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By T. Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques and controlled bulk leaching studies. The anodic dissolution process has been established to be a sevenelectron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions, which suggests that the sulphur is oxidized to thiosulphate and the copper and iron released as Cu+ and Fe2+ in these systems. The deportment of Fe2+ and S2O3 2- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, supporting formation of different sulphur species as proposed for the sulphate and carbonate salts. Scanning electron microscopy and energydispersive spectroscopic analysis of the mineral surface after leaching indicate presence of an iron–sulphur surface layer completely free of copper in the sulphate system, an iron-rich surface layer in the perchlorate solutions, and absence of surface layer build-up in carbonate solutions. XRD analysis of a bulk leach residue from leaching in ammoniaammonium sulphate solutions showed the surface layer to be mostly amorphous (90%). The crystalline content (10%) is composed of 95% polymorphs of anhydrous iron oxide hydroxide FeO(OH). Choice of ammonium salt and the hydrodynamic environment of leaching have been shown to influence the presence or absence of the surface product, as well as its nature. IntroductionHydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different routes for hydrometallurgical treatment of chalcopyrite can be followed. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilization of copper (I) and copper(II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation [1] (Beckstead and Miller., 1977a):"

Jan 1, 2016

1. Book reviews Nonparametric geostatistics, by S. Henley. London, Applied Science Publishers, 1981. xiv + 145 pp. Reviewer: Douglas M. Hawkins Mineral deposits and global tectonic settings, by A. H. G. Mitchell and M. S. Garison. London, Academic Press, Geology Series, 198!. Reviewer: J. Lurie The mining and mineral laws of South Africa, by B. L. S. Franklin and M. Kaplan. Durban, Butterworths, 1982. Cloth, 240 X 150 mm, Lxxcii + 853 pp. R197,50 + GST. Reviewer: M. J. Martinson Aluminium- Volume II, by M. H. Govett and J. Larsen. Sydney, Australian Mineral Economics (Pty) Ltd, 1982. Reviewer: D. G. Maxwell International technology for the nonferrous smelting industry, by Noyes Data Corporation. Reviewer: D. A. Viljoen 2. New publications Coaltransport- an analysis of technical and economic factors, by Dag Pike. London, Financial Times, 1982. £86 (D.K.), D.S. $175 (overseas including first class airmail postage). Small solute concentration differences determined by interferometry, by H.E.L.G. Schweigart. Pretoria, CERG-CSIR (P.O. Box 395, Pretoria), 1982. 3. Mintek reports Report M8A determination, using solid zirconia electrolytes, of the activities of chromium oxide in ferrochromium alloys and slags at 1650°C. Report M31Software for the design of multivariable control systems by use of the Inverse Nyquist Array. Report M37A literature survey of the metallurgical aspects of minerals in Witwatersrand gold ores.This survey reviews the information in the literature Report M 39 The use of masking agents in the determination, by hydride generation and atomicabsorption spectrophotometry, of arsenic, antimony, selenium, tellurium, and bismuth in the presence of noble metals. Report M40 The use of X -ray-fluorescence spectrometry in the determination of uranium, cobalt, and sulphur in materials from mine dumps. Report M44 A n on-line dilution system for spectrometry ustng an inductively coupled plasma source. Report M47 The separation of trace elements from iron, and the analysis of iron-rock ores for use as reference materials. Report M49 A programme in BASIC for the appending of computer files. Australian coal The editors of World Coal and World Mining have announced plans to sponsor the IVth International Coal Exploration Symposium. The symposium will be held in Sydney (Australia) from 15th to 19th May, 1983. Small mine economics The editors of World Mining and World Coal have announced plans to sponsor the Second International Symposium on Small Mine Economics and Expansion in Helsinki, Finland, from 12th to 16th June, 1983. The first symposium was held in Taxco, Mexico, in May 1981.

Jan 1, 1982

"Chairman: Mr R. A. PLUMBRIDGE Rapporteur: Dr D. M. HAWKINSPapers:The relevance of computer methods to the economics of the mineral industry by R: A. PerlmanDynamic control of a mining enterprise by R. G. CoyleAn economic model of the mineral sands industry by G. P. A. HoweMr M. Splaine, in opening the discussion on Mr Perlman's paper, asked whether the model, as fitted by data up to 1963, predicted the rise in the price of copper in 1967, and whether the model could be used to capitalize on short-term price fluctuations.Answering the second question first, Mr Perlman said that the horizon used is six months to one year. In the very short term the activities of speculators obscured the effect of the fundamental econometric variables. This effect, however, was removed if one moved to a longer term, say, quarterly. In 1963 the model had predicted a price rise in 1964 and 1965 and a drop in price in 1966. The rise in 1967 had been caused by a strike, and imponderables such as large strikes were difficult to include in the model since they were unpredictable. Model simulation can be used to show the effect of strikes on price and the effect of small strikes is small.Mr B. R. van Rooyen said that because models are both calibrated and tested on historical data a bias was introduced which gave rise to an overoptimistic estimate of the accuracy of the forecasts. To this Mr Perlman replied that there seemed to be no alternative to the use of historical data for calibrating and testing models, and thus little hope of avoiding the bias. A second point made by Mr. van Rooyen was that manage¬ment tended to be suspicious of complex models and that frequently more heuristic models were sufficiently accurate and preferable for investment decisions. He added that if management were not involved in the model building the econometrician might easily go astray, Mr Perlman replied that symbiosis between data analysts and users of the model was essential and that the experience of the practitioner must be reflected in the model.Mr M. R. Fuller-Good remarked that a clear understanding of future price trends was essential for effective capital planning, and asked, first, how one went from the compiled data on supply and demand to the determination of their effect on price, record, whether necessary data, for example, capacities, could be obtained timeously, and, third, when strikes restricted supply, whether stockpiling by consumers induced large price fluctuations."

Jan 1, 2014

By R. Thomas

A Honeywell TDC 2000 central process control system was installed at Rössing in 1984. The system controls the metallurgical operations from crushing to the finished product of uranium oxide and manufacture of sulphuric acid. The operation was previously controlled from nine separate local control rooms. The paper briefly reviews the design and commissioning of the control system on an operating plant and discusses the impact on manpower organisation and training needs. Development of the process control system during its first two years of operation is reviewed and a summary is given of the current status of computer control at Rössing. The impact of the new system on overall plant operation and performance efficiency is also briefly described. In conclusion, future developments of computer control and overall optimisation of metallurgical operations are reviewed.

Jan 1, 1987

By C. Pamukcu

In this paper, which is aimed to serve as a review article, first of all a breakdown of the earth?s total water reserves is given. The usage areas of water in the mining industry are mentioned and these uses are briefly outlined, together with the main pollution potential of each. According to this, most of the water (almost 80% of it) is utilized in processing. Later on, probable damages that the mining would give to groundwater as a result of acid mine drainage, heavy metal pollution, euthrophication and deoxygenation is described. Finally, the measures and controls that should be taken against water contamination in mines are presented.

Jan 1, 2008

By W. J. C. Pothas

This paper describes the state of the art in backfilling techniques used on East Driefontein Gold Mine. Areas covered are the preparation plant, the distribution plant, the pipeline network and finally placement techniques. The in-situ performance of placed backfill has been assessed by the Chamber of Mines Research Organization, and results to date will be shared. Details of the backfill expansion programme that will enable this facility to be made available to all working places are included. Benefits obtained by the introduction of backfilling are described, together with certain management aspects to be considered in the control of quality and quantity of support supplied via a pipeline.

Jan 1, 1988

By C. Pamukcu

In this paper, which is aimed to serve as a review article, first of all a breakdown of the earth?s total water reserves is given. The usage areas of water in the mining industry are mentioned and these uses are briefly outlined, together with the main pollution potential of each. According to this, most of the water (almost 80% of it) is utilized in processing. Later on, probable damages that the mining would give to groundwater as a result of acid mine drainage, heavy metal pollution, euthrophication and deoxygenation is described. Finally, the measures and controls that should be taken against water contamination in mines are presented.

Jan 1, 2008

Professor R.F. Sandenbergh matriculated at Germiston Afrikaans High School, and then he obtained the degrees of B.Eng. (Chem.) in 1972, M.Eng. (Chem.) in 1975, and D.Eng. (Met.) in 1983-all from the University of Pretoria. Mr J.A.D. Britz matriculated in 1958 at the Roodepoort Hoerskool, and joined the mining industry in 1959 as a student mine official at the Rand Mines Training Centre. Mr J.A. Cruise matriculated at Durban High School and joined Union Corporation as a Learner Official in 1962. He was awarded a scholarship to read for B.Sc. and M.Sc. degrees in mining engineering at the University of the Witwatersrand

Jan 1, 1990

SACPE has asked the Journal to bring the following points to the notice of members who are about register with SACPE. When to Apply There is no set time to apply for registration. Engineers should apply when they believe that their training has met all the requirements of Policy Statement No. 1/3. Pitfalls Remember that it is the applicants' training that must be evaluated, and this requires the avoidance in the application of vague generalities such as 'My duties were design plant including its economic evaluation' or 'I was engaged in . . Requirements An example of what is required can perhaps best illustrate the point.

Jan 1, 1982

Each year the South African Institute of Mining and Metallurgy offers a prize (or prizes should the entries warrant it) of up to RlOO for the best paper or dissertation on a topic appropriate to the interests of the Institute. The competition is open to all Student Members of the Institute. A Student Member who is in fulltime study at a university may submit the dissertation or thesis he has to write in part fulfilment of his university degree, provided that it is presented in a manner and on a topic suitable for publication in the journal. Entries for 1976 should reach the Institute by 31st December, 1976.

Jan 10, 1976

By A. E. Landsberg, K. C. Corin, G. Stroebel, J. A. Miller, M. Becker, H. J. J. Gordon

Geometallurgy represents an integrated approach to mine planning and operation whereby the naturally occurring ore variability and its effects on all key downstream activities in the mine life cycle are considered. Process mineralogy is one of the key components of this integrated approach. This paper focuses on understanding some of the mineralogical variability across the Swartberg Cu-Pb-Zn sulfide ore in South Africa and its consequent effects on flotation performance. This process mineralogy project is motivated by the planned changeover and expansion of the Black Mountain Mines concentrator to process solely Swartberg ore compared to the run-of-mine blend currently being treated at the plant. Eight samples spanning the main lithological units of the ore body are described using quantitative mineral-textural data and bulk sulfide batch flotation performance to establish five process mineralogical or geometallurgical units comprising: quartz-pyroxmangite-magnetite, quartz-amphibolemagnetite, quartz-magnetite, garnet-magnetite-quartzite and mica-quartzite ores. Important mineralogical characteristics affecting Cu, Pb and Zn recovery, grade and selectivity specific to the different ore samples are discussed. Ultimately, the use of ore-specific process mineralogical and geometallurgical knowledge allows for better mine planning and plant optimisation. Keywords: Flotation, polymetallic base metal sulfide ore, process mineralogy, ore variability

Jan 1, 2020

By E. Schoeman

Ion exchange resins were investigated for the effective recovery of platinum, palladium, and gold from a pregnant cyanide heap leach solution. Screening results indicated that strong-base anion exchange resins proved to be most effective in the recovery of these metal cyanides. Gold was selectively recovered with the use of Minix, while effective recovery of gold, platinum, and palladium over the base metals, copper, and iron, was achieved with Amberlite PWA-5. Successful elution of these metal cyanides was possible from both Minix and Amberlite PWA-5, using a 2M potassium thiocyanate solution at ambient temperature. Acidic thiourea was unable to elute platinum from either Minix or Amberlite PWA-5. Effective elution of palladium and gold were, however, achieved with use of acidic thiourea. Using these results, two conceptual flow diagrams for the recovery of these metals from cyanide solutions are proposed.

Jan 1, 2012

By F. P. Agterberg, A. G. Fabbri

"A statistical analysis was done on the locations of 718 copper and 1 257 gold deposits in Abitibi. This area of about 20 000 square miles is one of the better-explored metal-producing areas of Canada.Patterns of clusters were studied by harmonic analysis. Several two-dimensional power spectra showed a number of distinct peaks. Sets of crest lines for patterns of interfering waves were constructed on the basis of these peaks. They pass through elongated clusters of deposits which are spaced more or less equally. For copper these periodic regularities in location may coincide with geological structures largely of Archean age (major fractures and sedimentary belts indicating synclinal structures). A directional relationship with swarms of diabase dykes of known ages and distinct attitudes indicates that the gold mineralization is, in part, younger than the copper mineralization."

Jan 1, 2014

By G. Drennan, A. Cameron

"South African mining operations depend on the skilled professionals produced through the tertiary education sector. In geoscience courses at the University of the Witwatersrand, which lead into the mining sector, there has been a significant increase in student intake over the past 15 years. This increase has been characterized by a radical shift in demography: in classes where white male students once formed the majority, black female students are now in the majority. This demographic shift appears closely linked to policies addressing issues of social justice and transformation in post-apartheid South Africa. We document this change and consider the role played by employment equity legislation (as in the Mining Charter) and corporate social investment strategies in the mining industry, notably through bursaries offered to black female students. We also look at the changing needs of the industry, where the critical need for managerial skills, not just technical knowledge, is highlighted through data from surveys of past students and industry managers. Our findings indicate the need for a curriculum adjustment to meet these changing requirements, as well as more rigorous selection criteria for bursars than simply gender, race, and appropriate matric results. IntroductionThe South African economy has historically been linked to mining and the exploitation of mineral resources. South African mining operations are dependent on the professional labour that is produced through the tertiary education sector, with critical thinking, teamwork, and the art of negotiation having been identified as the crucial skills required for this industry (Sideropoulos, 2014). Over the past three decades the South African system of education has gone through a period of dysfunction that it is struggling to rectify (Maphai, 2014). This has impacted on the levels of academic preparedness of students applying for places in higher education. Concurrently, government and university policies have widened access to higher education in response to the need to address issues of social injustice and transformation related to South Africa’s history of apartheid. As a result, the number of students admitted to universities has increased dramatically. In the School of Geosciences at the University of the Witwatersrand (Wits), the increase in student numbers has been accompanied by a significant change in demographics: classrooms which in the past were dominated by white males have given way to classrooms in which black females are often in the majority. This demographic shift is related to legislation such as the Mineral and Petroleum Resources Development Act and the Broadbased Socio-Economic Empowerment Charter, developed to reshape the socio-economic and equity frameworks of the country (Botha and Cronje, 2015). Requirements aimed at transformation in terms of management, skills development, and employment equity, together with corporate social investment (CSI) requirements, have resulted in bursaries being made available to attract students from designated groups, which in turn has increased the number of black students, and notably black female students, taking courses in geosciences. However, due to the economic downturn, instability in the mining industry has recently resulted in the downsizing of some mines, with international investors pulling out of South Africa. This instability resulted in devastating strikes across all sectors of the mining industry (Stewart, 2013) and in Marikana, an important platinum mining area, the strike culminated in a deadly shoot-out between miners and police. The resulting tensions spilled over into the gold mining sector, resulting in further strike action, shaft closures, and retrenchments. These challenges have implications not only for the mining industry in South Africa, but for the tertiary education providers whose graduates would have been absorbed into the mine-related workforce."

Jan 1, 2017

By L. Forbes, G. Forbes, J. Wang

Bubble size measurement is a vital part of flotation system analysis and diagnostics. Over the years, a great many different bubble size analysis tools have been developed. However, all of them rely on ex-situ measurement and in-pulp sampling techniques. This paper evaluates the Mettler Toledo ParticleView™ Measurement probe as a novel method for in-situ bubble size measurement. This device is then compared to the conventional Anglo Platinum Bubble Sizer (StoneThree). It was found that the in-situ bubble size analysis technology appears to be a more user-friendly and reliable option for determining bubble size in flotation. However, the current instrument design is not suited to industrial applications. Keywords: Bubble size measurement, bubble coalescence, PVM probe

Jan 1, 2020

By T. van Heerden

A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2?5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50?500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complement the typically used electron microscope techniques.

Jan 1, 2012

By C. A. Snyders

The research presented in this paper investigated the practical aspects of the recovery of platinum group metals (PGMs) from a dilute cyanide leach solution containing base metals, in a manner similar to that used for gold extraction in a typical CIP process, and focuses on both the adsorption and elution stages. The carrier-phase extraction of precious metals using activated carbon offers significant advantages over other processes in terms of simplicity, the high pre-concentration factor, rapid phase separation, and relatively low capital and operating costs. As a sorbent, activated carbon is still by far the most important material because of its large surface area, high adsorption capacity, porous structure, negligible environmental toxicity, low cost, and high purity standards. Adsorption tests were conducted on a pregnant alkaline leach solution (0.15 ppm Pt, 0.38 ppm Pd, 0.1 ppm Au) resulting from cyanide extraction performed in column leach tests. The initial adsorption rates of Pt, Pd, and Au were very fast and recoveries of these three metals were approximately 90 per cent after 2 hours, and 100 per cent for Pt, 97.4 per cent for Pd, and 99.9 per cent for Au after 72 hours. The parameters that influence the extraction of PGMs and Au were examined to assess their relative importance during the adsorption process in order to provide the basis for process optimization. The concentration of thiocyanate was not identified as significant factor for PGMs adsorption, while Ni concentration was the most significant extraction process parameter. Base metal cyanide complexes adsorb and compete with the PGM complexes for sites on activated carbon, and while copper adsorption can be minimized by adjusting the residence time, Ni adsorbs at approximately the same rate as the PGMs, influencing the loading capacity and adsorption kinetics of the PGMs. The feasibility of eluting platinum and palladium cyanide complexes from activated carbon using an analogue of the AARL process was investigated. Platinum and palladium elute from activated carbon almost to completion in 4 to 5 bed volumes at 80°C, while the elution of gold at this temperature is slow, with a significant amount of gold still to be eluted after 16 bed volumes. The equilibrium loading of gold is exothermic in nature (Fleming and Nicol, 1984) which will result in an increase in gold elution kinetics with an increase in temperature at similar pre-treatment conditions. A similar result was found for the elution of Pt and Pd. Cyanide pre-treatment was found to have a significant influence on PGM elution. Higher cyanide concentration in the pre-treatment step results in more efficient elution up to a point, and results suggest the possibility of an optimum cyanide concentration, beyond which elution efficiency starts decreasing due to increased ionic strength.

Jan 1, 2013

By H. J. R. Way

Dr H. J. R. Way: In his reply to my queries Mr Bath still adheres to his statement that it may be possible to replace the estimated R200 million reduction in gold revenue in 1980 by exports of ferro-chromium, and apparently based his conclusion on a growth rate in demand for corrosion resistant steels of 10 per cent per annum in the next few years. As I pointed out at the previous discussion at Middelburg this would entail a production of about one million tons of ferro-chromium in 1980. Exact statistics of South African ferro-chromium production are not available, a fact which is very much to be regretted. But statistics of exports of ferro-chromium are available from "Foreign Trade Statistics" of the Customs and Excise. These show that South Africa exported 99,580 short tons in 1967. The quantity of ferro-chromium consumed in South Africa in 1967 was fairly small and we can therefore assume that the production was 99,580 tons. For this amount to grow to 1,000,000 tons in 1980 would require a growth rate of 19.4 per cent per annum. At 10 per cent this would grow to 344,000 tons and at 7 per cent 240,000 tons. The following growth rates in the form of average trends are pertinent: STEEL - Per annum World steel ingot production - 1957-67 – 6.8 per cent Free-world ingot production - 1957-67 – 6.0 per cent Consumptions of crude steel by four major Free-world Consumers - 1957-67 - 5.6 per cent CHROMITE World production - 1952-67 - 2.5 per cent South African total sales - 1948-67 – 5.4 per cent South African exports - 1948-67 – 3.9 per cent United States consumption, very irregular, but - 1962-67 – 6.5 per cent FERRO-CHROMIUM - Per annum United States consumption - 1952-67 - 6.5 per cent South African exports - 1957-62 - 25.2 per cent South African exports - 1962-66 - 41.9 per cent South African exports - 1966-68 - 21.2 per cent These figures show that exports of ferro-chromium have been growing at a very high rate varying from 21.2 per cent to 41.9 per cent since 1957, but in view of the market situation it seems somewhat doubtful if that high rate can be maintained up to 1980. Of our 1966 exports U.S.A. took 63 per cent which was 53 per cent of their total imports. Their average consumption is trending at a growth rate of 6.5 per cent per annum from 1952-67, but the growth from 1964-66 was 5- 2 per cent and 1966-67, -12 per cent!

Mar 1, 1968

By F. Botha

South Africa is amongst the 40 driest counties in the world, with extreme weather conditions and beset by both droughts and floods. Coupled with economic growth is an increased demand on water resources and, as with all other industrial developments, mining requires large volumes of water, which is likely to have an impact on the environment. Further to this, the mining industry also realizes that minerals are a non-renewable resource and the contribution to wealth creation from mineral extraction is not everlasting. It serves as an economic boost and careful planning is required to ensure that the legacy of mining is sustainable, and that some of the returns from mining provide continual economic and social prosperity.

Jan 1, 2012

By H. L. Monro

The price received for a commodity decreases as the quantity sold increases. all other factors remaining the same. This has been the position with gold since it was demonetized in August 1971. The result is that the marginal revenue per kilogram of gold decreases steadily with increased production. If operating losses are to be avoided, the marginal cost of production must not exceed the marginal revenue. This requirement, although not seriously violated by most invididual mines, is not met by the industry as a whole, resulting in large losses of income to the State and the shareholders. These losses are increasing, and a way of curbing or reversing this trend is described.

Jan 1, 1984