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By C. W. Davis

Two general schemes have been used for the determination of gold and silver in material containing considerable quantities of copper ; one is known as the " all fire " method , and the other as the , " combination " , or " wet and dry" method . The all fire crucible method , using an excess charge of litharge , has been found satisfactory when the copper content of an ore is under 6 per cent , ( Loevy , J. , Zur Edelmetallbestimmung in hochprozentigen Kupfererzen : Chem. Ztg . Jarhrg . 35 , 1911 , p . 278 ) , or where the precious metal value is so great that a small sample can be used . In the latter case , silica is added until the copper ratio is sufficiently low . If there is more than 6 per cent of copper in an ore , the lead button obtained from a crucible fusion will require repeated scorification before . it can be cupelled successfully . Rescorification is not only tedious , but also causes a slag loss of precious metals . In combination methods , the copper is dissolved , and the gold and silver in the residue . is determined by fire assay Although some combination methods have given satisfactory results for gold and silver , they are not applicable when an estimation of the platinum metals is required . Since substances containing platinum are frequently high in copper , a study of methods which might be used for the estimation of small quantities of gold , silver , and the platinum metals in such material was considered worth while . The estimation of platinum in ores by fire assay methods has been described in Technical Paper 270 of the bureau; ( Davis , C.W. , The detection and estimation of platinum in ores : U. S. Bureau of Mines Tech . Paper 270 , 1921. ) the present paper , which is supplementary to that report , deals chiefly with the application of combination methods , taking them up to the point where the fire assay is to be applied .

Mar 1, 1921

By D. J. Bauer, V. E. Shaw

Bastnasite concentrate was processed to recover total rare - earth content and obtain high - purity ceric nitrate . Reaction of the concentrate with 45 percent caustic soda for 1 hour at 180 ° C in stainless steel vessels resulted in 99 - percent conversion to rare - earth hydroxides . A drying step followed by solution in nitric acid produced a tetravalent cerium fraction amenable to extraction with TBP . Single- stage separatory funnel experiments resulted in 90 -percent recovery of ceric nitrate at a purity of 99.9 percent . Fractional extraction in pressure - bubbler columns resulted in 98.5 - percent recovery of 99.5 -percent - pure ceric nitrate .

Jan 1, 1964

By T. OnIin, F. F. ApIan

"A study has been made of the surface properties of coals of differing ranks, in their natural state and as modified by the addition of collectors. The evaluation of their surface properties has been done by captive bubble contact angles, water and methylene iodide sessile drop contact angles, zeta potential, point-of-zero charge (PZC) shift, and flotation. .changes in the hydrophobicity of coal is a function of both the rank of the coal and the collecting reagent.INTRODUCTIONThe chemical and physical properties of a raw coal will determine its response to a given beneficiation process. .For such processes as flotation, filtration, flocculation, dispersion, handling, dust supression and agglomeration, however, it is also necessary to consider the surface properties of the coal and mineral matter constitutents of the raw coal. In the case of a specific particle to be floated, it is also necessary to consider the properties of the coal as modified by the addition of some reagent designed to modify (usually increase) the hydrophobicity of the coal surface. General properties of the coal have been well summarized by Van Krevelen (1) and Elliott (2), while the data for the surface properties of coal are much more scattered in the literature (see, e.g.: Parekh and Aplan (3), Gutierrez-Rodrigues et al. (4), Aplan (5), Arnold and Aplan (6), Hogg and Chander (7) and Rosenbaum and Fuerstenau (8)). While a knowledge of the inherent surface properties of a sample are important, of much greater practical significance are the properties of the particle in the presence of a reagent, such as a collector, designed to enhance the hydrophobicity of the particle. This study will focus on the surface properties of coals of various ranks in the presence of a variety of collectors."

Jan 1, 1989

This manual is for use by mine operating personnel and vehicle manufacturers in the selection and proper use of automatic fire protection systems for underground metal and non-metal mining vehicles. Most of the currently available systems are manually operated, dry chemical fire suppression systems. When properly designed, installed, and maintained these systems have proven to be effective both in fire suppression and in withstanding the rugged mine environment. Portable fire extinguishers and manually actuated systems have provided adequate protection for most of the reported fire incidents. However, there have also been incidents where injuries and property losses would not have occurred if the vehicle had been protected with an automatic fire protection system. The need for reliable automatic systems exists when the operator is not present, especially when the vehicle engine is running without the operator in the cab; and also in cases where the operator leaves the vehicle to fight a small fire with a portable and is then forced to abandon the vehicle because the small fire becomes uncontrollable. In the later cases manual systems on the vehicle are never actuated. Although these incidents have been relatively few in number in the past, the increasing use of mobile diesel powered equipment and the related importance of personnel safety, high costs of the mining vehicles, and high cost of down time warrant consideration of automatic fire protection systems. The fire history data and the design concept discussed in this manual were developed under the Bureau of Mines Contract H0252038 which is part of the government's mining research safety program. The purpose of the contract was to develop a low cost, reliable, prototype automatic fire control system for underground vehicles. The industry needs were determined through an extensive mine visitation program, and the prototype system was demonstrated on a vehicle in an underground mine fire test. The system developed under this contract was specifically designed for a load-haul-dump. However, the design concept is applicable to the full general class of mobile underground mining equipment.

Jan 1, 2011

By Edward W. Parsons

The explosive-anchored rockbolt was field tested in six mines where rock conditions varied from incompetent shale or mudstone through fairly soft sand-stone to firm sandy shales. The purpose of the testing was to document, under a wide variety of conditions and in comparison to other rockbolt anchors, the quality of the anchorage produced by the explosive-anchored bolt. In addition, the length, strength, and design of the explosive charge necessary to produce positive anchorage up to the yield strength of the weakest component of the bolt were determined. A l4-inch length beaded explosive charge was found to be suitable, in general, in relatively weak strata, and the length can be reduced in more competent strata. Of the 127 explosive?-anchored bolts tested, 118 bolts produced an evaluated anchorage in excess of 17,000 pounds. Only 4 of 43 expansion-shell bolts and 4 of 14 wedge bolts produced anchorage this good. In preliminary tests, properly coupled explosive-anchored bolts did not ignite an explosive gas mixture. Some minor phases included in the investigation were as follows: (1) effect of explosive-anchored rockbolt on surrounding rock; (2) effect of time on anchored bolts based on torque tests; (3) effect of submersion in water on rockbolt anchorage; (4) pull tests to higher loads; and (5) ignition tests.

Jan 1, 1965

Develop geophysical techniques suitable for enhancing miner safety. Specifically, to use geophysical methods to detect hazardous conditions in a rock mass in deep underground mines as well as to assess the mechanical integrity and monitor changes of the rock.

Jan 1, 1997

By Ivette E. Torres

World investment 10 all mineral and mining industry sectors is not available. However, partial information available provides some information useful for analysis. Information available in this section covers limited geographic information on investment in the steel industry, limited information for petroleum industry capital spending, and total U.S. foreign investment in comparison to the mineral-related sectors (tables 13, 14, and 15). Annual steel industry investment is available for the European Community, almost all countries within the European Free Trade Association (EFTA), Latin America, and other countries with significant mineral industries, such as Canada, Japan, and the United States. Although information was not available for 1992, data for 1991 indicate that for those countries aforementioned, total investment increased by 8 %. However, investment patterns were very different within the different groups of countries. While the European Community had a net increase of 12 %, dominated by an almost °40 % increase in Germany, EFTA member countries had a 26 % decrease in investment for the same period. Investment in EC countries was almost seven times that of EFT A countries. Japan's investment in the iron and steel industry, by far the largest of those available, almost twice that of the EC and almost four times that of the United States, increased by more than 20 %. In North America, investment in Canada and the United States decreased. Almost all of Latin America decreased investment in the sector. The notable exception was Mexico, with a 60 % increase. Changes in Mexico's investment policies of the recent past, its economic growth, and privatization of its iron and steel industry are some of the reasons for such an increase. The other country covered individually in Latin America, where investment in the iron and steel industry increased, although slightly, was Argentina. This limited information does not allow a comprehensive analysis of global industry trend, which in turn impacts many other mineral commodities, and with the transition in many countries within Europe and Central Eurasia that are now effecting the steel industries of the countries that were members of the U.S.S.R. and its CMEA partners, it is most regrettable that comprehensive and comparable data, both current and historic, on investment in this area are not available.

Jan 1, 1994

By F. S. Kendorski

This report covers the work on developing criteria for determining when a hazard exists when mining stratified mineral deposits beneath bodies of surface water. The nature of water bodies is considered, the disturbance to the strata induced by mining is described, inundation case histories reviewed, reasonable water inflows derived, and methods of mining to prevent or minimize the hazard are presented. Criteria are given whereby effected industries and agencies can recognize a potential hazard and plan a mine accordingly, releasing considerable mineral reserves otherwise considered unminable.

Jan 1, 1979

By Edward P. Barrett

This investigation was a part of the Bureau of Mines program for the production of critical and essential materials needed for the war. The Boykin Committee for investigating the steel shortage aided in obtaining an appropriation to be expended by the Bureau of Mines in studying the utilization of North Dakota lignite in the manufacture of hydrogen that could be used in the production of sponge iron from the low-grade iron ores of Minnesota. This investigation was conducted by the Bureau of Mines to determine the workability of the proposed shaft-furnace process and its possible use in connection with an experimental plant for the gasification of lignite operated by the Coal Division of the Bureau of Mines at Grand Forks, N. Dak.

Jan 1, 1948

By Natesa I. Jayaraman

This report describes recent improvements the Bureau of Mines made in the design of its shearer-clearer water-spray system for dust control on lonwgall shearer faces. The improvements were based on findings from a field survey of six mines and laboratory test results. The report in-cludes information on installation and use of the improved shearer-clearer system and describes a field installation and 3-week underground test of the system. The improved shearer clearer, like its predecessor, reduces dust concentrations in the shearer operator's walkway by splitting the airflow on the upwind side of the shearer and confining the dust cloud to the face side of the shearer. The improved shearer-clearer system utilizes more practical-mounting locations for the water sprays and requires less water consumption. In the underground test, the improved system maintained the clean-air split in the walkway up to 40 ft downstream from the shearer. To further improve dust suppression, cooling-water manifolds were relocated into the loading zone. The laboratory and underground tests showed that the improved shearer-clearer system and the techniques described can significantly reduce the respirable dust exposure of shearer operators from shearer-generated dust.

Jan 1, 1985

By John S. Berber

Olefin and paraffin mixtures (C10-C16 and C10-C22) were separated from low-temperature lignite tar by urea adduction and sulfated to yield secondary alkyl sulfate detergents. The C10 ?C16 secondary alkyl sulfate showed a 99.3 percent biodegradability, and the C10-C22 fraction showed a 96.8 percent biodegradability, exceeding the required standard of 80 percent for the biodegradability of anionic detergents in washing and cleaning compounds. Chlorination of paraffins yielded a detergent of 93.2 to 93.4 percent biodegradability.

Jan 1, 1968

By Alla D. Mah

The heats of combustion of three chromium carbides, Cr23C6, Cr7C3, and Cr3C2, were determined by combustion calorimetry. Heats of formation calculated from the results follow: ?Hf°298 (Cr23C6) = -94.7 ± 5.0 kcal/mole, ?Hf°298 (Cr7C3) = -43.3 ± 1.7 kcal/mole, and ?Hf°298 (Cr3C2) = -22.5 ± 0.8 kcal/mole.

Jan 1, 1969

By F. P. Haver

The purpose of this investigation was to determine the effect of common impurities, that is, oxygen, nitrogen, carbon, and iron, on the Brinell hardness of electrolytic titanium. On a weight basis, nitrogen had the greatest hardening effect, followed by oxygen, carbon, and iron in order. The hardening effects of oxygen and carbon were almost identical up to a concentration of approximately 0.1 percent by weight. Above this concentration, the relative hardening effect of carbon decreased rapidly, possibly because of its limited solid solubility in a-titanium. Hardness vs. composition curves for both oxygen and nitrogen were essentially straight lines over the range of Brinell hardness numbers (B.h.n.) covered in the investigation. The hardness of titanium was also determined as a function of the percentage of impurity atoms. On this basis, iron in concentrations up to 0.17 atomic percent had a greater hardening effect than either oxygen or carbon. INTRODUCTION Determination of the as-cast hardness of arc-melted titanium is a method of quality control widely used in industry. Numerous studies4/ have been made of the effect of impurities on the hardness obtained by this method. However, most of them have been based on the use of either iodide titanium or commercially pure Kroll sponge (B.h.n. >90), as a starting material.

Jan 1, 1959

By Foster Fraas

This Bureau of Mines report describes a method for separating minerals at magnetic susceptibilities within the diamagnetic susceptibility range. The maximum feed rate varies directly with the square root of the lower limit of permissible susceptibility, while the lower limit of permissible susceptibility varies inversely as the square of the magnetic field strength. Minerals may be separated at particle sizes smaller than possible on conventional dry-type magnetic separators.

Jan 1, 1969

By Irving Kabik

Chlorates and perchlorates, when mixed with certain reducing materials, may give a detonating explosive of considerable power. Concerning explosive chlorate mixtures, Guttman3/ states that they "have at all times fascinated inventors on account of the large amount of oxygen stored up in potassium chlorate, which can be given off so readily. When Lavoiser and Berthollet tried to make a chlorate powder in a stamp mill in 1788, they made a great show of it, and even two ladies were present. Unfortunately, after a certain amount of pounding the powder exploded and killed an official and the daughter of the Government commissary, who assisted at the experiments.***. It is interesting to observe how the same old mixtures are proposed over and over again with slight alterations only, in order to qualify for a patent. Potassium chlorate with some carbonaceous matter like charcoal, sugar, starch, glycerin, flour, or sometimes a vegetable or mineral oil and the like occurs again and again." Sprengel explosives, in which some of the undesirable sensitivity of the chlorate was minimized by coating the crystals with a liquid reducing agent, received some attention after a patent was issued to Dr. Herman Sprengel in England in 1871.4/ A somewhat similar explosive, known as Rack-a-

Jan 1, 1945

By L. E. Schultze

[The Bureau of Mines conducted bench-scale studies to develop techniques for stripping tetravalent cerium from tri-n-butyl phosphate solutions. Experiments were conducted in a constant-temperature bath using beakers and mechanical stirring. Ninety-five pct of the cerium was stripped from a 50-pct tri-n-butyl phosphate 50-pct kerosene solution containing 0.18 M cerium in 15 minutes at 50° C using 0.11 M aqueous formaldehyde.]

Jan 1, 1974

By Russell R. Trengove

Bureau of Mines exploration at the property of the Tulare County Tungsten Mines was by core drilling from the surface from May 16, 1950, to July 13, 1950. The property is in the western foothills of the Sierra Nevada Range, 18 miles northeast of Lindsay, Calif. It has been in almost continuous production since 1942 and has produced 40,831 units of tungsten trioxide (W03) with a grade of approximately 67 percent. The work performed comprised a study of the geology, mapping the area, sampling the outcrops, and diamond drilling the area adjacent to the mine workings. Ten holes were drilled for a total of 1,824 feet. Ore reserves were found to be confined to tactite zones in a surface area approximately 250 by 400 feet and extending downward about 350 feet.

Jan 1, 1956

By J. K. Whyatt

The Bureau of Mines, under a cooperative agreement with Callahan Mining Corp., measured rock displacement at the 4,7S0-ft level of the 5,100-ft-deep rectangular, timbered Caladay Shaft in northern Idaho. Displacements were measured with multiple-position borehole exten-someters (MPBX) installed 4 ft above the face and timber extensometers (TE) installed with the timber sets. This report presents the displacement data along with preliminary, qualitative observations of rock behavior. The measured displacements showed an instantaneous response to shaft sinking and significant time dependency. The relative magnitudes of displacement measured at the shaft walls were heavily influenced by local geologic structure and distance from the shaft bottom.

Jan 1, 1987

By J. A. McAllister

In the course of a study of domestic Manganese resources, 2-ton representative samples of ore were taken by Bureau of Mines' engineers from the Payday claim, Weber County, and the Newcomb-claims, Rich County, Utah. The Payday No. 1 deposit is situated 13 miles northeast of Huntsville, Weber County, Utah. The manganese ore is a. replacement deposit in limestone and consists of manganese oxides imbedded 'in clay and also as the cementing agent consolidating small pebbles and pieces of quartz and limestone.

Jan 1, 1949

By D. J. Bauer

A pure scandium solution was concentrated from 10-4 mole per liter to 0.5 mole per liter by continuous foam fractionation in a spaced, packed column. Recovery in the foam was 77 percent using a spaced, packed draining column with sodium n-methyl-n-"coconut oil acid" taurate as the surfactant. The technique was first studied batchwise in a small unpacked column to determine the more important variables. Optimum surfactant concentration was found to depend on scandium concentration. Extraction and, in general, enrichment ratios were highest in the 2.5 to 3.5 pH range at temperatures ranging from 50° to 70° C. An airflow rate of 136 ml./min. was satisfactory in the equipment used.

Jan 1, 1962