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By L Cooper, J Sharma, M J. Hendry

Thick clay tills below potash mine tailings and brine ponds are important natural barriers protecting fresh water aquifers in Saskatchewan. Centrifuge modelling was applied to assess geochemical processes and impacts of dilute brine (0.1 M NaCl) migration through clay till core samples obtained from non saline, unoxidised clay till at a mine site. At accelerated gravity of 876 + g, during each day of centrifuge modelling, flow driven through a 52 mm length core simulated transport through a 45 m thick clay over ~2100 years. Hydraulic conductivity, monitored continuously before and during brine permeation, was low and relatively constant (8.5 + 10-12 m/s), confirming that confining stresses prevent permeability increase. Core density and porosity measurements confirmed that reactive transport occurred under realistic in situ conditions. Breakthrough (defined by C/C0 = 0.5) of non-reactive Cl- occurred at 25 days. The slight delay for Na+ breakthrough, associated with small increases in Ca2+ and Mg2+ concentrations in the effluent were attributed to ion exchange, but carbonate reactions were relatively unimportant. Cation exchange analysis of core samples was inconclusive without corrections for porewater Na+ and carbonate dissolution. Geochemical processes that were observed during centrifuge modelling were successfully simulated using the 1D geochemical transport code PHREEQC. Solute transport was dominated by diffusion with limited ion exchange to delay Na+ migration. Brine would not break through a 45 m thick clay for tens of thousands of years. Based on these findings, the thick clay till at this site, if laterally extensive and undisturbed by drilling activity, is likely to act as an effective natural barrier to vertical brine migration over the long term.

Jan 1, 2003

By I Gray

Other than being reasonably certain of the average vertical stress being lithostatic, there can be little certainty about stress in the ground. The stresses and strains in rock are a function of gravitational effects, external load, thermal changes, diagenesis and their mechanical properties including elastic, creep and post failure behaviours. It is highly desirable to measure stress where mining is going to take place, even if the virgin stress condition has already been changed by mining. The concept of some far field stress value that is more or less constant is usually invalid and can be dangerous to use in mine design. Measuring stress is not simple. The basic processes are broken into two categories, one where the rock will not fail around the borehole in which the stress is being measured and one where the rock has failed or will fail. Because of the complexity and cost in obtaining a single, precise stress measurement it is highly desirable to have some system to be able to obtain an idea of the uniformity, or otherwise of the stress situation between precise measurements. Table 1 shows the methods for measuring stress. The first five methods work on the basis of some fairly direct measurement of mechanical rock behaviour while the last three are attempts to get some idea of stress out of core long after it is removed from the host rock. While these latter methods appear to tick all the boxes for applicability there is a great deal of uncertainty in the results that they deliver. This paper reviews the methods for measuring stress and presents two new methods. These are a three dimensional overcore system to provide precise stress measurements in rocks that will not fail around the borehole and a core ovality system. The latter can be used to provide information on the stress difference orthogonal to the core. It is particularly useful because it can be used every metre of core length.

Nov 29, 2022

The New Southern Railway (NSR) involves the excavation of approximately 10 km of single bore tunnel from Tempe Reserve, Tempe, to Prince Alfred Park (PAP). PAP is located just south of Central Railway Station in SydneyÆs Central Business District (CBD). From Tempe Reserve the alignment takes the tunnel under Sydney Airport including the main north/south runway. Sydney Airport is approximately 8 km south of the CBD. The NSR is being constructed by a private group, the Transfield Bouygues Joint Venture (TBJV). Transfield is a major Australian contractor and the French contractor, Bouygues, is providing the soft ground tunnel construction expertise and is also responsible for the design of the concrete segmental lining. This paper sets out to present in some detail the issues involved in tunnelling under the airport and in particular under the north apron, the main north/south runway and the new elevated roadway. The paper concentrates on these three areas on the airport with an emphasis on the following. The risks involved and measures taken to minimise the risks in tunnelling under the International Terminal north apron (with Jumbo Jets parked immediately above). Secondly, settlement predictions, settlement and runway operation criteria and the actual settlements that have occurred on the main north/south runway. Finally, the criteria that was developed during the construction of the deep bored piers for the elevated roadway at the Domestic Terminal as the TBM passed through this area of construction activity.

Jan 1, 1999

A nine-month investigation was conducted into the effect on coke quality and blast furnace operation of the addition of bentonite and southern coal to the northern coal fed to the coke ovens at the Newcastle steelworks.Additions of 0·3 per cent bentonite or 25 per cent southern coal to the northern coal increased the coke strength from 15-20 A.S.T.M. stability to 25-30 A.S.T.M. stability. It is likely that improved mixing and blending facilities would, in both cases, give a coke of over 30 A.S.T.M. stability.For the same coke strength, the use of 0 3 per cent imported Wyoming bentonite was considerably cheaper than the use of 25 per cent southern coal, but the use of Australian bentonite promises the same coke strength for still lower costs. Other additives such as coke breeze, charcoal, iron ore fines, and certain other finely divided materials, gave relatively minor improvements in coke quality.There appeared to be sufficient improvement in blast furnace operation and production to justify full scale addition of bentonite to improve coke quality, although other variables, particularly iron ore physical quality, overshadowed on many occasions the effect of coke quality. Further coke trials with southern or bentonite will be carried out when ore quality has been improved by the introduction of ore sintering at Newcastle.INTRODUCTIONDuring the period of operation of the Newcastle coke ovens and blast furnaces from April 1960 (when No. 3 blast furnace was blown in after rebuilding) to December 1960, a bentonite coke trial was carried out based on earlier research findings (Gregory, 1959a, 1959b; Felton and Gregory, 1960; Gregory, 1960) that as little as 0 3 per cent to 05 per cent bentonite clay added to northern N.S.W. high volatile coking coals gave a significant increase in coke strength. The bentonite coke trial was followed by trials...

Jan 1, 1962

Mineral sands are different to almost any other commodity; however, it shares similarities with other commodity types, such as the importance of quality constraints of iron ore and coal or the importance of physical properties of diamonds. The mineral sands industry consists of two principal product streams; titanium dioxide minerals û in the form of rutile, ilmenite and leucoxene, and zircon. The principal valuable heavy minerals (VHM) include ilmenite, leucoxene, rutile and zircon. Variations of other titanium minerals occur between the end members of ilmenite and rutile, including pseudo rutile and anatase. Most mineral sands deposits are found in unconsolidated fossil shorelines several hundreds of metres to tens of kilometres and occasionally hundreds of kilometres inland from the present coastline. Mineral sands orebodies essentially fall into two categories based on the mode of deposition: alluvial or aeolian. Alluvial deposits are further split into marine beach placers (or strandlines) and lacustrine heavy mineral (HM) accumulations. Exploration for mineral sands involves the positive identification of key criteria leading to the focus of exploratory surface sampling, augering and drilling. Assaying is primarily focused around determining the percentage of HM contained within a given sample. Other results of interest include clay fines, sand and oversize. Metallurgical/mineralogical assessment is often undertaken via laboratory scale bench tests that replicate the wet concentration and dry mill processing routes. The most critical component in resource assessment for mineral sands is about quantifying HM grade, then mineralogical assemblage and then quality of those mineral species. This will determine whether a mineral sand final product is marketable or not. Mining of mineral sands is conducted either wet or dry. Wet methods are generally preferred for large tonnage, unconsolidated and low clay orebodies. Where ground conditions are hard and orebodies are small, high grade and discontinuous, dry mining techniques are generally employed. Concentration of mineral sands from the primary ore is carried out in two sections; wet, utilising sizing and gravity differentiation between HM, VHM, clay and quartz, and dry, exploiting the magnetic, electrostatic and to a lesser extent specific gravity (SG) properties of the minerals of interest. Mineral sands exploration, mining and processing faces the same operating challenges as the rest of the resource sector. Added to this are the issues that are unique to mineral sands and to which the industry devotes considerable resources to developing solutions.

Jan 1, 2009

By P Jonsén, S Larsson, M Parian, B I. Pålsson

The question of effective energy utilisation in grinding mills is not new. There are several conflicting arguments about tumbling mills, whether the efficiency is around 1 per cent or maybe 10 per cent, or even much lower. The energy not used is assumed to be lost as heating of the pulp, the grinding mill body, the charge, generation of shock waves and vibrations, etc. Stirred media mills on the other hand are generally considered to have better energy utilisation, but their energy efficiency is still not that clear. To shed some light on this a pilot-scale, wet stirred media mill was investigated over a range of operating conditions. The wet stirred media mill is a Drais PMH 5 TEX pearl mill fitted with an electric motor at 11 kW. It has been investigated over a range of operating conditions to try to balance the dissemination of the input energy in forms of the net grinding energy, mechanical energy losses, and the heating transferred to the pulp, the mill, the charge, and the cooling water. It is found that approximately 20–40 per cent of the input energy accounts for the grinding process. Also, that the difference between gross and net input electrical energy is mainly disseminated as heating of the pulp and cooling water. Mechanical energy losses appear to be much smaller than the heating effects. The use of a dispersant seems to mainly influence the heating effect.

Aug 24, 2022

By Szymanski J, Planeta S

For many hard rock mines with near surface deposits, the surface crown pillars form the first line of protection for the immediate underground workings. Underground stopes are typically contained by crown pillar, which protects the level above, rib pillars, and a sill pillar through which the ore collection system is cut. This paper discusses the mining of these pillars, with particular emphasis on the overall stability of the mined out upper part of the mine areas. An area of interest is located in the Canadian Shield, where the mining has progressed below four thousand foot level in the ultramafic high grade sulphide type of orebody.

Jan 1, 1995

Changes in mining technology have led to an increase in the number of underground sulfide dust explosions reported in Australian and overseas mines. Samples collected at the Elura mine consisting primarily of pyrite, pyrrhotite, arsenopyrite, sphalerite and galena, were tested in 8 litre explosion chamber. The dusts were found to be capable of producing dangerous dust explosions with maximum explosion pressures of 440 kPa and rates of pressure rise of 5200 kPa/s. The hazards of a sulfide dust explosion are associated with the pressure wave and flame front of the explosion and the toxic gases remaining after the explosion.

Jan 1, 1984

The basic methods to remove material from underground mines are to: convey continuously, batch in trucks, or batch in a shaft hoisting system. A critical aspect in shaft hoisting is accurately batch loading the conveyance or skip. During the 20th century, the almost universally accepted method of loading was via a measuring flask. A measured quantity of material was filled into the flask as the conveyance traveled through the shaft and then, when the conveyance arrived at the loading position, it was ædumpedÆ into the skip for hoisting. Two skip loading conveyor systems have been developed in Australia: BHP BillitonÆs Cannington Hoisting System, installed in 1996, is believed to be the first conveyor loading system designed for two skips. Two parallel conveyors were installed with a two-way gate controlling feed onto each belt. Cannington was ideally suited to conveyor loading as the very high ore density and relatively low production rate required a relatively small volumetric storage capacity on the weighed belt. Newcrest MiningÆs Telfer Hoisting System, which is to be commissioned in 2005, consists of a single slewing conveyor loading each skip with 32 tonnes of ore. The development of this system eliminates the two-way transfer, improves the accessibility and minimises the excavation required. While every hoisting system must be considered on its merits, conveyor loading offers significant advantages to the Mining Industry in the 21st century.

Jan 1, 2005

By C Young

The identification of Critical Risks, their associated Critical Controls, and the implementation of processes to ensure their ongoing management can be difficult and resource intensive. Answering the following Critical Risk Management related questions can be challenging: • What is a Critical Risk? • What is a Bow-tie Analysis and when should it be used? • What is Critical Control? • How is the effectiveness of a Critical Control assured, and how is this measured? • Who is responsible for managing Critical Controls? • What are the implications if a Critical Control is not effective? It appears that in the mining industry’s efforts to implement the Critical Control Management Process outlined by the International Council on Mining and Metals (ICMM), instead of embedding an integrated, well understood, value adding process, we have instead created a resource hungry monster that is poorly understood by numerous layers of the organisation.

May 5, 2022

Structural assemblages of veins, shear zones, and wallrock alteration zones arising from fault-valve action on steep reverse fault systems are reviewed using observations from mesothermal gold-quartz lodes in the Archean Yellowknife, Abitibi, and Yilgarn greenstone belts of Canada and Western Australia, the Cretaceous Mother Lode system in the Foothills Metamorphic Belt of the western Sierra Nevada, California and the Victorian goldfield hosted in a folded quartz-turbidite succession of Paleozoic age in Australia. Despite differences in the host rock assemblages, the deposits have many structural characteristics in common. These form a useful exploration guide when re-evaluating comparable, but poorly described gold-quartz vein systems such as those in the Reefton area of New Zealand.

Jan 1, 1992

The light microscopic study of the physical structures of coal and associated mineral matter is an important technique in providing information on the characterisitics and possible behaviour of coals in industrial processes. However the ultrafine nature of coal and mineral particles together with the limits of resolution of the light microscope restrict such studies. Scanning electron microscopy (SEM)with its better resolution and higher magnifications is the means by which further information on coal properties can be obtained. An associated energy dispersive X-ray specrometry (EDS) method allows non-destructive in-situ chemical analyses to be carried out at the same time.

Jan 1, 1989

By M Fylak, R Wenda

Advanced preparation techniques open new ways for SEM and X-ray diffraction (XRD) investigations on hydrating cementitious systems. In this paper the early time hydration of Portland cement is studied with advanced cryo scanning electron microscopy techniques in combination with in situ X-ray diffraction and heat-flow calorimetry. The application of preparation techniques and analytical methods to Portland cement hydration are presented and discussed. Some aspects of hydration reactions are focused. The reaction products of the first minutes, changes in ettringite morphology, AFm formation during the deceleration period and the visualisation of C-S-H microstructures were special points of interest. X-ray diffraction analyses and Cryo-SEM images gave essential information about phase development, reaction kinetics, microstructure and morphology of hydration products. Portlandite, AFt and AFm phases were detected by in situ XRD. Cryo-SEM analyses enabled high resolution imaging and EDX-analyses of cement particles and reaction products. The results of the different analytical methods were compared to obtain detailed information about crystallisation processes and microstructural development during the first three days of Portland cement hydration.

Jan 1, 2008

By K M. Watling, F M, G K. Parker

Surface enhanced Raman scattering (SERS) spectroscopy at surfaces under electrochemical control has been applied to elucidate the adsorption of thiol collectors. SERS spectroelectrochemical studies at coinage metal electrodes have been carried out on ethyl xanthate and three iso-xanthates, O-isopropyl-N-ethylthionocarbamate, 2-mercaptobenzothiazole, diisobutyl- dithiophosphinate and butylethoxycarbonylthioura. For each collector, adsorption occurs via charge transfer to form a metal-sulfur bond and, in situations for which the reversible potential of the formation of the bulk phase is known, at underpotentials.

Jan 1, 2005

The Mt Newman Beneficiation Plant uses a combination of heavy media deans, heavy medium cyclones and Reichert cones to produce saleable iron ore concentrates from low grade iron ores. The aim of this paper is to discuss score of the changes that have been made to improve the operation of the heavy medium circuits.

Jan 1, 1987

By M Nehring, M Kizil, P Knights

Mining and beneficiation can be described as sequential processes of separation of valuable minerals from waste. There is a great deal of interest in how the industry can be more effective – and efficient – with these processes. In particular, many mining companies are looking towards digital technologies to improve precision mining practices; that is, the targeted identification and separation of valuable ore from waste during the mining process. Greater precision will help unlock the value in many complex orebodies that are currently considered Tier 2 or 3 deposits. CITATION: Knights, P, Kizil, M and Nehring, M, 2018. Selection of precision surface mining methods for complex metalliferous orebodies, in Proceedings Complex Orebodies Conference 2018, pp 31–34 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By M D. Urbani

HiTec Energy Ltd has been conducting research since 1996 into novel process routes for the treatment of low-grade and waste manganese sources for the production of high value and high quality electrolytic manganese dioxide (EMD) for the alkaline battery market. HiTecÆs approach is to treat previously unsaleable manganese deposits and mine site tailings using a novel sulfur dioxide leach route, followed by purification and electrowinning to generate the sought-after EMD product by an environmentally superior processing route to those presently practiced throughout the world today.HiTec Energy Ltd expects to be in commercial production with its Stage 1 facility in Kalgoorlie in the last quarter of 2004 for the production of 12 500 tpa EMD. With this production facility being adjacent to a laterite nickel producer with available waste manganese units, the opportunity arose for HiTec to combine its existing technologies with processes (that will be discussed in this paper) to turn two waste by-products into products that are used for high-tech purposes.HiTec Energy Ltd and the Parker Centre have had a collaborative research relationship for a number of years in areas involving EMD and battery related technologies. Meanwhile the solvent extraction (SX) group of the Parker Centre (CSIRO Minerals) has developed SX processes to separate manganese from nickel and cobalt. A project was initiated by HiTec Energy to recover manganese from waste laterite leach solutions using SX technology. Batch tests were conducted to select a suitable organic system for the extraction of manganese in terms of selectivity and extraction and stripping kinetics.A total of eight organic systems were tested by determining pH isotherms of metals using a laterite nickel process waste stream. Two organic systems, the Versatic 10 and Versatic 10/synergist systems, were chosen for further test work with Shellsol D70 chosen as the diluent for both systems.The Versatic 10/synergist system would be advantageous over the pure Versatic 10 system because fewer SX stages are required, resulting in a smaller organic inventory and lower capital costs. The risk of gypsum formation is also significantly lower with the synergistic system.

Jan 1, 2004

By G Brooks

The control of phosphorus in steelmaking is one of the famous challenges of pyrometallurgy. It is well established that highly basic slags, the presence of FeO in the slag and lower temperatures (less than 1650°C) are favourable for phosphorous removal. The thermodynamics of this reaction have been extensively studied under laboratory conditions and the general trends confirmed through industrial trials. However, in general, phosphorus slag/metal distributions measured in industry are far from equilibrium and quite specific to the oxygen steelmaking technology being used. This variability was quantified by Urban, Weinberg and Cappel (2015), who found that the phosphorus partition ratio measured in plants varied with blowing practice, stirring intensity and even converter life. Some recent kinetic studies by Gu, Dogan and Coley (2017) have shown how the kinetics of these reactions vary with FeO content and dissolved sulfur at the droplet scale. A global kinetic model by Rout et al (2018) provides meaningful predictions of where dephosphorisation occurs in an industrial basic oxygen furnace (BOF) and some recent heat transfer modelling by Madhavan et al (2021, 2022) implies that temperature difference between droplets and slag has a role to play in explaining why equilibrium is not achieved. This paper will review the current state of knowledge and provide suggestions on predicting phosphorous removal for industrial operations and how greater removal could be achieved.

Jun 19, 2024

By G Swayn, J Harpley

Spent Pot Lining (SPL) is an unavoidable waste product of the electrolytic process in the smelting of aluminium. SPL is considered to be a hazardous waste in various countries because it contains significant quantities of absorbed fluoride along with traces of cyanide. The disposal of SPL has been primarily in landfill because of difficulties in the development of a successful techno-economic SPL treatment process. Increasing concern about SPL landfilling practices is resulting in regulations in some countries to ban this form of disposal. As a consequence stock piling of SPL is occurring in an increasing number of countries pending the development of a successful treatment process. In 1992 Portland Aluminium investigated a SPL treatment process based on pyrometallurgical technology and approached a company called Ausmelt in Dandenong, Victoria, Australia, to ascertain if their submerged lance technology furnace process would be suitable to treat SPL. This approach resulted in Portland Aluminium, Alcoa and Ausmelt personnel working together on trials during 1992 - 1994 in Ausmelt's demonstration furnace to produce a slag and off gases containing hydrogen and sodium fluoride. The trials also evaluated the effect of oxygen enrichment to increase the concentration of hydrogen fluoride and the ability to recycle sodium fluoride particulate produced as the furnace off gases cooled. Other separate developmental work by Portland Aluminium, using CSIRO, resulted in the production of aluminium fluoride from the offgases from the pyrometallurgical process. The results of these projects influenced Portland Aluminium and Alcoa to authorise up to $A26 400 000 in December 1995 to construct a Research and Development processing facility to treat SPL at Portland. The Portland Aluminium unique gas treatment process converts hydrogen fluoride in the furnace offgases to aluminium fluoride in a multistage fluidised bed reactor, designed by Portland Aluminium. The aluminium fluoride produced in the reactor has been trialed successfully in Alcoa's aluminium smelting process as a replacement for imported aluminium fluoride. The installation in mid-2001 of a slag granulation system has enabled the production of a granulated vitreous slag having leachability qualities that conform to Victorian EPA criteria for the unrestricted use of the granulated vitreous slag from 'The Alcoa Portland SPL Process'. The unrestricted use of the granulated slag successfully completes 'The Alcoa Portland SPL Process' which treats the hazardous waste material SPL and converts it into non hazardous useful products.

Jan 1, 2002

By N Nosaka

Sinter plants currently have to use many types of ores with different properties due to the great demand for iron ores, which was driven by the massive growth in Chinese iron and steel industry. On the other hand, the development of iron ore mines is limited and the quality of iron ores is in a tendency of deterioration. Therefore, the quick evaluation of iron ores has become more important for a stable sintering operation. In addition to such a background, the CO2 gas emission should be decreased from sinter plants according to the Kyoto Protocol on reduction in greenhouse gases. The present paper first describes the methods for testing the metallurgical properties of iron ores, which use a small volume of sample mainly focusing on magnetite ore that is effective for reducing CO2 and NOx emissions from sinter plants. The sintering properties of ores are evaluated separately according to each stage in sintering process, that is: heating stage before melt formation, primary melt formation in adhering fines layer of pseudo-particles, and assimilation of nucleus ore particle with calcium-ferrite system melts.Next, the application of the tests to the blending ores is introduced showing examples of the studies on the effective usage of the magnetite ores with Marra Mamba type ores.

Jan 1, 2005