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By William J. McCloy, Robert L. Gamble

A coal-fired fluidized bed steam generator rated at 12.6 kg/s has demonstrated the industrial and institutional application of fluidized bed combustion by burning high sulfur coal in an environmentally acceptable manner within a populated area. Designed to provide steam for heating and cooling, the unit was placed into service at Georgetown University in Washington, DC, and has already logged 5275 hours.* The unit has consistently operated well within Washington's strict regulations governing emissions of sulfur dioxide (SO2), nitrogen oxides (NOx), and particulates. The Georgetown program, cofunded by the university and the US Department of Energy, has shown that fluidized bed combustion is a promising way to realize the full potential of coal, the nation's most abundant energy resource. In a fluidized bed steam generator, a layer of granular limestone is placed on top of a grid designed to prevent particles from falling through. Air is passed upward through the bed with sufficient force to lift and float the particles. At this point the bed material resembles a boiling liquid. Crushed coal is then introduced into the bed and ignited. When high sulfur coal is burned, limestone absorbs the SO2 produced. The operating temperature of a fluidized bed steam generator is relatively low (approximately 871°C). As a result, NO, formation is minimal. Another potential problem encountered in burning coal is fly ash, a form of particulate. A feature of the fluidized bed design, developed by Foster Wheeler Energy Corp., is a fly ash reinjection system. Fly ash is reintroduced into the bed where it is burned again, thereby enhancing fuel efficiency. Nearly all remaining fly ash is captured by a baghouse dust collector. At Georgetown, the fluidized bed steam generator and all auxiliary equipment are enclosed in a structure aesthetically compatible with the surrounding university complex. The steam generator has two separate beds that can be fired independently, and operation to date has been with one and two beds in service, based on steam load demand. During several operating periods, when the fluidized bed unit was the only boiler in service, it supplied all the steam required by the 18.5 hm2 of buildings on campus. Initially fired with low sulfur coal, the unit was quickly switched over to higher sulfur fuel which will be used most of the time.

Jan 3, 1981

By Kenneth N. Han, Yuhong Chen

The removal of carbonaceous material from Carlin gold ore has been investigated via froth flotation. The effect of type and concentration of various oils as flotation collectors and of sodium silicate as the dispersion agent on the overall recovery of carbonaceous material has been studied. Other variables affecting froth flotation efficiency were also examined closely. These included particle size, pH of the solution, and temperature. The effect of reduction and oxidation of carbonaceous material on froth flotation efficiency has also been investigated. This investigation showed that aromatic type oil was the most effective collector. Also found in this investigation was that oxidized carbonaceous material was difficult to float unless the oxidized portion was subject to reduction before flotation. More than fifty percent of the carbonaceous material was able to be removed via froth flotation. It can be concluded from this study that the effect of pH and temperature during the rougher flotation state is of little significance to the overall recovery of carbonaceous material. Since pyrite is responsible for the high consumption of chlorine, removal of pyrite is very important in order to reduce the overall consumption of chlorine.

Jan 1, 1990

By S. Chander

A comparison of gold, platinum and sulfide ion selective electrodes was made for determination of Eh in solutions containing hydrosulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. The sensitivity of each electrode towards changes in hydrosulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of hydrosulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1992

By A. S. Ibrado, D. W. Fuerstenau

"Gold, silver and copper form various complexes with cyanide, of which only the singly charged dicyano form adsorbs appreciably on activated carbon. The adsorption of the dicyano complexes appears to be controlled predominantly by chemical reaction at the surface of a shrinking unreacted core. Metal uptake over time is non-linear, which eliminates control by boundary layer diffusion. The rate of adsorption is not enhanced by a reaction interruption, which suggests the absence of concentration gradients in the pores. Finally, the rate of adsorption increases with decreasing activated carbon size in a manner consistent with the shrinking core model. The results of this investigation accentuate the importance of efficient acid washing of carbon and removing carbon fines from the barren carbon stream. INTRODUCTION With the dwindling reserves of high-grade ores, most of the world’s gold is produced from low-grade ores by cyanide leaching. In the past, leaching was followed by the Merrill-Crowe process, in which gold is precipitated from clarified pregnant solutions by zinc cementation. This process is still being used for high-silver ores, where the cost of carbon stripping becomes prohibitive. For deposits with silver-to-gold ratios of about 4 or less, adsorption on activated carbon would be the usual solution purification step taken. The process simplifies solid-liquid separation and offers a viable solution to preg-robbing organic carbon in some ores. The modern industrial application of carbon adsorption started with the carbon-in-pulp (CIP) process, where carbon adsorption was used mainly as a solution purification step. In 1973, Homestake Mining Company commissioned the first large-scale CIP plant in the U.S.A.1 Later, carbon was added earlier in the circuit to control preg-robbing by adsorbing gold cyanide onto activated carbon as soon as it is dissolved. The scheme is successful because activated carbon is a stronger adsorber than the organic carbon found in preg-robbing ores. This process came to be known as the carbon-in-leach (CIL) process. Numerous research investigations have been performed on the chemistry involved in the CIP process, which at the time of its introduction was not clearly understood. Of these, research on the kinetics of adsorption probably bears the most immediate impact on industrial practice,2,3 where adsorption systems rarely reach equilibrium, if at all, and slight slowdowns in the adsorption rate can translate into significant decreases in revenue. To illustrate this, organic compounds, like flotation reagents, have been known to impair CIP circuits. However, laboratory tests showed that the organic compounds do not significantly affect the adsorption capacity of activated carbon. Rather, the harmful effect may be attributed to a lowered adsorption rate.4,5 Also well known is the faster rate at which fine activated carbon powders reach equilibrium compared to coarse activated carbon, even though the final (equilibrium) amount of material adsorbed per unit weight is the same."

Jan 1, 2015

By B. A. Slaker, T. Miller, M. M. Murphy

An underground limestone mine in eastern Ohio was experiencing significant floor heave and roof falls, attributed to high horizontal stresses. Areas of the mine showing floor heave were monitored with roof-to-floor extensometers and photogrammetry surveys to determine the rate and magnitude of heave. Extensometer data were recorded hourly at four locations across adjacent entries while photogrammetry surveys of the floor were performed at the same locations every two to five weeks. A final survey was performed using an I-Site 8200 laser scanner. Following instrumentation, floor heave up to 10.1 cm (4 in.) was measured by the extensometers, photogrammetric reconstructions and laser scanner over a six-month period. The extensometers were biased by the location where they were placed, failing to consistently capture the location and extent of floor heave and cracking. The photogrammetry surveys were not precise enough to capture small magnitude movements. Mining in the area was halted and within several months the floor movement and incidence of roof falls were significantly lessened.

Jan 1, 2018

By Nathaniel White, Todd Kilduff, Justin Laviolette, Dan Laviolette, Randy Zeigler, Sean Sundermann

The Mitchell Point tunnel is a part of several ongoing efforts to connect the 12-mile-long Historic Columbia River trail between Mitchell Point Outlook to Mitchell Point Drive. The tunnel lies inside the Mitchell Spur entablature basalt geologic feature, extending 647 linear feet utilizing a typical horseshoe section with a height of 14.5 feet. The Oregon Department of Transportation (ODOT) required proper vibration control to minimize potential impacts to Interstate 84 and Union Pacific rail immediately below the tunnel excavations and sensitive, rare plants. The method of designing the vibration monitoring program and the results of its implementation show the iterative process of using monitoring to improve blast design as excavation proceeds, such as reducing air overpressure and COVID-related supply chain-constraints.

Dec 1, 2022

By Yi Luo

Simulation of the multi-entry and multi-crosscut (MEMC) ventilation systems commonly employed in U .S. underground coal mines can be very tedious, due to the large number of crosscuts with stoppings to be represented in the network models. In order to reduce the amount of work needed to build the models, a common practice is to represent a number of crosscuts with one equivalent airway. However, this introduces certain errors into the simulation results. In this paper, algorithms have been proposed to simplify the ventilation networks of common MEMC systems encountered in panel development operations. The algorithms can be used to reduce a MEMC system into one airway with an equivalent resistance and to determine the airflow distributions in the system and the leakages through the stoppings.

Jan 1, 2011

By Shamim A. Dar, Mohd Shuaib, K. F. Khan, Samsuddin Khan

Petromineralogical studies of late Paleocene–middle Eocene phosphate nodules in the Subathu Basin of Solan District, Himachal Pradesh

By R. A. Williams

Surface and electrochemical techniques have been used to describe the surface chemistry of ferrosilicon powders, as a function of pH and electrochemical potential, for conditions typical of operating DHS plants. The practical consequences on the likely corrosion behaviour and associated electro- kinetic particle-particle interactions (which affect stability to sedimentation) in the suspension, are discussed.

Jan 1, 1987

By M. Heger, V. Lund, P. Mongeon, D. Bogunovic, V. Kecojevic

The U.S. coal mining industry consumes a significant amount of energy, primarily diesel fuel and electricity. The continuous global increase in energy demand, high energy prices and environmental issues related to carbon dioxide emission represent a substantial challenge for the mining industry. This paper presents the result of research on development of an integrated data environment system for analysis of energy consumption in a surface coal mine. A case study on an operating surface coal mine is carried out to demonstrate the practical application of the developed system. The research work presented here may be used by mining professionals to help provide the answers to the crucial questions of when, where and how much energy is being used. This developed system represents a framework for efficient management of energy consumption.

Jan 1, 2009

By G. Van Weert, J. F. Breedveld

Both regular and Silver Impregnated Activated Carbon (SIAC) were studied for their effectiveness in removing WAD (Weak Acid Dissociated) cyanides from solutions at pH = 10. SIAC has already been shown to be effective in the removal of free cyanide down to 30 ppb or less. The present work deals with complexed cyanides. Zinc cyanide was used to represent the WAD component. At pH=10, in either batch or column tests it was not possible to lower the total cyanide in solution from either 30 or 8 ppm to less than 1 ppm, using SIAC, regular activated carbon as received, or after grinding. Silver (metal) impregnation of the carbon was not beneficial in the removal of WAD cyanide. However, when silver is added as silver ions (nitrate), the cyanide is adsorbed as silver cyanide in preference to zinc cyanide. The latter compound converts to zinc (hydr) oxide. This way, the cyanide concentration in solution can be lowered below 1 ppm, even when zinc cyanide is already adsorbed on the carbon used. A single exploratory test with added copper ions indicated a similar effect for that system.

Jan 1, 2004

By Norman F. Schulz

Representative sample s of typical manganiferous iron ores from the Cuyuna Range, Minnesota, were reduced to the metallic iron state at temperatures just short of fusion with an excess of coke in the manner prescribed by the R-N Direct Reduction Process. The magnetic separation characteristics of the reduced ores were determined at several grinds by means of the Davis magnetic tube concentrator. The efficiency of metallic iron concentration by magnetic separation was a direct function of the degree of metallization of the ore sample and of the degree of liberation attained in grinding. Some improvement of liberation characteristics was observed if a small amount of sodium chloride was present in the ore during reduction. Despite the extremely fine -grained structure of the crude ores, iron concentrates containing more than 90% Fe at iron unit recoveries of 90% or more were obtained from well-metallized samples of three of the four ores tested. The rejection of manganese to the tailings corresponding to such separations varied from 80 to 95%.

Jan 1, 1967

By Mollie Hunt, William Riley, Russ Downer, Kate Willa Brown Requist, Víctor O. Tenorio, Geoffrey Gill

One of the first activities after returning to the Moon will be finding sources of water and materials for the construction of human settlements and other infrastructure. There is evidence of the existence of deposits in the bottom of craters at the South Polar region and in flat areas around. Based on geological data from the Moon, a block model representing a deposit or icy regolith has been defined in the vicinities of Shackleton Crater, with unique characteristics of shape, thickness, and water contents. A mine plan utilizing surface mine modeling software for ore extraction from an open pit- type of excavation to a delivery point near a water processing facility is proposed, with monthly, quarterly, and yearly schedules. Production results, dashboard charts and progress of the topographic changes are also presented.

Feb 1, 2024

By A. M. Gaudin

In a recent paper we have reviewed principles and applications of measurement methods for contact angles and their hysteresis (22). In this paper we apply these methods to a system consisting of rutile, an organic liquid (benzene, decane, or dodecane) and water. Surfactant (dodecylamine hydrochloride) was used at various concentrations and various pH values.

Jan 1, 1964

By M. Kaya

This paper presents an experimental method to determine the degree of gangue entrainment in mechanical flotation cells and proposes new and inexpensive methods to lessen it. The applicability of froth washing and vibration was studied in laboratory, pilot plant, and plant scales. The effect of wash water on metallurgical performance was tested with various streams from the Falconbridge Strathcona mill at laboratory, pilot, and plant scales, with the 2nd cleaner at the Eastmaque Kirkland Lake mill, and with the 2nd and 3rd zinc and 3rd and 4th copper cleaners at Les Mines Selbaie mill. It was found that gangue recovery was closely related to water recovery in all systems. Wash water at an optimum superficial rate from 0.03 to 0.07 cm/s reduced entrainment by anywhere from 30X to 70X. Wash water can be further assisted by mechanical and ultrasonic vibration of the froth. A further rejection of 10 to 20X becomes possible. As a result of this work, a number of plants in Canada and in the United States have evaluated and/or are now using froth washing.

Jan 1, 1990

By V. F. Hollister

Computer programs developed as part of the PROSPECTOR project at SRI International can indicate where the highest grade hypogene copper occurs in porphyry copper prospects. The programs are useful in selecting drilling targets in untested porphyry deposits. Because of mineralogic, structural and lithologic variations in porphyry-type deposits, three distinct computer programs have been constructed; however, this paper considers only the stockwork type in homogeneous rock (similar to the Lowell and Guilbert model). The programs represent models in the form of inference networks that utilize the mineralogic, alteration, lithologic, structural, geochemical and geophysical data normally collected prior to a drilling decision. One example of an application of the PROSPECTOR program for a stockwork-homogeneous porphyry is given: Island Cooper in British Columbia. Computations based on the surface geologic, geochemical and geophysical data for Island Copper clearly disclose the best hypogene grade of the deposit. Other deposits were tested in the programs as well, and in each case PROSPECTOR programs indicate the region with the highest hypogene grade.

Jan 1, 1983

By P. T. Bissert, J. P. Ducarme, J. L. Carr, A. K. Smith

The continuous mining machine is a key piece of equipment used in underground coal mining operations. Over the past several decades these machines have been involved in a number of mine worker fatalities. Proximity detection systems have been developed to avert hazards associated with operating continuous mining machines. Incorporating intelligent design into proximity detection systems allows workers greater freedom to position themselves to see visual cues or avoid other hazards such as haulage equipment or unsupported roof or ribs. However, intelligent systems must be as safe as conventional proximity detection systems. An evaluation of the 39 fatal accidents for which the Mine Safety and Health Administration has published fatality investigation reports was conducted to determine whether the accident may have been prevented by conventional or intelligent proximity. Multiple zone configurations for the intelligent systems were studied to determine how system performance might be affected by the zone configuration. Researchers found that 32 of the 39 fatalities, or 82 percent, may have been prevented by both conventional and intelligent proximity systems. These results indicate that, by properly configuring the zones of an intelligent proximity detection system, equivalent protection to a conventional system is possible.

Jan 1, 2016

By Takahide Wakamatsu

In Japan all the complex sulfide ore deposits of base metals have been developed as underground mining. The underground mining cost is extremely high as compared with open pit mining case. Therefore, in milling section of base metal mines, technical advance for maximum recoveries of valuable constitutents in ore has been required all the time to utilize as much ore mined as possible. At present, in mill plants treating "Kuroko", complex sulfide ore, concentrates of copper, lead, zinc, pyrite and barite are produced, with gold and silver contents in the copper, lead, and zinc concentrates being estimated as extra profit. As in the case of Kuroko milling plants, gold and silver contents in the lead and zinc concentrates of lead-zinc ore milling plants are also varuable from an economical viewpoint. Silver content is very high in Kuroko crude ore as well as lead-zinc ore.

Jan 1, 1982

By Jafar Safarian, Leiv Kolbeinsen, Stian Seim, Hossein Salehi

The present work aims to investigate the link between the oxidation and reduction of a weathered ilmenite concentrate in terms of phase transitions, microstructural changes, and element distribution. An ilmenite concentrate sample was pelletized and fired at 1000 °C in air, and as a result, the pellets were oxidized. The oxidized pellets were reduced by hydrogen gas at 1000 °C, which yielded almost complete metallization of the iron content of the pellets. The ore and the pellets were characterized in each step by XRD and SEM techniques, and distribution of elements and phases were investigated. Ilmenite, pseudorutile, and rutile were the main phases detected in the ilmenite concentrate sample, and depending on the weathering degree of the particles, different fractions of the phases were identified in their microstructure. It was found that irregular rutile grains dispersed in a pseudobrookite matrix is the morphology of the oxidized ilmenite phase. However, increasing microcracks and porosities were the only microstructural changes in the pseudorutile phase after oxidation in air. Studying the specific types of the ore particles and their oxidized and reduced forms indicated that the phase distribution in the ilmenite ore particles dictates the phase distribution in the oxidized and reduced ones. Results show that the morphology of the reduced particles includes a titanium (III) oxide matrix in which reduced iron globules are dispersed.

Feb 8, 2021

By R. Miller

Lowering our globe’s emissions is a major effort as we move toward a future net-zero carbon environment requiring significant investment in a new, low-carbon infrastructure, along with key market incentives to change. Industry will play a key part in this transformation, requiring expertise in both energy and emissions. Key elements of the de-carbonization strategy are: energy data, emissions reporting method, governance, de-carbonization project generation and drivers, the MACC, electrification, and the de-carbonization checklist. For a zero carbon future, it will be key for business leaders to understand decarbonization, anticipate technological changes, and implement new business me

Mar 2, 2022