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By J. C. Reed, J. M. Hansell

Cinnabar was discovered in southwestern Arkansas on Little Missouri River in sec. 1, T.7S., R.26W., in April, 1930, and near Antoine Creek in sec. 28, T.6S., R.23W., some 15 miles farther east in May of the same year. It was not, however, until June, 1931, that cinnabar was identified as such in a specimen from the original discovery area sent to W. M. Weigell by Walter F. Hintze of Murfreesboro. Almost simultaneously2, in July, 1931, Moritz Norden of Hot Springs identified specimens from the Antoine Creek area as cinnabar. Immediate interest in the district followed the identification of cinnabar and by January, 1932, the district was known to extend as a mineralized belt about one mile wide trending east-northeast from sec. 13, T.7S., R.27W., in Howard County across central Pike County and into Clark County to sec. 19, T.6S., R.23W., thence extending southeast into sections 33 and 34 of the same township. Since then, cinnabar has been found in sec. 6, T.7S., R.22W., thus giving a total east-west length to the district of approximately 30 miles. Interest focused mainly on the two discovery areas, with the result that mining development has progressed most rapidly in those localities. In the Antoine Creek area the Arkansas Quicksilver Co. has done considerable exploration work and has retorted the high-grade ore so obtained. In the Little Missouri area the Southwestern Quicksilver Co. has had a 12-ton rotary furnace in more or less continuous operation since April, 1932, and has been the largest producer in the district. In March, 1934, the United States Geological Survey began a study of the Arkansas quicksilver district, which was made possible by an allotment of funds from the Public Works Administration. Until

Jan 1, 1935

By Richard P. Hight

Abrasives include the substances, natural or artificial, that are used to grind, polish, abrade, scour, clean, or otherwise remove solid material, usually by rubbing action but also by impact (pressure blasting for example). They do not include abrasive tools, for instance, lathe tools and files--or polishing agents such as waxes, which act by filling pores. Detergents and cleaners whose action is chemical rather than physical are omitted al- though some chemical-action polishes and cleaners may also contain solid abrasives, for example, many automobile and metal polishes. General Considerations The most important physical properties of materials that qualify them for use as abrasives are hardness, toughness (or brittleness), grain shape and size, character of fracture or cleavage, purity or uniformity. For making bonded abrasive products such as grinding wheels, additional important factors are stability under high heat and bonding characteristics of grain surfaces. The economic factors of cost and availability are always important. No one single property is paramount for any use. For some uses extreme hardness and toughness are needed, as in diamonds for drill bits; for others, the factors of greatest importance are hardness and ability to break down slowly under use, to develop fresh cut- ting edges when grains become worn-for example: in garnet for sandpaper neither highly cleavable or friable grains nor extremely tough grains are wanted. For still other uses, great hardness is objectionable; for example, abrasives for dentifrices and for glass-cleaning soaps. For the most efficient use in the more critical applications, the different types of abrasives are rarely completely interchangeable; thus, while crushed quartz and garnet are both used in sandpaper, the papers are not at all interchangeable in their use applications. In the last analysis, the choice of a high grade abrasive depends upon the quality and quantity of work done by the abrasive per unit of cost. Initial cost of an artificial abrasive may be much greater than that of a natural abrasive but the artificial abrasive may do so much better work than the natural one, and do it so much faster that the ultimate cost will be less. It is for this reason that artificial abrasives have largely replaced natural abrasives. Abrasive Value Mineralogical hardness or "scratch" hardness as expressed in Mohs' scale is an important property in evaluating abrasive materials, but, as noted before, it is only one of several essential properties. The mineral hardness of pure crystal almandite garnet is about 7.5, but if the crystal is crossed by incipient fracture planes, or if it contains inclusions of other minerals, the apparent or useful hardness may be much lower. While the quartz grains in a sandstone have a hardness of 7, the bond holding the grains together may be so weak that the stone is valueless as a commercial abrasive. In artificially bonded wheels and stones, the hardness, strength, and character of the bond are fully as important as the hardness of the abrasive grains. Thus, in an overall consideration of abrasive hardness of loose abrasive grains, both "scratch" hardness and toughness must be considered. In naturally or artificially bonded abrasive stones, bond characteristics are a third factor, which is most important. The problem of abrasive hardness is further complicated by the inadequacies of methods of testing hardness and of expressing relative values. The Mohs' scale is inadequate both because the methods of testing are very crude and

Jan 1, 1975

By K. E. Beu

IN the measurement of retained austenite concentrations in steels using the integrated intensity method,1 Averbach has pointed out" that the absorption factor A(0) for a flat sample making a glancing angle 4 with the incident X-ray beam can be combined with his constant factor R to obtain our constant factor" G provided that "1—There is no preferred orientation in the sample, and 2—The geometric requirements [for the sample, film, and X-ray beam] have been met precisely."' If A(0) can be combined with R to give G according to the equation G = R . A(0) [14] then the possibility for making non-compensating errors in the austenite determination has been eliminated. This has been described previously in a technical note." Because of the brevity of the previous note,3 it was impossible to emphasize the fact that the two conditions on preferred orientation and geometry can be easily met experimentally, contrary to Aver-bach's statement that: ". . . the necessary conditions must be tested experimentally for each determination, and this is done most easily by observing whether the apparent absorption has the form of Eq. 2 [the theoretical equation for A(0)]."" he way in which these two conditions can be met experimentally will be discussed briefly to help clear up this point. In addition to these two conditions, other factors such as sample shape, homogeneity, and grain size which also affect A will be included in this discussion. A (0) depends on sample shape. The theoretical function for A was derived originally for a flat surface.' In general we have found that a flat sample surface is readily obtainable." If such a surface can * The effect of surfaces which are not flat on the measurement of retained austenite will be discussed later. be obtained, it has the following advantages: 1—it is easily reproducible from sample to sample, 2—it is the form required for metallurgical examination —this type of examination being frequently desirable for this work, and 3—it is an efficient shape for diffraction purposes. Perhaps the most important of these features is that a flat sample surface is easily reproducible; hence, this requirement on the repro-ducibility of A from sample to sample is met for all such samples. Fig. 1—Schematic diagram of the quartz crystal monochromator diffraction unit. The centerline of the main beam is at 6' to the target face. The tangent to the crystal face is at 16.8' to the moin beam. The centerline of the monochromatic beam is at 33.6 to the main beam. The sample surface can be rotated in its own plane. The angle of the sample surface and the monochromatic beam can be adjusted by rotating about the vertical axis, The film holder can also be rotated about B so that the film can be exposed over the desired angular range. For Fe K, X = 1.932A. 1011 planes of quartz have d = 3.35A. A(0) depends on homogeneity and grain size. If the sample is badly segregated or the grain size is large, the effect of micro-absorption and primary extinction1. ' must be considered. It has been shown, however, that for most plain carbon or low alloy hardened steels, neither micro-absorption nor primary extinction effects are present.' A (0) depends on camera geometry. For a given angle 0, A remains theoretically constant from a geometrical viewpoint only if the following factors are kept constant: 1—the angle of inclination .+ of the sample to the X-ray beam, and 2—the centering of the sample with respect to the film cylinder. These are mechanical problems which can be solved readily if the facilities of a good machine shop are available. The arrangement used to insure that the angle 4 remains constant and the centering of the sample is reproducible is indicated schematically in Fig. 1. The sample is clamped against a thin plate with a hole in it by means of a spring-loaded pres-

Jan 1, 1954

By Benjamin Talbot

(New York Meeting, February 1913.) THE problem of segregation and cavities in steel ingots is a subject which has given and is still giving metallurgists, en¬gineers, and operators matter for serious consideration.. This question has come more into prominence lately in the United States, clue largely to the desire of railroad engineers to secure a better rail than they have obtained in the past, as the service they demand is increasing in severity; and no doubt manufacturers will be able to meet what is required of them. The rails here are as good as those made in other countries, but the conditions of service and the extremes of climate are more severe and consequently more breakages occur. Various reasons have been advanced to explain why rails may not be as good in quality to-clay as in the past. Some engineers consider that modern methods of manufacturing, designed chiefly to obtain large output, tend to reduce the standard of excellence of more deliberate methods. Others think that 4-ton ingots are worse than those of 2 tons. Again, it is .stated that the 100-ton heat in one ladle is too large, and is a :step in the wrong direction in casting. My experience upon the question of the size of the ingot is that in rolling rails of from 85-to 100-lb. sections, the range of ingot is only practically such that the difference in the size does not help in the question of segregation, cavities, or blow-holes.

Jan 4, 1913

EUROPE continued to be unsettled, financially, commercially and socially. October opened with Germany in a state of turmoil following the Government's cessation of passive resistance to the French and Belgians. In many places there were riots with much bloodshed. In Bavaria a military dictator-ship was set up in order to keep peace. In the meanwhile France continued in an uncom-promising position.. Great Britain, having been diplo-matically discredited, disappeared from any prominence in the international picture. Under the constraint of circumstances the policy of deflation in Great. Britain was temporarily abandoned. Perhaps no other course was open, for with declining trade and heavily reduced revenue, and no chance for cutting expenses propor-tionately, a check to deflation comes of its own accord. The effects of this should become manifest in the course of a few months and should appear in the form of an improved margin between the prices for commodities and the wage costs in producing them. About Oct. 20 an effort was made to set up the Rheinland as a separate republic. On Oct. 26 were published communications from Lord Curzon to Secre-tary Hughes and the latter's reply. In these Lord Curzon drew attention to the gravity of the situation in Europe and expressed the hope that France might listen to renewed suggestions for a general inquiry. Secretary Hughes promised American cooperation, in this, with the reservation that the question of inter-national debts should not enter into the situation. In the latter part of October there were military mutinies and disorders in Greece, which resulted in the reestablishment of martial law by order of Col. Plas-tiras, who is virtually the dictator of Greece. The incipient revolt was promptly crushed.

Jan 10, 1923

By Frank G. Miller, Ralph A. Seban

Problems relating to thermal methods of oil recovery have been given increasing attention during the past year. The nature of the physical and chemical processes underlying thermal recovery are not yet well understood. The need for pertinent basic information is recognized generally. One of the processes involved is the transfer of heat by conduction in oil reservoir rocks containing moving reservoir fluids. This technical note deals with heat conduction in a laboratory sand column filled with a moving hydrocarbon and therefore should be contributory to the presently inadequate fund of knowledge on thc over-all subject. In an analysis of the flow of vaporiziny propane through a horizontal column of sand, one of the present author9 demonstrated correspondence between thc measured values of pressure along the length of the column and those predicted by a theory which postulated that the enthalpy of the propane was invariable along the length of the column. This postulate way implied as a deduction from the principle of conservation of energy but the details of the deduction were not given. The specific purpose of this technical note is the presentation of these details both as an adjunct to the earlier analysis and to supply some additional details on the processes involved in this type of flow. Results disclose that rates of heat transfer by conduction, in the direction of fluid motion, generally would be small for systems of the type studied. FUNDARIENrAI. ENERGY EiQUAI-[ON The principle of conservation of energy may be applied to a section of the porous material on the basis that heat transfer, like fluid flow, is possible in the x direction only. Transfer of heat in the y and z di'rections is prevented by suitable insulation or by taking the medium as infinite in directions perpendicular to the x axis. For steady state heat conduction and conditions of steady fluid flow the principle of conservation of energy specifies that any reduction in the enthalpy rate increases the flow of heat in the same proportion. Stated mathematically, dH KA 87 —- = - — - — U) * dx W dx........ Lvhere is the flow of heat in the positive x W dx direction. TEMPERATURE DISTRIBUTION IN DIRECTION OF FLOW The column of sand used in the previoi~sly described research is divisible into three different flow regimes. each of which may be analyzed independently. In the entrance region the liquid approaches the saturation state. A transition region is postulated following the transverse section at which the saturation state of the liquid is attained. In this transition region gas and liquid phases are both envisioned as present, with no vaporization occurring and with fluid movement restricted to the liquid. The upstream end of the exit region is at the transverse section of the column where the fraction of the pore space occupied by gas first becomes great enough for gas flow and where vaporization of the liquid begins. Fig. 1 indicates schematicaHy the thermodynamic processes undergone hv the fluid in the three flow regimes.

Jan 1, 1956

By A. T. Peters

DURING an investigation concerning the use of large nozzles for pouring of low-carbon rimming steels, the practical details of which were reported elsewhere, it was noticed that increases of nozzle sizes were generally followed by improvements of slab surface quality. It is the purpose of this note to present the data available and some tentative opinions about this phenomenon. The problem of correlating pouring rates with the metallurgical performance of steels is complicated by several factors. The two most important are; 1) Variations of the steel pouring rate throughout a pour, these being due to the nozzle erosion, which enlarges the bore area, and the dropping ferrostatic pressure in the ladle. The pouring rate is lowest towards the end of a heat when the ladle is nearly empty. 2) Variations in the ingot pouring time due to the different ingot weights poured. Consequently, the use of the average pouring rate of a heat may not be exact, but in large-scale production it is not practical to treat ingots separately according to their pouring rates. The variations of ingot weights and sizes may be overcome by considering the rate of rise of steel in the mold. Hence, the average rate of filling of molds throughout the pour of a heat, inches per second, will be used in this note. Every ingot rolled at Inland is rated at the blooming mills prior to hot machine scarfing as being good, fair, or poor for cracks, scabs, and checking. The latter term refers to the network of breaks or lines associated with overheating or burning in the soaking pits. It is also known that thin-skinned steel is prone to show this defect if the subsurface blowholes are exposed during reheating or rolling. The experiences with the surface quality of slabs rolled from ingots poured at different rates are presented in Fig. 1. The data represent nearly 11,000 ingots. It appears that all three types of defects are in-

Jan 1, 1960

By John Branner

FIVE of the geologic horizons that yield oil in other parts of the world are represented in Brazil; namely, the Devonian, Carboniferous, Permian, Cretaceous, and Tertiary. Thus far, the first two have shown no, evidences of being oil bearing within Brazilian territory. Not enough exploring has been done to permit trustworthy comparisons of the relative importance of the Permian, Cretaceous, and Tertiary as oil-bearing horizons in this country. The most important, indeed almost the only, information available relates to the locations of the areas and to the structural features of the several horizons. The theories regarding the physical conditions under which these rocks were laid down, however, I regard of the utmost importance. PERMIAN Rocks of Permian age cover an enormous area in Brazil, extending from Rio Grande do Sul to Maranhão on the north, and to Matto Grosso on the west. These Permian rocks in many places are known to include oil-bearing shales and in some locations contain small veins of gilsonite. The geologic map of Brazil shows that the Permian area is widely distributed, but there is considerable doubt about 'the origin of some of the rocks:. Some of the lower Permian beds in southern Brazil contain marine fossils, but in Minas no fossils have as yet been found in them, and in Bahia, at only one locality have a few Permian plants been found. Indications of oil have been found in the states of São-Paulo, Paraná, and elsewhere farther south, but wells drilled in the Permian of São Paulo near the Morro do Bofete did not find oil. One well has been started, by the Brazilian government, in the Permian of Paraná near Marechal Mallet, close to latitude 26° south, but thus far oil has not been found.

Jan 6, 1922

(Members are urged to send in for this column any notes of interest concerning themselves or their fellow-members.) Members and guests who called at Institute headquarters during the period Apr. 10, 1916; to May 10, 1916: Philip P. Baily, New York, N. Y. George W. Otterson Seattle, Wash. John M. Brooks, Jr., Knoxville, Tenn. C. Q. Payne, New York, N. Y. C. A. Burdick, New York, N. Y. Charles F. Potter, Los Angeles, Cal. W. N. Crafts, Oberlin, Ohio. Albert E. Rhoads, Harrisburg, Pa. Andrew B. Crichton, Johnstown, Pa. M. F. Sayre, Schenectady, N. Y. 0. P. Hood, Pittsburgh, Pa. H. V. Smythe, Northpines, Ont., Canada. W. McA. Johnson, Tulsa Okla. W. 0. Snelling, Long Island City, N. Y. G. H. Morgan, New York, N. Y. W. H. Staver, Ophir, Colo. E. G. Norton, Chicago Ill., A. W. Tucker, Salisbury, N. C. M. L. O'Neale, Coal City, Ala. Andrew Weisenburg, Philadelphia, Pa. Arthur H. Brown has resigned his position with the Dome Lake Mining & Milling Co., South Porcupine, Ont., Canada. Robert Sterling has resigned his position as chief engineer of the Goldfield Consolidated Mines Co., Goldfield, Nev., to accept the position of assistant manager of the vanadium mines of the Primos Chemical Co., Vanadium, Colo.

Jan 6, 1916

By D. J. Carney, R. L. Stephenson

M. O. Holowaty (Inland Steel Co., Chicago)—Messrs. Stephenson and Carney should be commended on the presentation of this very interesting paper. They have introduced new ideas on sampling of sinter and have thereby made a valuable contribution to the qualitative evaluation of sinter. The paper undoubtedly presents a novel approach to the problem of sinter sampling and this is to be regarded as its main value. Sampling of sinter from the pallets prior to the discharge is by no means new. This sampling procedure was used in the past by Philbrook; Hamilton and Ameen and others. The sampling basket used by the authors of this paper, however, permits one actually to obtain a good sample of the sintering mixture. The basket which can also be described as a removable pallet goes then through the entire process of sintering and thus offers a sample which is positively representative of the batch in question. The authors' method of evaluating physical properties of sinter seems to be not altogether clear, however. It is felt that the following points should be clarified: I—In the section describing the shatter test the authors state that a 5-lb sample was used in the actual tests. There is no mention of the initial size of sinter particles used and the method of obtaining this 5-lb sample from the sinter cake weighing about 100 to 120 lb. It is also surprising that the sample was dropped from a height of 3 ft instead of the conventionally used 6 ft. Unfortunately there is no mention of the number of drops to which the sample was subjected. 2—The tumbler test used by Messrs. Stephenson and Carney in testing the samples of iron ore sinter was performed in a standard ASTM coke tumbling drum. The drum measures 3 ft in diam and is equipped with two 3-in. lifter bars. The distance of fall in this testing drum is identical with the distance used in the previously described shatter test. The number of drops in the tumbling drum is approximately double the number of revolutions. The basic difference then between the drop-shatter test used by Stephenson and Carney and the tumbling test seems to be the number of drops to which the sample is subjected and the abrasive action to which the sinter particles are exposed in the rotating drum. In any case, the choice between the shatter test and the tumbler test seems to be only a matter of taste and convenience. 3—The authors of the paper state that "in order to insure getting results that were representative . . . the entire sample obtained by means of the sampling basket was used as the starting material for the tumbler test. If the sample broke in pieces, all the pieces were used regardless of their size." The initial size of the material is known to be a very important factor, influencing seriously the final size of the particles. This should be particularly important in case of hard sinters. It seems also very troublesome and inconvenient to charge 12-in. cubes of sinter weighing about 100 lb into the testing drum. This could be eliminated by taking a standard fraction of somewhat smaller particles.

Jan 1, 1954

By John M. Lovejoy

I take pleasure in transmitting herewith "Petroleum Development and Technology in 1927," in which we have attempted to set out in a series of 40 papers with attendant discussions the advances made in Production Engineering and Refinery Engineering during the year. The volume also contains a digest of round table discussions on Petroleum Engineering Research problems and Petroleum Engineering Education. In addition to the above we set out in 16 papers a review of production of each producing area of the United States and of the more important foreign countries, together with a review of the world's production and forecasts for 1928. We also include 8 papers on the Economics of the oil industry. The papers and discussions included herein represent the contributions of more than 200 engineers, including the foremost in each line. These papers were presented at technical sessions held in Fort Worth in October, 1927, and at the annual meeting in New York in February, 1928. We desire to express our thanks and appreciation to all those who have contributed to this volume. As in previous years, we have attempted to emphasize the value of both written and impromptu discussions. -We have made a practice of returning all impromptu discussions to the authors for correction and amplification, and because of this practice we feel that the discussions contained herein are in very presentable and readable form. It was decided by the nominat,ing committee when meeting for thc purpose of nominating officers for 1928 to eliminate the vice-chairrnanship for Transportation Engineering, as that branch of the industry seemed to come more naturally under the activities of the American Petroleum Institute. It was also decided by this committee to institute a new vice-chairmanship for Petroleum Engineering Research. Wc have had heretofore round table discussions on engineering research, but through the newly created vice-chairmanship, to which Mr. L. C. Uren was elected, we expect to have more comprehensive sessions on engineering research than heretofort.

Jan 1, 1928

By R. G. Schaal

The Magma Mine at Superior, Arizona had an unimpressive beginning as a. worked out silver mine that was purchased in 1910 for $130,000 and then incorporated into the Magma Copper Company which has been continuously mining the deposit since 1915. Copper is the principal metal produced. However, zinc, gold, silver and iron have also contributed to the total metal product. Prior to 1973, the production rate of 1500 tons per day was maintained by hoisting 4 and 5 ton pay-loads at speeds up to 1100 FPM through four small hoisting shafts. The hoists used included 8' and 7' diameter double drum, double clutched doc. and a.c. motor driven geared units built as early as 1917. One old timer that did yoeman's service for many years was an 8' Bollen Pulley with a.c. geared drive that utilized an endless rope system with mechanical grip and release mechanism built into the pulley's throat. Primary power for all of these old production hoists was 25 Hertz. Exploration that was completed in 1967 developed a reserve of 10 Million tons of 5 per cent copper which was sufficient to justify new capital expenditures for enlargement of productive facilities to 3300 tons per day. To reach the new reserves a 22' I.D. concrete lined vertical shaft was sunk to an initial depth of 48431. A 12 ½ diameter adit was bored from the mill side of the mountain to intercept the shaft at a point about 1100' below the collar. This 9200' long adit provides the right-of-way for the mine to mill railway and egress for heavy supplies from rail head as well as a conduit for potable water, electric power, compressed air and mine drainage. Mine operating levels begin 3582' below collar and thereafter have been cut at 100' vertical intervals. Skip loading stations have been installed 4282' and 46821 below collar with an in-shaft skip dump station located 800' below collar. This provides for 4500 tons of storage above the mine to mill train loading station located 1100' below collar. Ore and waste are moved horizontally from stope chutes and drift headings by rail haulage to transfer raises which channel all material to the two mentioned skip loading stations. The 22' diameter shaft crossection is arranged with the two skip compartments on the south side separated from the manway and utility compartments by the cage compartment. The cage counterweight operates in a portion of the southwest quadrant of the shaft. The hoisting plant consists of two conventional Nordberg double drum, single clutch, geared, d.c. motor driven units that are identical except for the drives and automatic controls. The drums are 15' diameter x 105" face with LeBus grooving for 2-1/8" diameter wire rope wound in three layers. Mechanical design emp1o::ed is the same as has been used for the past twenty- five years. One drum is attached to the main shaft by 2 large bolted integral shaft flenge. The loose drum is engaged by a 4-arm positive tooth clutch meshing with radially cut teeth of the clutch ring which is bolted to the drum. The drums are one-piece steel plate weldments having a finished weight of 60 tons each and are mounted upon a 36" diameter shaft that also weighs 60 tons. With the addition of brake rings, clutch, bull gear and rope, the total dead weight adds up to nearly 250 tons that is supported by just three double row spherical roller pillow block bearings. There is no bearing between the drums. All pinion shafts as veil as all head sheave journals are supported in the same type of antifriction bearings.

Jan 1, 1975

By W. L. Phillips

Single crystals of aluminum, brass, and copper oriented for (100) and (110) slip were extended at 25°, 400°, and 600°C in simple shear. Aluminum specimens oriented for nonoctahedral slip began to shear at a higher critical resolved shear stress than specimens oriented for octahedral slip. Parabolic stress-strain curves were obtained from zero strain. The initial rate of parabolic hardening was lower for specimens sheared on the (100) plane in a close-packed direction <110>, than for specimens sheared in a nonclose-packed direction <100>. metallographic evidence, however, showed that all slip traces could be explained in terms of (111) <100> slip. All attempts to cause nonoctahedral slip in copper and 70-30 a-brass single crystals were unsuccessful. Instead of shearing, the crystals bent, allowing {111} type planes to come into action. NONOCTAHEDRAL slip in aluminum has been reported under three different conditions: first, as the main mode of slip in tension experiments at elevated temperatures;&apos;-&apos; second, as the main mode of slip in direct shear experiments at room temperat~re; and third, as a minor mode of deformation, i.e., as cross-slip, in tension, shear, and bicrystal experiments at room and elevated temperatures."-l2 However, as far as the author knows, nonoctahedral slip has not been reported in either copper or 70-30 a-brass. The present study was undertaken to determine whether nonoctahedral slip could be obtained in aluminum, brass, or copper at room or elevated temperatures when the shear stress was approximately constant over the cross-section, a maximum at the center, or a maximum at the surface. EXPERIMENTAL PROCEDURE A detailed description of the crystal preparation and shearing apparatus has been given previo~sly. Cylindrical crystals 1/2 in. in diam and 8 in. long were grown from the melt in a temperature-gradient furnace. The aluminum contained 0.001 pct Zn, 0.001 pct S, and 0.001 pct Fe; the 70-30 brass contained 0.015 pct Pb, 0.001 pct Fe, 0.01 pct Ni, 0.02 pct Sn, and 0.005 pct Se; the copper was certified OFHC of 99.98 pct purity. All samples were electropolished prior to testing. The shear apparatus was a modified Bausch type. The strain sensitivity was 4 x lob4 Load was applied by clamping the rods attached to the shear plates in an Instron tensile machine. The rate of loading was 0.02 in. per min. In all cases a 1/8-in. gage length was used. For the tests performed at 400° and 600°C the shear plates, collars, and rods were made of stainless steel. These elevated-temperature tests were performed in an argon atmosphere. A) Aluminum at Room Temperature. Values of a and ß for the various slip planes and slip directions investigated are shown in Table I where a is the complement of the angle between the specimen axis and the slip direction, and ß is the angle between the specimen axis and the normal to the shear plane. The shear stress is a function of a (assuming ß - 0);10 when a is less than 27 deg, the shear stress on the slip plane for which the specimen is oriented has a maximum at the center of the crystal; at a = 27 deg the shear stress is constant across the slip plane; for a greater than 27 deg the shear stress is a minimum at the center. Fig. 1 shows the stress-strain curves for specimens cut from crystals 1, 2, and 5, which were sheared on the (010) plane in the [loll direction at room temperature. These three crystals have shear-stress distributions corresponding to the three dif-

Jan 1, 1962

By Lawrence W. Aldrich

At the San Francisco meeting of the Institute last year, I presented, through the courtesy of Dr. James Douglas, some results of experiments on the roasting and leaching of concentrator tailings. After it became apparent that flotation rather than leaching was clearly the better method of handling the particular problem under consideration, before dismantling the experimental equipment, some data were secured on roasting and leaching the concentrate itself in competition with smelting. Some of the results obtained are given in the following paper and they are of particular interest at this time in view of the large quantities of flotation concentrates with their somewhat difficult smelting characteristics now being produced. A complete wet processt consists of roasting and leaching the calcines in dilute sulphuric acid produced from the roaster gases, roasting the residue with salt and leaching with dilute tower liquors (the well-known Longmaid-Henderson process) and recovering the copper, silver and gold by cementation or electrolysis or a combination of both. It is evident, however, that the residue from the first leaching, carrying about 20 per cent. of the copper and all of the silver and gold, can be smelted if preferable. In considering the application of the scheme to individual cases, it must be remembered that freight plays a large part in any reduction process wherein smelting is not conducted at the mouth of the mine, and that it is not practicable today to build small smelting plants for individual operations, The experiments may be grouped under four main heads: Roasting, leaching, chloridizing residue, and recovery of copper from solutions. The products of two concentrators were used: The Nacozari concentrates were the product of a large modern mill not using flotation, the copper mineral being largely chalcopyrite; and the Tyrone concentrates, the product of an experimental mill including flotation, the copper mineral being chiefly chalcocite. Typical analyses are given in Table 1. Fig. 1 shows screen analyses of calcines obtained by dead roasting the

Jan 1, 1917

By E. J. Koval

Practical miscible displacement processes will be characterized by lingering of the solvent into the oil. The lingering process is brought on by viscosity differences, and can be accentuated by channeling and longitudinal dispersion. The effects of these factors on the efficiency of unstable completely miscible displacements are combined in what is called the K-factor method. This method, analogous to the Buckley-Leverett method, predicts recovery and solvent cut as a function of pore volumes of solvent injected. Experimental data are included and show excellent agreement with theory for a wide variety of sandstone cores and viscosity ratios. INTRODUCTION Theoretical considerations,1 laboratory experiments,2 and pilot tests3 lead to the conclusion that miscible displacements in the field will be unstable In an unstable miscible displacement, the solvent fingers through the oil. This fingering leads to early breakthrough of the solvent and an extended period during which both oil and solvent are produced. For such a system, there appear to be four principal factors which bring about or accentuate the effects of instability: longitudinal dispersion (including geometrical effects), channeling, viscosity differences and gravity differences. Other factors, such as diffusion and flooding rate, can also influence the effects of instability, but at the flooding rates considered in this report, circa 15 ft/D, they are unimportant. Longitudinal dispersion can be thought of as a spreading of the solvent front caused by the presence of microscopic inhomogeneities. Channeling of the solvent occurs when a porous medium has macroscopic inhomogeneities; i.e., gross permeability variations. Viscosity differences lead to fingering of the less viscous solvent. This difference in viscosity accelerates the growth of fingers along paths previously developed because of permeability variations. Gravity differences lead to overriding by the usually less dense solvent. Al- though gravity effects are generally small at a flooding rate of 15 ft/D, they would, nevertheless, unnecessarily complicate the interpretation of flooding experiments. For this reason, all the experiments reported herein were done with matched density fluids. Fingering and the resultant poor areal sweep were recognized early as the dominant influences on the efficiency and the economics of miscible displacement processes. Much research effort has been spent on ways to minimize fingering and increase areal sweep such as the use of graded viscosity slugs4 or water slugs. Some researchers attempted to work out ways to prevent fingering completely; i.e., to achieve a stable displacement through gravity or latitudinal dispersion stabilization. l Others did not attempt to control fingering but obtained an economic process by merely recycling the solvent and sweeping pattern by pattern.6 During this period, all aspects of fingering came under close scrutiny. Some researchers reported on how fingering looks2 and how it is affected by viscosity ratio,7 geometry,7 and slug size.2,* Peaceman and Rachfordg suggested a mathematical approach to the prediction of unstable miscible displacements in relatively homogeneous sand packs, but their work cannot be extended conveniently to heterogeneous systems. Hence for a heterogeneous system, no method is presently available for predicting solvent cut and recovery as functions of pore volumes of solvent injected. The purpose of this investigation was to attempt to fill in the gap in our knowledge concerning the prediction of performance of unstable miscible dis placements. Necessarily, the system selected for study was a relatively simple one. The restrictions placed on the system were: (1) The system was linear; (2) The solvent was miscible in all proportions with the oil in place; (3) The solvent was continuously injected into the porous medium; (4) Gravitational effects were eliminated by matching densities and (5) All the flood rates were high and constant at 15 ft/D to avoid any small rate effect and to minimize any diffusion effects. To simplify and to indicate that both longitudinal dispersion and channeling arise from permeability variations, the effects which they cause or influence have been termed heterogeneity effects. The use of

By AIME AIME

INSTITUTE HEADQUARTERS, Hotel Statler. On Monday evening, Oct. 28, 1912, the visiting members and guests were informally received by the Local Committee at the Headquarters of the Institute at. the Hotel Statler. The evening was very pleasantly spent in renewing old acquaintances and friendships and in forming new ones. The first session, held Tuesday morning, Oct. 29, 1912, in the impressive Assembly-Room of the hotel, was called to order by David T. Croxton, Chairman of the Local Committee. Mr. Croxton introduced the Hon. Newton D. Baker, Mayor of Cleveland, who extended a cordial welcome to the members and guests present. James F. Kemp, President of the Institute, who subsequently presided at the meeting, responded in behalf of the Institute.

Nov 1, 1912

By ALEC CROWELL

Mississippi has had oil production for only the past six years and natural gas production of minor magnitude since&apos; 1926. The search for oil and gas commenced in 1903 and 1496 wells had been drilled in search of oil and gas up to Jan. 1, 1946. As the year 1945 ended, 659 wells were producing oil and gas from 23 separate reservoirs. The production for the year was 8,353,719,000 standard cubic feet of natural gas measured on a pressure base of 15.025 lb. per sq. in. abs., 15.316,009 bbl. of oil¬field water and 19,093,766 bbl. of crude oil and condensate. Production for the year 1944 was 2,636,067,000 standard cubic feet of gas, 14,979,793 bbl. of salt water and 16,420,346 bbl. of crude oil and condensate.

Jan 1, 1946

By H. E. Nold

THE raw materials of the ceramic industry are mostly clays. This raw material is ground, water is added and the mixture pugged into a moist, plastic, rather stiff mass. From this mass the desired units of manufacture are made (bricks, hollow building tile, sewer pipe, etc.). These units are dried; then placed in kilns and heated until the desired degree of vitrification is obtained.1 For firing ceramic ware, two distinct types of kilns are used; namely, periodic and continuous tunnel. PERIODIC KILNS Periodic kilns are those ordinarily seen in a brick plant. They are either round or rectangular. The raw, dried, formed ware is piled or set in the kilns to depths frequently exceeding 10 ft. The kiln is heated until the ware is matured, then gradually cooled sufficiently to allow men to remove the ware; then the cycle is repeated. The time duration of the cycle may be more than two weeks. In order that heat can be distributed uniformly throughout the pile or setting, the units are placed so as to leave open spaces or flues through-out the pile for the passage of the hot gases. Each kiln is provided with a number of fireboxes (usually 10 or 12) spaced equally in the outside wall. The fireboxes may be equipped with flat or inclined grate bars or they may have no grates at all (dead bottom). Down-draft kilns are most used. In these the hot gaseous products of combustion from the fireboxes are deflected upward by bag walls just inside the fire zone. From the top of the kiln the gases are drawn down through the setting, off through holes in the kiln bottom, and conducted to a stack or stacks. In up-draft kilns the fireboxes are usually set somewhat lower. The hot gases are drawn inward and upward through the ware and pass off from the top. Up-draft kilns find their greatest use in the firing of common brick. In either case the problem is to maintain, as nearly as possible,

Jan 1, 1933

By Paul C. Ragland, P. Geoffrey Feiss

The Piedmont province of the southern Appalachians is the focus of interest for many exploration geologists. In the past, only those deposits with significant surface exposure were exploited. Thus, few deposits have been found and relatively little exploration has been conducted in recent years. Modern geochemical and geophysical techniques can alleviate this problem of concentrating on exposed ore bodies by allowing us to "look through" the soil and saprolite to detect the presence of significant mineralization at depth. This paper will attempt to evaluate the feasibility and effectiveness of several geochemical exploration techniques in the Piedmont province of Cabarrus and Stanly counties, N.C. The area chosen for study is shown in [Fig. 1], lying almost wholly within the Mt. Pleasant quadrangle, N.C. The area is on the eastern boundary between the Charlotte belt, a zone of plutonic and intermediate grade metamorphic rocks, and the Carolina Slate belt, a series of complexly interbedded volcanic and sedimentary rocks of predominantly low metamorphic grade. The area is considered to be an early Paleozoic active, continental margin. l As is typical of most of the piedmont, outcrop is sparse. [Figure 2] is a sketch map of the general geology of the area under study, showing the Charlotte belt rocks in the northwestern quadrant and slate belt rocks to the east. Within the area are a number of old mines and prospects, the most famous of which are the Furniss and Phoenix mines in Cabarrus County. All are reported to have contained Au and Cu. Ag and Pb were reported from some. A summary of the deposits is given in [Table 1]. Data used in this study are from three Master&apos;s theses completed at the University of North Carolina at Chapel Hi11. 3, 5, 6 In separate studies, well waters, 5 B-zone soils,3 and vein and float from the area were sampled and analyzed. Each study concluded separately that geochemical anomalies in the vicinity of the ores justify use of that specific sampling technique in a geochemical exploration program. However, no comparative study of the methods has been made. It is our intention

Jan 1, 1980

By M. T. Simnad, C. E. Birchenall, M. H. Davies

THE marker movements observed by Davies, Simnad, and Birchenall during the growth of magnetite on wustite have been misinterpreted. It is the purpose of this note to correct the original interpretation. In that investigation wustite specimens were prepared by oxidizing pure iron disks in water vapor until the iron was consumed. Argon was used as a carrier gas for the water vapor and on the complete conversion of the metal to its oxides (&apos;FeO&apos; plus a small amount (10 pct) of surface Fe3O) the water supply was bypassed and the specimens were annealed in argon alone in order to equilibrate the wustite with the overlying magnetite. After cooling, the magnetite was ground off, a crude magnetic test being employed to determine its complete removal. Radioactive silver streaks were then applied to the surface and the specimen was oxidized completely in water vapor to prevent hematite formation. After complete oxidation the markers were found to enclose about 80 pct of the magnetite with the other 20 pct lying outside the markers. This observation was interpreted to mean that oxygen transport was four times as great as iron transport during the growth of the magnetite. The conclusion would have been correct if, as in the case of wustite growing on iron, all the iron had started from one side of the marker and all the oxygen from the other side initially. Actually a material balance is required. For simplicity, take wustite to be exactly FeO, and magnetite to be Fe3O,. Then at the start of the reaction 3 FeO + O -> Fe,O., All of the iron and three-fourths of the oxygen of the final product will be within the marker inter- faces. The other fourth of the oxygen is in the gas phase outside the marker. From the experimentally determined final position of the markers simple calculation shows that one-fifth of the total iron has crossed the marker interface, while one-twentieth of the total oxygen has crossed in the reverse direction. The simplified result favors iron transport in the ratio four to one. However wiistite is not stoichiometric FeO. At 900°C, the temperature of the measurement, the composition is about FeO When the material balance for the same experimental result is repeated, assuming the product will be 1 mol of Fe3O4, it is found that 0.6 gram atoms of iron and 0.19 gram atoms of oxygen must have passed the marker in the same direction. (This is readily apparent from the reaction to form 1 mol of Fe3O4 SFeO The total oxygen supplied from the atmosphere is 0.61 gram atoms, but the iron which passes the marker interface, i.e., 0.6 gram atoms, requires 0.8 gram atoms of oxygen to convert it to Fe,O,.) If all the transport during magnetite growth is due to iron ion diffusion, then the marker would enclose about 85 pct of the final magnetite and the original measurement is in error by about 5 pct. This error is probably less than the uncertainty in locating the markers by autoradiography. The possibility also exists that the starting wustite was not quite saturated with oxygen and underwent further enrichment with consequent envelopment of the marker before magnetite caught up with the marker interface. In any case it appears that these measurements actually favor iron ion diffusion in magnetite overwhelmingly as the factor controlling its growth, although further experimental measurements are needed to eliminate the error in material balance described. Such studies are planned.

Jan 1, 1954