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By J. E. Murphy, R. Y. Wan, K. R. Sandgren, M. C. Fuerstenau

As part of a U.S. Bureau of Mines program to evaluate alternatives to sodium cyanide in gold leaching, three organic nitrile compounds were tested for their effectiveness as gold lixiviante. The organic compounds examined were malononitrile, acetonitrile, and cyanoacetamide. The reagents were tested on an oxide ore, two carbonaceous ores, and a eulfidic ore. Acetonitrile and cyanoacetamide were shown to be ineffective gold leachante. Malononitrile was the most successful of the organic lixiviants. On an oxide ore, malononitrile performed shilarlyto sodium cyanide with extractions of around 80 pct. For carbonaceous "preg-robbing" oree, sodium cyanide was completely ineffective while malononitrile extracted 24 pct of the gold. When using a resin-in-leach technique, extraction with sodium cyanide increased to 60 pct and the extraction with malononitrile increased to 80 pct. On the sulfide ore, sodium cyanide and malononitrile performed similarly with 80+ pct extraction as long as the pH of the malononitrile solution wae maintained above 10.5. Malononitrile is six times less toxic than sodium cyanide as measured by LD, levels. Therefore, malononitrile has a significant advantage over eodium cyanide, but its high cost and undemonstrated usefulnees make it unlikely to gain acceptance.

Jan 1, 1993

By R. E. Muller, L. G. Martin, J. M. Stonehouse

Erratic distribution of values in free gold ore bodies presents severe problems in sorting material in large scale open pit mining. However, an intense program of modern blasting techniques and less than modern gold panning results in good sorting at Houston International's Manhattan mine. Blasting technique is important. If the sample location cannot be relocated because of blasted material movement, information acquired while drilling is useless. So short benches are critical to minimize dilution. Though not very accurate, panning allows for rapid analysis. The more accurate fire assay does not provide the needed speed. Panning can be fairly accurate and errors made are mostly on the low side. Samples of mixed and broken stockpile material are used as checks on pit procedure and to develop stockpile content in¬formation. Added tonnages discovered offset the higher labor costs of this careful sorting technique. The mine is located in central Nevada's Toquima Range in the small mining town of Manhattan, 322 km north of Las Vegas. The mine has four epithermal stockwork ore bodies that are mined in two pits. The mine problem was that conventional ore control was not separating ore from waste. Assays of 6-m blast-holes were used on 5-m centers. The blastholes were relocated by stadia survey after blasting. Holes assaying above the cutoff grade were flagged and mined as ore. This system is practical and useful in high concentration ore bodies or in evenly disseminated mineralization. But it was not practical at Manhattan because of large gold particles and small ore pocket sizes. Ore pockets were often missed when drilling a grid area for blasting. Also, large gold nuggets made assay results unreliable. The probability of a nugget being contained in an assay charge is small. So most results were low, compared to actual grades mined based on stockpile samples. When a nugget found its way into a fire assay charge, the result would be far higher than the actual grade of material represented. In addition, disturbance by blasting created problems in relocating ore. Because of these problems, the grade control program was intensified in September 1979. It successfully separated ore and waste in blocked out ore areas and located more ore in "waste" areas. Known reserves mined to date have increased up to 50% on some benches. The methods used are modern blasting techniques, detailed assaying, and traditional panning of samples collected from active mining faces. These methods allow mining flexibility, to match the variable mineral occurrence in ore bodies. The united effort of the geology and engineering departments has been important to the program's success.

Jan 12, 1980

By Richard L. Ash

Less than optimum production in mining always results when poorly blasted material is provided at loading points. More often than not the cause is due to blasting founds that fail to fully control and utilize explosive energy. In many cases the problem exists because too few blasters understand how blastholes actually break rock and recognize that blasting is a three-dimensional process in designing their blasts. To better understand how blasts can be more effectively designed the two major rock breakage processes are described. In addition, the respective contributions of the borehole and detonation pressures are defined as are the specific roles of the several important blasting design variables. The concept of stiffness as an engineering principle and its significance in blasting design is introduced for explaining the breakup of rock. Basic guidelines for affecting control over fragmentation and side effects like over-break are offered.

Jan 1, 1975

By Shawn Benner, David Blowes, Carol Ptacek

A full-scale reactive barrier was installed into an aquifer impacted by acid mine drainage in August 1995 at the Nickel Rim mine site near Sudbury, Ontario. The primary mechanism of water quality improvement is bacterially mediated sulfate reduction and metal sulfide precipitation. Dramatic changes in the groundwater chemistry are observed with up to 90% decline in Fe (from >18 to <2 mmol L-1) and increases in alkalinity from <1 to >10 mmol L-1 (as CaCO3). Over a 3 year period, the rate of Fe removal declines by approximately 35%. Primary controls on barrier performance are organic carbon reactivity, groundwater temperature, and variable residence time within the barrier.

Jan 1, 2000

By Claude A. Chapallaz, Dominique L. Butty

Bauxite is derived by surficial weathering of aluminosilicate rock forming minerals under warm and humid climatic conditions. Variations in climate combined with base level changes promote cyclical, evolutionary weathering/concentration patterns, the residual products of which are closely controlled by biological activity. Rock decomposition results mainly from hydrolysis, chelation and solution, the effects being (a) removal of bases and silica in dilute solution, (b) depletion of iron in areas where low pH-Eh prevail and, (c) concentration through direct precipitation, or more generally via intermediate amorphous phases, of aluminium hydrates in variable associations with iron hydrates and clay minerals. Bauxites can be regarded as aluminous soils, and as such they result from cyclic or polygenetic pedogenesis. The ferralitic pedological evolution is essential for bauxite formation. Under some specific conditions, related to local climate and parent rock composition, the podsolic- or andosolic-type of pedogenesis is an effective precursor to bauxitization.

Jan 1, 1984

By Ron L. Schmiermund

The Ferris-Haggarty underground mine was abandoned circa 1910, and portal discharge has since resulted in degradation of a trout fishery in the receiving waters of Haggarty Creek. Although tunnel discharge varies dramatically in volume throughout the year due to infiltration of snowmelt, compositionally it is a nearly constant low-TDS, pH-neutral, low-sulfate, copper-silicate dominated water. Between infiltration events, components of ARD accumulate in unsaturated, oxygenated environments within upper workings and are delivered to the main haulage level by the subsequent annual snowmelt flush. Mixing with non-ARD mine waters results in neutralization, dilution, and precipitation of amorphous copper carbonate and silicate phases. These mechanisms, combined with variations in the water balance, control the composition of the portal discharge. Understanding the chemical and hydrologic control mechanisms was critical to the design of a passive treatment system to decrease effluent copper concentrations.

Jan 1, 2000

By Paul A. Gerding

PURPOSE: Presentation to Society of Mining Engineers, Technical Session, Wednesday, February 19, 1958 - 2:00 P.M. General Industral Minerals - Penn Top South The silica industry is relatively small and in general is made up of small plants located near the consumer. In the United States there are approximately 155 established operating plants located in 37 states, extending from coast to coast. Silica, in varying degrees of chemical purity, enjoys a very diversified market. Silica is the basic ingredient of glass, bothcontainer and flat glass, and is used for grinding and polishing of flat glass up to the final polishing stages where rouge is generally used. Silica is used for foundry molds and cores, sandblasting, stone cutting, refractories, placing sand in furances, glass coatings and linings, laboratory glassware, construction, oil well fracturing for increased oil flow, filtering purposes, silicate of soda, silicon carbide, and others.

Jan 1, 1958

By Joseph Fernandez, Luminita Calin

INTRODUCTION The Tunnel and Reservoir Plan (TARP), commonly known as the Deep Tunnel Project, is the daring and unique concept developed by the Metropolitan Water Reclamation District of Greater Chicago (MWRDGC) as a two-phase solution to the problem of waterway pollution and basement flooding due to sewer system backups created by the combined sewer over-flows (CSOs). Phase I, primarily for pollution control, includes the tunnels, shafts, connecting sewers and structures. These Phase I facilities intercept, during wet weather events, the CSOs within the MWRDGC TARP service area. The tunnels and shafts provide temporary storage of the CSOs for subsequent treatment at Water Reclamation Plants (WRP) before discharging into waterways. Ultimately, upon completion of Phase II, the tunnels, located from 45 m(150 ft) to 100 m (330 ft) below ground, will convey the CSOs to reservoirs for storage until WRP capacity is available. Phase II, which includes the reservoirs, pumping facilities, additional tunnels and shafts, has been planned to serve a dual purpose. The reservoirs provide storage of excess flows during wet weather events, those beyond the WRP capacity. Following the wet weather events, the stored flows can be conveyed, at controlled rates, to the WRPs for full treatment. These excess flows previously would have resulted in both overflows into the waterways and eventually backups in the local sewer systems. The storage capacity of the reservoirs also will promote the full utilization of the conveyance capacity of the tunnels and shafts, which in turn results in optimizing the conveyance capacity of the existing sewer systems. Therefore pollution control is further enhanced by allowing for capture of a greater volume of CSOs and greatly minimizing backups in the local sewer systems. The TARP project consists of four systems: O’Hare, Mainstream, Des Plaines, and Calumet, covering a total area of 971 km2 (375 mi2) and serving the City of Chicago and 51neighboring communities as shown in Figure1. With only two contracts left before completion of the Phase I tunnels, the 12.7km (7.9mi) Torrence Avenue leg, to be awarded in 1997, and the 12.4km (7.7mi) Little Calumet leg unfunded as of yet, both part of the Calumet System, the pollution control phase of the project is now 86% complete (Table 1).

Jan 1, 1997

By Peter P. Harvey

The Nonel Primadet is a non-electric blasting initiation device. The system incorporates the safety advantages of a cap and fuse system with the precision blasting afforded by electrical blasting caps. Each unit is made up of a delay blasting cap factory-crimped to a Nonel® shock tube lead line. The delay elements in the blasting caps are manufactured in both millisecond and long period series. There are 16 periods available in both series - period 0 through period 15. The units are manufactured in 12&apos;, 16&apos;, and 20&apos; lead lengths. The hollow shock tube is made of surlyn plastic and it is coated on the inside with a reactive material. The powder train has a density of only 1/10 grain per linear foot of tube. A typical blast round is timed precisely the same way it would be with electrical caps. After the round has been timed and loaded, the tube leads are gathered in convenient bunches and tied into a detonating cord trunkline. The Nonel® tube bunches are initiated by the output of an 18 grain per foot detonating cord trunkline. Once initiated, the Nonel® shock tube will reliably propagate at 1800 meters per second. The energy from this shock front initiates the delay elements in each delay cap. The shock tube is inert to electrical energies, including; stray current from AC/DC power sources, as well as, electrostatic discharges. The tube is also inert to initiation by impact. The system has proven to be particularly advantageous in both tunnel and shaft blasting applications. The major advantages in using the Nonel® system in this type of work are: 1) faster and easier tie-in techniques through the use of bunch-blasting. 2) electrical power can be left on during loading and tying-in. a. electrical lights can be turned on at the working face - better lighting facilitates loading and tying-in. b. electrical pumps can continue to function throughout loading and priming procedures (this is particularly advantageous in shaft work with water problems). 3) down-time due to approaching electrical storms is minimized. 4) increased overall efficiency in the blasting cycle: a. it is easier to train a man in the proper use of the system. b. fewer missed holes per round. c. less time required for tie-in. 5) safety-advantage--The system is not susceptible to involuntary initiation from extraneous electrical energies.

Jan 1, 1979

By K. N. Han

The leaching behavior of palladium in ammoniacal solutions was investigated by using the rotating-disk technique in an autoclave. The study included the effects of rotation speed, temperature, oxygen pressure, composition of ammoniacal solutions and catalysts on the overall leaching rate. The dissolution of palladium in ammoniacal solutions was discussed in terms of the thermodynamics and a kinetic model. Even though the Eh-pH diagram suggests that palladium metal can dissolve in ammoniacal solutions at room temperature, it was found that the dissolution was very slow at temperatures below 100 °C but was significantly improved at higher temperatures. It was also found that the rotating speed of the palladium disk had no effect on the leaching rate. The apparent activation energy was found to he 69.7 kJ/mole. Based on the results obtained, it was concluded that the dissolution of palladium is controlled by chemical reaction.

Jan 1, 1999

By F. M. Doyle, P. E. Richardson, E. Peters

A number of studies have attempted to correlate the semiconducting properties of mineral sulfides with their chemical reactivity. Frequently such studies are conducted on polished or abraded electrodes. Defects produced by abrasion may mask the influence of the semiconducting properties of electrodes, e.g., by pinning the Fermi level at the surface or by reducing the lifetimes of photogenerated charge carriers. It is shown that pyrite and galena electrodes have photocurrents that are extremely sensitive to abrasion of the electrodes. On freshly fractured galena surfaces, the space charge layer is readily polarized. Wet-abrasion is shown to produce a relatively thick ptype layer on galena electrodes and this p-type layer has a pronounced effect on the photoresponse. On freshly fractured pyrite surfaces, the Fermi level at the surface is pinned by a surface state. Wet-polishing reduces the magnitude of the photocurrent by over an order of magnitude.

Jan 1, 1993

By John Chapman, Daryl Hockley, Michael Paul, Silvia Jahn

As part of the waste characterisation program to address site reclamation, WISMUT GmbH initiated 56 columns operated as large-scale humidity cell tests. The columns were initiated to assess the acid generation characteristics of waste rock from 14 waste rock piles distributed around the site. Of the 56 tests, 11 are ongoing and have been operational in excess of 160 weeks. The results to date from these long-term tests are surnrnarised. In particular, the methods for, and importance of, establishing the availability of the carbonate neutralisation potential and acid generation potential respectively, are discussed. Geochemical controls on uranium, and the conformity between the geochemical models MINTEQA2 and EQ3/6 in assessing these controls are discussed. Testing indicates that waste rock with an MS-NP:AP ratio in excess of about 2.7 should result in net neutral pH conditions.

Jan 1, 2000

By D. J. Simbi, T. R. C. Fernandes, M. Nyamhunga

The recovery of P2O5 from a 90-95% minus 45 microns phosphate slimes sample was carried out in a 5.08-cm internal diameter and 549-cm high flotation column cell. The influence of the feed rate, feed percent (%) solids, and frother dosage on the recovery was investigated following a truncated cubic 3 level by 3 variables experimental design. Two three-variable interactions of feed rate (-l)/feed percent solids (+l)/frother dosage (-1) and feed rate (-l)/feed percent solids (-1)/ frother dosage (+I) gave the region of optimum column performance: recovery (52.60-74.50%), mass yield (15.68-18.80%), and concentrate grade (22.87-31.2196). The collector dosage also showed a significant influence on the column performance. The high reagent consumption relative to the current plant levels points to the need for the removal of ultrafine particles (<10 µm).

Jan 1, 1999

By Fathi Habashi

THE MOST important arsenic minerals are shown in Table 6-1. The recovery of arsenic from arsenic sulfides is treated in Chapter Four. Arsenical ores may be either leached directly, or first smelted to volatilize as much arsenic and sulfur as possible, and the resulting product, called speiss, is then leached. A speiss is mainly a complex mixture of metal arsenides, but its [Table 6-1. Arsenic minerals. Arsenides Niccolite NiS Smaltite CoAs2 Skutterudite CoAs3 Sulfarsenides Cobaltite CoAsS Enargite CuaAsS4 Arsenopyrite FeAsS Arsenic sulfides Realgar As4S4 Orpiment As2S3] composition varies widely, depending on the type of ore treated. A speiss usually contains 15-35% arsenic. Methods of leaching are describedd in the following paragraphs.

Jan 1, 1970

By Silvia H. M. Grimaldi, Afonso H. Martins

The scope of this experimental work was to study the yttrium extraction and stripping behaviour in a solvent extraction system with mono(2-ethylhexyl)2-ethylhexylphosphonic acid (IONQUEST 801) in a chloride system The study was performed for only one contact between organic and aqueous phases The experiments were carried out according to a factorial design. Due to the statistical analysis and its experimental proof, the optimum conditions for maximum yttrium loading into the organic phase of the extraction stage were 16 minutes for time of contact between phases, 980 rpm of stirring intensity and pH=2.3 for the aqueous phase of the sovent extraction system. The optimized experimental conditions by the statistical approach for the stripping stage were: time of contact between phases equal to 20 minutes, 1050 rpm of stirring intensity and 1.75 M HCI into the stripping aqueous solution.

Jan 1, 1995

By J. Cassells, N. Chrisman, R. Arnold, P. Rusin, L. Quintana

Toxic substances in On solutions can retard biological leaching of sulfide dump ores. On solutions were ana1yzed for metals, organics and chloride and showed inhibitory concentrations of aluminum, manganese and chloride. Inhibition of bacterial activity by the solid fraction of On solution with and without the organic constituents, was evaluated. Bacterial toxicity was evaluated by monitoring bacterial numbers, pH, Eh, and rates of iron oxidation. The On solution solids were toxic at 50% to 60% of their field concentration. Most of the toxicity of the On solution was due to the organic fraction. Different solvent extraction (SX) reagents show varying degrees of inhibition of T. ferrooxidans. Bacterial inhibitory effects of carriers and lixiviants used in the SX plant should be determined so that entrained SX reagents do not retard biological dump leach systems. The reagents used should be the most cost-effective and the least toxic.

Jan 1, 1996

By J. A. Pagliero, R. T. Quiroz, S. H. Castro

Selected voltammograms in tetraborate buffer solutions in the presence of ethyl xanthate or isopropyl xanthate at pH 9.3, for chalcocite, covellite, chalcopyrite, and enargite mineral electrodes, are presented. The concept of critical Eh of dixanthogen condensation (Ehc) is introduced, and the line of Ehc is thermodynamically defined in plots of log [X i] vs Eh, for methyl, ethyl, propyl, and butyl xanthates. A reaction scheme of xanthate oxidation in four steps, involving the dixanthogen condensation step, is proposed. A first attempt to interpret mineral flotation from a more general point of view is made. The electrochemical mechanism of dixanthogen formation and condensation is considered as a particular case of a more general and relevant phenomenon, which is the decomposition of the collector giving hydrophobic colloidal forms, whose associative behavior in bulk solution and at the mineral/solution interface is governed by colloid chemistry.

Jan 1, 1989

By Daniel R. Hack

Mine planning software companies have recently focused some resources on the development of industrial minerals packages useful in the aggregate industry, which is years behind other mining industry sectors in the use of computer-based planning techniques. This paper presents and compares characteristics of aggregate / quarrying software packages currently on the market, each product having strengths beneficial under different circumstances. To be successful, the developers must confront the limitations of their packages under a variety of situations, address the unique characteristics of the aggregate industry, and pay particular attention to the applicability of their products in real situations.

Jan 1, 2002

By Ron Allum, Ed VanDerPas

The application of high speed tunneling in a deep underground copper mine is essential for an ambitious expansion project at Magma Copper Company&apos;s San Manuel Mine. At stake is the future of over 1,300 employees at the largest producing full gravity block caving copper mine in the world. A joint venture of Frontier-Kemper Constructor&apos;s Inc. and Deilmann Haniel GmbH is helping create that future through the successful application of tunnel boring technology. This paper examines the details required to assemble, deploy and operate a 4.62 m open main beam tunnel boring machine (TBM) in a 1048 m deep operating mine accessible only by shaft.

Jan 1, 1995

By B. D. Shah, H. S. Soto

Lack of selectivity in mixed mineral flocculation can be attributed to one or more of the following factors: dissolved ion interference, hetero- coagulation, mechanical entrapment in flocs, and entrainment of fines between flocs. In a study of the apatite-dolomite system, it was determined that dissolved ions do not have a significant effect on selectivity. Heterocoagulation was minimized by choosing proper process conditions and addition of a dispersant. Mechanical entrapment was proved to be insignificant and efforts were made to reduce entrainment by choosing an appropriate method of separation of flocs from fines. A new factor termed "polymer induced entrapment," which occurs due to limited affinity of the polymer to the mineral that is not flocculated, is postulated to be the cause for the loss of selectivity.

Jan 1, 1988