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By H. Saeedi Ali, A. J. Monhemius

"Anglo Asian Mining’s Gedabek mine is situated in the Lesser Caucasus mountains in Western Azerbaijan. The ore body is a complex copper-gold porphyry deposit, comprising intermixed oxidized, transition and sulphidic gold and copper-bearing ores. Gold in the sulphide ores is generally not refractory and is recoverable by cyanide leaching, but the secondary copper minerals, which are also cyanide soluble, lead to high cyanide consumptions. Ore processing at Gedabek is by agitation leaching for high grade ore (>1g Au/t) and heap leaching for lower grade ore. In order to cope with the high copper concentrations in the cyanide leach liquors, a unique combination of resin-in-pulp for selective gold extraction and SART processing for copper removal and cyanide recovery is used. In 2015, a flotation plant was added to treat the tailings from the agitation leach plant before the tails are sent to the tailings dam. This plant produces a copper sulphide flotation concentrate and also recovers some of the residual gold and silver in the tailings. Since February 2017, due to lower grades of gold and higher copper in the feed ore, the decision was taken to alter the flow sheet and to carry out flotation ahead of agitation leaching, to reduce the cyanide consumption during leaching by removing soluble copper minerals. The paper compares and contrasts the performance of the plant in the two configurations, namely, (i) leaching followed by flotation and (ii) flotation followed by leaching.INTRODUCTION In May 2009, Anglo Asian Mining started open pit mining for gold on its Gedabek property in the Lesser Caucasus Mountains in western Azerbaijan. Gedabek is situated on the highly mineralized Tethyan Belt that runs from the Himalayas to the Balkans. The ore body at Gedabek is a complex copper-gold porphyry deposit, comprising intermixed oxidized, transition and sulphidic gold-bearing ores. The sulphidic ores contain mainly pyrite and chalcopyrite, with some secondary copper sulphide minerals, such as bornite and chalcocite, and minor amounts of sphalerite, galena and tetrahedrite. Gold in the sulphide ores is generally not refractory and is recoverable by cyanide leaching, but the secondary copper minerals, which are also cyanide soluble, lead to high cyanide consumptions and passivation of free gold."

Jan 1, 2017

By R. Krentz, P. D. Cordingley

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Major changes to the refining process were required when the Moa sulphide feed, with its unusually high cobalt content, was introduced in the early 1990's. In the period 1994 to 2005 the production capacity of the refinery has increased dramatically to match increases at Moa, and significant process improvements incorporated. The process flowsheet consists of the original ammonia leach process, optimized for cobalt chemistry and overall leaching capacity. Extraction of metal values is followed by the unique nickel-cobalt separation technology, in which most of the cobalt is separated from the ammoniacal nickel sulphate leach solution by precipitation as a nickel-cobalt hexammine salt. This salt is refined from a Co:Ni ratio of 1:1 to over 10,000:1 by selectively leaching nickel, redissolution and recrystallization in ammonium sulphate solution. Nickel and cobalt are recovered using the well-known Sherritt hydrogen reduction technology. This paper reviews the chemistry described above, examines some of the changes in operating conditions made over the years and highlights some of the recent physical changes made to the refinery.

Jan 1, 2005

By P. C. Santos-Munguía, F. Nava-Alonso, O. Alonso-González

"The gold recovery of a Mexican cyanidation plant, in Sonora, has been decreasing due to the increasing presence of gold tellurides. This work presents the results of different processes aimed to recover the remaining gold from the cyanidation tailings of the operation. The cyanidation in the mine is performed at 0.1 g/L NaCN and pH = 10.3, adjusted with lime. The treatments studied in the laboratory with these tailings were: cyanidation at higher cyanide concentration than that used in the plant, cyanidation with oxygen injection, cyanidation with oxygen and lead nitrate addition, and thiourea leaching. The results obtained with each of these treatments are presented and discussed with the final objective of proposing a method to recover the gold associated with tellurium.INTRODUCTION It has been demonstrated that gold telluride is refractory to the conventional cyanidation process and, for this reason, some alternative methods to recover precious metals from tellurides have been proposed. (Zhang et al., 2010). These include cyanidation with modified conditions or the use of non-cyanide leaching agents. This work presents the gold leaching results of tests performed with a sample of cyanidation tailings obtained from a Mexican deposit containing telluride species. The mine exploits a mesothermal deposit with a molar Te/Au ratio of 1, containing also lead, molybdenum, bismuth and tungsten. Gold is recovered from the ore by standard cyanidation, however, lately the gold recovery has decreased, likely due to the tellurium content of the ore. The sample used in this work was the cyanidation tailings of this deposit. It was treated in the plant by cyanide heap leaching (0.1 g/L NaCN, pH = 10.3 adjusted with lime). Some gold remained after the cyanidation and it was thought that this gold was associated with tellurium. The objective of this work was the recovery of the remaining gold from the tailings by an alternative process."

Jan 1, 2017

By A. Bezama

For over a decade European countries have addressed contaminated sites by developing technologies for managing both polluted soil and groundwater. This development has not only been driven by health and environmental aspects, but also because of economic pressures, as the remediation and redevelopment of derelict areas can be a meaningful alternative to undeveloped areas for the establishment of new industrial, recreational, housing and service locations. In most developing countries, however, the subject of contaminated sites is a new environmental issue that authorities have recently started to deal with. Among these countries, Chile has just started to prepare the country's legal context as well as to foster the formation of research and investigation groups that will deal with the exploration, investigation and management of contaminated sites. That requires a comprehensive technical, scientific and legal support in this stage. Goal of this article is to present the state-of-the-art technologies for site remediation currently applied in industrialized countries, in order to identify the most interesting approaches that can be implemented within the Chilean situation, especially considering the influence of the copper mining industry on the soil and groundwater quality of the environment surrounding their production facilities.

Jan 1, 2007

By Jan Drzymala, Przemyslaw B. Kowalczuk

Froth flotation is widely used for upgrading of ores and other materials. Efficiency of flotation depends on many parameters, including type, chemical structure and dose of flotation reagents. Selection of a proper frother in flotation depends on the material used, necessary dose of frother and its selectivity. The selectivity of flotation can be characterized by proper separation factors and indices. In this paper separation selectivity and power of frothers were evaluated basing on separation data for a given material and frother, plotted as the recovery of the useful component in the concentrate versus the recovery of the remaining components in the tailing. Such a plot is called the Fuerstenau upgrading curve. The selectivity was defined as the location of the whole upgrading curve in relation to no and ideal separation lines, expressed on the scale from 50 (no separation) to 100% (ideal separation). In turn, the flotation power was defined as the dose of frother to reach a certain upgrading level at which recoveries of the useful and unwanted components are equal. The power and selectivity of frothers were determined for the Kupferschiefer stratiform copper ore floated in the presence of a fixed amount of xanthate and varying doses of frothers using a laboratory flotation machine. Basing on the separation results for different poly(propylene glycol) (CnH2n+1O(C3H6O)mH, CnPm) and poly(ethylene glycol) (CnH2n+1O(C2H4O)mH, CnEm) alkyl ethers, it was found that the concentrate yield and recovery of copper as the useful component in the concentrate were greatly influenced by the type and dose of frother. However, the same results plotted in the form of the Fuerstenau upgrading curve clearly indicated that the selectivity of frothers was similar, while their power was different. It proves that both selectivity and power of frothers are useful parameters for characterizing flotation systems.

Jan 1, 2016

By D. Lascelles, J. A. Finch, E. El-Ammouri

Flotation separation is expected to be related to the degree of dispersion of the pulp. For instance, highly aggregated systems may show reduced selectivity, reduced entrainment and increased flotation rate. In an attempt to test the impact of aggregation on flotation, we have taken advantage of the effect of Mg ions. Using combinations of Mg2+ and pH gave a wide variation in aggregation of several Cu-Zn ores (measured by settling rate) and corresponding flotation response was determined by batch tests. The trials were conducted on-site at Louvicourt and Agnico-Eagle. In a majority of cases a similar trend in aggregation and flotation selectivity (grade at given recovery) was observed. At Louvicourt, improved selectivity with increasing aggregation at pH 10.5 was found. At Agnico-Eagle, an analogous association between aggregation and selectivity was observed at pH 11.5. It is suggested that aggregation influences particle entrainment, the increased effective particle size reducing gangue recovery and hence improving selectivity.

Jan 1, 2004

By Richard E. J. Putman

THE MINERALS INDUSTRY has always been a heavy user of energy in most of its unit operations: power in the mining, comminution, flotation and electro-winning processes; fuel in its smelting and other metallurgical processes; and, of course, fuel in the on-site generation of power and steam. Many of the techniques for using computers to perform energy management and conservation tasks have been known for some time, but they have not been widely implemented because the return on investment has hitherto been insufficient. Recent trends, however, have not only caused the dollar return to rise due to higher purchased energy costs, but the cost of the investment to fall. One trend has been the generally lower cost of computer control systems themselves, due to vendors having adopted the newer, lower-cost and more reliable electronic component technologies now becoming universally available. The second trend is the development of low-cost, but high-speed, remote multiplexing devices, which have reduced considerably the expense of bringing data from points scattered over a wide area, which is typically the case when applying energy management systems to a minerals processing plant. By taking advantage of these and related developments, computer control systems can now have a rewarding impact on plant energy management and conservation practices, and recent advances in application technology have opened up new and additional opportunities for energy cost reduction and control.

Jan 1, 1978

By Alan E. Gallie

FOR many years the Witwatersrand has been the leading gold mining r camp in the world and, to a Canadian mining student, could not fail to be of overwhelming interest. The vast scale upon which the operations are conducted, the enormous production accomplished, and the perfection of the operative technique, have all so forcibly impressed themselves on his memory that it is difficult to select any one feature as more outstanding than another. For the purposes of this paper, however, the author has selected the very first feature of mine operation with which he came in contact, namely, shaft sinking, as it reflects, quite as well as any other, the spirit of mining in South Africa. Early mining in Johannesburg was by open cuts or trenches, dug along the outcrops of the reefs. The ore was thrown from bench to bench to the surface. As the depth increased, rock was hoisted by bullocks. In 1887, the first shafts were sunk and true underground work began. At the same time, boreholes were put down to test the continuity of the reefs at depth. The first was at the Village Main reef. It cut the South reef at 517 feet and the Main reef leader at 581 feet. The Main reef leader assayed eleven penny-weights. Subsequent boreholes proved the reefs down to thousands of feet. Many companies secured deep-level claims as a direct result of the information obtained from the early holes. These companies then held land on which there was no readily available ore. In order to get to their pay rock, vertical shafts through the upper strata were necessary. Shareholders were impatient, and shafts had to be sunk as speedily as possible. The old methods of shaft sinking were investigated, new methods developed, and soon all records were being broken. In the last thirty-five years, the record has been slowly advanced, and last summer it was again broken to stand at 430 feet in a 31-day month. During the period from 1915 to 1935 inclusive, in the Witwatersrand district, 96 miles of shafts were sunk. Today, with the advance in the price of gold and the increase in the mining area, there are over twenty-five major shaft-sinking operations being carried on.

Jan 1, 1937

By C J. Coveney

This paper, after a brief introduction to the mineralization and structure in the mine area, outlines the methods now being employed for grade control at Bethlehem Copper Corporation. Sampling, subgrade drilling, blasting and the actual outlining of the ore are among the topics covered. The paper concludes with a summary of the results obtained, showing a reduction in dilution and an improvement in the grade of the copper ore going to the mill. Introduction T HE Bethlehem property is located in southern British Columbia in the Highland Valley about 30 miles southeast of the town of Ashcroft. The property is located within the Guichon batholith. The rock comprising the batholith is a massive, coarse-textured diorite, which, at Bethlehem, has been intruded by a younger quartz diorite, porphyries and breccia, referred to as the "Younger Complex." Mineralization, consisting of chalcopyrite and bornite with minor pyrite and molybdenite, occurs as disseminations, fracture fillings and coarse blebs. The ore zone lies close to the Guichon -Younger Complex contact where, prior to the development of the breccia, the rocks were shattered and jointed. Subsequent mineral

Jan 1, 1965

By Grant J. Goddard

"The Iron Ore Company of Canada (IOC) has been in operation for over 30 years. Today, and in the future, technology and its application will play an ever more critical role in the company’s business success.The Carol Mining and Concentrating (CMC) division of IOC is energetically applying technology today to enhance performance and results, and is aggressively exploring opportunities to apply technology to support improved business results in the future.A critical area of focus is the application of technology to maintenance management performance. CMC has taken a “back to basics” approach to the fundamentals of maintenance management in 1995 and 1996. In parallel, the mine is aggressively implementing its Vision 2000 maintenance integration plan. This plan is targeted at levering the energies applied to sound maintenance management fundamentals as the company moves to a fully condition based maintenance approach.This paper discusses some of the strategies, key technologies and objectives of theVision 2000 maintenance integration plan at the mining operations of IOC."

Jan 1, 1996

By N. Hosking, M. Nichols

Aluminum alloys are increasingly used for automotive body construction but are susceptible to filiform corrosion or paint blistering in service. Filiform corrosion resistance of two 6000-series aluminum alloys was investigated in this work. Test panels were produced with full automotive coating layers and scribed parallel and perpendicular to the rolling direction. The corrosion exposure comprised an inoculation step with acidified salt solution followed by a 6-week exposure period at 95% relative humidity and either 25°C or 70°C. Greatest corrosion activity was measured on the alloy with higher copper content, AA6111. Higher temperature exposure led to greatly enhanced corrosion activity for AA6111 compared to the lower temperature exposure. The 70°C exposure also led to greater mean corrosion-affected area measurements for the low copper aluminum alloy, AA6022, but the effect was not as stark as that observed for AA6111. Rolling direction affected the propagation direction, and possibly mechanism, of the corrosion effects. Cross-sectional analysis revealed dense corrosion products within the filament, comprising mostly aluminum and oxygen but with traces of chloride and sulphate. Development of varying filament and blister types on a single test panel and the progression of corrosion underneath a filament into the substrate indicate that several corrosion mechanisms can develop on the test panel, testament to the complexity of the corroding surface developed on an aluminum automotive body panel.

Jan 1, 2015

By A. Coulombe

"RésuméL’analyse des séquences d’exploitation, actuellement en usage pour les gisements très inclinés, a démontré qu’elles ne sont pas toujours optimales du point de vue du contrôle des terrains et de la concentration des travaux d’abattage (nombre de chantiers simultanément en opération). Effectivement plusieurs séquences sont très propices à la création des nombreuses zones de hautes contraintes, qui sont à l’origine des effets de pilier. L’étude de cas de la mine Lac Shortt a démontré que certaines séquences d’exploitation, actuellement en usage, ne sont surtout pas adéquates dans le cas d’un état élevé des contraintes naturelles. En effet la mine a eu de sérieuses problèmes avec le contrôle des terrains (coups de terrains et les effondrements des épontes). Ces effondrements étaient responsables de la dilution excessive et des pertes importantes des réserves minières. Les deux nouvelles séquences proposées, visent la meilleure redistribution des contraintes d’exploitation en vue d’éliminer la création des effets de pilier. En plus elles permettent une concentration plus élevée des travaux d’abattage.À notre avis les séquences proposées pourraient améliorer substantiellement la stabilité des chantiers d’abattage et par la suite les performances technique et économique des opérations souterraines. ABSTRACTThe planning of underground mining sequences represents an important aspect of the mining operation. The analysis of mining sequences actually in use for very steep orebodies has demonstrated that they are not always optimal, considering ground control and the number of stopes simultaneously in extraction. These sequences are conducive to the creation in the rockmass of several stressed zones caused by pillar effects. The case study of Lac Shortt mine showed that the sequences of exploitation currently in use are not adequate especially in the case of a high state of the natural constraints. Indeed, the mine had serious problems with ground control (rock bursts and collapse of walls). These collapses were responsible for excessive dilution and significant losses of mining reserves. The two new sequences suggested aim for the best redistribution of exploitation constraints in order to eliminate creation of pillar effects. Moreover, they allow a higher number of stopes to be extracted simultaneously. In the opinion of the authors, the sequences suggested could substantially improve the stability of working areas and, thereafter, technical and economical performances of the underground operations."

Jan 1, 1998

"The successful commissioning and ramp up of the Albion Process™ at the GPM Gold Project relied on the successful scaling up of the process from batch and continuous pilot plant campaigns (Voigt et al., 2015). Critical information about reaction kinetics and residence time, grind size and pulp density were determined at the laboratory scale and successfully applied to the commercial scale. A limitation of small scale testwork, is that some parameters cannot be measured reliably and scaling up is a function of the physical size of the equipment which isn’t possible to test with laboratory scale equipment. Oxygen mass transfer rate is one such parameter since this is a complex interaction of many factors including slurry temperature, solution and slurry chemistry, slurry viscosity, agitator type, dimensions and power, oxygen bubble residence time, oxygen purity, tank geometry and oxygen injection technique. Oxygen generation represents an important operating cost for the Albion Process™. Pivotal to the Albion Process™ operating economically at atmospheric pressure is the capability to efficiently transfer oxygen while utilising as much oxygen injected to the process as possible. To respond to this Glencore Technology developed the HyperSpargeTM supersonic gas injector. This paper compares the HyperSparge™ against other sparging techniques to quantify the benefits of oxygen injection via a supersonic gas jet on scale up of the oxygen mass transfer system. The paper then examines plant survey data from the GPM Gold Project to demonstrate the very high oxygen utilisation that can be achieved with a correctly designed oxygen mass transfer system.INTRODUCTION One of the main challenges in chemical reactor design is the scale-up of processes from the laboratory to industrial scale. Processes which cannot be faithfully simulated with an experiment at the laboratory scale face challenges due to the physical dimensions and complexity of full scale operation. One example of this is the design of oxygen mass transfer systems in atmospheric oxidative leaching circuits such as the Albion Process™. A number of constraints associated with the use of laboratory scale equipment to design full scale circuits are involved in gas mass transfer processes in agitated slurries such as the Albion Process. Chiefly, typical laboratory and pilot size equipment lacks the required volume to provide useful design data without relying on empirical correlations: the specific agitator power input is artificially high, the bubble residence time in the vessel is artificially low, the oxygen partial pressure at the base of the vessel is artificially low and the oxygen delivery method may differ significantly to the industrial process. Further, the dynamic nature of the process introduces additional impacts on gas mass transfer, including the presence of solids, recycle streams and minor elements, plus the variances within the reality of a process plant such as disruptions or variance of feed quality."

Jan 1, 2017

By S. Esfahani, M. Barati

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, slags with different basicities were studied during non-isothermal cooling. Their continuous cooling transformation (CCT) diagram were plotted and compared with each other. Then, a mathematical model was developed that predicts the amount of crystallization during cooling. The results were validated by experiments performed by Single Hot Thermocouple Technique and image analysis. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow optimizing the slag/air ratio for both heat recovery and slag glass content.

Jan 1, 2015

By S. Razavialavi

In the planning phase of every construction project, layout of temporary facilities is a crucial task; site layout can affect safety, travel cost and time, construction productivity, and space utilization. However, site layout planning can be a complicated problem, due to the interdependency of influencing factors. Although interaction among activities is one of the major drivers of site layout planning, it has not been properly addressed in past research. In this study, simulation is presented as a promising tool to address this gap. The capability of simulation technology to model complex processes in construction projects makes use of simulation tools in site layout optimization problems effective, while existing methods are unable to perfectly model these problems, in some cases. Additionally, the advantages and challenges of implementing simulation are assessed and a generic framework for simulation application in site layout planning is proposed.

Aug 1, 2013

By Gaston Gendreau, Marcel Allard

"Sidbec-Normines Inc. est une société formée de trios partenaires soient: Sidbec, British Steel Corporation et la Compagnie Minière Quebec Cartier. L'objectif de l'opération minière est d'exploiter à ciel ouvert le gisement d'hématite spéculaire de Fire Lake et de produire au concentrateur de Lac-Jeannine, près de la ville de Gagnon, 6 million de tonnes de concentré pour alimenter l'usine de bouletage de Port Cartier.Le présent exposé a pour but de fa ire ressortier les caractéristiques d'une opération dont la mine est située à plus de 100 km du concentrateur, d'en faire ressortir les particularités touchant le transport du personnel et du minerai. En plus, on traitera de l'importance dans une telle situation d'une organisation efficace dans la gestion des services et de l'opération (atelier, concasseur, entrepôt, etc.).IntroductionSidbec-Normines Inc . a entrepris l'exploitation minière du gisement de Fire Lake, le 1er janvier 1977. Le but de l'entreprise est de produire annuellement six millions (6 000 000) de tonnes de concentré d'hématite (oxide de fer) titrant 66% Fe au concentrateur de Lac-Jeannine a partir d'un minerai d'une teneur moyenne de 33% Fe, extrait de la mine de Fire Lake. Ce concentré est ensuite achemine à Port-Cartier et alimente I'usine de bouletage.Les installations minières de Sidbec-Normines sont situées a trois endroits différents : la mine à Fire Lake, le concentrateur à Lac-Jeannine et l'usine de bouletage à Port-Cartier. La mine de Fire Lake se situe à 83 km de la ville de Gagnon et à 100 km du concentrateur de Lac-Jeannine. Une route provinciale relie la ville à la mine et au concentrateur. Le minerai est acheminé de la mine au concentrateur par chemin de fer et le concentré est transporté par train sur une distance de 309 km à l'usine de bouletage de Port-Cartier."

Jan 1, 1982

"These guidelines set out information on timely disclosure of news releases which are intended to provide, existing shareholders and potential investors, factual information on which a reasoned investment decision can be made.Consider the problems and concerns raised by the following hypothetical news releases:Natural Resource Company""The Company has recently optioned a large and exciting gold property near the ""XXX"" gold discovery area. In describing the property, the Company's independent consultant has said: ""The favourable location of, and some of the results of prior work done on the property give the Company a worthwhile mineral exploration opportunity .... "". The Company proposes to expeditiously conduct a sizeable exploration program on the property as soon as the appropriate financing has been arranged.""Non-Resource Company""Based on discussions with several European countries, the Company anticipates that it will have orders to ship over 200,000 crates of widgets to those European countries over the next two years. These orders, which considerably exceed the Company's forecasts for the first year, represent a projected profit to the Company in excess of $1,000,000 over the next five year period.""GuidelinesTimely disclosure news releases are intended to provide, to both existing shareholders and potential investors, factual information on which a reasoned investment decision can be made. National Instrument 43-101 Standards of Disclosure for Mineral Projects provides requirements for disclosure of a scientific or technical nature for a mineral resource company.The examples do not provide sufficient detail and are misleading because material information is omitted. The following guidelines should be observed when preparing a news release:"

Jan 1, 2003

By L. T. Raevskaia

We discuss the stability problem of a piston of the reversible axial-piston pneumatic motor called DAR-14M. We performed the full analysis of stress and deformation characteristics of the piston near a resonant frequency with the help of FEM ANSYS. We estimated the own frequency of the piston analytically for the given motor, this estimate was confirmed numerically in the model analysis FEM ANSYS. It was also shown in harmonic analysis that loaded piston end behaves very different in comparison to the unloaded end. As expected, maximum deformation was found in the area of the holes of the bearing shaft, indicating an optimization necessary in that region of the motor.

Aug 1, 2013

By B. Panton, J. Carvalho, E. T. Brown

"A major consideration in the design of high capacity tiedown anchors for dam, bridge and tower foundations is the tensile resistance of the rock mass to pullout, typically as a result of overturning moments or hydrostatic uplift. Rock mass pullout capacity for installed anchors is developed from the tensile strength and fracture propagation properties of intact rock, the orientation and physical properties of the discontinuities and anchor confinement at depth. The typically assumed, but generally conservative, design approach is to calculate anchor pullout capacity using the dead weight of a uniformly shaped inverted “cone” with an assumed initiation point and breakout angle. In some cases, some tensile or shear strength is considered across the area of the assumed pullout cone, however, these strength estimates are based primarily on based on limited historic testing data, empirical relationships for rock mass strength developed for other applications, and engineering judgement.As an alternative to the current foundation anchor design method, this paper presents a new approach to the rock cone pullout problem using Discrete Fracture Networks (DFN) combined with numerical simulations. The simulations presented in the paper investigate the influence of fractures in a synthetic rock mass on ultimate anchor strength. In addition, the global influence on fracture network statistics on rock mass pullout failure is also discussed and it is contended that some of the aleatory and epistemic uncertainty inherent in the design of rock anchors can be reduced by considering fracture statistics in anchor design."

Jan 1, 2015

By J. T. Liu, G. H. Han, W. C. Chai, Y. F. Huang

"In beneficiation process, metal ions could adsorb onto clay mineral surfaces or interact with flotation chemicals, and then result in the flotation behavior changing of desired minerals. Al(III) is the dominating ion existing in the bauxite flotation system. In this research, the adsorption behaviors of Al(III) on two silicate clay minerals (including bentonite and kaolin) were investigated by means of UV-Vis spectra, zeta potential testing and scanning electron micrograph analysis. The adsorption experiment results show that the adsorption capacity of clays for Al(III) ions increases with the initial Al(III) concentration, contact time and solution pH. There are some different adsorption behaviours for two clays. Increasing the clay concentration decreases the adsorption capacity of bentonite, while increases first then decreases for kaolin. Higher temperature favours the adsorption of Al(III) on bentonite but goes against for kaolin. The adsorption capacities of bentonite and kaolin for Al(III) respectively reach 12.48 and 0.875 mg/g at initial solution pH 5. Zeta potential results show that the adsorption of Al(III) on two clays is characterized by electrostatic attraction mechanism.INTRODUCTIONIn beneficiation process, there is inevitably a wide variety of metal ions generated from mineral crushing, mineral dissolution and water chemistry conditions. Metal ions adsorb on the mineral surfaces or interact with the beneficiation agents, affecting the flotation efficiency of desired minerals (DiFeo et al., 2001; Parolis et al., 2008; Shackleton et al., 2012; Shengo et al., 2014). Therefore, it is necessary to have a detailed investigation on the adsorption behaviour of metal ions on clay minerals.Having good ion exchange capacity and negative surface charge, the clay minerals could take up various metal ions from the mineral-water system. Bentonite and kaolin are very common aluminosilicate clays in the mineral processing system. These two clays both hold a permanent negative charge, =X- on the basal surfaces, and a smaller variable charge, =SiOH on the mineral edges (Gu & Evans, 2008; (Gu et al., 2010). Adsorption experiments are usually used to study the adsorption affinity of metal ions for clay minerals (Sen & Bhattacharyya, 2012). The adsorption of Zn(II), Cu(II) and Pb(II) onto natural bentonite showed that the adsorption amounts of metal ions increase with contact time, solution pH and metal ion concentration, but decreases with adsorbent concentration and system temperature (Sen & Gomez, 2011; Melichova & Hromada, 2013). Cr(III) adsorption on bentonite was significantly pH dependent. The adsorption process followed pseudo-second-order model and the equilibrium adsorption was consistent with Freundlich isotherm (Lollino et al., 2015). The adsorption behaviours of Pb(II), Cd(II), Ni(II) and Cu(II) onto kaolin indicated that increasing pH favoured the adsorption of metal ions (Jiang et al., 2010). The adsorption of Cd(II), Cu(II), Pb(II) and Zn(II) onto kaolin showed that an ion-exchange reaction occurred at pH<7.0 and inner-sphere surface complexes were prone to form at higher pH (Srivastava et al., 2005)."

Jan 1, 2016