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By M. J. Ferrante

Relative enthalpies of V20S from 298.15 to 1,101.0 K were measured at the Bureau of Mines to provide data needed for the advancement of min-eral technology. Enthalpies were measured with a copper-block calorimeter. A sharp melting point was found at 951 K, with [~~ = 15.690 kcal/ mol ] for the standard enthalpy of melting. Tabulated values are given at selected temperature increments between 298.15 and 1,500 K for the standard relative enthalpy [(HO -H~98),] heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)/T]. Standard relative enthal-pies are also given in equation form and combined with data from the literature to derive values of standard enthalpies of formation and Gibbs energies of formation.

Jan 1, 1986

By Donald R. Irving

ALTHOUGH the quantity of material handled at metal and nonmetal mines in the United States in 1962 was 2.7 billion tons, the same as in 1961, a larger proportion was waste. At metal mines, crude ore production declined 1 million tons and waste output rose more than 18 million tons; at nonmetal mines crude ore production declined 6 million tons and waste output rose 36 million tons. Copper and iron ore producers increased their share of crude ore and material handled from about three-fourths to four-fifths of the national metals total, and sand and gravel and stone producers in-creased their share of the nonmetals total, also from three-fourths to four-fifths. Six States-Arizona, California, Florida, Michigan, Minnesota, and Utah-each handled more than 100 million tons of ore and waste, and together they accounted for 43 percent of the U.S. total. When the large-volume construction materials (sand and gravel and stone) were excluded from the totals, four States-Arizona, Florida, Minnesota, and Utah-supplied over half of the material handled.

Jan 1, 1963

By W. E. Robinson

Sixty samples, selected from a 2,300-foot core of the Green River Formation in Colorado, were studied to ascertain differences in the structure of the organic material present in the oil shale samples. Emphasis was placed upon relating differences in the aromatic content of the insoluble kerogen and the alkane content of the extractable material obtained from the selected samples. The methods used in determining these differences consisted of fractionation of the soluble material, carbon and hydrogen analysis, volatile material determination, carbon residue determination, oxidation rate determination, and infrared analysis. In general, it was concluded that the organic material in this core does vary in chemical structure and that same of these variations resulted from factors related to depth of burial. Other observed changes in structure of the organic material were not depth-dependent and resulted from other factors such as source material variations, biological alterations, or ecological differences.

Jan 1, 1971

By Peter F. Steidl

As part of the Bureau of Mines methane control program, the Upper Free- port coalbed was studied in Fayette County, Pa., where this coalbed lies about 650 feet below the Pittsburgh coalbed and contains the largest remaining reserves of any coalbed in the county. Coal and overburden isopachs, structure and joint pattern maps, and a fence diagram were prepared using data from gas and oil exploration logs and coal outcrops. These maps will aid in determining the need and/or feasibility of degasifying the Upper Freeport coalbed in the study area. Much of the coalbed in this area is under 600 to 1,400 feet of overburden. By correlation with data from the Pittsburgh coalbed, the gas content at depths of this order is estimated to be between 140 to 300 cf/ton of coal, for a total of 190 to 400 billion cubic feet of methane in this coalbed in Fayette County.

Jan 1, 1977

By Charles L. Kimbell

The concept of data availability must be addressed, because there are perceptible changes from year to year, and the availability of accurately reported, precisely defined statistics and nonstatistical information provides the only sound basis for analytical studies required for government policy planning or industry market analysis. As the countries of Eastern Europe and the former U.S.S.R. undergo the transition from centrally planned economies to market economies, there has been a perceptible increase in information availability for rather obvious reasons. Any industrial operation seeking economic assistance from Government and/or private sources outside the country in which the facility is sited must provide some appraisal of its operations at the time it seeks assistance, as well as some information on previous performance to serve as tools in evaluating its potential under the proposed development scheme for which it seeks financial assistance. Additionally, there was growing governmental recognition that concealment of much of the national mineral production, trade, and consumption data for purposes of national military and/or economic security probably never was very successful, never was really necessary for most commodities, and certainly proved unnecessary with the end of the so-called cold war. Indeed, the long-term unwillingness to publish uniform statistical series of reliable,

Jan 1, 1993

By Margaret R. Egan

The U.S. Bureau of Mines investigated the product-of-combustion (POC) characteristics of combustible materials used in typical coal mining operations in a series of experiments conducted in an intermediate-scale fire tunnel. The materials examined include wood cribs, transformer fluid, coal, conveyor belting, brattice cloth, and ventilation ducting. Smoke and toxic gases evolved from burning materials contribute to panic conditions and hinder escape. Smoke irritates and obscures vision, while toxic gases physically debilitate and disorient the victims. However, POC emissions may be used for early warning fire detection. POC levels will vary not only between materials but also between stages of combustion and the conditions in which they are burning. This report summarizes the POC characteristics of each material and evaluates their effectiveness for early warning mine fire detection. Results show that smoke was the POC most readily detected from the smoldering materials tested.

By E. D. Wilson

This is the second of a series of progress reports describing work undertaken at the San Manuel copper mine to study the geologic factors influencing block caving of the deposit. The first report described the work done from April 1954 to March 1956.3/ This report describes the progress from March 1956 through March 1958 and presents additional maps, factural data, inferences, and conclusions resulting from a continuation of the underground geological work. As outlined in these reports, the study thus far has shown that the principal geologic factors affecting block caving are structure, rock types, alteration, mineralization, oxidation, and presence of water. Structure is fundamentally the most important. Systematic fracturing governed the extent and grade of primary ore mineralization and tangibly affects the subsidence or ground movement, which extends from the mine workings to the surface because of the block caving.

Jan 1, 1960

By D. E. Traut

A fluidized, countercurrent ion-exchange system was developed, operated, and evaluated by the Bureau of Mines in support of its objective to help assure an adequate uranium supply for future national needs. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows are continuous, except for short periods when resin increments are withdrawn. The exchange of uranyl sulfate between a simulated acid-leach-uranium solution and a strong-base, ion-exchange resin was studied, together with subsequent elution using an acidified sodium chloride solution. The effects of the number of compartments, compartment height, amount of resin withdrawal, solution flow rate, and column diameter were investigated. Also examined were the kinetic and equilibrium relationships for the absorption and elution steps. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable in the absorption process, while resin residence time is the determining factor in the elution process. The columns system was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1978

By Ronald S. Conti

This is the fourth and final article in a series that discusses underground fire-fighting preparedness. As with the previous three articles, it is based on interviews with 214 miners at 7 underground coal mines (referred to as Mines ?A? through ?G?) conducted by researchers of the National Institute for Occupational Safety and Health?s(NIOSH) Pittsburgh Research Center[Vaught et al. 1996]. The first article presented an overview of the study conducted by NIOSH on mine fire response preparedness and provided a general perspective on underground mine fires. The second article discussed miners? preparedness to evacuate a fire and their experience with incipient fires. The third article described miners? experiences in fighting underground mine fires and presented their perceptions of training and readiness for fire-fighting. This final article in the series offers suggestions to improve mine fire-fighting preparedness.

Jan 1, 1997

By Brian Kenner, Peter Swanson, Todd Krahenbuhl

NIOSH has developed an automated PC-based seismic event (induced earthquake) monitoring system for use in mine ground control studies. The distribution and coordination of data acquisition and processing functions across a local area network is a central feature of the system. Mine-wide installations utilize multiple, autonomous seismic networks located both underground and on the surface. Seismic event locations, magnitude estimates, and other processed data are distributed for display and analysis on network nodes both underground and in the offices of mine engineers and managers. This paper describes the system’s design philosophy, hardware and software components, examples of installations, and a few observational results.

Improve the safety and reduce the cost of longwall entry support. Approach Replace the conventional wood cribbing with stronger, non-rotting and lower cost cribbing made of steel-fiber-reinforced (SFR) concrete. How It Works Conventional concrete can suddenly fail under excessive compression loads, but adding steel fibers to the concrete, before it is mixed with water, changes the failure mode to a gradual and controlled failure characteristic similar to wood. A system for making SFR concrete crib blocks was designed and developed (or use in constructing walls and cribs to support coal mine roofs. The SFR concrete cribbing is stronger and stiffer than wood, and avoids wood's disadvantages of: flammability, deterioration under chemical or bacteriological attack, methane generation, and relatively high cost. Use of SFR concrete also allows freer movement of miners, equipment, and ventilation air, because much less volume of SFR concrete is required than wood for a given amount of support, and because the roof-to-floor closure is greatly reduced by the stiffer supports.

Jan 1, 1981

By T. E. Gray

This report describes the preparation characteristics of the more significant coal beds in Allegheny County, Pa. It is one of a series planned to determine coals suitable for producing metallurgical coke, either as mined or after beneficiation. More than 7 million tons of coal was produced in Allegheny County in 1957. Of this, more than 5 million tons was cleaned mechanically in nine cleaning plants. The Bureau of Mines estimated that, as of January 1, 1953, more than 384 million tons of recoverable coal remained in the county in beds 28 inches or thicker.

Jan 1, 1959

By T. R. Jolley

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and, from the data developed, to determine: I. Which coals either as mined or after beneficiation by conventional preparation are chemically suitable under present standards for producing metallurgical coke. 2. Which coals require special and more intensive treatment in preparation than is now practiced. 3. Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation by present-day methods. This report is one in the county series that describes the preparation characteristics of the coals of Bell County, Ky.

Jan 1, 1957

By Charles Vaught

This is the second in a series of four articles that discuss underground firefighting preparedness. As with the first article in the May-June issue, it is based on interviews with 214 miners conducted at 7 underground mines (?A? through ?G?) by researchers of the National Institute for Occupational Safety and Health?s (NIOSH) Pittsburgh Research Center [Vaught et al. 1996].In the first article, the authors presented an overview of the study conducted by NIOSH on mine fire response preparedness and provided a general perspective on underground mine fires. In this article, we will describe miners? preparedness to evacuate a fire and their experience with incipient fires

Jul 1, 1997

By Michael J. Brnich

Since 1991, Pittsburgh Research Center (PRC-formerly part of the Bureau of Mines) researchers have recorded extensive interviews with 30 individuals who are experts in the area of mine emergency response. These individuals, who have an average of 35 years of mining experience and 29 years of mine emergency response experience, related stories and observations from events that they experienced during their combined 850 plus years in mine emergency response. The purpose of this effort was to gather information that could be passed on to both today?s and tomorrow?s mine emergency responders to train and guide them in handling future events. This is the first of two articles which report the responses that these experts gave when asked how they think people who may have to respond to a future mine emergency should be trained. During the interviews they discussed how training should be conducted, who should be trained, and what topics should be included. This article will cover the first two areas: what training methodologies would be most effective and who needs to participate.

Jan 1, 1997

By Michael J. Brnich

Since 1991, Pittsburgh Research Center (PRC- formerly part of the Bureau of Mines) researchers have recorded extensive interviews with 30individuals who are experts in the area of mine emergency response. These individuals, who have an average of 35 years of mining experience and 29 years of mine emergency response experience, related stories and observations from events that they experienced during their combined 850 plus years in mine emergency response. The purpose of this effort was to gather information that could be passed onto both today?s and tomorrow?s mine emergency responders to train and guide them in handling future events. This is the second of two articles which report experts responses to questions about training for future mine emergencies. During the interviews they discussed how training should be conducted, who should be trained, and what topics should be included. This article will cover the third area: Topics that should be included in training for mine emergency response managers.

Jan 1, 1997

By D. E. Seizinger

The Bureau of Mines has developed analytical methods, primarily gas chromatographic, for measurement of exhaust oxygenates produced from selected simple fuels. The resulting data were used to estimate levels of carbonyls and noncarbonyl oxygenates in exhaust from gasoline fuels. Estimated noncarbonyl oxygenates in gasoline exhaust may comprise as much as 30 pct of total oxygenates which include unsaturated carbonyls and noncarbonyls believed to be significant potential pollutants.

Jan 1, 1972

This Volume documents the Phase 111 effort on the Seismic Detection and Location of Isolated Miners on Contract H0122026 undertaken during the fall of 1972 by a task team composed of ADL staff and several seismic consultants. The team was assembled specifically to work together on complementary tasks, at an accelerated level of effort for four months, to meet the Bureau of Mines' time schedule for obtaining independent, objective, technical judgments regarding seismic methods and systems for detecting and locating isolated miners. The impetus for this work resulted from a compilation and analysis, during the first half of 1972, of new experimental data obtained from a series of in-mine field tests conducted by Westinghouse Corp .+ using the CMRSS* interim seismic location system. The Bureau of Mines took advantage of the availability of these new data to reassess the potential and limitations of various seismic methods and systems, and to direct its seismic system improvement program accordingly. ADL assisted the Bureau in this reassessment by drawing on the skills of seismic consultants from industry, universities and government, to supplement the skills of the ADL project team. The consultants were principal resources of broadly-based and detailed technical expertise in the areas of seismic signal-source and signal-propagation characteristics, natural and cultural seismic noise, seismic sensors and field instrumentation, seismic signal and data processing for detection and location, and overall seismic system utilization in the field under operational emergency conditions. Specifically, the participating consultants were: F. Crowley, Air Force Cambridge Research Laboratories ; W. Dean, Teledyne Geotech, Alexandria Laboratories; R. Greenfield, Pennsylvania State University; J. Kuo, Columbia University; D. Peters and R. Crosson, University of Washington; and F. Pilotte, U.S. VELA Seismological Center. The principal ADL participants were J. Ginty, R. Lagace, M. Roetter, and R. Spencer.

Jan 1, 1974

By J. E. Dooley

An analytical procedure developed by the Bureau of Mines was applied to the separation and characterization of a 370° to 535° C distillate from Swan Hills (south field), Alberta, Canada, crude oil. Investigators determined the general characteristics of the crude oil by the Bureau's routine method for crude oil analysis. Suitable fractions were prepared for instrumental analyses by utilizing such techniques as isothermal and molecular distillations, chemical treatment, silica-alumina gel chromatography, and gel permeation chromatography (GK). A detailed characterization of the 370° to 535° C distillate was possible by the application of GPC-mass spectrometry correlations and nuclear magnetic resonance spectrometry. Semiquantitative data based on mass Z series distributions were determined and are shown. The data will be valuable in developing future processing techniques and in calculating yields for converting high-boiling distillates into more useful energy forms.

Jan 1, 1973

By Thomas E. Marshall, Gerald L. Finfinger

The Bureau of Mines has developed a practical methodology for deter- mining occluded gas contents of domal rock salt samples. The method, which is portable and field worthy, provides results in 5 min or less and does not require a laboratory environment or specially trained personnel to obtain meaningful results. The results can be used to identify gas-enriched zones, and thus may aid mine operators in production planning or ventilation design. The test method is based on the relationship between gas content and the acoustic response of salt samples as they are dissolved in water. The relationship is defined by an equation, and the results are repeat- able. The equation was derived by testing a series of rock salt samples collected from domal salt mines in Louisiana.

Jan 1, 1987