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By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By J. W. Matousek

Tonnage oxygen plays a critical role in the primary production of two of the most important industrial metals - copper and iron - and minute quantities of oxygen play equally critical roles in determining the properties of the market products. For refined copper, oxygen in the final metal is balanced between maximizing electrical conductivity, neutralizing the effects of harmful impurities, and ensuring that the metal takes on the desired "set" during casting - the surface texture and physical properties required for subsequent rolling and drawing. For refined iron, oxygen must be removed to minimize reaction with carbon during cooling from the molten state with the generation of CO and CO2 - leading to a loss of carbon and the creation of "blow-holes" in the solid ingots and the potential for defects in rolled and forged products. This paper reviews the thermodynamics of oxygen in molten copper and iron at the levels of primary interest to production metallurgists.

Jan 1, 2014

By John Eggert, Paul Benford

"Since 1982, Placer Dome Inc. -Dome Mine has steadily increased mill throughput. Tonnage has increased from a nominal design capacity of 3000 short tons per day, attained in 1985, to 4130 stpd by the end of 1992. Many minor and major circuit adjustments were tried to maximize tonnage.Having utilized most conventional means of increasing tonnage, further increases required a newer approach. This paper discusses the Dome experience in the development and implementation of an expert system.The Comdale/C system was chosen for a controlled trial. The criteria for acceptance were: increased tonnage had to be sufficient to pay for the system; the increase had to be visibly sustainable and the mill operators had to be willing to accept the system.The criteria for purchase were met during the trial and the system was purchased. The system continues to perform well. The tonnage throughput increase has been sustained while operator acceptance remains high.IntroductionPlacer Dome Inc. -Dome Mine is Canada's oldest operating gold mine. The mine was among the first established in the Porcupine camp in what is now Timmins, Ontario. The City of Timmins is located approximately 500 miles or 800 kilometres north of Toronto. Figure 1 shows a map of the province of Ontario and the mine location.In 1912, milling began at a rate of 350 short tons per day. With two minor exceptions, milling has been continuous since this time. The first of these shut downs was in 1918 during the first world war. The war created labour shortages which forced the mine to stop production for more than a year. The second was in 1930 when fire destroyed the mill."

Jan 1, 1994

By D. W. Davis, P. Landais, L. J. Robb

Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Ph-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter Ol3C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoidand sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994

By John F. Vynne

This paper will discuss several of the systems and processes that have been developed over the past few years, and are now being utilized by major mining companies on draglines in North America, Australia and South Africa. These technologies include production monitors and reporting systems, GPS navigation systems, structural integrity monitoring systems, structural analysis studies to increase the dragline RSLs, and inspection and response strategies. The use of these technologies provides significant increases in dragline production, and reduces maintenance costs and downtime. The question that needs to be asked is what value is there in monitoring? Increasing dragline productivity is dependent upon to two items with the overall goal being to maximize the number of bank cubic meters moved and to uncover more coal: 1) maximizing payload and 2) maximizing the number of cycles. If you do not measure and try to optimize the parameters that impact payload and number of cycles, there is very little chance that you can improve overall dragline productivity. These parameters are: Maximizing payload is dependent upon the following: ? Geology ? Blasting ? Monitor weighing accuracy ? Engage location ? Disengage Location ? Rigging ? Suspended load ? Bucket characteristics ? Operator skills ? Minimizing rehandle Maximizing the number of cycles depends upon maximizing digging time, and minimizing cycle and delay/down times by: ? Minimizing Operational Delays ? Minimizing Mechanical Delays ? Minimizing Idle time ? Minimizing Walking time ? Minimizing Fill Time ? Minimizing Swing Angle ? Maximizing Swing & Return Rates ? Minimizing Spot Time A third reason to monitor, conduct structural analysis studies, and have inspection strategies is to prevent catastrophic failures such as shown in the following photographs (figures 1 & 2).

May 1, 2008

By R. E. Whitehead

"Abstract - Biotite from aplite that appears to have crystallized simultaneously with disseminated Cu-Mo mineralization at MacLeod Lake in northern Quebec yields K-Ar dates in the range 2032 ± 44 Ma to 2097 ± 47 Ma. The mean value, 2065 Ma, is some 400 Ma younger than the 2485 ± 64 Ma date obtained from a hornblende concentrate separated from a granodiorite sill that is spatially, but apparently not genetically, associated with the disseminated Cu-Mo deposit. The mean biotite date of 2065 Ma at MacLeod Lake, a K-Ar date of 2055 Ma reported from an area 50 km east of MacLeod Lake and published dates of about 2000 Ma for galenas from the Chibougamau Cu-Au ores, suggest a widespread thermal and mineralization event, in that part of the Superior Province east of James Bay, that differs from the common late Archean mineralization that is related to volcanism and metamorphic-intrusive activity.Sommaire - Les datations au K-Ar sur des biotites qui auraient cristallise en même temps que la minéralisation disséminée en Cu et Mo dans une aplite mise en place au Lac MacLeod, au nord du Québec, s'échelonnent entre 2032 ± 44 Ma et 2097 ± 47 Ma. La datation moyenne, soit 2065 Ma, est d'environ 400 Ma plus récente que la datation obtenue pour un concentre de hornblende extrait d'un filon-couche de granodiorite qui est spatialement mais ne serait pas génétiquement associée à la minéralisation disséminée en Cu et Mo. La datation moyenne de la minéralisation au Lac MacLeod, soit 2065 Ma, la dataion au K-Ar à 2055 Ma citée pour une région à 50 km à l'est du Lac MacLeod, de même que les datations d'environ 2000 Ma établies pour des galènes qui se trouvent dans le minerai aurifère et cuprifère à Chibougamau, suggèrent un phénomène thermique répandu qui aurait produit la minéralisation dans cette région à l'est de la Baie James, dans la province du lac Supérieur. Ce phénomène serait diffèrent de celui qui aurait produit la minéralisation répandue d’âge archéen tardif qui elle serait associée à l’activité volcanique et à l‘activité intrusive accompagnée de métamorphisme."

Jan 1, 1992

By Terry Aben

Outline ?Review of standards that can be used to identify current coating conditions and optimal points to perform coating maintenance. ?Identify how standards can be used to extrapolate the future condition of coatings to achieve predictive maintenance planning. ?Demonstrate how the above can be combined with project estimating to generate a data driven, quantitative, predictive, risk-based asset integrity maintenance program for Protective Coatings. The Value of Asset Integrity Programs ?Maximize the benefit produced from the investment in maintenance spending. ?Get the best bang for your buck! ?Don?t perform maintenance work before it is necessary ?Money is invested early with no increase in the service life extension. ?Don?t delay until it is too late. ?Planned Maintenance is far less costly than Reactive Maintenance. ?Identify the Optimal Point for Maintenance.

Nov 1, 2011

By C. Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in the flotation circuit were calibrated using a dynamic grinding/flotation simulator. Predicted values are multiplied by g/t ratios to calibrate reagent flow. The transfer functions are currently integrated into the distributed control system at Les Mines Selbaie.INTRODUCTIONThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970's there have been numerous publications dealing with practical applications of flotation process control. A review of that literature shows that basic feedback and feedforward controls are the two preferred strategies for flotation processes. Some advanced control schemes started to emerge (e.g. Zaragoza and Herbst, 1988). Feedforward and feedback aim at reducing the effect of the following flotation process disturbances (e.g. McKee, 1991):0 Changes in throughput;0 Changes in feed grade;0 Changes in particle floatability (size, liberation, surface oxidation ... );0 Deliberate changes of set-point;Feedforward strategy acts on manipulated variables, mainly reagent addition, to attenuate the effect of disturbances such as changes of feed rate and grade. The feedforward strategy is driven by measurements of disturbances. Feedback control acts to compensate unmeasured disturbances, such as ore floatability, and to bring process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by set-point error, caused by either a deliberate change of set-point or unaccounted disturbances.This paper proposes a way to improve feedforward control schemes by addition of a simple model of solids transportation. The feedforward strategy considered in this paper is of ratio type, i.e. the manipulated variable is changed according to a predefined ratio between this variable and the measured disturbances. A typical example is the ratioed reagent addition to mass flow of ore."

Jan 1, 1993

By P. C. Holloway, M. J. Collins, K. R. Buban

Historically, there has been little incentive to process copper-arsenic concentrates by leaching, rather than via established smelting operations. However, with ever tightening environmental emission standards and more arseniferous concentrates being produced, increasingly sophisticated and upgraded off- gas handling facilities are required in smelting operations, generating greater quantities of challenging metallurgical dust. In this context, oxidative pressure leaching offers distinct advantages. The current state of pressure leach technology delivers high extractions from copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. However, as was shown in an earlier study, copper extractions and environmental leach residue stability are impacted negatively by arsenic levels above 2.5 to 3.0 wt%. In further studies on pressure leaching of copper concentrates, Sherritt has developed process conditions that allow even highly arseniferous (> 7 wt% As) feed materials to be converted into environmentally stable residues, with excellent copper extractions. At the same time, pressure leach residues can be generated that are amenable to silver recovery via direct cyanidation, without pre-treatment by lime boiling or hot curing. The results of pilot plant test work are discussed. INTRODUCTION As the production of copper has expanded over the years, resource exploitation has extended beyond relatively clean, high grade and easily accessible ores, and copper sulphide concentrates increasingly come with higher levels of contaminants, such as As, Hg, Sb and Bi, and lower copper and sulphide sulphur concentrations. However, as concerns on the impact of the emission of such contaminants into the natural environment have mounted, import/export restrictions have made the trading of copper concentrate more difficult, and, in particular, the export of concentrates with greater than 0.5 wt% As; under ever tightening environmental emission standards, these lower quality concentrates can be a significant strain on the off-gas handling facilities in smelting operations. The processing of arsenic bearing copper concentrates is, therefore, an increasing challenge as copper producers seek to exploit more complex mineralization and to extend the life of their operations. In this environment, processing arsenical copper concentrates with high temperature pressure leaching (>200°C) must be considered as an alternative to pyrometallurgical processing. Leaching kinetics for copper minerals at these temperatures are rapid and acid is generated for potential use in heap leach operations. Pressure leaching of copper concentrates eliminates gaseous emissions of arsenic and sulphur, while generating environmentally stable residues, as measured by the Toxicity Characteristic Leach Procedure (TCLP) (Kalanchey et al., 2007). Both medium and high temperature pressure leaching of copper concentrates have also proven themselves technically on an industrial scale (Marsden et al., 2004) with high copper recoveries.

Jan 1, 2019

By H. Ardehali, P. Lind

Many gold deposits also contain significant quantities of deleterious elements such as arsenic. Several biological pathways are possible for arsenic exposure; special care and caution must be used while undertaking metallurgical testwork on ores and concentrates that contain high levels of arsenic. Laboratory precautions pertaining to handling of airborne dust concentrations, necessary personal protective equipment, and effluent treatment are discussed.

Jan 1, 2014

By B. R. Maas

Processing material at a consistent rate through the continuous countercurrent decantation (CCD) thickeners presented a major bottle neck to unlocking additional value from one of the post-flotation streams at the Kansanshi processing plant. The manual operation of the thickeners making up the CCD train resulted in frequent imbalances and process upsets across units. The automation of CCD trains is notoriously tricky as the available manipulated variables are outnumbered by the parameters requiring regulation. The implementation of an advanced, auction-based, control philosophy to manage the movement of both slurry and solution inventory through the train addressed this parameter imbalance and lead to the stabilisation of the circuit. Since the commissioning of this control strategy: an additional 7 200 dmt/day (+36% throughput) of material can reliably be processed through the train, the number of monthly downtime events has reduced, and a saving of $354 000/month in reagent cost has been achieved. INTRODUCTION CCD operation Agitated leaching is a common method used in hydrometallurgy to extract a metal from its host ore. The host ore is initially finely ground to liberate the surfaces of the valued minerals and improve the kinetics of the leaching process. The ore is then contacted in an agitated tank with a lixiviant to dissolve the desired metal into the aqueous phase. The resultant slurry from the leaching process comprises of a solution pregnant in the metal salt and a barren ore. The first purification step taken after leaching is to wash the pregnant liquor solution (PLS) from the depleted ore. On the industrial scale, a set of between two to ten thickeners arranged in a countercurrent configuration is often used to carry out this separation (Perry & Chilton, 1973). The slurry is introduced at the head of the train and a wash solution at the tail. The two streams are pumped through each thickener countercurrent to one other. At each stage the residual PLS in the slurry is mixed and diluted down with the countercurrent overflow solution from the downstream thickener. The diluted slurry is fed into the thickener where the solids separate out through gravity sedimentation. The settled solids are channelled towards the underflow of the thickener by a rake mechanism and pumped downstream to the next thickener in the train. The outcome is the recovery of a PLS from the overflow of the lead thickener and a slurry of washed solids from the underflow of the tails thickener.

Jan 1, 2019

By Matthew Russell, Bobby Randhawa, Leopoldo Mariscal Samaniego, Jose A. Puente, D. Brosig, Paykan Safe

The La Caridad copper smelter, located in Nacozari, Mexico, have started a multi-year plan to reduce sulfur dioxide and particulate matter emissions into the environment. In 2014 the smelter completed a voluntary plant-wide SO2 process emissions inventory as part of the smelter’s proactive environmental stewardship policy. In turn, this triggered the development of several environmental projects to alleviate these emissions. A strategy consisting of improved capture efficiency of the sources with greatest impact has been followed to maximize cost-effectiveness. The reduction of secondary emissions from the Teniente Converter, as well as of primary and secondary emissions from the Peirce-Smith Converters have been key areas of priority. Additionally, a new system to capture and recover particulate matter from the Anode Refining Furnaces off-gas is also in the process of being implemented. This paper presents an overview of the work developed behind this effort and the smelter’s vision towards a greener future. INTRODUCTION The La Caridad copper smelter is owned and operated by Metalurgica de Cobre S.A. de C.V. (a subsidiary of Grupo Mexico). Currently, the smelter has a production capacity of 300,000 tonnes of anodic copper per year. The smelter is coupled with a 300,000 t/y electrolytic refinery. Other by-products (such as precious metals and sulfuric acid) are also generated as part of an integrated process. The original smelter started operating in 1986 with one Furukawa concentrate dryer, one Outokumpu Flash Smelting Furnace (FSF), two slag cleaning electric furnaces (SCFs), three Peirce-Smith Converters (PSCs), two Anode Refining Furnaces (ARFs) and one casting wheel. In 1997, a plant expansion project was concluded with the installation of one steam dryer, one Modified Teniente Converter (MTC), one additional ARF, one additional casting wheel, and the electrolytic refinery [1]. Over the years, the smelter management has implemented numerous environmental projects to alleviate SO2 and particulate matter (PM) emissions. The smelter process gas handling system captures the process gases from the FSF, MTC, and the three PSCs. The process gases are cleaned and conditioned and sent to the two acid plants. The first acid plant (with a capacity of 226,000 Nm3/h, wet basis) was commissioned in 1988 to process the FSF and PSC off-gases. A second acid plant (with a capacity of 195,000 Nm3/h, wet basis) was commissioned as part of the smelter expansion project [1]. The PSCs also have a secondary gas handling system with a dedicated baghouse and stack. The Furukawa dryer off-gas reports to a dedicated electrostatic precipitator (ESP) for dedusting before venting via a local stack. Process gas from the two SCFs, along with hygiene ventilation from various sources inside the smelter (including matte and slag tapping hoods from the FSF) report to a baghouse-based gas handling system and vent to atmosphere via a local stack. The original ARFs do not have an off-gas handling system, however, each ARF has a post- combustion chamber which naturally vents the process gases to the atmosphere via a dedicated stack.

Jan 1, 2019

By Bradford C. Wesstrom

An overview of the challenges encountered at the Freeport McMoRan El Paso Copper Refinery with higher concentrations of antimony electrolyte will be shared. The observations will cover the detrimental effects on copper starting sheets, commercial cathodes and anode slimes. The study will show negative effects on quality and productivity. Experimental work will utilize a test cell to study the effects on electrolytes by different Antimony, Arsenic concentration and anode molar ratio. Best practices will be shared for producing high quality cathodes while effectively managing the detrimental effects of higher antimony electrolyte.

Jan 1, 2014

By Marty Hudyma

Mining-induced seismicity and rockbursting is one of the primary risks in deep mines. Seismic data management software has been created to facilitate analysis of mining-induced seismicity. The Mine Seismicity Risk Analysis Program (MS-RAP) is a purpose built database with mine seismicity analysis tools. One of the primary features of MS-RAP is the creation of seismic hazard maps in quasi-real time. The seismic hazard maps identify areas that are more prone to large seismic events and rockbursts, allowing risk management measures to be focused on the areas of greatest risk. These maps allow mining engineers to be more proactive about identifying and managing seismic related geomechanics risks in mines.

Oct 1, 2009

By Rainer Süss

An investigation was carried out by Mintek to investigate the influence of a range of alloying additions (vanadium, cobalt, zirconium, antimony and germanium) on the formability and hardenability of alloys with gold content >90 wt%. This paper reports on the hardening mechanisms that can be utilised to increase the hardness of gold (>90 wt% Au) by conventional alloying, as well as the hardening effect obtained by alloying with specific elements. Preparation methods for the alloys are described, which include the steps of melting, annealing, quenching, cold working and age hardening. Focus is given specifically on alloys that were developed at Mintek with a gold content >90 wt%, which are not only harder, but exhibit good resistance to tarnishing and corrosion.

Oct 1, 2003

By Farzad Mohammadi, Patrick Littlejohn, David Sanguinetti

Arsenic levels in metal concentrates are increasing as mining companies turn to developing low grade and complex ores. When arsenic bearing minerals are smelted, arsenic deports as gases which must be neutralized by a scrubber system. The resulting scrubber effluent is high in dissolved arsenic and requires treatment before the wastewater can be discharged or re-used. Conventional arsenic removal relies on lime addition followed by calcium arsenate formation and precipitation as hydroxides. As an alternative, arsenic removal with sulphide precipitation is receiving more attention due to potential advantages of the technology. Process streams high in arsenic often contain concentrations of dissolved metals that may be selectively recovered during sulphidization, producing a product that can be reprocessed and reducing waste generation. This paper will review laboratory testing completed for arsenic removal through sulphide addition and precipitation of arsenic (III) sulphide in combination with metals recovery to offset arsenic removal costs.

Jan 1, 2014

By Terry McNulty

"Previous papers (McNulty 1998 and 2004) have dealt with the causes of successful and less successful achievement of design production rate by new processing plants in the minerals industry. Examination of many case histories has allowed the construction of curves or profiles that represent projects with similar characteristics that equate to differing degrees of care exercised during the project development phase. Simplistically, decreasing care is reflected by increasing risk and a heightened likelihood of poor technical and/or financial performance.This contribution provides an update, including recent case histories, and presents a modified Series 1A curve that includes the best 23 case histories, out of a total of 81 examined, or 28%. This is done to show that some very carefully developed and executed projects can ramp-up quickly and that owners of new projects should avoid being too pessimistic in projecting early cash flow if they are certain that they have done their homework. The role of metallurgical process development in the reduction of project risk is discussed and several financial analyses are presented that express the potential monetary value of a well-designed and professionally executed metallurgical program."

Jan 1, 2014

By J. N. Cram

"The comments given are to help allay generally accepted ideas that the handling of arsenic as arsenic-trioxide (As2o3J in and from off gas pyrometallurgical operation fumes is difficult, hazardous and expensive. It need not be any of these things if the basic and rather unique chemic3l and physical properties are understood and taken care and advantage of through present day technologies. These particular characteristics are:-(1) As2o3 sublimes and re-condenses, at a relatively low temperature;(2) As2o3 is, for practical in-plant purposes, insoluble in water at ambient temperatures and quite soluble in water just below the boiling point;(3) residual suspended and dissolved As 2o3 can be removed from water by complete dissolution with very little sulfuric acid, followed by the addition of small amounts of ferrous sulfate and calcium chlorate, with oxidation to the ferric and arsenite state and precipitation of an insoluble ferric calcium arsenate, thereby lowering the As2o3 content of solutions to acceptable levels. Even lower levels of non-toxic forms of arsenic solids and residual As2o3 in the water solutions can be attained by also using phosphate, and lime, along with the above.A background re past arsenic processing methods, present day operations, plus predictions re future trends, and hazards, are outlined."

Jan 1, 1979

By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Thorium is frequently the main radioactive element in rare earth ores and is a resource that can potentially substitute for uranium. Thorium must be separated from rare earths in order to obtain products with low radioactivity. There are abundant resources of thorium in the rare earth ores in China, especially in Baiyunebo mixed ores. As an associated element coexisting in rare earth ores, thorium is, or can be, separated from rare earth concentrate, iron concentrate, as well as from waste water and slag to achieve recovery of thorium. The methods of separation include ion exchange resin, liquid-liquid extraction, and liquid-solid extraction. TBP extraction has been the main method applied to separate thorium by domestic and foreign scholars. This paper presents a comparison of different processes for the separation of thorium from rare earth ores, especially Baiyunebo mixed ores, single bastnaesite and monazite ore, and provides suggestions for the future recovery of thorium resources.

Jan 1, 2014

By Timothy W. Ellis

Gold-based materials have been a mainstay of the electronics and semiconductor industry since the physics was just a laboratory curiosity. Gold is the workhorse material in wire bond, flip chip and off wafer interconnections due to its corrosion resistance, ability to form metallurgical bonds by soldering or cold welding, and ease of fabrication. As the electronics and semiconductor industries grew, so did the use, of Gold in spite of the feature size reduction so elegantly demonstrated in Moore?s law. However, several revolutions in the Silicon miracle are threatening Gold?s place as the material of choice. Although cost is always an issue, the limitations are associated with the chemistry of Gold based alloys. Will Gold remain? Emerging requirements of bioelectronics, photonics and power requirements in conventional device represent new opportunities for Gold to shine. Additionally, as the world market demand for electronic, semiconducting, bio-electronic and photonic technology increases, given the right technology, Gold still can provide value proposition.

Oct 1, 2003