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By G. W. Sparkes

The use of CR-39 plastic polymer as a solid state nuclear track detector in the textural analysis of radioactive minerals in geological samples was first described by I.R Basham in 1981. CR-39 autoradiographs provide a detailed, high-resolution image of the in situ distribution of the radioactive minerals within geological samples on both the macroscopic and microscopic scales. This technique is an inexpensive and effective means of obtaining detailed textural information that provides insight into the style of mineralization, its relationship to primary and secondary structures in the host rock, and its association with particular geological features or mineral phases. Although this technique does not provide any information on the identity of the minerals responsible for the radioactivity, the resultant autoradiographs can be used to select regions for further detailed analysis such as petrography, microprobe analysis, or SEM imaging. This paper summarizes the procedure and outlines the appropriate time and materials required for both the exposure and etching of the CR-39 with respect to the intensity of the radioactivity emitted by the geological samples.

Jan 1, 2013

By R. ZapataN.

"In the following report, Altonorte Smelter owned by Xstrata will explain its experience with its denominated furnace called ""Continuous Altonorte Reactor"" since started up in March 2002. The Reactor is the main and only smelting furnace since the operation of Reverb Furnace was stopped (15 days after the start up of the Reactor) and it can be operate with dry concentrate for injection by tuyere and wet concentrated via Garr Gun when the injection system fails. From the started up of the Reactor, three operational campaigns have been carried out where in each one they have been increased their smelting throughput and availability. The flexibility reached by the technology bath smelting has allowed a high level of smelting of concentrate and revert materials. The high availability of the Reactor and overcoming problems that were considered of high complexity like the extraction of white metal and slag, refractory campaign, etc. has allowed the Altonorte smelter to project to smelting 1,200,000 tonnes per year with its only Reactor in next year."

Jan 1, 2007

By C. O. Campbell

THE recognition by C. W. McKee, field engineer for Springer Sturgeon Gold Mines, Limited, in the fall of 1940, of the economic possibilities of a small outcrop of baryres near Pembroke, in Hants county, Nova Scotia, followed by aggressive exploration and development by the Company, has placed Canada for the first time in its history in the position of becoming a major producer of barytes and its products. In past years, production of this mineral in Canada has been unimportant. Thus the coral output from 1885 ro 1933, inclusive, amounted to only 41,027 short tons, following which there was no production until 1939. Deposits in Nova Scotia, and particularly in the Lake Ainslie district, Cape Breton, have been the main source of supply, with a production between 1866 and 1925 of 31,689 tons. Following the examination of the outcrop of baryres near Pembroke by Mr. C. W. McKee in October, 1940, the area surrounding it was trenched, and, as this work gave encouraging results, a diamond drilling programme was commenced. A grid system was laid our and sixteen holes aggregating 2809.3 feet were put down, spaced at 100-foot intervals, the deepest hole being 300 feet. This drilling outlined a body of high-grade baryres over 600 feet long and 200 to 250 feet wide, with an average depth of 120 feet and estimated to contain well over one million tons of ore. The limits of the body were reached on the west, north, and southwest, but the drilling was suspended before the eastern limit was determined. Quarrying operations, and construction of a 100-ton mill, were commenced in February, 1941. The mill was placed in operation on May 29th, and on June 15th, eight months after the initial discovery, the first shipment of 2,500 long rons of milled baryres was made to Trinidad, British West Indies.

Jan 1, 1942

By A. Saki, P. Gebski, W. Ying

Industrial smelting furnaces are subjected to significant structural changes and deterioration caused by the conditions under which they operate. The current methods for the structural assessment of furnaces include visual inspections, analysis of thermal data, acousto ultrasonic-echo (AU-E) of the refractory lining and surveying of the key structural elements. Acoustic Emission (AE) non-destructive testing (NDT) technique has proven its capabilities for continuous monitoring of industrial installations and structures. Recently, Hatch Ltd. has been successful in applying acoustic emission for monitoring furnace tapblocks, and expanding the scope of the acoustic emission monitoring to the structural integrity of the entire furnace. The capability of detecting emissions related to the fracture development in the furnace shell, movement of the refractory, electrode arcing, combined with efficient source location algorithms makes an acoustic emission system a comprehensive tool for the real-time furnace integrity monitoring. In this paper the concept of such state of the art system for structural integrity assessment is presented. The initial results of the acoustic emission monitoring together with data analysis techniques are discussed.

Jan 1, 2011

By Zihe Ren, Edouard Asselin, Marcus Tomlinson, Tianbi Zhang, Jing Liu

"Raman spectroscopy is used to quantify the extent of disorder in the carbonaceous matter associated with preg-robbing ores. Previous studies of Goldstrike ores showed that the height and width of the peaks for the “D” (disordered) and “G” (graphite) bands, the so-called “Raman ratio” had a strong correlation to the preg-robbing value (PRV) measured for various ore samples. A brief literature review on Raman spectroscopy as it applies to preg-robbing ores is presented. Further, recent studies, presented here, have shown no correlation between the Raman ratio and the PRV for a wide variety of ores. This suggests that the extent of organic carbon crystal disorder is not the main factor in determining preg-robbing characteristics.INTRODUCTION Valuable base metals, such as nickel, cobalt, molybdenum, vanadium and tungsten, are used in a wide range of important technological applications. The demand for many of these metals has increased significantly over the last few decades, driven especially by economic expansion in Asia generally and China in particular. This has led in turn to a large growth in the output of mines in order to satisfy this increasing demand, as shown by the data in Table 1 (USGS, 1994, 2014). These data reflect an even longer trend of growth of these metals, with nickel, for example, showing an average rate of 5.3% per year from 1980 until 2015 (International Nickel Study Group, 2017). This rapid and sustained rate of growth means that annual mine outputs for nickel, tungsten, molybdenum and vanadium have had to double roughly every 11 to 14 years, whilst cobalt mine output has had to double roughly every 7 years, over the period from 1994 until 2014. With the average working life of a nickel mine being between 17 and 22 years (Statista, 2017), this means that from the time a nickel mine opens until it closes, the industry needs to find the equivalent of another three or four mines of a similar output to satisfy this relentless growth in demand for the metal."

Jan 1, 2017

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

By Elma van der Lingen

Gold is considered the most inert of all metallic elements, but the metal can show catalytic activity when prepared by specific techniques. Preparation techniques being used to prepare gold catalysts systems mainly involve precipitation methods incorporating gold compounds or complexes. This paper introduces a totally different method for the preparation of gold-based heterogeneous catalysts that can be used for oxidation and reduction reactions, as well as electrocatalysts. The method involves alloying of gold with a less noble metal, such as aluminium, to form a gold-containing intermetallic precursor. AuAl2 was produced by melting gold and aluminium together in a vacuum arc furnace under a protective atmosphere. The aluminium is then dissolved from the AuAl2 precursor by means of NaOH to produce a highly porous gold structure. The paper also reports on a method of incorporating transition metal oxide(s) with the porous gold to form an active heterogeneous catalyst. Promoter elements can also be melted with AuAl2 to improve catalytic activity. Alloying has the advantage that the promoter element can be in contact on atomic level with the gold. In-situ xray photoelectron spectroscopy (XPS) studies have also been done on the porous gold catalysts to further clarify the CO oxidation mechanism on gold-based catalysts.

Oct 1, 2003

By Ralph L. Rutherford

Geologists or mining engineers familiar with geology are frequently requested by mine operators to give correlation in-formation regarding some mining property with respect to an adjacent area on one at some greater distance. It is the object of this article to mention a few of the difficulties involved in securing this information and to point out some of the salient factors upon which correlation is dependent. In view of the nature of the following discussion, a brief statement of the general character of coal formations .. seems appropriate. Coal formations, by reason of their environment of deposition which is in fresh or brackish water, exhibit the features common to continental deposits, in contrast to those of marine deposits. Such deposits are characterized by rapid variation in thickness and in lithological character both later-ally and vertically. (Plate 1 A). They consist essentially of sandstones and clay shales with all gradations between them, and also a few beds of coal and frequently some conglomerates.

Jan 1, 1924

By B. A. McKee, T. Adamcewicz

For a capital expenditure of only $46,000, Caland Ore Company has successfully converted its three dry grinding center peripheral discharge rod mills to dry grinding ball mills. The conversion has resulted in a significant capacity increase, operating cost reductions and in-plant environmental improvements. This paper describes why and how• the conversion was made.

Jan 1, 1972

By Lorne Sivertson, Peter Kitrredge

"World metallurgical coal imports totalled 110million tonnes in 1978. Of this amount, Japan imported 50 million tonnes, making it by far the largest and most important coking coal market . British Columbia and Alberta exported 12.0 million tonnes of coking coal in 1978, or 11% of the world total. Virtually all of these exports were directed to Japan, making up 22% of total imports.Some observers have suggested that because Japan is almost the exclusive buyer of British Columbia and Alberta metallurgical coal, the benefits of the coal trade may be primarily on the side of the powerful Japanese buyers. Buttressing this suspicion is the fact that Japanese trading companies have taken substantial equity positions in B.C. coal mines, thus presenting the possibility of non-arms-Iength transfer arrangements. There is then at least some evidence to support the hypothesis that Canada's western coal producers receive prices that are less than would prevail in a more competitive market; that is, that they are exploited.This paper produces evidence that Canada's coals are not underpriced in respect to U.S. and world markets. The conclusion is drawn that British Columbia and Alberta metallurgical coals receive prices that are equal to prices known to be competitively determined. This conclusion follows an in-depth analysis of prices, coal qualities and the economic characteristics of all major coals traded in the Japanese market. A by-product of the analysis is an equation capable of predicting the value of any metallurgical coal sold to Japanese buyers, or, for that matter, any buyer. Hopefully, this can be of some use to coal producers in developing their marketing strategies."

Jan 1, 1980

By W. G. Q. Johnston, J. S. Fox

"A semi-continuous belt of Aphebian magnesian extrusive and related sub volcanic rocks has been delineated by the authors over a distance of 150 kilometres in the central La Ronge lithostructural domain in Saskatchewan. They range in composition from peridotite to basalt and attain true thicknesses of up to 800 metres. For the most part, they are confined to a basal position in the La Ronge/Wasekwan metavolcanic sequence, and appear to have been extruded onto sialic crust. However, at Lynn Lake, Manitoba, in the eastern continuation of the domain, similar rocks seem to be found only at a relatively high stratigraphic level.Although metamorphism seems to have obliterated any quench textures that may have existed in these rocks, ultramafic pyroclastics, pillows and amygdules as well as intercalated, fine-grained clastic sediment attest to the volcanic nature of these rocks. Bulk chemical analyses indicate that these rocks are heterogeneous, with komatiites, tholeiitic picrites and even rocks with some of the characteristics of boninite all being present. The close temporal and spatial relationship of ""boninites"" and komatiites in the belt may suggest a high degree of Aphebian mantle inhomogeneity in the domain.Nickel-copper mineralization has been found in differentiated tholeiitic stocks within the La Range domain (e.g., at Lynn Lake), but none has yet been found in the ultramafic volcanics. However, the tholeiitic picrites do host one economic gold deposit - the Agassiz Mine at Lynn Lake .Because of the depleted nature of their mantle source, the ""boninites"" of the domain are not considered to be likely hosts for mantle-derived nickel sulphide mineralization. However, the opposite is true of the komatiites, and this points to the need for whole-rock geochemistry in setting priorities for nickel exploration in the belt. In contrast, all of the magnesian rocks of the domain probably have the same gold potential. Inasmuch as the geophysical response to gold mineralization in the domain is likely to be unpredictable, lake-sediment geochemistry, followed by base-of-till and/or alteration oriented lithogeochemistry, should be emphasized during gold exploration."

Jan 1, 1981

By Hyung Sup Choi

The preparation of high-purity zirconyl compounds was studied in order to develop an economical process for obtaining pure zirconium via the caustic fritting of zircon sand. The direct dissolution of caustic frits with concentrated hydrochloric or nitric acid at 80c. followed by the addition of a small amount of acidified gelatin, gave high-purity zirconyl chloride or nitrate. The addition of a small amount of gelatin caused a mutual flocculation between colloidal silica and gelatin. The precipitation of this silica floc markedly lowered the content of silica in the product. The silica content of the compounds (or solution) so produced, generally less than 100 ppm., was sufficiently low for tributyl phosphate extraction for nitrate solutions. It was found that the degree of purification de-pends not only on the procedures employed but also on the nature of the frit itself. Silica was more effectively eliminated from the fritted product produced at higher temperatures, and less silica was present in the com-pound prepared from the frit produced in a shorter heating time. In order to ascertain the nature of the

Jan 1, 1965

By Adam Moore, Ryan Gillespie, Jarrett Quinn, Audrey Walters, Peter Radziszewski

"Vale Long Harbour Processing Plant (LHPP) was designed to process Voisey’s Bay nickel concentrate into finished nickel and associated copper and cobalt products. The plant includes a secondary grinding circuit comprising two Stirred Media Detritors (SMDs) operating in parallel. The ultrafine grinding circuit was designed to process concentrate at a rate of 33 t/h and produce a ground product (P80) of 20 µm to feed the leach circuits. Start-up of the grinding circuit at LHPP was undertaken in December 2014.The objective of this paper will be to describe the design, commissioning, start-up and performance of the secondary grinding circuit with a focus on the two Metso SMD-355-C mills. Following a brief overview of Vale’s LHPP and the SMD technology, the paper will review the design of the SMD secondary grinding circuit from lab tests through to scale-up performance prediction. This will be followed by the results of circuit commissioning outlining some of the issues raised and addressed after which SMD performance will be outlined. Specifically, the SMD circuit grinding performance will be examined since start-up which will include the effect of media size and wear on grinding. Furthermore, impeller wear will be examined by determining initial “shear volume” and worn “shear volume” as well as its effect on mill power and the means to maintain it. The paper closes with a discussion on grinding performance."

Jan 1, 2016

By J. F. Adams, V. G. Papangelakis

Chemical modelling is becoming increasingly useful in the development, analysis, design, and control of hydrometallurgical processes. The paper presents the development of reliable databases for chemical modelling of selected hydrometallurgical systems using state-of-the-art software, such as OLI. The modelling strategies are also demonstrated. The high pressure acid leaching (HP AL) of laterites, oxygen solubility in the oxidative leaching process of zinc sulfide, gypsum solubility and lead chemistry in mixed sulfate-chloride solutions are presented as case studies. This on-going work attempts to bridge the gap between theoretical research and industry needs. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists ofCIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By M. Behrouz

Thermal power plants convert thermal energy due to nuclear reactions or the combustion of coal, gas, heavy oil, or some other hydrocarbon to electrical energy. They consist of a variety of equipment, such as boilers, turbines, generators, cooling towers, and auxiliary equipment. Any factor that affects the equipment efficiency affects the overall efficiency. Analysis of the cooling tower and raw water using the Langlier Saturation and Ryznar Stability Indices showed that the cooling water at Sarchesmeh was slightly scaling with respect to silica. Cold lime softening was found to be a cost-effective method to produce cooling water with adequate properties to reduce the cooling water make up from 85 to 70 m3/h and blow down rate from 35 to 20 m3/h.

Jan 1, 2007

By W. D. Gould, A. Kapoor

Acid mine drainage (AMD) is characterized by low pH and high concentrations of sulfate and dissolved metals such as iron, manganese, aluminum, zinc, and copper. Chemical treatment of AMD achieves pH neutralization and toxic metal removal but also produces large quantities of bulky sludge that requires long-term storage facilities and monitoring. Chemical treatment of AMD achieves only partial removal of sulfate (SO4) and total dissolved solids. Sulfate reducing bacteria (SRB) have been used for the removal of sulfate from industrial process wastewaters. The biological sulfate reduction process generates sulfide and alkalinity. The sulfide produced in the biological sulfate reduction process is used to precipitate metals present in AMD as their respective sulfides and the alkalinity generated is used to neutralize the AMD. This review article will present an overview of biological sulfate reduction processes using SRB, bioreactor configurations, AMD treatment studies, and full-scale systems in operation for the treatment of acid mine drainage.

Jan 1, 2004

By Edward Thomas

Note. - Securing mine roof through consolidating thin or otherwise incompetent strata to increase overall thickness of the immediate roof beam is a new method of roof support and control which has aroused great interest amongst mining engineers and which is now being experimented with and thoroughly investigated by the United States Bureau of Mines. A paper on Roof Bolting, illustrated by photographs and motion-picture films, will be presented by Edward Thomas, of the U. S. Bureau of Mines, at the forthcoming Annual Meeting of the Mining Society of Nova Scotia. In the following pages, Mr. Thomas describes the methods used in roof bolting as illustrated by the photographs that accompanied his paper. The photographs are supplied through the courtesy of the United States Bureau of Mines, whose willing cooperation with miners and mining engineers in Canada is very well known and even more greatly appreciated. This method of publishing Mr. Thomas's paper is adopted because few, if any, Canadian mining engineers have actually seen installations of roof bolts and it is felt that the best possible presentation of such an interesting subject through the medium of the Bulletin will be attained by publication of the photograps over explanatory captions. - Ed.

Jan 1, 1950

By B. A. Strathdee

An arsenical ore containing both pyrite and arsenopyrite was heated to a temperature at which decomposition and distillation took place. The condensate consisted of metallic arsenic and arsenic disulphide, although the analysis of the ore showed that volatile arsenic and sulphur were present in proportion to produce a condensate of arsenic trisulphide and sulphur. Distillation tests on the mineral arsenopyrite also produced a condensate of metallic arsenic and arsenic disulphide. This arsenic sulphide gave a distinct x-ray diffraction pattern which was not listed in the A.S.T.M. data file. This same sulphide can be produced by heating a mixture of arsenic and sulphur in vacuo. Its chemical analysis corresponds to As2S2. The dissociation pressures of arsenopyrite and the vapour pressures of arsenic disulphide and arsenic metal were measured, using a quartz "spoon" gauge. The dissociation pressures of arsenopyrite were compared with the published data for the dissociation pressures of pyrite to account

Jan 1, 1961

By A. Aaltonen, S. Paloranta, H. Myllykangas

A property based dynamic model of flotation was built and validated for training purposes. The model is based on the work of the AMIRA P9 project. The recovery of each particle with composition and size is calculated in a given simulation step. The model takes into account machine and operational parameters such as air flowrate and froth height. The model was created using fullscale test data on Pyhlisalmi Cu-Zn-pyrite ore with flotation kinetics of multiphase particles determined. Simulation and validation shows that model can predict the dynamic behavior of the process accurately enough for training purposes.

Jan 1, 2009