Search Documents

By D. A. Wilson

A laboratory method for processing lead battery scrap has been developed that eliminates virtually all of the S02 emission that normally is produced when a reverberatory or blast furnace is used. The method employs a hydrometallurgical step to convert the PbS04 to PbO and CaS04 by mixing the battery scrap with a slurry of Ca(OH)2. The reaction is exothermic and goes to completion in 2 to 5 minutes at room temperature. The dried product is mixed with a KC1-NaC1 flux and carbon and reduced at 6500 C. A minimum charge ratio of 3 parts of carbon to 100 parts of battery scrap is required for reduction. The process produces lead reductions and recoveries as high as 97.0 and 94.9 percent, respectively. The KCI-NaCl flux is recovered using a standard counter-current water leach followed by evaporation.

Jan 1, 1976

By C. M. McKinney

This report contains Bureau of Mines analyses of 291 samples of crude petroleum from the Gulf Coast Area of Louisiana and Texas. Included are 65 analyses from 51 Louisiana fields and 226 analyses from 216 Texas fields. Analyses from the Texas fields include 90 from 58 Upper Gulf Coast fields, 47 from 28 Middle Gulf Coast fields, and 89 from 40 Lower Gulf Coast fields. The analyses represent fields that produced 1,000 barrels or more per day during at least one of the years 19.57 through 1961, with the exception of 23 analyses from the Texas fields. The fields considered are listed by state and geographical groupings, with field names arranged alphabetically within each grouping. The tabulation also includes information concerning the geological sources of the samples. General characteristics of the crude oils and analytical and computed data determined from the analyses are summarized. Crude oil production data are given for the fields for 1960 and 1961 and are cumulative through 1961.

Jan 1, 1963

By M. C. Malamphy

A general description of the activities and results of bauxite investigation by the Bureau of Mines at its bauxite project in Saline and Pulaski County, Ark., has been given in Report of Investigations 4251. The factual data obtained during the project are reported in a series of Reports of Investigations beginning with No. 4251, of which this is the eighth. The data are accompanied by maps showing the location of holes drilled and the deposits developed. Each area upon which work was done is reported by half townships. Each bauxite deposit investigated was assigned a name and a number for ready reference and identification, and its location and name are shown on the appropriate half-township map. The description of each half township is no followed by a description of each deposit developed in that half township. The 14 half township maps and 77 detail maps of the bauxite deposits in this series of reports give the locations and numbers of all the holes drilled on the project, except the deep holes drilled to test the geophysical anomalies. The locations at those holes show on figure 13 in volume I. The descriptions of the deposits developed are followed by complete detailed logs at the drill holes. Many at the widely spaced exploratory holes did not discover bauxite of minable thickness and gra.de. The pertinent information obtained from the widely spaced exploratory drill holes has been summarized and tabulated, and a table for each halt township is given with the discussion covering that area.

Jan 1, 1948

By R. L. Cosgriff

A commercial, battery-powered mine vehicle has been equipped for remote operation in coal mines. This vehicle is controlled by an operator from the remote station. Command signals originating at the remote station as well as video and data signals originating on board the vehicle are relayed between the remote station and vehicle using a single coaxial line. This coaxial line is normally 2,000 feet in length and is reeled in and out from a drum mounted aboard the vehicle The vehicle has a maximum speed of 6 ft/sec and a minimum speed of 4 ft/sec using 36-volt excitation of the traction motor. If this traction motor is excited by two of the three batteries, 24-volt excitation, the vehicle will travel at approximately 2 ft/sec. The speed can be reduced by the operator to 1 ft/sec. This vehicular system has been tested in coal mines. Presently, the major limitation of this system is associated with fatigue failure of the splices in the coaxial line and lack of mobility caused by its 3-wheel design.

Jan 1, 1974

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) spin trapping experiments have been carried out to investigate the mechanism of sulfite oxidation em¬ploying 5,5-dimethyl-l-pyrroline-1-oxide (DMPO) as a spin trap. The results show that sulfite autoxidation, catalyzed by Mn(II), involves not only the SO-3 radicals but also the •OH radicals. An addition of H2 02 to the sulfite aqueous medium significantly increases the •OH radical formation. This result provides new clues to the chemical mechanism of the sulfite oxidation and the sulfite toxicity.INTRODUCTIONStudies of the oxidation of the sulfite (SO 2-/3) ions under various conditions are of high current interest because excessive exposure to sulfite is toxic and the origin of this toxicity seems to involve sulfite oxidative pathways [1]. An important fact is that human exposure to sulfite is on the increase [1,2]. Some of the increase in the sulfite exposure is linked to the fact that SO2 is a major air pollutant [2] and in aqueous media SO2 exists in equilibrium with SO2-/3. In addition, beverages and foods are common sources of sulfite intake. For example, sulfite is used extensively in the wine industry as an inhibitor of yeasts and bacteria and is present in finished wines in concentrations up to 6 mM [1]. Sulfite is also often added to dehydrated fruits, vegetables and soups, as well as fruit juices and beer [1,3,4]. Because of these, the mean daily intake of sulfite from diet (in the United States) has been estimated to be between 0.0014 and 0.14 mM/kg body weight [1]. At such high levels, sulfite exposure can have toxic effects, such as the induction of an acute asthmatic state [5,6]. Sulfite also appears to have adverse genetic effects [7] and can act as a mutagen or comutagen [8] and a cocarcinogen [5,7-9]."

Jan 1, 1990

To design an apparatus that advances the state of the art in gas content testing equipment. The goal of the design is to incorporate improvements in testing sensitivity/accuracy, durability, and ease of operation over existing equipment. It is also desirable for the new design to successfully perform gas content determinations of multiple chemical species from a rock sample.

Jan 1, 1999

[RESULTS OF THE PRIMARY CONVENTIONAL PERFORMANCE AND COST MODEL OF THE UNIT OPERATIONS OF UNDERGROUND PERCUSSIVE DRILLING AND BLASTING]

Jan 1, 1977

By D. W. Bridges, L. Crocker, R. O. Dannenberg

About 95 pct of the beryllium was dissolved from most ore samples by agitation leaching with 600 lb of H2SO4 per ton of ore for 24 hours at 65 ° C and 35 pct solids . Leach slurries generally were viscous , and the limiting pulp density for thorough mixing was about 35 pct solids . Settling of the leached pulp required 0.6 to 0.8 lb of a polyacrylic flocculant per ton of ore leached with 600 lb of H2SO4 per ton , whereas ore leached with 800 lb of H2SO4 per ton required only 0.2 to 0.3 lb of flocculant per ton . Terminal densities of the settled pulps were about 28 and 35 pct solids , respectively , from leaches using 600 and 800 lb of H2SO4 per ton . Vacuum filtration of settled pulps at 15 in . Hg resulted in a filter cake containing 50 to 59 pct solids . Roasting the ore at 500 ° C before leaching increased the limiting pulp density for effective mixing to 50 pct solids . Acid requirements , however , were not diminished , although leaching roasted ore with 600 lb of H2SO4 per ton resulted in densification of settled pulps to about 40 pct solids . Filter cake from leaching preroasted ore contained about 20 pct less water than that from unroasted ore .

Jan 1, 1963

By Andrew Allan

During recent years underground production for the Pennsylvania anthracite region has reached the lowest output per man per day figure of the last decade and a half. This fact, combined with increased unit costs for labor and material, has forced the market price of anthracite ever higher. Over the years the mines have become deeper, and haulage distances have increased, thus adding to the mining costs. The industry now recognizes the need for new mining techniques to offset increasing costs. The Federal Bureau of Mines, through its Anthracite Research Laboratory, is engaged in a program of underground-mining research in cooperation with anthracite-producing companies to aid in reestablishing the economy of the region by introducing methods and/ or machines that will reduce underground-mining costs and, at the same time, enhance the safety of the workmen.

Jan 1, 1953

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous selective flotation tests of barite-fluorspar ores from two deposits near Marion, Ky., to determine the technical feasibility of recovering commercial grade fluorspar and barite concentrates. The lignin sulfonate-sodium fluoride method of floating the fluorspar successfully produced acid-grade fluorspar concentrates. Flotation of the barite from the fluorspar tailing using petroleum sulfonate collector yielded concentrates suitable for use in compounding oil-well drilling mud. The fluorspar and barite recoveries were about 82 and 85 percent, respectively.

Jan 1, 1963

By A. L. Engel

Production of chromite in California has been from many small, high-grade mines. The opening of the Purchase Depot at Grants Pass, Oreg., in 1951 has stimulated chromite mining in California, and a large number of properties are being reexamined as there is a possibility that some low-grade ores from many of these properties can be beneficiated to meet the purchasing schedule. The Bureau of Mines in its program of conservation is continuing ore-dressing tests on chromite ores to better evaluate their potential. This report is a compilation of preliminary concentration tests on samples from five different properties in California. The concentration tests were made on ores from the David mine, Butte County, the Seiad Creek mine, Siskiyou County, the High Plateau mine, Del Norte County, Bud's mine, Tuolumne County, and tailings from the Miller concentration plant in San Luis Obispo County, Calif., to determine the possibility of beneficiating these ores so that they will meet the specifications for the Government stockpile.

Jan 1, 1956

A preliminary research and development program dated April 25, 1974, was prepared for Development Engineering, Inc. (DEI) for laboratory, field and other engineering studies on the disposal of retorted oil shale. This program was revised and published as a final document dated December 17, 1974. The document included discussions on the peculiarities of retorted shale materials to be investigated and discussions of the various laboratory and field tests which would need to be conducted to define their physical and chemical properties. The proposed research and development program was divided into eight work phases as follows: I Program Development. II Exploratory Laboratory Tests on Old U.S.B.M. Retorted Shale. III Laboratory Tests on Pilot Plant Retorted Shales. IV Laboratory Tests on Retorted Shales from the Semi-Works Plant.

Jan 1, 1976

By William R. Roy

Seven coal-related waste samples (mining, cleaning, and gasification) were characterized chemically and mineralogically. Laboratory extracts of each sample, using a variety of different extraction methods, were used in both acute and chronic bioassays. A coal slurry sample (coarse fraction) and two coal cleaning refuse samples were chemically and mineralogically similar, and generated acidic water-waste systems, both in the laboratory and in the field. Acidic laboratory extracts and field samples of acid mine drainage in the area where the solid samples were collected, tended to be in equilibrium with some type of CaSO4 phase and with maghemite. The chemical composition of the extracts was sensitive to the method used to generate the extracts, but generally had the same prevalent chemical character as the field samples. The acidic wastes contain appreciable quantities of soluble Al, Mn, Ni, SO4, and Zn as indicated by both laboratory extraction and field data. Long-term extractions suggest that some constituents (Al, Fe, SO4) continued to be released by the acidic wastes after 22 weeks with no apparent associated change in pH. Two mine spoil samples, essentially shale, tended to generate water-waste systems that were neutral in pH and consequently released lower quantities tit potential pollutants than the acid wastes. The gasification residue was compositionally similar to coal-fired power plant slag and fly ash and generated moderately alkaline extracts with low concentration of soluble potentially toxic constituents. All of the solid wastes contained a variety of organic compounds, many of which are on the EPA Priority Pollutant List. However, these compounds were essentially insoluble in aqueous media. Each extract was tested for acute toxicity with tour species of freshwater aquatic organisms; green sunfish (Lepomis cyanellus), fathead minnow (Pimephales promelas), a crustacean (Daphnia magna), and a snail (Physa anatina). The extracts of the two mine spoil samples and of the gasification residue were not toxic to any of the organisms while the extracts from the acidic refuse and slurry samples were acutely toxic to all of the organisms. For all cases, pH was significantly correlated to mortality while Al, Fe, Mn, Ni, and Zn were significantly correlated to mortality in specific instances. Data from 96-hour LC-50 determinations showed that dilutions up to 1:1000 were necessary to eliminate mortality. The most toxic extracts were those with the lowest pH which necessitated the largest amounts of dilution to eliminate mortality. Chronic bioassays with the same test organisms were investigated with leachate samples from a relatively unweathered refuse sample and an older, more weathered refuse sample. The unweathered refuse sample generated a leachate that was acutely toxic while the leachate from the weathered refuse sample was not acutely toxic. No detrimental chronic effects were noted in organisms exposed to dilutions of the non-toxic leachate while low concentrations of the acutely toxic leachate produced lower hatchability for the Lepomis cyanellus and Pimephales promelas eggs, increased mortality with chronic exposure for Lepomis cyanellus, Daphnia, Physa, and reduced weight gain for Physa. Dilutions of a toxic, high-Fe leachate resulted in the precipitation of ferric hydroxide that was implicated as the major causative factor accounting for the physical and physiological toxic effects exhibited by all of the test organisms in these acutely sublethal concentrations. The toxicity of this leachate demonstrates the potential effects that these types of wastes can have on the aquatic ecosystem if they enter a receiving water in a natural setting.

Jan 1, 1984

By J. R. Boyle

The Bureau of Mines developed cost estimates fur the disposal of phosphate rock washer slimes by pond settling, from a study of the method used at the International Minerals a Chemical Corp., Moralyn Phosphate Operations, Polk County, Fla. Data were obtained by basing phosphate production and slime generation statistics on plant capacity rather than on actual company records. Cost estimates, which were prepared as a guide in evaluating alternative disposal methods and in identifying needed areas of research, could be applicable to any Florida plant using the same disposal method. To conserve mineral resources and to improve environmental conditions, the Bureau recommends further research directed toward developing alternative methods of disposal, including the recovery of water and P205 values from the slimes.

Jan 1, 1969

By Foster Fraas

Review of the literature on solid solutions discloses that the relation between composition and magnetic susceptibility is not linear . Recalculation using a transformation of composition values to parameter v values provides for a linear relation with the magnetic susceptibility to the 1/2 power . Application to minerals is illustrated by the olivine and enstentite series .

Jan 1, 1964

By R. V. Lundquist

This report describes results of tests on the desilication of solutions resulting from the leaching of lime-soda sinters. Desilication was accomplished by heating the solutions in an autoclave. A liquor relatively free of silica was obtained after 30 minutes of heating at 200 p.s.i.g. in the presence of lime. The addition of lime improved desilication, but the rate and efficiency of desilication was effected by the quality of lime used. The optimum quantity of lime for effective desilication was about 6 grams per liter. A lesser quantity gave poorer desilication, and a greater quantity increased the alumina loss without improving desilication. The alumina loss was approximately proportional to the lime added. A complex structure, called artificial noselite in this report, was the only silica bearing compound detected in the desilication precipitate. Other compounds present were Ca(OH)2 (calcium hydroxide), CaCO3 (calcium carbonate), and Ca [A1(OH)6]2 (hydrated tricalcium aluminate). Sodium carbonate in the leach liquor retarded the formation of the calcium aluminate; hence it decreased the alumina lost to the precipitate. The extraction of alumina from aluminum silicate materials by the limestone soda-sinter process has been investigated by the Bureau of Mines for many years. The process consists of the following major operations: Blending the aluminum silicate with limestone and soda ash in such proportions that dicalcium silicate and sodium aluminate are formed on sintering; leaching the sinter in a carbonated caustic solution to extract the soluble alumina; purifying the leach liquor by the precipitation of soluble silica (this precipitate is designated desilication precipitate in this paper); precipitating alumina trihydrate from the purified liquors by carbonating with carbon dioxide gas; and calcining the trihydrate to alumina. Commercial grades of

Jan 1, 1962

By Charles L. Kimbell

In overview, 1988 appeared to be the best year for the world's mineral industry since 1980, although the all-important petroleum component suffered severely from low prices. With this notable exception, the traditional statistical measures of mineral industry performance, namely production, trade, and consumption, reflected growth in most elements of the world mineral industry from crude material extraction through the gamut of downstream processing. Moreover, the growth was reasonably well distributed geographically, with many countries sharing in the substantial upturn in activity. World crude mineral output value was estimated at over $1,272 billion in current dollars ($1,090 billion in constant 1983 dollars). The value added by the processing component of the mineral industry raised the total value of the industry's output to an estimated $3,057 billion in current dollars ($2,620 billion in constant 1983 dollars). Less easily assessed was the value of mineral commodities moving in 1988's international world trade, particularly because of the declines in world crude oil and refinery product prices. It remained to be seen if increased volume and value in nonfuel mineral and coal exports, coupled with an increase in the volume of oil exports, would be adequate to offset the drop in oil prices. Whether or not the value of world mineral commodity trade topped the 1987 level of over $498 billion, an increase in the volume of mineral commodity trade was almost assured. Similarly, although comprehensive statistics were not avail-able on consumption of all mineral commodities in all countries, available data on selected major commodities in selected major countries suggested that not only had output of most mineral commodities advanced, but so too had consumption levels for most commodities.

Jan 1, 1990

By A. R. Mumford

During the course of an investigation conducted by the fuel section of the Bureau of Mines , on a hand- fired return- tubular boiler plant , it was found that the average cost of fuel to produce 1,000 lb. of steam was $ 0.5287 . Tests conducted after some simple changes had been made in the furnaces , and in the control of the boilers , showed the previous high cost of fuel per 1,000 lb. of steam could be reduced to the reasonable figure of $0.3540 , or the equivalent of over 30 per cent saving in fuel cost .

Mar 1, 1923

"INTRODUCTION Early in 1936 the Interstate Oil Compact Commission and other groups interested in forecasts of demand for petroleum requested the Bureau of Mines to make a physical inventory of crude-oil stocks in the United States, Accordingly, the 74th Congress appropriated funds for conducting such a survey during the fiscal year ended June 30, 1937. In the discussions and hearing 2/ relative to the need for the survey, the opinion was expressed that crude oil held in storage for long periods had lost so much of its gasoline content that the economic significance of total stocks should be discounted materially. Therefore, a primary objective of the survey was to make a physical inventory of the crude oil held in storage above ground and to determine the quantities and characteristics of the light fractions contained in the various stocks."

Sep 1, 1938

By Forrest T. Moyer

THE injury data and experience in this bulletin are presented in three general sections. The first section contains general and detailed data relating to 1948 injury experience in bituminous-coal and Pennsylvania anthracite mines, separately and combined into totals for all coal mines. The related employment, worktime, production, and productivity data are given in each breakdown of the statistical data. Tables 1 through 22 constitute a subsection and present statistics on number of injuries, frequency and severity rates, average severity, detailed and major causes of injuries, injury records of the coal-producing States, distribution of injuries by part of body, and distribution of injuries by days of disability. Tables 23 through 45, the second subsection, present injury experience in bituminous-coal mines by various selected factors of physical or operating conditions that ma contribute to the occurrence of injuries. The degree of mechanical loading, productivity, size of mine by number of men working and by tonnage mined, thickness of bed, length of shift, number of shifts, type of cap lamps, rating of mine as gassy or nongassy, type of ventilation, and combinations of these factors influencing mine safety are presented in this group of tables. Similar data on Pennsylvania anthracite mines are listed in tables 46 through 63, which comprise the third subsection. The second section of the report contains the generalized annual injury records of bituminous-coal, Pennsylvania anthracite, and all coal mines from the earliest available data through 1948. Tables 64 through 97 list the number of fatal and nonfatal injuries, injury rates, and causes of injuries on an industry basis, the long-term injury records of each coal-producing State, and the related employment, worktime, and production data.

Jan 1, 1952