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By Artem Dolotov, Alexander Ter-Oranesyants, Saveliy Kaplan, Boris Axenov, Vasiliy Kovalev, Valeriy Tsyplakov, Konstantin Grigorjev, Nikolai Vorob’ev-Desyatovskii

The issues of double refractory gold ores pressure oxidation were considered. It was demonstrated that along with chloride autoclave preg-robbing which has been studied there are other negative external and intra-autoclave processes resulting in gold losses. It was found that an ingress of even low concentrations of NaCN, ferrum(II) and ferrum(III) cyanide complexes, as well as thiocyanate compounds into the autoclave leads to decrease of gold recovery during further cyanidation in a "carbon in leach" process (CIL). Admixtures depressing recovery of gold can get into the autoclave together with water in the result of industrial accidents or due to peculiarities of recirculation of industrial water used for feed pulp preparation or with quench-water used for process temperature maintenance. In contrast to a chloride preg-robbing which occurs only at pressure oxidation of double refractory gold ores, cyanide preg-robbing starts in the autoclave feeding tank (so-called «upper» preg-robbing). Possible causes of cyanide autoclave preg-robbing and requirements to the quality of water supplied to autoclaving were discussed.

Jan 1, 2014

By Rogerio C. Guimarães, Antonio E. C. Peres

The production of phosphate concentrates (phosphate rock) from slimes represents a challenge to the phosphate industry worldwide. In Brazil, this challenge is particularly relevant due to the consistently low P2O5 grades and the igneous origin. The first industrial experiences of producing phosphate rock from slimes (-44µm or -325#) fraction started at Arafertil, currently Bunge Fertilizantes SA, in Araxá, in the 1980.s. This production corresponds, nowadays, to 35% of the total production of concentrates in the company (830,000t/year) in a circuit consisting of desliming in 40mm microcyclones and concentration in flotation columns, corn starch and fatty acids being utilised as reagents. The performance of slimes flotation and the process control, at Bunge´s concentrator, were improved after the introduction of column flotation technology, in the first half of the nineties. The column flotation technology for slimes recovery was expanded to other Brazilian concentrators still in the nineties: Ultrafértil (Catalão - GO), Bunge (Cajati - SP), Fosfértil (Tapira - MG) and Copebrás (Catalão - GO). At present the Brazilian production of phosphate rock is approximately 4.5Mt/year, with a strong trend for a market increase. Genuinely Brazilian technology is utilised for the processing of slimes, the concentrates representing 11 to 13% of the overall production. The production of apatite concentrates from slimes was relevant to increase phosphate recovery and reduce costs, contributing to the growth of the fertilisers industry.

Jan 1, 2003

By J. Vilcáez

The copper extraction yield from thermophilic bioleaching of chalcopyrite depends on temperature, pH, and the oxidation-reduction potential (ORP), as well as the activity of the microbe used. We studied copper extraction yields obtained from chalcopyrite with three thermophiles, Acidianus brierleyi, Sulfolobus metallicus, and Metallosphaera sedula, under various pH and temperature conditions and with different initial amounts of ferric iron. The results indicated that the capacity of each thermophile strain to leach iron as Fe3+ differed, which affected the influence of pH, temperature, ORP, and microbial activity level on the yield of copper. Microbial activity can cause ORP to be close to the critical value (450 mV) at which copper extraction at 65 °C can be higher than that at 80°C. An initial pH of 1.5 retards the precipitation of jarosite, allowing temperatures as high as 80°C to result in copper extraction yields close to 100%. However, if a thermophile with a poor capacity to form Fe3+ is employed, 100% copper extractions can also be obtained at pH 2.5, because ORP is low as result of low amounts of Fe3+ in solution. Optimum temperatures for the growth of thermophiles did not always mean high copper extraction yields. Conversely, high biomass concentrations depending on the capacity of the thermophile strain to leach iron as Fe3+, can result in excess Fe3+ in solution, leading to the precipitation of large amounts of Fe3+ as jarosite. The bioleaching capacity of A. brierleyi was reduced or suppressed when insufficient initial Fe3+ was pro-vided to trigger the leaching reaction, whereas S. metallicus and M. sedula were less sensitive to the initial availability of Fe3+. This result confirmed that a direct enzymatic attack on the mineral surface could initiate the leaching reaction, but later ORP governed the leaching rate of chalcopyrite.

Jan 1, 2014

By G. C. He

Effects of irregularity, rough surface and aggregation of fine particles on ultrasonic attenuation are significant. The effects should be considered while predicting particle size by ultrasonic attenuation technology. The scanning electron microscope micrographs analysis also shows that particles surface is rough and irregularity. Any slurries has its fractal structure and its special fractal scale and dimension, so, effects of irregularity, rough surface and aggregation of fine particles can be de-scribed by fractal model. The discrepancies between predictions of ultrasonic attenuation based on the assumption of smooth spherical particles and data obtained from slurries of irregular particles indicated that there were different fractal structures. The ultrasonic attenuation model was modified by fractal dimensions. The result of experimental data and analogue calculation indicated that pre-dictions of the fractal modification of ultrasonic attenuation model show good agreement with experimental data. On the other hand, from the values of fractal obtained by inversely calculation, the degree of effects of irregularity, rough surface and aggregation of particles can be estimated. The positive value of fractal dimension indicates that the aggregation has the dominant effect on ultra-sonic attenuation, otherwise, the irregularity and rough surface has the dominant effect.

Jan 1, 2014

By Avinash Tripathi

It is now well known that the size distribution of the particulate solid has a significant effect on the breakage behavior of particles in the wet as well as dry modes of ball milling operation. In the context of the size discretized batch grinding kinetic model, grinding behavior of particles is characterized by the breakage rate parameters, k, and breakage distribution parameters, B. Understanding the nature of variation of these two sets of parameters with particle size distribution is important for simulation and control of operation of production mills. However, so far it has not been possible to track the variation of both the set of parameters with grinding time simultaneously. In this paper an attempt has been made in this direction by using a modified functional form approach with time dependent constants. Keywords: dry and wet ball milling, breakage rate and distribution parameters, effect of particle size distribution

Sep 1, 2012

By Agnieszka Surowiak, Tomasz Niedoba

The paper presents a way of determining relations between ash content in coal, particle size and particle density by means of regression, multidimensional Morgenstern distribution functions and kernel approximation. The three-dimensional random vector (D, ?, ?), where D is a random variable describing particle size, ? - random variable describing particle density and ? - random variable describing ash content, where function ?=?(d, ?) is obtained by means of regressive function. The multidimensional Morgenstern distribution functions and kernel estimators with the use of Gauss function were applied to approximate the functions f(d, ?, ?) and f1(d, ?). This approach is a new way of multidimensional description of grained materials such as coal and it also allows to evaluate material features more properly than the classical statistical approach. The results were verified statistically.

Jan 1, 2014

By Francisco Vicuña, Miguel Becerra, Gonzalo Montes-Atenas

"The optimization of the copper recovery from smelting slag by a process of comminution / flotation has been a widely discussed topic during the last few decades. Several studies covering the characterization of different types of slag, the impact of the slag cooling rate and of different flotation operating conditions on the flotation performance have been widely published. Currently, at El Soldado mine site (Angloamerican), there are large copper bearing slag deposits that can be a profitable alternative for the concentrator with capacity to treat this material. Under this process schema, the optimization of the flotation process to obtain better copper recoveries is a relevant topic of study. The aim of this study is to assess the efficiency of a sulfidation stage of a slag and to correlate that process with copper recoveries results in a flotation circuit. This article presents a detailed examination at both laboratory and plant scales of the slag sulfidation on the recovery of copper in the flotation process. The experimental methodology involves studying the effect of the sulfidation agent dosage, the pH, the particle size distribution of the flotation feed and the conditioning time. Furthermore, the performance of the sulfidation stage was analysed through the XPS analytical technique. It was observed that the sulfidation of particles in floatable size fractions correlated well with the increase in copper recovery. The results indicated that it is possible to increase between 2 to 4 points the total copper recovery with a sulfidation process implemented appropriately."

Jan 1, 2014

By I. Blayda

The purpose of this work is to study and make comparative analysis of germanium extraction and related valuable components of the sublimates from the burning of domestic power coals (product 1) and germanium sulfide materials, which are a waste of lead-zinc production (product 2), by traditional chemical methods (distillation of germanium in the form of tetrachloride from raw and preliminary burning source) and by microbial bioleaching of sulfur-oxidizing bacteria. The dependence of the germanium extraction by chemical methods from phase composition of the initial raw materials was installed. The germanium tetrachloride extraction from products 1 and 2 were 78.50 and 19.52%, respectively. Such difference in indexes on extraction, is caused by germanium confinement as concomitant trace component to the basic phases to carriers. The share of acid-non-soluble compounds (tetragonal modification GeO2 and silikogermanaties) in the product 1 account for 21.5 % of germanium. Ratio between acid-soluble and acid-not -soluble germanium forms are 19.52 and 80.48 %, respectively, in the product 2. Our experiments have shown, that implementation of restorative firing (with addition of 30-40 % carbon at 1150 0?) of sulfide product 2 considerably impacted on the extraction of germanium tetrachloride (91.76 %) in comparison with its low enough extraction at straight distillation of hydrochloric acid (19.52 %). The results are confirmed by a set of physical methods. The results of processing the same so-called hard phase?s material (product 2) with the help of microorganisms are presented. It Has been established, that selected strains of bacteria are capable of extracting from initial raw materials not only macro components (iron, zinc, lead, manganese, aluminum, nickel), but also micro impurity of rare metals (gallium, germanium, zirconium). It is important that these metals were not extracted by traditional chemical methods (with application of aggressive conditions and heats) independently of the phase composition of the source. Almost complete extractions of germanium in solution using sulfur-oxidizing bacteria take place in the first day of the process independently of the phase composition of the source and the type strain. The results have practical significance and can be the basis for developing a unified biotechnological method of technogenic waste processing with a purpose of their sterilization and detoxification with simultaneous obtaining concentrates of valuable metals. Keywords: germanium, extraction, sublimates, bioleaching, sulfur-oxidizing bacteria.

Sep 1, 2012

By Saveliy F. Kaplan, Valeriy N. Tsyplakov, Vasily N. Kovalev, Igor A. Agapov, Nikolai V. Vorob’ev-Desyatovskii

"Based on the experiments, a possibility of successful processing of double-refractory gold sulphide concentrates with a high content of natural organic carbon, which has a high sorption capacity toward gold chloride complexes, has been demonstrated. The proposed approach involves deep burnout of sorption-active organic carbon in an autoclave at a higher temperature and a longer retention time. INTRODUCTION It is known that one of the reasons why gold-bearing ores and concentrates are refractory is the occurrence of fine gold in sulphides (usually in pyrite and arsenopyrite) in ores and concentrates. In addition, refractory gold-bearing ores and concentrates also contain an organic carbonaceous material, which has a sorption capacity towards gold chloride complex, making the ore or concentrate even more refractory. In pressure oxidation, metallic gold is oxidized by Fe (III) aqua-ions and complex Au(Cl)4- ions are formed at temperatures over 180°C, in the presence of chlorides contained in ores. Complex gold anion is adsorbed on the organic carbon surface and then reduced to Au0; the chloride ion is regenerated and gold, adsorbed on organic carbon microparticles, is ultimately transferred to tailings (preg-robbing). Currently, there are several suggestions how to suppress preg-robbing (Simmons, 1998, Pyke, 1999, Rees, van Deventer, 2000, Zhao Jun-wei, 2008). It can be done by reducing the organic carbon content by processing (flotation, etc.),reducing chloride ion concentration by preliminary washing of concentrates in thickeners, reducing the adsorption capacity of organic carbonaceous material by introducing some organic substances that are strongly adsorbed on its surface (blanking agents), and reducing the redox potential of the slurry liquids by introducing neutralizing agents (limestone)."

Jan 1, 2018

By Marco Le Roux, Quentin Campbell

"Most coal supply contracts include strict limitations on the moisture content of the products. This limitation exists because of calorific, transport cost, and handling reasons. Managing the retention time on product stockpiles to facilitate drainage commonly controls the moisture content in coarser coal products. A large-scale pilot rig has been commissioned to facilitate research in this regard. A stockpile of about 15 tonnes of a typical washed power station feed coal from the South African Witbank coalfield was loaded onto a 6 x 6 m platform on load cells. The platform was shielded from the elements, like rain and wind, and an artificial rain sprinkler system was installed. A variety of rainfall intensities and durations were simulated and the water accumulation and run-off was measured. The material was also sampled for moisture and particle size before and after the series of tests. At the same time, the drainage characteristics of the same coal were determined in smaller scale drainage columns for comparison. Data is presented in this paper on the drainage rates, maximum accumulated moisture, final moisture, and the effect of evaporation. The results showed that for all rainfall patterns tested, drainage ceased after 2 - 3 days, but evaporation continued for at least the time period under investigation, albeit at a low rate. Evaporation contributed to dewatering at rates that depended on wind, temperature and humidity conditions. This caused a slow reduction in moisture content even after the run-off had ceased. The value of the final moisture depended on the coal PSD. It was also found that the intensity and duration of the more intense rainfall events did not significantly affect the maximum water accumulation, with drainage rates equaling the corresponding water addition rates which suggested that water ran off over the surface of the stockpile with limited penetration. During more intense rainfall scenarios, some penetration was apparent."

Jan 1, 2014

By J. B. Yianatos

A practical an interactive model to describe the operation of a flotation bank of mechanical cells was developed based on the hydrodynamic and metallurgical characterization of large industrial flotation cells. Thus, the mineral grade and recovery, as well as the stream properties along the flotation bank can be described in terms of the operating variables. The model was built considering the flotation bank as a distributed system, so the solution for the water and solids mass balances, per size classes, for each single cell, are sequentially solved. Also, each cell was described by two distinct zones, the collection zone characterized by the flotation rate constant and the froth zone characterized by the froth recovery. The mineral feed was described in terms of the mineral species and particle size classes, using a rectangular flotation rate constant distribution. Also, the effect of changing the actual operating variables (air flowrate, pulp level, pulp density, pulp flowrate, etc.) on the mineral collection process, in the collection (pulp) zone, was considered downstream along the bank. The froth recovery of floatable mineral has been estimated by measuring the mass flowrate of particles entering the froth by true flotation together with the concentrate mass flowrate (ton/h). The mass flowrate of collected particles at the pulp/froth interface level was calculated from direct measurement of bubble load (ton/m3) and gas flowrate (m3/h). Flotation recovery is mainly related to the froth depth and air flowrate. All parameters considered in the model have been adjusted from direct measurements in plant site. Also, the effects of other operating variables such as reagents dosage, top of froth grade, or froth discharge velocity are presently under study. This procedure has been tested using data from industrial rougher operations consisting of flotation banks with 5 cells to 9 cells in series, and different cell sizes, such as 45m3, 130m3, 160m3 and 250m3. Thus, it has been shown that the model approach is a powerful tool for flotation cells diagnosis, operation and development of new control strategies, as well as, to evaluate the effect that de-sign and operating variables have upon the collection and froth zones performance in large flotation cells.

Jan 1, 2014

By Ye Junjian

The feed ore is the concentrate of low intensity magnetic separation of pyrite tailings, containing TFe47.47%, S19.41% and SiOpyrrhotite. The exploratory tests showed that using a process of flotation followed by magnetic separation could respectively obtain a sulphur concentrate of S 31.08% with a recovery of 82.89%, and an iron concentrate of TFe 59.97% and S 9.52%with a recovery of 30.93%. The reason of iron concentrates with high sulphur grade was that the sulphur grade of flotation tailings was 7.03%. So enhanced flotation for pyrrhotite was investigated in this research. Results show that when the natural pH of ore pulp varied from 5.5 to 6.0, a reagent combination of FS, LH, and BJ displayed the optimum flotation performance for pyrrhotite. After comparisons made on different flotation processing, the previous flotation flow of ?one roughing, one cleaning, one scavenging system and middling reprocessing?, was found, among others, to have the best flotation effect, as the grade and recovery of sulphur concentrate were 31.08% and 82.89%, respectively, and sulphur content of the flotation tailings was 7.03%. The above results indicated it was difficult to raise further the effect of flotation desulphurization. The authors therefore suggested that oxidizing roast should be adopted following the magnetic process for the purpose of further desulphurization. Besides, flue gas containing SO2 8.25%. And the valuable minerals are magnetite and 2 generated from roasting could be reused for sulphuric acid production. Keywords: pyrrhotite, enhanced flotation, desulphurization

Sep 1, 2012

By M. Kosugi, M. Kawata, J. V. Satur, K. Mitsuhashi, R. Kawarabuki, W. Kracht, Y. Ebisu

Copper concentration is becoming more difficult because remaining copper ores are more complex and of finer copper mineral grain size, making copper minerals harder to float because of the fine particle size required to liberate the valuable species. The purpose of this work was to study the flotation behavior of fine copper sulfide ores at different conditions of agitation and aeration. The experimental campaign was carried out in a laboratory Denvertype flotation cell of 1 L volume modified to be operated with forced air that allows decoupling air flow rate and agitation speed. Four ore samples from Chile were used, all of them containing copper sulfides such as chalcopyrite, bornite, chalcocite, and tennantite, but with varying grain sizes and compositions. Preliminary flotation tests for establishing the flotation conditions of grinding size and collector dosage were conducted before the kinetic flotation tests that were carried out at different agitation speeds varying from 900 to 1300 rpm for gas flow rate ranging from 1.6 to 7.2 L/min. The flotation products were analyzed by ICP-MS and MLA (Mineral Liberation Analyzer). The results showed that high agitation speeds with corresponding air flow rates resulted in better recovery than moderate agitation speed and air flow rate, and an excess in gas flow rate resulted in bad performances. The flotation rates of the fine copper minerals were improved despite the different improvement rates among the fine size fractions. The impact of these operational variables, however, was different when comparing the results for the four ore samples. While it was found that the order of floatability in the four samples was the same, that is, chalcocite > tennantite > bornite > chalcopyrite, the kinetic constants of the copper minerals in the samples were different, indicating that mineral composition in the sample affects the flotation kinetics.

Jan 1, 2018

By O. D. Khmelnitskaya

The research on selecting of an efficient technology of pyrite cinders complex treatment, sulfuric acid production wastes, have been made. The grades in the initial product were 2.04 g Au/t, 35.0 g Ag /t, 0.38%Cu, 1.1% Zn. Laboratory tests on cyanide technology, thiourea and sulphite leaching were carried out. Magnetic and flotation beneficiation and biohydrometallurgical technology were tested. After considering the results of the tests, the most economically efficient technology of pyrite cinders complex treatment with cyanide leaching of precious metals was determined. The technology involves water washing of soluble copper and zinc compounds, lime treatment and cyanide leaching of gold and silver, detoxification and utilization of mineral wastes. The precious metals are recovered from solutions by cementation onto zinc. Copper is recovered from rinse waters by SW/EW and then zinc is precipitated as hydroxide. All the solutions and organic agent are used in recirculation and therefore the technology is practically waste-free. Mineral wastes can be used as iron-containing materials for cement industry. The technology has been tested in pilot-plant scale under continuous operation with complete re-circulation of cyanide solutions. In this process recovery of 54% Au, 45% Ag, 30% Cu and 50% Zn has been achieved.

Jan 1, 2014

By L. X. Zeng

The low-grade nickel resource is very abundant in the western China. To make the best of the low grade nickel ore, we studied the process mineralogy and beneficiation process of nickel ore in the Yangliuping of Sichuan province. The grade of nickel is 0.45% in the nickel ore and the nickel exists in the sulfide including pyrrhotite, nickel pyrite, chalcopyrite primarily. The nickel distributes in pentlandite and magnetite over 90% and the copper does in the chalcopyrite over 95%. The carri-er minerals of useful elements tend to concentrate in space for concentration. As is shown in grain-size analysis of three major minerals, there are some more fine-grained grains with the percent of from 10% to 15% (<40 µm) and from 3.5% to 5.5% (<20 µm). So there will be some smaller size disseminated sulfide minerals difficulty to liberate in the process of concentration. The liberation degree of sulfide is not high and there are much associativity in the sulfides. Therefore, we should reclaim the sulfide aggregation dominating as pentlandite when concentrating. In addition, the sulphide minerals is so brittle that we should take care of preventing from crashing when grinding. The gangue mineral is mostly metamorphic mineral including serpentine, chlorite and amphibole which is easy to be argillization and difficult to concentrate.

Jan 1, 2014

By P. Somasundaran, Tarun Bhambhani, D. R. Nagaraj, P. Patra

"Certain non-sulfide gangue minerals are known to have a detrimental impact on flotation performance. When present in large amounts, they can negatively affect recoveries, grades and throughput at current operations, and dictate the viability and economics of a greenfield project. While the problem has been investigated for a long period of time, a scientific understanding of the mechanisms by which these minerals affect performance has not been obtained, and no acceptable solutions have been developed. This study focused on the role of physical aspects (e.g. shape, size and morphology) of these minerals as the underlying factors for poor performance. Flotation tests were conducted using model mineral systems to understand the impact of one phyllosilicate mineral (muscovite) on flotation kinetics, recoveries and grades. The study reveals that there is minimal impact on flotation kinetics, no impact on recoveries, but a very strong detrimental impact on concentrate grade. The traditional mechanisms of transport such as true flotation and entrainment are not sufficient in describing the extent of transport. The transport is attributed to the unique platy morphology of muscovite, which allows for action of buoyancy forces. Data also shows that the muscovite transport to the froth phase depends on particle size; coarser sized muscovite (100-150@) report to the froth phase in much larger amounts than medium sized muscovite (50-100@). At finer size fractions (<50@) the transport is also increased, and this is likely due to entrainment."

Jan 1, 2014

By R. Mukherjee

Consistency of Run-Off-Mine (ROM) quality plays an important role in mineral processing which is not very often talked about. The major impediment is limitation of sampling ROM ore, which makes processing plants to run without any realtime feedback on ore quality that comes in. The process of direct determination of Run-Off-Mine (ROM) ore quality is expensive and time consuming as drawing and preparing representative samples from blasted muckpiles are constrained by large sample size and inherent heterogeneity in terms of size and chemistry. In absence of techniques for direct measurement of quality, monitoring and control of ROM, feed to the processing plant at Joda East Mine, like all other iron ore beneficiation plants worldwide, is largely based on blasthole sampling and subsequent chemical analyses of blastcone chips. While such indirect methods proves to be more accurate for representing whole of a mining block or blasted muckpile (~30-50KT/blast), it is indeed a challenge to ascertain and predict day to day input quality for a part there off. This eventually leads to a gap between predicted and actual ROM quality, resulting in difficulties in process control, in turn, and leading to wide swings in product quality. Hence, it is imperative to bridge the gap between predicted and actual ROM quality by arriving at means, which ensure consistent plant feed grade to deliver consistent output. The paper discusses an efficient and affordable alternative for effective prediction of ROM alumina which has been developed by integrating blasthole quality database in GPS based Truck Dispatch System (GPS-TDS) at Joda East Mine. Initially, GPS-TDS has been installed for optimizing production parameters only, but this development has helped in further utilization of GPS-TDS for real time quality monitoring by improving ROM grade prediction and scheduling from several ore blocks in active mining areas. Keywords:run-off-mine (ROM), blast hole, feed grade, GPS-TDS

Sep 1, 2012

By Kyle P. Flynn, Frank J. Hrach, James D. Bittner

ST Equipment & Technology, LLC (STET) has developed a processing system based on tribo-electrostatic belt separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to other electrostatic separation processes that are typically limited to particles greater than 75µm in size, the triboelectric belt separator is ideally suited for separation of very fine (<1µm) to moderately coarse (300µm) particles with very high throughput. The high efficiency multi-stage separation through internal charging/recharging and recycle results in far superior separations that can be achieved with a conventional single-stage free-fall tribo-electrostatic separator. The triboelectric belt separator technology has been used to separate a wide range of materials including mixtures of glassy aluminosilicates/carbon, calcite/quartz, talc/magnesite, and barite/quartz. An economic comparison of using the tribo-electrostatic belt separation versus conventional flotation for barite / quartz separation illustrates the advantages of dry processing for minerals.

Jan 1, 2014

By D. Z. Wei

Amine collectors with different structures and length of carbon-chain have been widely used in oxide minerals flotation. In this paper, we synthesized one kind of binary amine, N-dodecylethyl- enediamine, and studied its flotation performance. From the results, we can see N-dodecylethylenediamine which has excellent frothability, is a new type of chelating surfactants. And it also has fine catchability to quartz and hematite. The recoveries of quartz and hematite increase with the augment of N-dodecylethylenediamine concentration. When the dosage of collector reaches 100g/t, the recoveries of quartz and hematite achieve 95.30% and 87.89% respectively. Meanwhile, the influence of pH on the flotation recovery of hematite is studied and test results showed that, as pH increases, the flotation recovery rises until pH=9. And the recovery reaches its maximum in alkalescence. The collector has better flotation capability to quartz than to hematite. And the maximum recovery of quartz is gained in alkaline media, which reaches 97.87%. Finally, the flotation mechanism of N-dodecylethylenediamine is discussed through the measurement of infrared spectroscopy.

Jan 1, 2014

By H. Deng

Oxidized zinc ores are the main source of zinc metal except sulfides. To have a better understanding about the performance of smithsonite and the main gangue, quartz, in flotation, the aggregation behaviors of smithsonite and quartz in water were confirmed by different techniques (sedimentation tests and optical microscopy). The experimental results show that smithsonite and quartz particles aggregate in the pH range 7.5-11. The results of zeta potential suggest that the aggregation does not correlate with the DLVO theory, when the iso-electric point of smithsonite and quartz is 8.0 and 2 respectively. When the solution pH is less than 8.0, smithsonite has an opposite charge to the quartz particles. Electrostatic adsorption makes effort on these two kinds of particles according to DLVO theory. Whereas, solution chemistry calculation shows the pH range 8-11 corresponds to hydroxide formation, suggesting that this is the species responsible for aggregation. And their concentrations are much higher in sodium hydroxide system than that in sodium carbonate system. Aggregation of smithsonite and quartz due to the flocculation action of zinc hydroxide is proposed.

Sep 1, 2012