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By R. R. Liebenberg, M. I. Brittan

The kinetics of the copper segregation process has been investigated. The experimental strategy used to isolate the rate-controlling reaction step is described. This step was found to be the chloridisation of the oxide copper minerals in the ore. The link between the rate of chloridisation and the overall rate of segregation is demonstrated experimentally. The influence on the kinetics of the various parameters in a TORCO system is examined and the implications are discussed

Dec 1, 1971

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

Jan 1, 1947

By H. L. Shergold, O. Mellgren

The conditions of amine concentration and pH necessary for the concentration of fine haematite particles at the iso-octane-water interface have been determined. Results obtained from the related studies on the effect of pH and dodecylamine concentration on the adsorption density, electrokinetic potential, contact angle and concentration of various amine species in the system are included. A good correlation was obtained between these different variables. Maximum concentration of haematite at the oil-water interface was obtained when the haematite zeta-potential was small or equal to zero

Dec 1, 1971

By G. R. Doughty

It is shown that sodium can be removed very readily from molten aluminium by the use of a beta"-alumina, the more highly conducting form of beta-alumina, provided that the surface of the tube is wetted by a layer of salt. From current/time plots the theoretical amount of sodium removed has been calculated and excellent agreement obtained. The beta"-alumina tubes can be immersed directly in the Al without fracturing if they are pre-heated for a few minutes prior to immersion. According to its stability beta"-alumina should be attacked by molten Al at low Na contents, but in these experiments the salt acted as a protective layer. Magnesium chloride is a relatively cheap salt, whose Mg product can be used within a foundry. The only other product is NaCl, which can be used in-house as a flux or sent for disposal. No polluting gases are used or produced and no drosses created. The time for removal of sodium was quite short, comparable to that for chlorination

Jun 21, 1905

By R. Scheepers, J. E. Misiewicz, A. C. Fitzgerald

Discussion by A.C. Fitzgerald of the paper, published in Trans. IMM A, vol.104, 1995, p.B121-B135, is presented together with the authors' response. Fitzgerald points out a number of problems with the idea of mineralising fluids leaving no trace in the large volumes of rock traversed before depositing all minerals of value in a particular horizon or rock type with which the required isobaric or isothermic surface also coincides. He suggested that in the case of the Rooiberg tin deposits, the Lebowa Granites may be batholiths that reached the surface and were capped by sheets of their own volcanics. The authors agree that they had considered a possible syngenetic origin for the stratabound deposits, explain that no conclusive evidence for this could be found, discuss the relative ages of the sediments and volcanics of the Rooiberg Fragment and explain the role of its low-intensity deformation and flat dip in the coincidence of an isobaric-isothermic surface with the lithological stratification

Jun 18, 1905

By Hirsch H. H.

The paper, presented at the North of England Institute of Mining Engineers' general meeting held in Newcastle-upon-Tyne on 12th February 1916, gives a short description of the Hirsch lamp, which, though largely used in the United States of America, has not yet been adopted in Great Britain. The lamps, which consist of (1) the watchman's lamp and (2) the miner's lamp, are portable, and have been designed to provide a safe and reliable light for use by watchmen, and in mines, rescue-work, powder-works, oil-refineries, and other places where special precautions become necessary on account of the presence of explosive materials or gases. The lamps are in each in­stance operated by a storage-battery contained within a casing, and this supplies the current necessary for a miniature incandescent lamp. Each safety-lamp forms a complete unit and can be carried from place to place or held in any position. Appendices give details of battery cleaning, test results and safety reports

Dec 1, 1916

By G. Mellgren, O. Mellgren

The conductivity of a solution is often used industrially to control the salt concentrations of reacting systems, normally using electrodes made of glass fitted with platinised platinum electrodes. When a standard platinum conductivity electrode was used to control the acid fed to the leaching circuit for an ilmenite flotation concentrate at Titania, Norway, a deposit of calcium sulphate (containing some calcium phosphate) covered both the platinum electrode and the external glass fitting, rendering the electrode inefficient in the course of a few minutes. A new electrode consisting of a casing, two measuring tubes and an electrode stem is described and illustrated. A significant advantage of its design is that the useful range of conductivity measurement can be adjusted by adjusting the concentration of the electrolyte in the electrode. It has been in use at Titania for about four years with an electrolyte consisting of 0-1 n HCI. It is robust and demands little maintenance.

Dec 1, 1971

By C. C. Harris

The use of Alyavdin's equation Y(x,t) = 1-e(-bt) for describing the effect of grinding time on size distribution is discussed. The equation transforms into linear form by expressing it as log-log reciprocal (1 - Y) versus log t. For plotting, specially divided grids are available; Rosin-Rammler or Weibull charts may be used. The data of Herbst and Fuerstenau are especially useful for illustrating the Alyavdin-Weibull chart in two applications: (1) presenting data (which are relatively unaffected by experimental scatter) and comparing them with theoretical predictions, and (2) as a test for the zero-order kinetics production hypothesis. The chart based on the Alyavdin-Weibull equation is suggested as a useful aid in the analysis of kinetic data (/ versus f), though not as a procedure in its own right. Proposed applications are (1) displaying data with excellent clarity, since it avoids the kind of congestion inherent in some other plotting methods, and (2) as a test for assumed kinetic relationships. Sometimes, equation 1 describes the data quite closely, and in these cases the parameter values appear to be related to certain operating conditions.

Dec 1, 1971

By T. F. Bamber

The South Nottinghamshire Area has not been greatly troubled by spontaneous combustion until the last few years, during which the Blackshale Seam has been developed and exploited. The problem was first encountered at a colliery which was heavily preoccupied with a major reconstruction scheme, and with the sudden appearance of a completely new hazard both men and management had to adapt themselves very quickly to meet the situation. The paper contributed to the Symposium by the South Nottinghamshire Area illustrates the problems by reference to actual incidents, and shows how the lessons learned from them have been applied to the shaping of future policy on the avoidance and treatment of spontaneous combustion.

May 23, 1905

By M. C. Amiri

The plant produces 130 kg slag per tonne of crude steel, to add to the basic oxygen steel-making converter slag stockpile of around 2 500 000 t. The slags contain 1.81% V2O5, which can be rendered water-soluble by salt roasting with NaCl and an alkali such as Na2CO3. Preliminary tests gave less than 3% V recovery from slag under optimum roasting conditions when NaCl, NaCO3 or Na2SO4 was used, but showed that sodium phosphate could make all the V water-soluble when roasted with slag in a ratio of 3:1 at 1 100-1 200 degrees C. Almost complete leaching was obtained within 2 h with water at boiling point. Sodium vanadate was precipitated by acidifying the leach liquor with HCl to a pH of about 2.2

Jun 21, 1905

By W. R. Chambers

A wide variety of mining conditions exists within the South Midlands Area and across this range of conditions more than one half of the mines are highly susceptible to spontaneous combustion. Two thick seams in which the greatest risk exists are described and illustrated. The different heatings which take place are categorized by the locations at which they occur in the mines: additional special cases not easily categorized by location are discussed separately. The discussion for each category of heating follows the pattern of: (i) the reasons why it occurs; (ii) when it arises the means by which it is fought, and (iii) the preventive measures taken in an attempt to avoid its occurrence. Relatively new factors which may affect the incidence of heatings are highlighted and suggestions are made which may assist in reducing the number of incidents in the Area. A new method of continuous sampling, analysis and recording is described and mention made of an original method of interpreting carbon monoxide results with the aid of the computer. The first results from this work show that an early warning is given of an adverse change in trend several weeks earlier than with the present methods. Lastly, suggestions are made about the direction in which research might proceed to assist in reducing the special hazards created by several features inherent in the present methods of mining.

May 23, 1905

By E. A. C. Chamberlain

New techniques for the continuous sampling and analysis of mine air are expected to replace traditional methods used for the early detection of spontaneous combustion. It has been established that the rate of evolution of carbon monoxide is the earliest indicator of incipient spontaneous combustion. Two methods of continuous monitoring of this gas are available and are now in use in the UK collieries. The first is the UNOR infra-red gas analyser, which is flameproof and may be used underground; the second is a system of tube bundles, which permits air to be drawn from any critical point in a colliery and analysed on the surface. Each system has its advantages and disadvantages but both provide the colliery manager with far more information on the condition of his pit than could previously be obtained by spot sampling and laboratory analysis. This paper describes the two systems presently in use and assesses likely future developments.

May 23, 1905

The probability of detachment of quartz particles from air bubbles during bubble oscillations was investigated by means of a vibration method. Theoretical calculations of the detachment force based on the work of Nutt and Schulze for a single spherical particle show a correlation with the experimental results described. However, the forces that were determined experimentally were considerably lower than the theoretically derived values. Some of the factors which were expected to affect the probability of detachment, such as particle size, bubble size, collector concentration and vibrational acceleration, were also investigated

Dec 1, 1991

By G. D. Nicholls

There have been very few attempts to isolate the various factors that contribute to the overall imprecision of geochemical analytical procedures, due in part to the difficulty of distinguishing between them. The technique of spark source mass spectrography permits a ready distinction between the contributions to overall precision from sampling error and instrumental and other errors. With conventional methods of sample preparation for this technique sampling difficulties are responsible for 80-90 per cent of the overall imprecision. Examination of the probable location of the major difficulties in sample preparation indicates that the preliminary stage of grinding, mixing and extraction of a first aliquot (about 1/100 of the original sample) is generally perfectly adequate. The difficulty lies in the subsequent stages of sample preparation. Dry mixing techniques are unlikely to give good precision if the sub-samples actually examined by the analytical technique are less than 10 mg in amount. Solution techniques are less prone to sampling difficulty. Fusion techniques, unless conducted with great care, can produce more difficulty than dry mixing. Sample preparation is critical to the success of many analytical procedures. Selection of appropriate sample preparation techniques requires just as much care as the selection of techniques for the actual analysis.

Dec 1, 1971

By G. B. Hooper, G. A. Ferguson

The technical capabilities and user-friendliness of the major computer-aided mining design software systems are reviewed. Recent experiences with three systems are outlined to indicate the practical problems that arise. The examples were: Microlynx software from Lynx Geosystems at the Great Dyke platinum mine in Zimbabwe; Lynx software from Lynx Geosystems at a copper mine in central Africa; and PC-MINE software from Gemcom Services at an open-pit gold project in Western Australia. Difficulties in the use of mining design software has led to an alternative approach. Falconbridge, Canada, has developed an integrated mine-planning system on a CAD platform that encompasses ore reserve estimation, stope design, development layout and survey control. Future directions of computer-aided mining design using this basis are discussed. A major advantage of using mainstream software packages, such as spreadsheets, databases and CAD programs, is that most engineers and geologists are experienced in handling such systems in the normal course of their work.

Jan 12, 1992

By R. F. Bell, Schultz

The paper briefly discusses the nature of spontaneous heating in mines in the Doncaster area, in the period immediately before 1967 and steps taken to prevent and treat such outbreaks. The changes that led to the increased rates of advice of Barnsley Seam faces since 1967 are listed and the effects of these increased rates on the frequency and location of spontaneous combustion are discussed. The change in methods of control required by the increased rate of advance of the faces and the changes in location of outbreaks are described. Some typical heating situations are evaluated. The methods described include the use of air sealants, water gels for filling of voids in wastes, the balancing of pressures across heating areas by pressure chambers, booster fans, and the resiting of air separation doors, and the sealing of air-ways by flooding. The authors discuss the influence of mine layouts on the risks of spontaneous combustion and advocate that future plans should be designed to limit the number of districts at risk when heatings occur.

May 23, 1905

By W. R. Donaghue, R. L. Robinson, C. Scott

Whilst spontaneous combustion has never been considered a major problem in south Durham, certain collieries in the area have a history of heatings and precautions are essential. Three collieries are affected - Shotton, Vane Tempest and Seaham - and in the case of the last two, there are huge areas of high quality coal to work under conditions where spontaneous combustion is a real hazard. The seam being extracted has an immediate roof in goaf left by the incomplete extraction of a contiguous seam worked before the turn of the century. The presence of residual coal stocks and old roadways and cavities adds to the difficulty of preventing unwanted air movement. The main preventive measures adopted are the construction of airtight gateside packs and the use of sprayed surface coatings in the gate. Sampling systems and sampling points are described and, in particular the field of continuous monitoring from the surface is examined. The resulting possibility of a quantitative as well as qualitative assessment of the preventative measures required is discussed.

May 23, 1905

By G. G. Lambert

The paper traces the pattern of spontaneous combustion in the workings of what was originally Hemsworth Colliery, but since July 1967 is now part of South Kirby Colliery. Examination is made of the Barnsley Seam sections and the part played by the top section of the seam as it comes in close proximity to the main seam. In this area of the colliery nine mechanised faces were set away between the years 1953 and 1968, every one "fired" at the pillar edge and six "fired" at the face line when production had ceased. The paper deals with the different preventative measures used, from sandbag walls, cement injections, spraying with polyurethane, until finally using Mandoseal as a sealant. Since the latter method was first used, the last three faces worked in this particular area were all salvaged completely, without any sign of a heating developing.

May 23, 1905