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By Kevin P. Plucknett, Z. Memarrashidi

"In the current work, factors influencing the corrosion mechanisms of TiC and Ti(C,N) based cermets are reviewed. Cermets were typically prepared with 30 vol.% of metal binder, in the form of various in-situ reaction-formed Ni3Al alloys. Commercial WC-Co hardmetals were also examined as baseline materials. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential and potentiodynamic polarisation. The corrosion potential and current density were determined, following Tafel extrapolation, allowing estimation of the corrosion rates. Post-corrosion characterisation involved scanning electron microscopy analysis and associated energy dispersive X-ray spectroscopy of the sample surfaces. It is demonstrated that the primary corrosion mechanism for this type of cermet is dissolution of the metallic phase during oxidation attack, and thus this response can be expected to increase with the amount of binder in the cermet, although degradation can be subtly affected by composition (i.e. alloy composition, C:N ratio, impurities in the ceramic phase, etc.) and test procedure (i.e. aerated vs. de-aerated electrolytes). It was observed that addition of N content into the ceramic phase is beneficial to the corrosion characteristics of TiC based cermets, through significant refinement in the grain size of the hard phase. Similarly, elimination of impurities, such as W in selected TiC powders, also improves the corrosion resistance.INTRODUCTION Cermets are prepared using the combination of a hard, high elastic modulus ceramic phase with a ductile, high toughness metallic binder. This pairing of hard and ductile components ensures wide application of cermets in demanding wear environments. These materials are consequently used industrially in both bulk and coating form. The most common example of such a composite system is based on the use of tungsten carbide with a cobalt-based binder (WC-Co), which has been widely examined over the past 80 years. However, while WC-Co has been shown to exhibit an excellent combination of high strength and wear resistance, the corrosion and high temperature properties of this material are relatively poor. In addition, WC-Co possesses a high density (~13–14 g/cm3), which makes it a less desirable option when the component mass is a design factor (i.e. use in aerospace). In particular, the aqueous corrosion response of WC-Co limits its use in wear environments where combined corrosive degradation may occur (i.e. tribo-corrosion scenarios). Alternate cermet systems are therefore being actively developed due to these performance limitations."

Jan 1, 2017

By M. C. Bétournay, J. E. Udd

"The Mining Laboratories of CANMET are the principal federal government vehicle for the delivery of mining research in Canada. With research being performed at five locations, which are mostly mining communities, the laboratories are in close proximity to the industry which they serve.The Mining Laboratories have three principal roles: (1) to support government in its development of policy; (2) to aid industry in the enhancement of productivity; and (3) to improve the health and safety of Canadians,both in the workplace in mines and around abandoned mine sites.From 1994 to 1996, CANMET’s mining research was re-focused into four programs. These are: (1) Underground Mine Environments; (2) Mine Mechanization and Automation; (3) Ground Control, and; (4) Coal Mining Health and Safety.In this paper, the authors outline the work of the Mining Laboratories and also identify the areas considered to be primary targets for future mining health and safety research in Canada."

Jan 1, 1997

By H. Bouzahzah

Sulfidic tailings, subjected to atmospheric water and oxygen action, can generate acid mine drainage (AMD); which is the most important environmental problem facing the mining industry. AMD generating potential can be assessed by the static tests which consist of a screening method where the neutralization potential (NP) and the acid-generating potential (AP) of a given rock sample are determined. The AP and NP are determined separately in the different static test existing procedures which can be divided into two distinct classes: chemical and the mineralogical methods. For some chemical method, the AP is calculated on the basis of total sulfide sulfur content in the sample which may overestimate its AP if significant quantities of non-sulfide sulfur species are present (e.g. organic S in coals, some sulfate as gypsum, barite, etc.). However, the mineralogical method evaluates the AP by the sum of the individual sulfides participation on acid generation based on their concentration within the sample and can be more accurate than the chemical method. For AP calculation, the Paktunc (1999a) mineralogical static test takes into consideration all sulfide minerals occurring in the sample. However, it does not take into account the rates of acidity production of these sulfides submitted to weathering conditions. So, the present study focusses on the modification of Paktunc AP calculation by considering the acidity production rates of these minerals. To reach this objective, five base-metal sulfides (pyrite as reference, chalcopyrite, sphalerite, arsenopyrite, galena), diluted within quartz (25?75 wt.%) simulating mill tailings were subjected to a kinetic test to evaluate their AP. The results show that all the studied sulfides minerals generate acidity at different rates, so the Paktunc?s equation for AP calculation has been adapted accordingly.

Aug 1, 2013

By E. Busse

"Heath Steele Mines Ltd. operates a lead-zinc-copper mining and milling complex in New Brunswick.• During the past seven years, as ore reserves increased, the mill capacity was first expanded to 1,600 tpd and then to 3,000 tpd. In the last expansion, instead of building a completely new 3,000-tpd mill, or adding to existing installations, Heath Steele retained service facilities, buildings, ore bins, Jab, etc., and removed and replaced almost all existing process facilities. Requiring a complete mill shutdown, the expansion had to be carried out in minimum time. Also, new equipment had to fit into existing space. Critical path networks of the project were prepared, a tight schedule for construction was mapped out and progress charted daily to detect problems before they could interrupt the schedule. Heath Steele supervised the purchasing, handling and storage of new equipment, maintained liaison with the engineering contractor and became a sub-contractor, using its own staff to install all flotation equipment and process piping. The 1,600-tpd installation was dismantled and a 3,000- tpd unit was successfully put onstream in 5 months - on time and within budget. One benefit stemming from the expansion: production increased 87 per cent while operating and maintenance labour rose only 8 per cent."

Jan 1, 1972

The Santa Rita mine is located in north eastern part of Bahia in Brazil and is owned and operated by Mirabela Mineração do Brasil Ltda. Typical SABC circuit was designed as the preferred option for the 4.0 mtpa (500tph) to produce a P80 of 125um for flotation. Although the SAG was originally designed to operate with conventional radial pulp lifters, later it was fitted with Outotec?s Turbo Pulp Lifters ? TPL (Latchireddi, 2005). The milling circuit commenced commissioning on the 24th of October 2009 and the milling circuit achieved the nameplate capacity within days. with small and relatively simple measures to rectify. Since commissioning, the SAG mill has been working in fully autogenous grinding (FAG) mode with no balls (in contrast to the estimated 10% ball charge) and has been consistently treated up to 650tph. This paper examines the comminution design process, the operating philosophies, start-up experiences, post commissioning optimization and future development works. An evaluation of mill performance relative to the design criteria for the project life to date is also included.

Jan 1, 2012

By Arthur Dubé

An account is given of the developments brought about in the last fifteen years by metallurgical research in the field of heat treatment of steels. The practical aspects of these developments are especially emphasized. Methods of representation of the phase-change during austenitizing and sub-critical transformation of austenite are described and the importance of time-temperature-transformation charts for the planning of heat treatment cycles is shown. Special copies such as retained austenite and internal stresses developed on quenching are also discussed in some detail. Due to the interest shown currently in these problems, it has been thought advisable to describe briefly the underlying principles and present some of the results already available.

Jan 1, 1945

By A. A. el-Geassy, A. A. el-Tawil, Hesham M. Ahmed, Bo Bjorkman

The Iron and steel industry is one of the most intensive energy consuming processes. The majority of iron making processes is now directed towards the uses of fossil-based energy sources like coke, coal and oil. Recently, emphasis has been paid to replace part of fossil- based energy sources with renewable biomass-derived reducing agents. In the present work, the possibility of the effective use of woody biomass in carbon-iron oxide composites was investigated. Wood powder was carbonized in N2 atmosphere at 300 up to 450oC. The carbon content in the produced bio-char increased with temperature. The porosity of the char arises from maintaining the cellular structure inherent in wood biomass increases with temperature. The reduction behavior of four iron oxide-bio char composites having different fixed carbon content were carried out non-isothermally up to 1200oC in Ar atmosphere using thermogravimetric anlyser (TGA). Quadruple mass spectroscopy (QMS) was also adopted to measure the CO, CO2 concentrations in the off gases resulted during reduction process. The effect of volatile matter on the reduction of iron oxide was intensively studied. The different phases developed in the reduced product were identified by X-ray diffraction (XRD). The reduction of composites was found to proceed in a stepwise manner (Fe2O3?Fe3O4?FexO?Fe).

Jan 1, 2015

By C. S. Lord

"AbstractThe slow progress of conventional geological reconnaissance of the northern Canadian Shield during the past twenty years clearly indicates the need for a radically new field technique. Operation Keewatin, involving the use of helicopters as the traversing vehicles, was planned and executed by the Geological Survey of Canada in response to this requirement.About 57,000 square miles of District of Keewatin, N.W.T., were mapped during the 1952 field season in appropriate detail for publication at 1 inch to 8 miles. The Operation disclosed about 14,100 square miles of Precambrian sedimentary and volcanic rocks ranging in •age from Archaean to Late Proterozoic. About 7,700 square miles of this area are underlain by greenstone. This work was accomplished in a field season of 113 days, including the spring break-up. Routine aerial geological observations were made from two helicopters flying about 300 feet above the ground; these observations were checked by more than 1,700 landings and about an equal number of aerial observations from heights of less than 50 feet. Logistical support was •provided by a Norseman aircraft on skiis or floats. Combined helicopter and Norseman flying time was about 990 hours. More than 1-00 square miles were mapped per helicopter-hour, and about 815 square miles were examined each day that both helicopters operated. The reconnaissance cost about $207,000, or $3.63 per square mile mapped.As a result of this trial use of helicopters there is now available a reasonably proven method whereby an acceptable geological reconnaissance of the barren grounds of the Canadian .Shield within the Districts of Keewatin and Mackenzie might be completed within a decade. Thus, within a few years, it could place at the disposal of the prospecting and mining fraternity data which, by conventional methods, might not be made available to this generation. Due weight must be accorded this time factor when evaluating the aerial technique."

Jan 1, 1953

By J. G. Bennett

Coal consumption has increased globally by 57% over the last ten years. Underground mining typically provides coal of the highest calorific value and accounts for the greatest proportion of production. Despite a negative environmental image and indeed impact, this industry appears likely to thrive on the global scale for many years to come. Such mining consumes large amounts of electricity with implications for carbon dioxide emission at power plants and emits substantial quantities of the powerful greenhouse gas methane. In response to this significant carbon footprint, the European Union has funded research to examine the potential for a range of improvement technologies in a project entitled Low Carbon Mine Site Energy Initiatives (LOWCARB). Coal properties related to seams and mines, together with longwall characteristics, provide the basis for research into modelling optimally efficient methane drainage with a view to assisting mining as well as maximising electricity generation at surface and hence oxidation of the methane. Possible systems for the oxidation of very low concentration methane in ventilation air, which contributes the greatest greenhouse gas impact due to the volumes emitted, have been studied and modelled. Simulation and investigation of intelligent optimisation of electricity demand patterns provide the basis for reducing the demand peaks at mines and hence the cost and ultimately the carbon footprint of a mine, while specific investigations have been undertaken into ventilation efficiency at an unusually challenging mine and simulation of mine water pumping in order to develop an innovative method to monitor pumping systems efficiency. For post-mining use, the potential of disused shafts for compressed air energy storage to improve the operation of future electricity grids with high renewable energy penetration by reducing peak generation capacity requirements has been studied. While underground coal mining will always by definition be related to a significant carbon footprint, this paper provides an overview of a set of initiatives that can make a positive environmental impact while controlling costs across a huge global industry.

Aug 1, 2013

By C. -K. Fang

"Aging effect on the wear resistance of alumina particulate-reinforced 6061 aluminum matrix composites with a block-on-ring wear tester has been investigated. Specimens with various Al2O3 volume fractions of 0%, 10% and 20% were employed in this work. Experimental results indicated that over-aged monolithic 6061 Al had the best wear resistance, as compared with under-aged and peak-aged conditions. For the composite containing 10% Al2O3, over-aging and peak-aging resulted in similar wear resistance, which was higher than that for underaging conditions. For the composite containing a high volume fraction (20%) of Al2O3, the wear resistance reduced with the increase in aging time. Although longer aging time was favourable to the wear resistance of monolithic 6061 Al, it was detrimental to that for the Al2O3/6061 Al composite with high volume fraction of particles. IntroductionMetal-matrix composites (MMCs) have received attention in many engineering applications because of the demands for high specific strength (strength-to-weight ratio) and specific stiffness, good high temperature capabilities and wear resistance. The manufacturing processes of fiber-, whisker-, and particulate-reinforced MMCs have been well developed (Hosking et al., 1982). Because of the reduction in fabrication cost, the applications of MMCs have been widely extended to light weight-bearing sleeves, calipers, automobile parts (brake rotors, drive shafts, connecting rods, piston rings, and cylinder liners), sporting goods, aerospace components, tanks (wheels, speed brakes, and track shoes) and other industrial applications. Among the three types of metal matrix composites, particulate-reinforced MMCs are promising because of their homogeneous and isotropic material properties and low cost. Additionally, they can be formed using conventional metal processing techniques."

Jan 1, 2003

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999

By C. M. Kleemann

The paper describes the present milling practice at Western Mining Corporation Limited's new nickel mine at Kambalda in Western Australia. It details the crushing, autogenous grinding, flotation and spray drying circuits for the production of a nickel concentrate. It also indicates some of the metallurgical problems which have been encountered in concentrating this ore.

Jan 1, 1973

By J. P. Thomson

Magnesium alloys are steadily improving their market share as structural components especially in the transportation sector. Therefore, there is a great deal of interest from the automotive and the metal casting industry to develop viable economic casting processes for magnesium-base alloys. This paper summarizes the preliminary results on the continuing projects within CANMET-MTL on casting processes such as gravity and low-pressure casting in sand molds, permanent molds and lost foam.

Jan 1, 2004

By M. S. Badollet

"IntroductionASBESTOS FLOATS may be defined briefly as blends of air-borne particles of fibrous asbestos and dusts produced during the milling stages and collected by Cottrell precipitators, dust sheds, or bag-houses.The various grades of asbestos floats on the market contain fibrous asbestos particles ranging in length from microscopic to approximately 1/4-inch. The fines or dusts present in the floats are from 40 microns to 2 microns or less in cross-section.Airborne asbestos particles are of diverse length because they are collected at numerous places in the mill. There are: (1) dusts removed from dry rock storage bins, (2) dusts removed from rock and fiber screens, (3) particles from the tops of collectors, and (4) fines removed by suction from the processing equipment. Sometimes the airborne particles are kept segregated, so that there is a partial separation by gravity. This is accomplished by a series of dust chambers enclosed in a long, rectangular building. The longest and heaviest particles fall nearest to the air flow entrance, the smallest at a point farthest away and nearest the exit. Sometimes the air from the dust chamber building is passed through a series of bag-houses or electric :precipitators ,to collect the extremely fine particles which normally escape to the atmosphere."

Jan 1, 1952

By Robert B. Parsons

"Finance Minister Paul Martin's second budget might be good for Canada's mining industry in the long run, but the budget raises a number of concerns for the industry in the near term. The budget papers suggest that the 25% resource allowance is not working as intended, and report that the Department of Finance will be reviewing this valuable allowance. The so-called ""large corporations tax"" rate will be increased. This annual tax, which is imposed on a corporation's capital even when the corporation is not in production, is particularly harmful to the mining sector.IntroductionThe Honourable Paul Martin, in his second federal budget, emphasized spending cuts and made only modest tax changes. However, two of these tax changes could have a serious impact on the Canadian mining industry: the proposed review of the 25% resource allowance; and, the increase in the large corporations tax rate.Personal Tax Measures Personal Tax Rates UnchangedThe government has been under political pressure not to increase personal tax rates. Mr. Martin's announcement that rates would not change will be popular."

Jan 1, 1995

"Previous studies on the effect of polytetrafluoroethylene addition during chalcopyrite leaching under conditions similar to those of the CESL process have reportedly resulted in complete leaching of the copper without the need for grinding of the flotation concentrate. However, these studies employed a pulp density of only 1% and finely sized PTFE particle that required the use of high impeller rotation rates that are not sustainable at an industrial scale. This paper explores the performance of 1/8” diameter balls of PTFE, that readily sink in the leach solution, on leaching performance at impeller rotation rates and ore pulp densities more typical of industrial practice. Possible routes for separation of the PTFE from the leach residues and their regeneration for recycling back to the leaching stage are also discussed.INTRODUCTIONChalcopyrite, CuFeS2, is the most important primary sulfide source of copper. While pyrometallurgical smelting of chalcopyrite remains the only widely accepted route for treating chalcopyrite concentrates, several medium temperature pressure oxidation processes are claimed to be economically feasible (Muir & McDonald, 2007). Among these, the CESL process has been extensively piloted and demonstrated at the prototype scale. The overall process chemistry of the CESL process may be summarized as follows (Marsden & Wilmot, 2007):4CuFeS2 + 5O2 + 4H2SO4 ? 4Cu2+ + 4SO4 2- + 2Fe2O3 + 8S0 + 4H2O (1)4CuFeS2 + 17O2 + 2H2SO4 ? 4Cu2+ + 10SO4 2- + 4Fe3+ + 2H2O (2)Though copper extractions of over 95 % are achieved, the CESL process requires extra grinding of the concentrate (Muir & McDonald, 2007). This is because leaching is conducted at temperatures around 150 °C, where the elemental sulfur produced is molten and grows thicker on the mineral’s surfaces as oxidation progresses, creating an increasingly large barrier for mass transport. In addition, the sulfur is sticky and tends to cause the mineral particles to agglomerate, effectively halting further oxidation of the particles that end up embedded within the agglomerates. Consumable surfactants, such as ligin sulfonate, have been shown to be effective at avoiding agglomeration, but they are not effective at removing sulfur from the minerals. Hence, their use does not obviate the need for fine grinding."

Jan 1, 2012

By L. V. Chugaev, Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

"Pressure oxidation (POX) is one of the most common and reliable methods of processing gold-bearing sulfide concentrates. However, when processing concentrates that contain natural carbonaceous matter, substantial gold losses occur due to autoclave preg-robbing. The latter involves formation of gold chloride complexes under typical POX conditions (high temperatures, high acidity and high ORP) and subsequent sorption of these complexes by carbonaceous matter. Naturally, chloride ion plays a significant role in the process of autoclave preg-robbing; its concentration in POX solution has a well-marked effect on subsequent gold recovery during cyanidation of POX residue. The previous research done by SRC Hydrometallurgy showed that autoclave preg-robbing of gold could be significantly inhibited by the addition of mercury(II) compounds to POX slurry. The positive effect of mercury(II) was well pronounced both at high (>20 mg/L) and low (<5 mg/L) Cl concentrations in POX solution. The successful bench-scale laboratory testing was followed by pilot plant trials at Ore Test Facility in Blagoveshchensk, Russia. The present paper provides the results of these trials. The bench-scale testing results were verified; the optimum oxidizing parameters and reagent dosage were specified. The behavior of mercury (II) at POX pilot plant was found to be in good consistency with industrial practice described in the literature.INTRODUCTION Pressure oxidation (POX) is one of the most common, reliable, and commercially proven methods of processing gold-bearing sulfide ores and concentrates. However, when processing double refractory materials that contain natural carbonaceous matter, POX technology advantages are compromised by autoclave preg-robbing of gold. The latter occurs when natural organic carbon and soluble halides are both present in autoclave feed. Strongly oxidizing conditions of POX (high temperature, oxidation-reduction potential or ORP, and acidity) favor formation of gold-halide (mostly, gold-chloride) complexes, which tend to bond with carbonaceous matter. The exact nature and mechanism of this bonding is unknown, but as the result of this, cyanide is unable to leach gold from POX residue and the precious metal is lost to the tails (Axenov et al., 2014; Dimov, Chryssoulis, & Sodhi, 2003; Fomenko, Zaytsev, Pleshkov, Chugaev, & Shneerson, 2013)."

Jan 1, 2017

By L. K. Daneshmend

"Competitive pressures dictate that the mining industry moves to larger mobile underground haulage equipment with more advanced equipment mechanization, higher levels of autonomous operation of machines, and longer periods between access by maintenance personnel. Since such new machines will of necessity be more complex than existing designs, machine reliability has become a key issue in progressing toward advanced mobile underground haulage equipment. Reliability and maintainability models of such equipment are practically non-existent in the literature. This paper addresses the issue of reliability and maintainability of mobile underground haulage equipment on two fronts: reliability modelling to enhance decision making for maintenance planning; and reliability simulation to enable evaluation of more rigorous production planning scenarios. A case study from a gold mine in the Chilean Andes is presented, for which reliability models of mobile underground haulage equipment, specifically load-hauldump vehicles and underground haul trucks, are developed, and a reliability-based simulation implemented. IntroductionMaintenance accounts for 20% to 35% of the overall operating budget for a typical underground operation, and hence represents the largest portion of the mine’s controllable operating costs (Cutifani et al., 1996; Campbell, 1997; Goddard, 1998). This, coupled with the fact that industry today is faced with an ever more complex and demanding marketplace, has led to an increasing interest in methods to reduce maintenance costs.Although significant effort has gone into developing effective maintenance strategies for industry in general, application of these to the"

Jan 1, 2003

By Tracey Bodnarchuk, Philipp Mirzoev

Sulfate balance control is a common problem for zinc plants. Roast-leach-electrowin plants are mostly concerned with the over-generation of sulfates while for the HudBay direct leach plant both extremes are possible including potential necessity to buy sulfuric acid to replenish a sulfate-depleted circuit, which makes the problem doubly important. Quantitative methods were applied at the HudBay plant to analyze sulfate generation/depletion based on a local sulfur balance and sulfate extraction calculation in the leach circuit, using a Pb-tie method. Main factors were established influencing sulfate generation/depletion, including the critical role of Pb and pyrite. Regression analysis proved to be effective and allowed the quantitative prediction of Pb concentrations necessary to reach the equilibrium for the sulfate balance. This in turn provided a firm basis for a sulfate-control strategy realized through concentrate blend correction, which allowed the plant to fine-tune sulfate generation/depletion effectively reducing economic consequences of excessive/deficient sulfate generation.

Jan 1, 2015

"The most widely used method for predicting the onset of continuous caving is Laubscher’s caving chart. A detailed examination of this method was undertaken which concluded that it had limitations which may impact on results, particularly when dealing with stronger rock masses that are outside current experience. These limitations relate to inadequate guidelines for adjustment factors to rock mass rating (RMR), concerns about the position on the chart of critical case history data, undocumented changes to the method and an inadequate number of data points to be confident of stability boundaries.A review was undertaken on the application and reliability of a numerical method of assessing cavability. The review highlighted a number of issues, which at this stage, make numerical continuum methods problematic for predicting cavability. This is in particular reference to sensitivity to input parameters that are difficult to determine accurately and mesh dependency.An extended version of the Mathews method for open stope design was developed as an alternative method of predicting the onset of continuous caving. A number of caving case histories were collected and analyzed and a caving boundary delineated statistically on the Mathews stability graph. The definition of the caving boundary was aided by the existence of a large and wide-ranging stability database from non-caving mines. A caving rate model was extrapolated from the extended Mathews stability graph but could only be partially validated due to a lack of reliable data."

Jan 1, 2003