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By Onuralp Yücel, Kağan Benzeşik, Ömür Can Odabaş, Selçuk Kan

Extraction and processing constitute an important area in the metallurgy of molybdenum. Molybdenum trioxide (MoO3) production is one of the most important stages in molybdenum production. In this study, the effects of different furnace types on MoO3 production were investigated by using molybdenum concentrate as a raw material obtained during the enrichment of copper ores. Preliminary experiments have been made using a chamber type furnace, and a transition to a pilot-scale has been carried out with rotary kiln experiments. The effects of a different time and atmospheric conditions on MoO3 roasting kinetics were investigated by experimental studies conducted in the temperature range of 500–650°C. It was determined that the optimum temperature and time for sulfur (S) removal was 625°C and 180 min in the studies carried out in the rotary kiln, and it was determined that 0.61%S content was reached with an average removal efficiency of 98%. The activation energy in these sets was calculated as 89.519 kJ/mol.

May 3, 2021

By V. Rajaram

The Metropolitan Water Reclamation District of Greater Chicago (MWRD) imposed a no-blasting specification (blasting is restricted to the construction shaft and shaft bottom or boot) on the Deep Tunnel project in 1988. This was prompted by numerous complaints from the residents in the vicinity of the project, and controversies experienced on previous projects from blasting the rock overlying the tunnel. This paper will describe the methods utilized by two major contractors who are driving 20 km (12.5 of tunnel along with drilling over 36 shafts under this restrictive specification. The impacts on design, construction, schedule, cost, and the environment are detailed.

Jan 1, 1991

By Allen Latham

It started' in 1936 when some Dutch adventurers wanted to scale the highest mountain in the South Pacific. Quite by accident, they discovered the Ertsberg, a contact deposit of magnetite laced with chalcopyrite, in a high mountain valley where it had been gouged at by glaciers and finally left as a solitary pillar for its discovery by a geologist who lent purpose to the expedition, Dr. J.J. Dozy. By the-.time a report was published describing the deposit, war had hit the Netherlands. Perhaps again by accident, the report was uncovered in 1959 by the East Borneo Company. At this point, Freeport entered the scene through its vice president for exploration, Forbes Wilson. During the course of a meeting on laterite prospects, the Ertsberg was introduced and he put the wheels into motion for Freeport to join in its exploration. You might, at this point, ask yourself whether you or your company would have taken on a venture to look at a reportedly large high grade copper outcrop in New Guinea, an unexplored land known best for its inhospitable climate, terrain and head-hunters. I heard the chief executive of one large mining company comment sometime back that neither he nor his company would have gotten involved. I won't attempt to describe the trials of the initial exploration expedition that passed through dense-man grove swamps, tropical jungle and across jagged mountains a distance of some 200 miles to get to the Ertsberg in 1960. It should be chronicled by its participants - Forbes Wilson, Del Flint, and John Bowenkamp. Needless to say, the participants relish the experience but wouldn't be among those volunteering for a return engagement. As a result, the Ertsberg changed from a reported outcrop to a mineral deposit containing an estimated 13 million tons with systematic surface sampling indicating a copper grade of over four percent. Moreover, the deposit extended to an indeterminate depth with the possibility of doubling or tripling. reserves well within reason.

Jan 1, 1971

By Taghi Sherizadeh, KUTAY E. KARADENIZ, Dogukan Guner, Samuel Nowak

Underground mining environments bring with them occupational health and safety issues with some severe dangers, such as mine explosions. During such events, miners may escape using main access openings or find a safe haven like a refuge alternative (RA) to wait and be rescued and evacuated to the surface. In this paper, RAs are explained with their early and current applications. A classification as permanent and portable is detailed, depending on conditions and abilities. This classification is followed by the utilization and survivability of RAs with the requirements and recommendations of the main mining countries. Based on the utilization and survivability constraints, basic human requirements, waiting for a rescue team, and the required physical specifications of RAs during the events are analyzed in detail for various countries with their regulations. Among these, the specification of resistance to explosion is discussed in particular, and studies in the literature are examined in terms of structural deformation.

Mar 1, 2023

By A. Guzman

The design and construction of a new 140-ton-per-day R. O. M. phosphate rock scrubbing and washing plant was undertaken by Western Knapp Engineering Company, a Division of Arthur G. McKee and Company, for the J. R. Simplot Company, Minerals and Chemical Division, Pocatello, Idaho. The new plant replaces the owner's existing facilities at Conda, Idaho, seven miles northeast of Soda Springs in the southeast corner of Idaho. Replacement of the existing facilities became necessary because of loss in production and recovery. These losses were due in part to varying grades of raw ore from the mine and to the type of process equipment used in the old plant to upgrade the ore. Increase In production and grade was further necessary by demands created by expansion of facilities in Pocatello, Idaho, where all process ore from this plant is shipped. The new process scheme includes an ore-feeding system, scrubbing, screening, classification, wet cycloning, attritioning, filtering, drying, storage and shipping facilities. Space was also left for future increases of scrubbing and classification capacity and for heavy media separation. It is the purpose of this paper to take up some of the considerations necessary in the design of small mills in order to achieve the desired objectives of a successful plant, such as production, minimum operating cost and maintenance cost.

Jan 1, 1969

By C. Newman, R. C. Ray

Originated and developed in the civil tunneling industry, the Ground Reaction Curve (GRC) has provided a robust methodology for evaluating and designing ground support in both tunnels and underground mining scenarios. This paper presents a preliminary assessment in the utilization of the GRC concept for the evaluation and design of the pillar-support system with respect to overburden stress and displacement. This initial assessment will be based on and backed by past research on this topic. Underground mine instrumentation is planned for a longwall mine in the Appalachian coal field based on the research and findings in this paper to support the postulated hypothesis. INTRODUCTION Since the early 1970’s, the mining industry has evaluated the structural stability of a pillar by dividing an approximated pillar load by an approximated pillar strength. While this design methodology has served the industry well in the past, as modern mining operations continue to develop in more complex geological and geometric conditions coupled with market economics, industry professionals are in dire need of a modified stability assessment approach which considers both the stress condition and material displacements. Within the civil tunneling industry, the GRC approach has been successfully utilized in designing underground support measures that enhance the stability of an underground excavation. Through the incorporation of current industry knowledge and understanding of ground and support behaviors this paper looks to investigate into preliminary assessment for the development of a Modified Support Response Method (MSRM) to further improve the analysis of local and global underground stability. CURRENT PILLAR DESIGN METHODS AND THEIR LIMITATIONS Globally, multiple pillar design methods have been utilized in the design of underground excavations. Each of these methods approaches the calculation of pillar stability a little differently with respect to material properties, underground geometries and stress conditions. Analytical solutions can be used to determine the strength of homogeneous materials like concrete, but not in case of non-homogeneous and non-isotropic mineral deposits in a mine. These equations are often derived using empirical methods. Pillar strength is defined as the maximum resistance of a pillar to axial loading (Brady & Brown, 1985). The strength of mine pillars is typically estimated through indirect methods. In the past, researchers have correlated the strength of a given size and width of a rock specimen to the strength of a mine pillar. The first study on the effect of geometry on rock strength was done by (Bauschiger, 1876) on Swiss sandstone samples. Since then several empirical equations to determine pillar strength had been published by many researchers like (Bunting, 1911), (Griffith & Conner, 1912), (Greenwald, Howarth, & Hartmann, 1939), (Holland & Gaddy, 1957), (Evana, Pomeroy, & Berenbaum, 1961) and (Holland C. , 1964).

Jan 1, 2019

By Shosei Serata

In the past, salt cavities for storage of liquid and gaseous fuels have been developed and operated using practical experience as a guide rather than rock mechanics principles and practices. Although many salt cavities are still operating satisfactorily. some of them are beginning to show various problems associated with long-term deterioration of the cavities. This paper describes a major breakthrough in the rock mechanics design of solution cavities which is the development and application of the REM computer simulation system. From the computer simulation analysis, the long-term deterioration process of cavities can be related to the basic parameters of rock mechanics design and the storage operations. The computer simulation system is also used for optimizing cavity design and operational specifications. This optimization technique is explained by its application to the three basic storage systems: 1) open dry storage system for liquids and solids 2) open wet storage system for liquids 3) pressurized storage system for gases, liquids and solids The effectiveness of the optimization technique is illustrated with some field examples by showing the direct interaction between the computer simulation system and field data of a test well including tectonic stress conditions, material property coefficients and geological anomalies.

Jan 1, 1974

By F. Segobia, H. Lozano, M. Portal, F. Ysla, L. Goicochea

This case study evaluates the long- term physical stability of various historical mining structures remediated by the Center for Mining Environmental Research and Studies (CIEMAN) in Hualgayoc, Cajamarca, Peru. The region has a long history of mining activity, with remnants dating back to pre-Inca times. CIEMAN has assumed responsibility for remediating 286 environmental liabilities in the area, including adits, shafts, pits, tailings, and waste rock dumps. The study analyzes the methods employed to stabilize these structures, including geotechnical engineering techniques and revegetation. Long-term monitoring results are presented, assessing the effectiveness of remediation measures and predicting the future stability of the structures. This study highlights the importance of responsible remediation of mining environmental liabilities to ensure the safety and sustainability of communities and ecosystems affected by historical mining.

Feb 1, 2025

By Ronald J. Riberich

The Mineral Economics and Management Society (MEMS) held its fifth annual conference in Montreal, Quebec, Canada earlier this year. “The Minerals Industry: Responding to the Global Challenge” was the first MEMS conference to be held outside of the United States. About 125 mining- and minerals-related professionals attended. The MEMS program included six sessions and three distinguished speaker addresses. The session topics included: “Minerals in the Macro economy: Development in Demand,” “Trends in Global Metals Supply: The Producers’ Challenge,” “Global Environmental Issues: Policy Perspectives,” “Global Environmental Issues: Quantitative Analysis” and “Minerals in the CIS: Phoenix or Albatross?” A student session was also offered. It provided a competition for monetary awards for outstanding papers.

Jan 1, 1996

By Charles A. Hickey

The dining industry game tome Spruce Pine area a few years after tine Civil War. Two Yankees came down from Massachusetts to mine sheet mica to sell to the stove manufacturers for windows in heating stoves. At this time the method of mining was very crude; it was done only with pick and shovel. They were mining mica from the soft veins. Later they progressed to hand grilling and blasting. Hand drilling was quite an art in the area. One man would hold and turn the steel while one or two other men would drive the steel with hammers. In shaft raining, the muck and water was removed by hand winches called windlasses. About 1920 air compressors and jack hammers came into use. These were perhaps tide greatest improvement that has ever come to the area's mining industry. Later carne gasoline hoists, air drive water pumps, and all electrical equipment. Mica mining has, for the past few years, been very modern and efficient.

Jan 1, 1962

By Shanming He, Jinliang Wang, Xiaoming Wang, Chunfa Liao

Large amounts of manganese-rich slag were generated from smelting low-grade manganese ore containing high iron and high phosphorus in electric furnace or blast furnace, which contain 25–40 mass% Mn. This paper describes an efficient hydrometallurgical process for the utilization of high manganese slag instead of conventional usage of pyrometallurgical route for manganese recovery. Pressure acid leaching of manganese-rich slag using air as pressurized gas is studied systematically. The effects of mass ratio of manganese-rich slag to pyrite, concentration of sulfuric acid, leaching temperature, partial air pressure, leaching time, and liquid-solid (L/S) ratio on the separation of manganese with other main impurity components were investigated comprehensively. Under the following optimal process conditions, weight of manganese-rich slag powder,100 g; mass ratio of manganese-rich slag to pyrite, 20:1; sulfuric acid concentration of 140 g/L; air pressure of 0.6 MPa; leaching temperature of 140 °C; leaching time of 1 h; L/S of 7:1; ore size of 75–80 μm; and stirring rate of 600 rpm, the extraction rate of Mn reached 94%, and the dissolution percentage of Si, Al, and Fe are as low as 2%, 6%, and 10%, respectively. The leaching slurry presented a good solid-liquid separation characteristic. The silicic acid formed during sulfuric acid leaching manganese silicates was converted to filterable dehydrated SiO2 particles which precipitated in the residue under the condition of higher temperature with higher pressure. The effect of adding pyrite may be to reduced iron ions and decreased the output of iron hydroxide colloid and also reduced MnO2 to manganese sulfate in sulfuric acid leaching. Thus the formation possibility of colloid such as silica gel and iron hydroxide was decreased, and higher yield of manganese sulfate could be achieved.

By P. Somasundaran

Three major types of solution chemical equilibria involving flotagents (Le. flotation reagents such as collectors, frothers and modifiers), minerals and solution play a crucial role in determining the behavior of complex flotation systems. Minerals of phosphates (apatite and francolite), tungsten (wolframite and scheelite) and associated carbonates (calcite and dolomite) are sparingly soluble in aqueous solution and form dissolved mineral species in bulk solution. Such dissolved species interact with mineral solids, often resulting in surface conversion of the minerals. In addition, they can interact with various flotagents and lead to surface or bulk precipitation and loss of selectivity in the flotation. Relevant solution equilibria of such sparingly soluble minerals and their interactions with oleic acid and structurally modified reagents were determined in this study using a multi-pronged experimental approach. Methods to manipulate and control the solution chemical equilibria and thus achieve selectivity in flotation systems are discussed.

Jan 1, 1990

By Scott D. Thayer, George H. Milly

INTRODUCTION Ambient concentrations of radon and its daughter products have been measured and analyzed by a number of investigators for a variety of purposes. Principal among these purposes have been: (1) descriptive, to characterize the distribution and changes in concentrations under various conditions; (2) research in the use of radon as a tracer gas in the study of atmospheric characteristics and motions, such as eddy mass transfer, diffusivity profiles, large scale circulations, and the like; and (3) the use of radon as an atmospheric tracer in exploration for uranium deposits.* This information forms the basic data for this paper and for its placing the ambient natural, or non-anthropogenic, radon concentrations into the perspective of ambient radon health standards and lung cancer risk calculations. To enable better understanding of some aspects of the ambient radon data, review and analysis is also performed on selected measurements of radon emanation or flux from the surface of the earth into the atmosphere. These measurements have generally been made for purposes similar to those for ambient radon, i.e., (1) description of radon emanation characteristics; or (2) to support and justify the use of ambient concentration measurements in atmospheric research; or (3) in exploration for uranium. Interest is also developing in the use of such measurements for earthquake prediction. In addition, to complete the perspective, brief examination is given to anthropogenic ambient and flux radon measurements related to the mining and milling of uranium, so that comparison can he made with the values from natural sources. As a frame of reference we cite here previous summaries of studies which have presented representative values and ranges of ambient concentrations and emanation rates. H. Israel, in the Compendium of Meterorology (1951), cites eight studies of ambient radon concentrations which we have selected as representative of non-anomalous continental values. Their means generally range from [0.06 to 0.15 pCi lit-1 with the smallest reported minimum of zero and the largest maximum 0.53 pCi lit-1. The overall mean is 0.10 with a standard deviation of 0.03 pCi lit-1. Means over oceans are much smaller, and the data scarcer, with only three values ranging from 0.0004 to 0.003 pCi lit-1 and a mean of 0.0016 pCi lit-1.] Thirteen studies from Israel's list were selected as representative of mountainous terrain. These data, except for the cases of higher elevations, frequently show significantly higher values than the average cases in non-mountainous terrain described-above. The averages range from 0.10 to 0.59 pCi lit-l; the smallest minimum is zero and the largest maximum is 9.2 pCi lit-1. The overall mean is 0.30 with a standard deviation of 0.17 pCi lit-1. Israel also cites five studies of radon emanation (flux) from the earth's surface. These show a mean of 0.40 pCi-2m-2 sec-1 and a range of from 0.21 to 0.74 pCi m-2 sec-1. Data on flux are naturally scarcer in the literature than data on ambient concentrations, because of the greater interest in and utility of the ambient information. In this paper we also give special consideration to observations of the variability in time and space of radon flux rates, and to the impact of these phenomena on the use of such data for a variety of purposes. NATURAL(NON-ANTHROPOGENIC)AMBIENT RADON CONCENTRATIONS We have examined the following reports for the data selected for this category; these studies were generally intended to describe radon characteristics in the atmosphere. Jonassen and Wilkening (1970); Bradley and Pearson (1970); Wilkening (1970); Lambert, et al (1970); Pearson and Moses (1966); and DickPeddie, et al (1974). Another set of studies which was reviewed was selected because the investigators made ambient radon measurements in the course of examining the use of radon as a tracer in atmospheric research. This set consists of: Israel and Horbert (1970); Carlson and Prospero (1972); Subramanian, et al (1977); Larson (1978); Cohen, et al (1972); Hosler (1966); and Shaffer and Cohen (1972). Finally, unpublished data from uranium exploration activities (Milly and Thayer, 1976) was analyzed. [Treating the ocean cases first, the mean values are generally consistent with those quoted earlier from Israel (0.0004 to 0.003 pCi lit-1); they range from 0.001 to 0.011 pCi lit-1, with 0.003 the most frequently reported value. Continental values, from eight studies, range in means from 0.07 to 0.41 pCi lit-1 (not including mineralized areas, or "uranium country", discussed later), with maxima as high as 2.4 pCi lit -l. For comparison, the means from Israel are 0.06 to 0.15 pCi lit-1, with a maximum of 0.53 pCi lit-1. Some of these studies also present the typical decrease of-1 concentration with height to 0.01 to 0.04 pCi lit at 5 to 7 km. The vast numbers of uranium prospecting radon data of]

Jan 1, 1981

By R. M. Campoy

Mexico's mineral wealth has long been recognised and indeed has played a historically significant role on a world scale. The dynamics of the Mexican mineral industry have experienced a dramatic transformation especially over the last two decades. This transformation has mainly been instigated by the high growth rates and industrialisation of the Mexican economy since the 1960's. This paper focuses on the base metals sector of the industry which represents one of the major contributors to this transformation. The objective is to present a brief base metals review and to discuss some recent occurrences which pertain to this sector of the industry. This is followed by a discussion of mining's relevance in the current economic situation in Mexico. With this overview as background, the investment climate, primarily from a domestic investor's perspective and secondly in terms of foreign investment, is discussed. Finally, some recent government initiatives, including tax and accounting changes, are outlined. Any one of the sections of this paper can easily be developed into an extensive and indepth analysis; however, the intention of this paper is to provide the reader with a broad overview of the topics discussed.

Jan 1, 1985

This paper addresses the valuation and development timing of an undeveloped mineral project. Traditional analysis has us developing the project immediately if its net present value (NPV) is positive. Option pricing theory finds that it is better to wait until the NPV of the property is significantly greater than zero before developing. Alternatively, when evaluating the development timing decision, we must calculate NPV using a higher "timing-adjusted" discount rate, and develop the property only if its NPV using this timing-adjusted discount rate is greater than zero. This paper uses option pricing ideas to convert this development timing advice into a more concrete and user-friendly decision rule: develop the project when its "development-timing NPV" is positive, this development-timing NPV being calculated using the normal discount rate.

Jan 1, 1997

By C. Sun

With complex component, higher salt content, low biodegradability, DSD acid oxidation wastewater could not be efficiently dealt with traditional methods. It is pointed that the coal water slurry could be made with DSD acid oxidation wastewater of different concentration and the density of coal water slurry could be up to 70%, while its viscosity is only 850~930 mPa?s. The coal water slurry could be perfectly jetted and burnt under different conditions. The higher density the DSD acid oxidation wastewater has, the better properties the coal water slurry have. The pollution components and characteristic group of DSD acid oxidation wastewater are similar to the additives of coal water slurry, so it could be used as a kind of usable additive of water coal slurry. It is so reasonable and feasible to make coal water slurry with DSD acid oxidation wastewater that the pollution of DSD acid oxidation wastewater can be solved completely.

Feb 23, 2014

By W. F. Mullen

Within the scope of this discussion, artificial dimension stone is defined as any manufactured product used as a substitute for natural dimension stone. The history of the development of these substitute materials is reviewed briefly, representative characteristics of each product are listed, several analyses of their market position are presented, and suggestions are made for recapturing markets lost to these products and preventing additional inroads.

Jan 1, 1959

By AKIHIRO YOSHIMURA, HIDEKAZU KATO, KOTA TAKATORI, YASUNARI MATSUNO

Chalcopyrite (CuFeS2) is the most refractory copper mineral when treated in conventional sulfate media leaching systems. This is the first study to examine the use of a dimethyl sulfoxide (CH3SOCH3, DMSO) solution containing copper chloride (CuCl2) for the leaching of chalcopyrite. Leaching experiments for a copper concentrate composed mainly of chalcopyrite were conducted at ambient pressure at 313–413 K. The leaching fractions of Cu, Fe, S, Au, and As were investigated. It was found that 90% of the Cu was extracted in 2 h, and 94% was extracted in 4 h at 373 K, which is competitive with other conventional processes. A DMSO solution containing CuCl2 could selectively dissolve the valuable metals Cu and Au from chalcopyrite, but leave minerals with little economic value such as pyrite (FeS2) and As in the residue. Chalcopyrite is oxidized by cupric ion in proportion to the stoichiometric ratio of Cu in the concentrate to the initial cupric ion in the DMSO solution, which is enhanced by the presence of oxygen below 373 K.

Mar 12, 2021

By Ihor Kunasz

The high lithium demand forecasted for some high tech applications and batteries for electric and hybrid-electric vehicles, in particular, has sparked increased exploration for lithium, particularly for lithium- and potassium-bearing brine deposits. The latter have generally followed the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) NI 43-101 guidelines on resource reporting, formulated for hard rock deposits (metals and industrial minerals). While a number of the requirements can be appropriately applied to brines, brines are fluids and require a specific analysis leading to a distinct set of reporting requirements. Brines cannot be considered industrial minerals because the various elements occur as ions in a dynamic fluid, rather than being chemically bonded in a solid. Although chemicals are produced from brines, brines have no relation to industrial mineral deposits. This article analyzes the recently released (Nov. 1, 2012) document CIM Best Practice Guidelines for Resource and Reserve Estimation for Lithium Brines, in light of the practical knowledge available from existing brine operations. It recommends modifications to the guidelines, which, if applied in their present format, will result in overstating resources and reserves and mislead potential investors. The CIM Best Practice Guidelines for Resource and Reserve Estimation for Lithium Brines document is generally descriptive and does not fully address the methodology for brine resource or reserve definition. Lithium and other elements (potassium, magnesium) are contained in a fluid, the hydrologic characterization of which should be the principal focus of a brine exploration program. The fundamental requirement in defining lithium brine resources and reserves in a salar is the identification and definition of those formations ? the aquifers ? that will yield brine in a usable quantity to a well, because brines can only be extracted by pumping wells. Fine-grained sediments will never, as required in the summary Table 1, have ?reasonable prospects of economic extraction,? cannot be considered and, therefore, need not be tested. However, the guidelines recommend the collection of solid samples and a high-core recovery for laboratory testing of various sediments instead of focusing on the brine.

Oct 1, 2013

The surface of chalcopyrite was studied in situ in aqueous solution by an atomic force microscopy (AFM). The AFM images showed that some absorbate in patches was detected on the mineral surface, after the chalcopyrite sample was soaked in 5x10-4M potassium ethyl xanthate (KEX) solution at pH 11 for 10 minutes. These patches increased in size with time elapsing. At the same time, as shown by the obtained AFM force curves, the adhesion between the AFM tip and the substrate increased greatly due to the adsorption. Rinsing with ethanol removed the absorbate from the chalcopyrite surface, as well as the big adhesion observed in KEX solution.

Jan 1, 2010