastern Standing Rock field (Menefee Formation). In the Bisti and Standing Rock areas, the original coal resource5 are estimated at 4.66 and 3.1 7 Gt (5.14 and 3.49 billion st), respectively. The Bisti coal resources are greatly reduced by the Bisti-De-Nu- Zin wilderness area, which contains an estimated 1.13 Gt (1.25 billion st) of coal. Technological restrictions remove 32.5% from Standing Rock's original resource. Available resources are 60%. 2.79 Gt (3.07 billion st), of the Bisti original resource and 65%, 2.07 Gt (2.28 billion st), of the original Standing Rock resource.

Jan 1, 2002

By Ö. Y. Gulsoy, L. Ergün, I. B. Celik

"In this study, the studies to develop a flowsheet for a low grade chromite ore are presented. The existing concentrator had to be suspended due to the decreasing metal prices. The study commenced with mineralogy and liberation profile of the chromite. The valuable mineral is chromite and the major gangue mineral is forsterite together with small amount of brucite and calcite. Heavy liquid tests were performed on different size fractions without any acceptable success. The concentration tests were performed using teetered bed separator (TBS) +shaking table, spiral concentrator+TBS+shaking table for different grind size. Based on the test results, 100% finer than 0.4mm was found to be optimum for grind size. Comparison of alternative circuits showed that the performance of both alternatives would be similar. A flowsheet was designed and operated for as 25 tph trial circuit in the existing plant. The results showed that the performance of the plant predicted was very close to the actual plant data. The paper describes the methodology used, presents the experimental data and actual performance figures.INTRODUCTION Turkey is one of the largest chromite producers in the world. Since 1850, chromite mining found industrial applications and geographically spread along six different regions in Turkey. Although the reserves in these locations are not as rich as the big producers, they are regarded as very valuable due to Cr/Fe ratio in terms of chromite utilization standards (1, 2). In this period, significant portion of high grade (=35% Cr2O3), directly marketable ore deposits have already been produced. According to General Directorate of Mineral Research and Exploration (Turkey) data; 83% of the known chromite deposits of Turkey which makes 242 341 000 tons in total, is consisting from the deposits those have a Cr2O3 grade lower than 10%. Only 5% of the known deposits (13 087 000 tons) has a grade of directly saleable (2, 3). Gravity concentration methods are well-known processes for chromite beneficiation and there are plenty of plants in the world and Turkey using these methods. As different equipment combinations can be used for the same enrichment method, different methods can also be used in combination for plant designs (4). Beneficiation of low grade and problematic chromite ores may lead to use these method and equipment combinations (5, 6). Ore liberation, the grades of Al2O3, SiO2, FeO and Cr2O3 in the obtained concentrate, Cr/Fe ratio, some physical and chemical properties between gangue and minerals (i.e. specific gravity, magnetic property, color, etc.) designate the selection and combination of these methods and equipment (7)."

Jan 1, 2017

By M. P. Neira

In-situ leaching of copper from chalcocite relies on ferric iron concentration in the lixiviant being reduced to ferrous. To re-establish the ferric concentration in solution, ferrous must be re-oxidized. This reaction is slow under normal chemical conditions but it is catalyzed by Thiobacillus ferrooxidans bacteria. BHP Copper's Miami In-situ unit developed a bio-reactor as a method of oxidizing ferrous to ferric. The effects on oxidation of temperature, CO2? oxygen, and air injection flowrate were defined. This paper summarizes the results of ferrous bio-oxidation using plastic column packing and oxide ores as bio-reactors and the leaching results of the bio-reacted lixiviant on chalcocite ores.

Jan 1, 1997

By F. M. Doyle, Jiang Tao, Xu Shi, Chen Jin, E. Peters

Tafel curve technique and leaching tests have been applied to study the kinetics of gold leaching with thiosulfate. Results show that cupric ions and ammonia play the part of catalysts in the leaching of gold with thiosulfate. The activation energy of gold dissolution is calculated as 27.99 KJ/mol in the absence of both cupric ions and ammonia. However, the energy is reduced to 15.54 KJ/mol in a solution of 0.01 mol/L Cu (NH3)2 4* and 0. 5moVL total ammonia. The reaction order of Cu (NH,) g is one in the range of 0.001~0.1mol/L. These results support the electrochemical-catalytic mechanism pro- posed by the authors and explains the behavior of cupric ion and ammonia (Jiang Tao, et al., 1993)

Jan 1, 1993