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By M. Bustillo, S. Ordonez

"Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The Mississippi Valley-type deposits occur in massive, homogeneous dolostones from which diagenesis has obliterated all primary sedimentary structures. The mineralisation forms irregular, lens-shaped stratabound bodies, mostly in the lower part of the dolostones. They are composed exclusively of sphalerite, galena, pyrite, marcasite and barite, with white sparry dolomite a common cementing phase. Mineral zoning can be recognised from pyrite and marcasite in the east to barite in the west. Sphalerite, the most common sulphide, occurs basically as colloform and banded crusts and galena as isolated cubic or skeletal crystals, mainly in the centre of the banded botryoidal sphalerite. The combined observations of the deposits' geology, geochemistry and ore petrology suggest a three-stage genetic model: carbonate sedimentation in a shallow-water environment; dolomitisation, probably after compaction, by fluids of connate origin and lateral evolution; and mineralisation by migrating solutions, perhaps related to oil-field brines, that originated in deep zones of the basin during diagenesis of the basinal mudrocks in the NE"

Apr 1, 1995

By S. Kelebek, J. A. Finch, Zhenghe Xu, S. R. (Ram) Rao

To improve SO2 emission compliance, pyrrhotite from Sudbury copper-nickel ores is being depressed with DETA. To understand the mechanism of depression, the role of complexing in controlling metal-ion activation of pyrrhotite was investigated. DETA was found to remove Cu and Ni ions but leave hydrophilic ferric species on the pyrrhotite surface. The metal:DETA ratio appeared to be 1:2. Cu was more readily removed than Ni, but the combination of DETA with sulphur dioxide was equally effective for both metal ions. Certain combinations of DETA, Ni ions, xanthate and dithionite (S2O4) or dithionate (S2O6), as representative derivatives of SO2 in water, produced hydrophilic precipitates. These may enhance pyrrhotite depression

Jun 19, 1905

By P. H. Carr, G. G. Marino, K. A. Patel

Extensions to a correctional institution at Wabash Valley, Indiana, required development over abandoned coal-mine workings, at 90 m depth, where subsidence was possible at surface. Backfilling of the flooded mine in critical areas was determined to be the most cost-effective method of limiting the risk of damage to the buildings. Containment grout was first placed in selected entries and cross-cuts of each mine area; the remaining volume was then filled with a readily flowing infill grout. Where a high proportion of an area was taken up by rubble, calcium lignosulphonate was used as a retarder and plasticiser to increase penetration. Grout movement was monitored from adjacent boreholes with an electrical resistivity probe during grouting, while after the work was finished core samples were obtained from verification holes drilled in the backfilled areas

Jun 19, 1905

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Phases of the Ir sub-group are present either as inclusions in or interstitially to chromite and are unaffected by (or only altered in situ during) hydrothermal processes. By contrast, almost all phases of the Pd sub-group are located in a secondary textural setting - in fractures in chromite or between fragments of brecciated chromite. The different settings indicate that the mineralisation episodes were associated with magmatic and hydrothermal stages respectively. The presence of an included Pd-group mineral in a hydrothermally Pd-group mineralised chromitite sample suggests that the hydrothermal Pd-group minerals were at least partly derived by remobilisation from magmatic deposits in the chromitite pod. These observations indicate that Pd-group elements are more mobile than Ir-group elements under hydrothermal conditions and point to the potential for hydrothermal platinum and palladium mineralisation in favourable environments

Apr 1, 1994

By G. D. Schena, C Chiaruttini

The feasibility is demonstrated of reconstructing the volumetric distribution of liberated particles and middlings by use of a damped, weighted least-square regularisation method. This allows a precise mass balance to be obtained around a separation/concentration unit, permitting evaluation of the partition curve (Tromp curve) of the separator. Areal grade measurements are made on polished sections of feed, concentrate and tailings and a kernel-based inversion technique is then used to obtain the volumetric grade distribution of the three assemblages. A plain kernel (number of occurrences) and a weighted kernel (each occurrence counted with its area) are used for the solution. Testing of the method on computer-generated synthetic areal grade measurements indicates that it offers a valid alternative to the tedious conventional procedure of conducting experiments with heavy liquids

Jun 21, 1905

By G. Zhan, P. Mousset-Jones, G. Danko, J. J. K. Daemen, C. Mezei

Paper presented at the conference Risk assessment in the extractive industries, held in Exeter, 23-24 March 1994, and first published London: IMM, 1994, preprint volume. 18pp., 12 refs. (Originally entitled: Tunnel roof diagnosis using a robotic sensor test bed.) An integral roof diagnosis method is proposed to assist in assessment of risk regarding the stability of an excavation. A Robotic Sensor Test Bed (RSTB) is being developed for the characterisation of roof stability. The sensor test bed consists of a sonic/ultrasonic wave response sensor, a laser surface profiler and a surface temperature sensor. These sensors are mounted on an articulated robot manipulator for performing remote-controlled or fully automated diagnoses. A number of laboratory and field sonic/ultrasonic tests were conducted. A high-energy ultrasonic transducer and an impact device were used to resonate rock slabs. The fracture depths of the slabs were found to be inversely related to the measured resonance frequencies. The agreement between identified and actual dimensions was acceptable. Field tests also showed that loose rock on the surface can be clearly distinguished from solid formation by comparing their wave responses. The robotic laser profiler part of the RSTB was used to measure surface geometry. Different scanning methods are being developed to achieve the fastest and most precise measurements and to provide pertinent information about rock joints and major fractures

Dec 1, 1994

By J. A. Hudson, D. L. Millar

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993 (original title: Rock engineering system performance monitoring using neural networks.) Synthetic and analytical approaches to objective-based design of rock engineering projects are discussed. Rock masses are considered as complex dynamic systems with components that concurrently interact with each other and their environment. The existence of a rock engineering system canon (i.e. a set of systems governing rules) is proposed. Its possible components are highlighted and an application is demonstrated using a "rock mass automaton" designed to simulate dynamic heat distribution in rock. In the example given, the canon implements the basic result from probability theory applied to the thermodynamics of solids. Rock engineering system performance is reduced to the mapping of the output of a rockmass to varying input (design) options, within the state space of the systems model. The Kohonen Self-Organising Map provides an extremely useful analytical tool to reduce the hyper-dimensionality of rock engineering system behaviour. Further, the hyper-dimensional state vector is mapped "quasiconformally" such that the neural map tends to spatially organise similar input state vectors, facilitating interpretation of rock engineering system behaviour (performance monitoring). Work is reported on the development and validation of the automation as a basis for an internal representation of the rock mass bahaviour. The results are reported of simulations compensating for the uncertainty of the exact mechanisms operating within the rock mass, using additive noise with the input state vector in the training stages of the self-organising map implementation. Initial work on adopting Grossberg's Adaptive Resonance Theory neural network architecture for classification of rock engineering systems behaviour is also presented

Apr 1, 1994

By A. C. Apling, N. B. Barrett

Roadstone production requires the generation of non-flaky material, as outlined in British Standard 812 section 105.1; with respect to this criterion, a mathematical model of a cone crusher must be able to predict the flakiness index of a particular size range as determined by the relationship between thickness and nominal size. The Whiten cone crusher model utilises breakage and classification functions to predict a product particle size distribution only, so a shape function has been proposed that is based on a phenomenological approach, taking into account the transfer between flaky and non-flaky material at each stage of breakage. The results of laboratory tests to determine material breakage characteristics and of examination of pilot-scale test products illustrate the method's potential

Apr 1, 1995

By G. S. Camm

Gwynfynydd is a small, high-grade black shale-hosted vein-gold deposit. The Chidlaw Link Zone is the only area being mined and contains 24 000 t ore grading 15.2 g/t gold. Within the Link Zone a complex vein structure occurs consisting of a mother vein up to 5 m thick and narrow (less than 0.5 m) leader veins. The former shows minor variations in dip, strike and thickness, whereas the latter show marked changes in all three. The leader veins are hosted within the footwall zone of the mother vein and both are composed of quartz with galena, sphalerite, chalcopyrite, pyrite and minor arsenopyrite. The vein system is transected by a series of cross-vein and intra-vein dip-slip faults. Pockets of gold occur at vein intersections or branches and within the complex footwall zone and are often related to variations in vein attitude and/or geometry. The Chidlaw Link Zone displays a complex, erratic distribution of gold mineralisation and a multi-stage history of structural activity, fluid flow and mineral deposition

Jun 18, 1905

By R. Lahtinen, M. Tiainen, R. Salminen

The application of similarity analysis derived from regional geochemical mapping data to the location of Ni-bearing intrusions was tested in southwest Finland, where a well-known nickel belt is situated. Samples of till from the vicinity of the Vammala and Kylmakoski Ni-Cu deposits, which were collected independently of the Geological Survey of Finland's regional geochemical mapping programme, were used to provide geochemical modelling data. The data consist of the aqua regia-leachable concentrations of 20 elements from the less than 0.06-mm fraction of glacial till. The variables used in the similarity analysis were selected on the basis of a factor analysis in which the method of oblique rotation was used. A hierarchical clustering of the modelling samples produced two main groups. The first group was described as the "nickel deposit environment model" and the second as the "nickel deposit location model". The data for the standardised variables were compared sample by sample with the model data by similarity analysis using the Simana program with a cos theta measure of pattern similarity. The nickel deposit environment model delineated the known Ni belt and indicated an extension to the east. The nickel deposit location model identified target areas of reasonable size with the greatest potential for Ni ores within the nickel belt

Dec 1, 1991

By P. J. Rowsell, M. D. Waller

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. The applications of artificial intelligence systems in the upstream petroleum industry are reviewed. Particular emphasis is placed on current and potential applications in drilling engineering. Several recent advances in drilling technology have led to a large increase in the quality and volume of data available. This combined with the escalating cost, particularly of off-shore operations, is testing the traditional reliance on the skill and judgement of rig operators. AI systems offer enormous scope in enhancing and aiding the performance of these operations

Apr 1, 1994

By R. G. Kidel, S. C. Doming

The project has shown that it is feasible for a junior company to reopen a narrow vein-style gold mine and successfully take it into production. An intimate understanding of the mineralisation and a flexible approach to mining are crucial, as are stringent cost control and efforts to keep overheads low. The project has confirmed the geological complexity of the Main Lodes, which consist of highly sheared quartz-sulphide infill in strongly sericitised granodiorite. The existence of discrete high-grade zones within the Hangingwall Lodes has also been confirmed. Broad low-grade zones continue to be recognised and require the local application of bulk longhole mining methods. The initial mine plan called for predominantly longhole stoping, but adverse ground conditions have meant that a switch to air-leg mining has produced higher run-of-mine grades. The excess capacity at the processing plant can best be used by batch processing, with its reduced maintenance requirements

Jun 21, 1905

By A. Dean, J. Roberts, I. Stone, J. R. Merefield

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 11 refs. No completely reliable method for characterising and quantifying airborne dust risk exists. A new monitoring technology has been developed whereby dust collected from four-way directional and high volume samplers is analysed for mineral content and particle size for integrated dust mapping. A dust database was set up for the area surrounding the Ffos Las open cast coal site in South Wales. It included XRD directional traces from 17 gauges over 20 months, XRD traces from window ledges in the nearby communities, the major soil types in the area, dust data from haulage roads and public roads and reference-type mineral samples. The database can be accessed relationally to compare and analyse the data using mineral, direction, time, weather and geographical relationships. The data has been used to assess areas of low, intermediate and high levels of risk from dust fall-out

Apr 1, 1995

By B. J. Breen, C. S. Mogg

Considerable borehole investigation work has been completed at a proposed site at Sellafield in Cumbria, supplemented by seismic surveys, other geophysical sensing and geological mapping. The focussing of investigation on the rock mass itself will be achieved by means of the planned underground rock characterisation facility, giving access to depths of about 800 m in the strong, low-permeability basement rocks of the Borrowdale Volcanic Group. Characterisation work undertaken during the sinking phase and interaction with continuing surface-based exploration and monitoring should permit a firmer assessment of the long-term safety of a repository. Key considerations in the choice of a design for the repository include the waste handling method, underground inlet cell, underground vaults, vault environment and environmental effects

Aug 1, 1994

By G. E. Christidis, P. W. Scott

The deposits were formed from low-temperature alteration of pyroclastic rocks. Properties investigated include their cation exchange capacity, swelling capacity, pH, rheological properties, the green and dry compressive strengths, shatter index, wet tensile strength, compactability and permeability. It was found that deposits with abundant opal-CT have poor physical properties. The rheological and swelling properties were found to be influenced by the bentonite grade (smectite content) and the degree of disaggregation of the smectite quasi-crystals. The only deposits of high grade which had good foundry properties were those with no opal-CT. Hydrothermal alteration was detrimental to the physical and chemical properties of bentonites in that it decreased the smectite content and the pH and changed the smectite layer charge and the lattice dimensions

Jun 18, 1905

By P Stone, J. M. Cook, P. R. Simpson, C Mcdermott

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The SW part of the Southern Uplands is a back-arc section of an accretionary thrust system, divided into structural blocks by major NE-SW shear zones and NW-SE faults forming the margins of Permian half-grabens. The highest arsenic levels in stream sediments (over 65 ppm) are associated with those blocks carrying brittle-ductile transition fabrics. Three factors combine to recomend the area as having potential for gold mineralisation: As-rich greywackes as country rock, felsic intrusions and a major shear zone. Selected stream sediments were analysed for gold using lead fire assay with ultra-pure flux and ICP-MS finish. Several localities showed over 15 ppb Au, the three most significant being within the hanging wall of the Orlock Bridge Fault and each having distinct characteristics

Aug 1, 1995

By R. A. D. Pattrick, R. A. F. Ixer

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. At Calliachar Burn, 14 steeply dipping quartz-sulphide veins, with and without gold, infill master joints that crosscut gently dipping metasediments and metabasics of the Pitlochry Schist Formation. The wallrock is extremely bleached and enriched in sericite, chlorite and carbonate. Gold grades vary from high with quartz-galena-pyrite to low with galena-chalcopyrite; the gold forms electrum inclusions smaller than 20 micrometres in pyrite or, rarely, arsenopyrite. At Urlar Burn, gold is present in small amounts in 4 quartz-galena-chalcopyrite veins. Although much of the mineralogy is similar to that at Calliachar, there are significant differences in Sb-, Te-, Bi- and Hg-bearing phases. Fluid inclusion data suggest mineralisation occurred over the range 320-140 degrees C, from fluids with significant CO2 and 2-13 wt% equiv. NaCl. Mantle-derived fluids appear to have been generated during the late Caledonian and focused by the Urlar Burn fault

Jun 19, 1905

By P. S. Heyns, M. Heyns

A computer model has been developed of mine hoisting systems in deep South African gold mines. Particular attention was paid to the contribution of different modelling assumptions for the guides and guide-roller assemblies. Objective functions indicative of guide-roller tyre endurance, slipper-plate forces and perceived vibration levels were introduced to quantify dynamic performance. These objective functions were used to compare models. It was found that the choice of guide and guide-roller models did not influence the forces on the guide rollers significantly for typical shaft and conveyance characteristics at typical levels of viscous damping coefficients. The rigid and finite-element guide models gave the same results as those of the effective-stiffness guide model, and while the latter is suitable for simulation for design purposes, the finite-element model should be used for unusual guide geometries

Jun 19, 1905

By P. Golledge, A. D. S. Gillies

An investigation has been carried on samples of three Queensland coal dusts to determine the potential explosibility of dust-gas mixtures. The explosion potential of the samples was classified by the lean and rich limits of explosibility and the limiting oxygen concentrations for each sample. Plotting of these points showed 2-dimensional flammability limit surfaces for coal dust/oxygen, methane/oxygen and coal dust/methane mixtures. From these plots the 3-dimensional flammability envelopes defining the explosibility of the mixtures were defined. The explosion limits of the coal dust/methane/oxygen system were seen to be influenced most by the explosibility characteristics of coal dust. Methane exerted a stronger influence over the explosion limits when the coal had a low volatile content

Jun 19, 1905

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905