Search Documents

By James D. Noll, Jon A. Hummer, Aleksandar D. Bugarski, George H. Jr. Schnakenberg, Steven E. Mischler, Larry D. Patts

The National Institute for Occupational Safety and Health conducted a study to determine the effects of selected, state-of-the-art emission control technologies on the ambient concentrations of particulate matter and gases emitted by underground diesel-powered mining equipment. Tests were conducted in an isolated zone of an underground mine to evaluate the effectiveness of alternative fuel formulations, namely, water-fuel emulsions, blended biodiesel fuels, ultralow sulfur diesel fuel, and #1 diesel; and selected exhaust after treatment devices, namely, diesel oxidation catalysts (DOCs), diesel particulate filter (DPF) systems, and filtration systems designed around high-temperature disposable filter elements. The results showed that using a cold-weather and warm-weather water-fuel emulsion formulation reduced mass concentrations of elemental carbon (EC) by about 70% and 85%, respectively. The 20% and 50% soy biodiesel blends reduced EC by 49% and 66%, respectively. The reductions were slightly less pronounced for the 20% and 50% yellow grease biodiesel blends—33% and 56%, respectively. EC concentrations were unaffected by using ultralow sulfur diesel in place of #1 diesel. Use of the reformulated fuels did not substantially alter the concentrations of nitric oxide and carbon monoxide. However, a measurable increase in the nitrogen dioxide (NO2) peak concentration was observed during the biodiesel tests. The ArvinMeritor (AM) fuel-burner DPF system with a palladium-catalyzed DOC reduced EC concentrations by 92%. The diesel filter elements from Donaldson Co., Inc., and Filter Service & Testing Corp. reduced the EC concentration of the mine air by 92% and 70%, respectively. When the palladium-based DOC was used with the AM DPF, it raised the average and peak downstream NO2 concentrations by a factor of three. Tests of the AM DPF system with a platinum-catalyzed DOC and CAP/ETG catalytic particulate oxidizer system had to be terminated because the elevated NO2 concentrations threatened to overexpose the operator. The tests with only a selected DOC also resulted in increased NO2 concentrations in mine air.

Jan 8, 2006

By Joseph P. Flick, Kathleen M. Kowalski, Lynn L. Rethi, Roberta A. Calhoun

Many miners are involved in tasks at the mine site that are similar to those sub-tasks performed in general construction, maintenance and repair (CMR) type work activities. As a result, many of the injuries in the mining industry today can be traced to employees performing these CMR type work activities. Indeed, a recent analysis of a major aggregate company revealed that 65% of all injuries documented originated from performing such CMR activities. It is hypothesized that the number of injuries to miners performing construction, maintenance and repair (CMR) work activities on mine property may be reduced through improved training that focuses on better hazard recognition using the numerous visual and other cues that are available for evaluating workplace health and safety hazards. To this end, researchers at NIOSH’s Pittsburgh Research Laboratory have merged two proven methods of training miners to recognize hazards, stereoscopic (3-D) slides and the concept of degraded images, into this training program. Stereoscopic (3-D) slides have been shown in earlier NIOSH and U.S. Bureau of Mines research to be an effective training aid for improving the ability of miners to recognize various geologic and mining-induced irregularities that can cause groundfalls.3 They realistically portray the natural mine environment, and thus are an excellent training aid for teaching miners to recognize such visual cues. The degraded image concept, originally developed by the military and used for target detection training, describes scenes where the target is partially hidden by cloud cover, dust, rain, natural barriers, buildings, or other obstructions that can camouflage or confuse the target. Research had shown that flight observers who were trained with less than ideal (or degraded) pictures were more successful in subsequent identification of targets than those trained using ideal (or highlighted) pictures of targets. In order to investigate this concept for training miners to recognize hazards, NIOSH researchers developed a prototype hazard recognition training program using such mining scenes. A control program based on traditional highlighted mining scenes was also developed. Both programs were applied to subjects in a field experiment. Results indicated that miners trained with the degraded images did significantly better on a follow-up test of hazard recognition.4 This hazard recognition program teaches trainees to look for hazards in a more realistic manner than that of the control program. This specific training program for CMR activities involves using the degraded image concept and 3-D slides. The module is designed to educate workers on hazard identification techniques and safe work practices. It focuses on teaching miners techniques for recognizing visual (sight) cues, and then uses these cues to evaluate mining conditions. It should be stressed that other senses, such as sound can also play an important role in hazard detection.

Jan 1, 1999

By T. F. Morse, R. Lundstrom, A. J. Brammer, D. Peterson, M. Cherniack, T. Nilsson, J. D. Meyer, E. Toppila, G. Neely, N. Warren

HAVIC is a collaboration of investigators from North America, Sweden, and Finland having a scientific mandate from NIOSH, to study the exposure response relationship between vibratory tool exposure and adverse health effects. Five cohorts, the Suomossalmi forest workers cohort, Volvo truck cab workers, Connecticut shipyard workers, and matriculating dental hygiene students and experienced dental hygienists have been under study. In the case of shipyard workers, there was survey and tool exposure data from 1988, although detailed subject testing was only available within the timeframe of the study. The truck cab assembly workforce was an inception cohort that had been followed from 1994 along with age-matched controls. The Finnish forest workers had cumulative health data on a cohort (n=52) that had been studied from 1976. For a subset of these subjects, there was detailed tactometry testing in 1990, 1995, and 2003. Accordingly, there was historical as well as new prospective data for the industrial cohorts. The Suomossalmi cohort was reassembled only for our study, which precluded follow-up evaluation and because of retirement is almost certainly the last time this historic group will be studied. The study features are: • Characterization of the exposure response relationship for hand-arm vibration through a study design, incorporating multiple cohorts, some having existing historical data, • Selection of cohorts to include different types of vibration: oscillatory (forest workers) impact (truck cab workers), high frequency (dental hygienists) and mixed (shipyard workers), • Inclusion of two inception cohorts: dental hygiene students and Swedish truck cab workers, • Methods for multi-site and historical integration A description follows. [ ] Methods The study included surveys, physical evaluation, and a selection of battery of “best tests” (cold challenge plethysmography, multi-frequency tactometry, segmental sensory nerve conduction velocity [SNCV]1,2,3) applied across groups to quantify responses to exposure. Exposure monitoring included exposure characterization through daylong data logging at the individual level. Workers at each site were instrumented with a microcomputer-based Vibration Exposure Monitoring (VEM) system, developed at the Biodynamics Laboratory of UCHC and about the size of a police walkie-talkie, to record user-specific tool-operating times, vibrations, and grip forces throughout all, or a representative part, of their workday. More specifically, data logging methods involved the direct monitoring of work cycles, involving tool operation time and measures of tool vibration, namely the root-mean-square (RMS), root-mean-quad (RMQ), and root-mean-oct (RMO), and grip forces, each calculated per minute. For this study, the questionnaire was homogenized with other vibration studies4,5,6. Cross-translation was directed by the multi-lingual investigators, and then reviewed by the study team. To extend comparability with future international studies, questions were also added from the Vibration Network (VINET) draft questionnaire, the product of a European

Jan 6, 2006

By W. W. Agey

The Calico silver-barite deposits near Barstow, Calif., are a potentially important resource. Exploration performed by two major mining companies out-lined large tonnages of ore that assayed at 2 to 3 ounces of silver per ton and 7 to 15 percent barite. Laboratory beneficiation work was done by the Bureau of Mines on four samples to develop methods for recovering the silver and/or barite. Cyanidation recovered from 47 to 60 percent of the silver from ore ground to approximately 100 percent minus 325 mesh. Salt roasting minus 10-mesh material, followed by regrinding and cyanidation, recovered 75 to 85 percent of the silver. From 75 to 90 percent of the barite was recovered in a plus 92-percent barite product from either the natural ore or from cyanidation residues. Salt roasting before cyanidation precluded recovery of the high-grade barite concentrate from the leach tails.

Jan 1, 1973

Legislation and Government Programs.-On February 4, 1977, the Occupational Safety and Health Administration (OSHA) issued its final environmental impact statement on the occupational use of inorganic arsenic.2 The statement examined the ramifications of the original proposed standard published in the Draft Environmental Impact Statement (DEIS).3 The DEIS proposed to limit the exposure of employees to no more than 4 micrograms of arsenic per cubic meter of air as determined on an 8-hour-time-weighted average basis; or a ceiling limit of 10 micrograms of arsenic per cubic meter of air based on a 15 minute sampling period. The purpose of the proposed regulation is to reduce the risk of smelter workers developing lung and skin cancer as a result of exposure. A comprehensive study compiled by the Committee on Medical and Biologic Effects of Environmental Pollutants concluded that "there is strong epidemiologic evidence that inorganic arsenic is a skin and lung carcinogen in man."' In April 1977, the Environmental Protection Agency (EPA) served notice to ASARCO Incorporated that its Tacoma copper smelter and associated arsenic-producing facilities were in violation of State laws which limit sulfur dioxide and particulate matter emissions. This notice followed the Washington State Pollution Control Hearing Board overturning a prior ruling by the Puget Sound Air Pollution Control Agency (PSAPCA) which had permitted a 5-year variance from the State of Washington air quality standards. In December 1977, ASARCO appealed in court the decision of the Hearing Board.

Jan 1, 1980

By L. D. Tracy

"Introduction In the course of the investigations by the Bureau of Mines into the various causes of coal-mine explosions, the fact that several gas explosions had occurred during or very soon after a mine was being un-watered, attracted the attention of the Bureau's engineers. The apparent coincidence was so marked that there appears to be an extra hazard present, whenever water, which has been standing against the face of the coal for some time, is suddenly removed either by natural drainage or by mechanical means.Actual Occurrences Case 1. - A typical illustration of this hazard is shown in a gas explosion which occurred in a mine in Central Pennsylvania. Four main entries, 50 feet apart with an average grade of 6 per cent, had been driven with the dip of the coal, and from these mains 7 pairs of entries, at intervals of 800 feet, had been turned at such an angle that their grade was slightly rising. Prom these latter pairs of entries, rooms were turned practically at right angles.The main entries had been driven for 4,500 feet and at the face there was 400 feet of cover. As far as could be observed, the roof was of sandstone and the floor of clay.The coal bed being mined was the Lower Kittanning, which has a thickness of about 4 feet. A typical analysis of the coal in that section is as follows:"

Oct 1, 1924

By G. R. Strimbeck

The Federal Bureau of Mines has been developing processes for producing synthesis gas directly from coal, oxygen, and superheated steam. An atmospheric-pressure pilot plant was constructed and operated to: 1. Determine the operability of the plant for gasifying coals of different ranks under various operating conditions. Listed in decreasing order of rank, these coals included a Pennsylvania anthracite, a bituminous A coal from the Sewickley bed, West Virginia, and a subbituminous C coal mined in the Lake de Smet region of Wyoming. 2. Determine the effect of varying operating conditions on: (a) Standard cubic feet (std.c.f.) of oxygen and pounds of coal of different rank required to make M std.c.f. of product gas (carbon monoxide plus hydrogen); (b) carbon gasified, percent; (c) exit-gas temperature, degrees F.; and (d) heat loss, B.t.u. per pound coal. 3. Compare the gasification characteristics, indicated in item 2, of coals of different rank: Bituminous A, anthracite, and subbiturninous C. 4. Determine the concentration of dust in the gases produced and the efficiency of dust removal, and investigate the relation between the sulfur content in the coals gasified and the gases produced.

Jan 1, 1960

By R. Barany

The heats of formation of gehlenite and talc were determined by hydro-fluoric acid solution calorimetry. The results are reported in terms of the constituent oxides (?H298.15 = -31.1 ± 0.5 kcal/mole for gehlenite and ?H298.15 = -44.9 ± 0.3 kcal/mole for talc) and in terms of the constituent elements (?H298.15 = -952.8 ± 0.7 kcal/mole for gehlenite and ?H298.15 -1,415.5 ± 1.4 kcal/mole for talc).

Jan 1, 1963

By Michael R. Grubbs

The Bureau of Mines is currently developing methods for reclaiming the metal and mineral values contained in unburned urban refuse. One important phase of this research deals with recovering Mastic from shredded refuse using in electrodynamic separation process. The results of this study have indicated that mixed plastic concentrates analyzing 99.4 percent plastic can be consistently recovered from the light material fraction of shredded refuse, leaving a mixed paper traction analyzing 99.9 percent paper. Recovery of the plastic exceeds 99 percent.

Jan 1, 1972

By Margaret R. Egan

In an underground mine fire, a toxic mixture of combustion product gases and particulate matter is transported by the ventilating system endangering everyone downstream. To determine the magnitude of the problem that these toxic combustion products pose, the U.S. Bureau of Mines is investigating the combustion products of typical materials found in underground mines. The total toxicity of the combustion products depends upon the evolving gas species and particulate matter, the amount of material involved, and the ventilation rate. In a simulated mine environment, the products from smoldering poly- vinyl chloride (PVC) brattice and conveyor belting were analyzed for gas concentrations and smoke characteristics. The primary toxic gases are hydrogen chloride (HC1) and carbon monoxide (CO). Smoldering conveyor belts are more detectable than smoldering PVC brattice cloths. These results, combined with previous analyses, are used to estimate relative toxicities, product levels, and detect-ability of smoldering mine combustibles.

Jan 1, 1992

By Donald J. Barnes

The Glacier View RARE Ii further planning area contains no identified mineral deposits, other than stone, which cannot compete favorably with similar deposits closer to major markets. Pierce County mining claim records show six coal claims were located in the study area between 190b and 1907; however, no coal was found at the described locations. Two coal prospects, the H.O. Lamming and Floyd Rice, are within 0.5 mi (0.8 km) of the area's west boundary (fig. 1). At these prospects, impure bituminous coal beds strike approximately north and dip east toward the study area. Analyses of samples 1/ indicated an average heating value of 2,767 BTU 2/ per pound (6,436 joules per kg). Because of the low heat value, this coal is subeconomic. Intense folding and faulting which disrupted the beds would limit the use of conventional coal mining equipment, making future economic development even less likely. Trinity Resources of Houston, Texas has leased approximately 1,404 acres (568 ha) inside the study area and an additional 1,020 acres (413 ha) adjacent to the study area for oil and gas exploration. However, no oil or gas wells are known to have been drilled in or around the study area.

Jan 1, 1983

By J. L. Stauffer, S. L. Lacey, L. J. Gaydos, L. M. Demers, D. C. Kuhn

"Tumor necrosis factor alpha (TNFa) and thromboxane A2 (TXA2) are major products of the activated alveolar macrophage and serve as key mediators of lung injury. In order to determine if the synthesis ofTXA2 and the release ofTNFa are associated, the production of these inflammatory agents by the human alveolar macrophage (AM), as a result of activation by lipopolysaccharide (LPS), was assessed in the absence and presence of the thromboxane synthase inhibitors UK 38,485 (Dazmegrel) and OKY 046. UK 38,485 and OKY 046 inhibited both LPS-stimulated TXA2 production and TNFa release in a dose-dependent manner. Prostaglandin E2 (PGE2) production was not increased by UK 38,485 or OKY 046. Neither LPS nor UK 38,485 had any effect on LT84 production by AM. Neither UK 38,485 or OKY 046 had any effect on LPS-stimulated interleukin-I beta release. However, the TXA2 mimetic, U46619, did not stimulate TNFa release by AM either in the absence or presence of UK 38,485. These findings suggest that 1) UK 38,485 and OKY 046 are inhibitors of both TXA2 production and TNFa release by activated human AM, 2) UK 38,485 probably does not exert its inhibitory action on TNFa release through effects on eicosanoid production and 3) the possibility that TNFa- and TXA2-induced lung injury may be subject to amelioration by imidazole-based compounds should be further evaluated.IntroductionTumor necrosis factor alpha (TNFa), produced by monocytes and macrophages, is a potent peptide mediator of lung injury (1,2). The exaggerated release of TNFa has been implicated in the etiology of acute lung reactions such as septic shock of bacterial or viral origin (3,4). The role of TNFa is expressed primarily through its ability to activate a variety of cell types within the lung environment including polymorphonuclear leukocytes (PMNs, ref. 5), type II epithelial cells (6) and fibroblasts (7). The role of lipid mediators in lung disease has also been extensively characterized (1). In particular, the relationship between pulmonary inflammation and fibrosis and the production of oxygenated derivatives of arachidonic acid (here termed ""eicosanoids"") appears to be a key factor in a variety of disease processes in the lung (8). The alveolar macrophage (AM) synthesizes primarily prostaglandin E2 (PGE2). thromboxane A2 (TXA2) and leukotriene 84 (LT84, ref. 9). These eicosanoids have been shown to produce a variety of effects in the lung including bronchial smooth muscle dilatation (PGE2, ref. 10), vascular smooth muscle contraction and platelet aggregation (TXA2, ref. 11) and oedema and immune cell extravasation (LT84, ref. 12)."

Nov 1, 1995

By T. R. Strombotne

The purpose of this report k to document a contract undertaken by TSA Systems, Incorporated for the United States Bureau of Mines to develop a commercially available source of a continuous, working,, level detector for the measurement of radon daughter products in various working environments. The basic radon measuring technique was devised by Robert Droullard and Robert Holub and has been applied here. For further details or purchasing information contact: TSA Systems, Incorporated 4919 North Broadway Boulder, Colorado 80302

Jan 1, 1982

By Thomas O. Glover

Cameroon's mineral industry continued to be dominated by crude petroleum, The economic development of the country depended on the production and export of crude on. Output was estimated to be 49 million barrels in 1985 compared with 56 million barrels in 1984 and 47 million barrels in 1988. The country's only refinery consumed approximately 12% of the daily production of crude oil while operating at slightly over 50% capacity. The refinery output, however, supplied the domestic need for motor fuel and heating oils. Cameroon's economic prospects were heavily dependent on the oil sector, which bad been responsible for the recent strong growth in the economy. The country consistently sought to avoid the problems associated with an overdependence on oil and followed a relatively broad-based development strategy, using oil revenues to sustain and encourage growth in other sectors. Approximately 75% of the gross domestic product (GDP) was attributed to the mineral industry in some form. GDP growth was approximately 6.5% during 1985.

Jan 1, 1987

By L. M. Demers, D. C. Kuhn

It has been suggested that radicals on the surface of dust particles are key chemical factors in the pathophysiology that results from the occupational inhalation of coal and silica dust. In addition, oxygenated derivatives of arachidonic acid (eicosanoidsJ have been implicated as important biochemical mediator5 of mineral dust-induced lung disease through their role in bronchial and vascular smooth muscle reactivity, inflammation, and fibrosis. Therefore, we assessed eicosanoid production by the rat alveolar macrophage (AM) exposed in vitro to mineral dusts with varying surface chemical characteristics in order to determine if radicals associated with the mineral dust could influence the production of proinflammatory mediators in the lung environment. Primary cultures of rat AM were exposed to freshly fractured or "stale" bituminous coal dust, as well as untreated silica or silica calcined to 500 and 1100°C. Prostaglandin E1 (PGE;V, thromboxane Ai (T}(Ay, and leukotriene 84 (LTB; levels in incubation medium were determined by specific radioimmunoassay. When AM were exposed to freshly fractured coal dust, PGE2 production was markedly increased. In contrast, exposure of AM to "stale" dust significantly reduced PGE1 production. Exposure of AM to freshly fractured coal dust resulted in a significant increase in production by AM, while exposure to stale coal dust did not influence AM TXA1 production. Neither "fresh" nor "stale" coal dust had any effect on LTB4 production. In vitro exposure of AM to untreated silica resulted in a significant increase in TXA1 PGE.,, TXA; and LTB4 production compared with control. However, exposure of AM to silica calcined to 11oo•c resulted in eicosanoid levels that were not significantly different from control. These effects were still apparent 8 wk after calcination of the silica particles. Silica was a more potent activator of AM eicosanoid production than was coal, and amorphous fumed silica was a more potent activator of AM eicosanoid production than was crystalline silica. These findings suggest that radicals associated with respirable coal and silica particles may play a key role in the ability of mineral dust to activate AM eicosanoid production and therefore may be important in the pathophysiological consequences of occupational mineral dust inhalation.

Mar 1, 1992

By A. E. Nagel, J. E. Carpetta, M. G. Zabetakis, T. D. Moore

The method of moving averages was found useful in assessing the nature of methane emission in coal mines. Emission rates were influenced markedly by the presence of abandoned oil and gas wells in the vicinity of the mine. Such wells appeared to increase the flow rate of methane into the mine by a factor of 2 to 30 in an active mine in the Pittsburgh coal seam.

Jan 1, 1972

By W. K. Kleysteuber

This report covers the design and testing of a novel bulk materials conveying device by the Bureau of Mines. The transport concept of the device is to create a traveling wave with a steep front so that the bulk material slides and cascades down the front of the wave with some horizontal motion. Ideally, the front should act like a continuous chute. The concept of moving bulk materials along a belt without any forward movement of the belt itself was demonstrated. The conclusions reached were that the mechanism as designed could not overcome the inherent major disadvantages that would make the undulatory conveyor suitable for practical applications.

Jan 1, 1974

By Alfred E. Schwaneke

An improved maximum-bubble-pressure system using the Sugden twin-capillary method for measuring the surface tension and density of molten metals is described. Improvements include (1) internally ground capillary tips, (2) electronic pressure transducers, (3) micrometer adjustment of immersion depth for density measurements, (4) valuing arrangements to allow operation at other than atmospheric pressure, (5) temperature range to 1,100° C, and (6) recorder readout of pressures. Data for surface tension of mercury from 20° to 300° C are given.

Jan 1, 1970

By G. E. Bobeck

The first year's work of a proposed three-year study of the effects of the exposure of coal mine roof rocks to the mine atmosphere has been completed. The project has been terminated. The goal of the project was to determine if possible the mechanism or mechanisms by which coal mine roof rocks interact with the mine atmosphere and weaken, and coupled with mechanical stresses, ultimately fail. The scope of the study was limited to the effects of environmental factors on the deterioration of the rocks. While mechanical stresses may play an important role in the interaction of environmental factors, stress effects were excluded from the study. In order to study the effects of environment on coal mine roof rocks, samples were obtained from several coal mines in the western states. The rocks forming the roofs of most of the mines visited were shales of varying composition. These shales were subjected to numerous tests to determine how the rocks changed with time after exposure. In addition, the identity of the minerals present in the shales was determined by x-ray diffraction analysis and by thermal analysis as well as by optical microscopy

Jan 1, 1973

By E. G. King

Existing thermodynamic data for compounds of the rare-earth metals are few in number and often inaccurate because, in the past, it was difficult to obtain samples that were pure enough and reasonable in cost--a situation that is rapidly improving. This paper reports the results of low-temperature heat-capacity and high-temperature heat-content measurements for cerous fluoride (CeF3) and supplies the first such published data for a rare-earth fluoride. The low-temperature heat-capacity data cover the temperature range 51°-298° K. and serve to evaluate the entropy at 298.15° K. The high-temperature heat-content data cover the temperature range 298°-1,799° K., including the temperature and heat of fusion. The results are assembled for ready use in thermodynamic calculations. Cerous fluoride is one of the important intermediate compounds in the production of cerium metal.

Jan 1, 1959