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By Richard Mainiero, Donald A. Hurd, James H. Rowland

In previous conferences the authors have reported on toxic fumes generated by the detonation of ANFO. The research reported here extends the earlier work to include an emulsion blasting agent and ANFO/emulsion blends. Explosive mixtures were shot in 4-inch Schedule 80 steel pipe in a chamber in the experimental mine at the Pittsburgh Research Laboratory (PRL). Following each shot, the fumes in the chamber were analyzed using on-line instrumentation. A major goal of the research was to gain a better understanding of the factors that lead to the generation of toxic fumes in blasting operations. Earlier studies have suggested that the high nitrogen dioxide and nitric oxide concentrations in product clouds might be the result of the poor confinement provided by relatively weak ground strata or the exposure of the explosive to ground water prior to shooting the shot. Various mixtures of ANFO and emulsion were detonated in schedule 80 steel pipe and galvanized sheet metal pipe to evaluate the effect of confinement. Explosive mixtures were also allowed to soak in water for less than one day, one week, one month, and two months to determine which explosive mixtures would be degraded and observe what effect this degradation had on fume production. Results indicated that the production of nitrogen dioxide increased with low confinement of the detonating explosive and with exposure of the explosive to water.

By Eliezer Kamon

To finalize the three years granted for the study of miners physiological responses to emergency situations, all the data obtained, were summarized into the following relevant sections; A.. Information on elements of the Man Test required under Subpart 4, Part 2, Title 30 in the Code of Federal Regulation (see Table M-T and Ref. I., Section A). B. Investigation on possible emergency activities, its simulation in the laboratory and the physiologic data obtained on miners performing them This included some studies under cool ambient conditions, expected to prevail in coal mines. C. While in section B the steady state responses have been obtained, time was devoted to establish a unit that will allow data gathering for non-steady state, i.e., transient responses to rapidly changing activities. Section B and C contained elements that were relevant to section A; the Man Test. Therefore some of the information described under section A Man Test, were actually measured during the battery of tests in either section B or in section C.

Jan 1, 1974

By T. R. A. Davey

The fundamental principles by which bismuth may be removed from lead by pyrometallurgical processes are enumerated. Qualitative discussion of the phase diagrams concerned is followed by presentation of quantitative diagrams. Brief mention is made of the practical aspects. Data presented show how chemical lead (<0.005 pct Bi) may be produced by the Jollivet, Dittmer, and Kroll-Betterton processes. BISMUTH is an element whose properties are very similar to those of lead, and its minerals are associated to a greater or lesser extent with nearly all the major lead ore deposits of the world. In consequence, the lead produced contains bismuth unless a special debismuthizing process is practiced. There does not appear to be any published comprehensive review of the effect of bismuth as an impurity on the properties of lead, and there is some uncertainty as to the beneficial or detrimental effects of small amounts of bismuth in lead used for particular applications. Standard specifications of most countries stipulate a maximum bismuth content of 0.005 pct for chemical lead. With one exception, this specification is met only by lead producers whose ores are relatively bismuth-free, or whose refineries are electrolytic. In lead for certain applications a higher bismuth content is preferred by some fabricators.&apos; In contrast to the refining for silver, copper, and antimony, the refining for bismuth does not usually result in a large overalil economic gain from the sale of byproduct. Thus, debismuthizing is customarily practiced only if market conditions demand a lead with a bismuth content lower than that produced by classical refining; i.e., softening, desilverizing, and zinc refining. Until this century, debismuthizing was carried out only a:; an incidental result of desilverizing, as later described. This century has seen the development of the Betts electrolytic process—the only successful one of many electrolytic processes proposed and patented —and a number of precipitation processes based on the pioneering work of Kroll,&apos; although only one of these, the Kroll-Better ton process,&apos; is in wide commercial use today. It is proposed in this paper to deal only with the pyrometallurgical processes, excluding those based on aqueous electrolysis. Historical Background Prior to 1833 silver (and incidentally bismuth) could not be removed from lead. To recover silver from rich bullion, the only course available to lead refineries was to cupel the bullion, forming a slag of litharge. The first slag tappings or skimmings, on reduction, yielded soft lead of very low silver and bismuth contents. Intermediate skimmings yielded a lead of somewhat higher silver and bismuth contents, which could if desired be recupelled. The last skimmings yielded a litharge very high in bismuth, which could by successive oxidation and reduction cycles be separated into high purity bismuth, and lead returns. This oxidation reduction process, with modern operating techniques, can still be used today to produce a portion of a lead refinery&apos;s output of very low bismuth content, as discussed later. In 1833 Pattinsone discovered that lead bullion could be purified of silver and bismuth by fractional crystallization, the primary lead crystals formed by partial freezing being purer than the melt. Repeated processing in pans produced a lead containing as little as 0.02 pct Bi. The simple explanation of this

Jan 1, 1957

By Henry Louis

THE work performed by the Royal Commission on Mining Subsidence is likely to prove of permanent value, less perhaps for the conclusions it has reached and for the recommendations it has based upon these than for the admirable exposition which it affords of the law concerning mining subsidence and of the legal status of the person who has suffered damage by reason of such subsidence, as also of him whose working has caused the damage. The Commission was appointed by Royal Warrant in the middle of 1925 and delivered its final report in the middle of 1927. The terms of reference to the Commission were as follows: "To consider the operation of the law relating to the support of the surface of the land, and of buildings or works on or under the surface, by underlying or adjacent minerals; to enquire into the extent and gravity of the damage caused by subsidence owing to the extraction of minerals and the incidence of the resulting liability; and to report what steps should be taken, by legislation or otherwise, to remedy, equitably to all persons concerned, any defects or hardships that may be found to arise in existing conditions."

Jan 1, 1929

By Wesley, Worner H

During the meeting of the Institute last year at Port Pirie, the opportunity was taken to sample the lead bullion coming from the blast furnace and various stages during the refining process. Also, in the desilverising section, the upper zinc rich phase was sampled as the silver content built up and in the cupellation operation a series of samples was taken as the silver content of the bullion increased. In these two cases, the samples were taken under the supervision of a member of the staff of the Broken Hill AssociatedSmelters.In the following account of the microstructure of the samples taken, only the main phases present have received attention. In this connection deduction from phase diagrams of binary alloys has been used in conjunction with the assays carried out on duplicate samples taken at the same time as those for micro examination.

Jan 1, 1938

By Mike Higgins

"Data management is emerging as a major concern for miners. Engineers today are faced with anextensive array of data from varying sources, and are required to consolidate and analyse thisinformation to produce an effective and efficient mine plan. The viability of a mining operation canbe dependent on the outcomes of this process. With so much at stake, it is no surprise that mostengineers prefer a standard approach to blasting which is designed to minimise risk rather thanoptimise performance."

Jan 1, 1998

By Gregg S. Hill, Bert J. Huls

"This paper on coarse particle recovery (CPR) summarizes a process to capture coarse particles that are not recoverable by regular flotation. Several porphyry copper operations in the world operate analogous circuits that recover non-floated copper from tailings; however, the case presented here is unique in that extensive underlying test work has allowed us to elucidate some fundamental principles behind recovery enhancement. This paper discusses an overview of the flow sheet that is proposed to Minera Escondida Ltda., the nature of copper in the feed to the CPR circuit, and the various unit operations within the recovery circuit. Details of the technology behind each unit operation will be presented in later publications.INTRODUCTIONSince 1996 BHPBilliton and MEL (Minera Escondida Ltda.) have developed a process to recover copper from coarse particles in the rougher tailings. Copper recovery from fresh tailings is not new. Several operations in Chile, such as Chuquicamata, El Teniente (AMEC, 2003), Mantos Blancos and others have operated various forms of tailings circuits. Both Chuquicamata and El Teniente practice cascade flotation scalping off froth containing fine copper particles after allowing sufficient retention time, air inducement and, sometimes, additional reagent addition. Chuquicamata tailings are not segregated but floated in sequential cascade and conventional large cell arrangements. At the Valle Central operation of El Teniente a coarse fraction of mill tailings is ground and floated, with the rejects recombined with fine tailings and subjected to cascade flotation through a sequence of concrete launders as the tailings flow towards their final deposition area. Mantos Blancos cyclone the rougher tailings and blend the underflow with scavenger concentrate from elsewhere in the principal circuit prior to flotation in Wemco Cells. Kemess in BC, Canada operates a 160 m3 Outokumpu cell to reduce the tailings sulfur content (Rasmussen, et.al, 2004)."

Jan 1, 2005

By J. J. Forbes

The activities of the Bureau of Mines include the development and testing of self-contained oxygen breathing apparatus and other devices for respiratory protection, the development and tasting of devices for detecting dangerous or noxious mine atmospheres, and the training of men in the mineral industries in the use and care of this equipment to enable them to render effective service in mine rescue and recovery operations following mine fires and explosions, or under other conditions where irrespirable gases may be found in mines or mining plants. The first use of self-contained oxygen breathing apparatus for com- bating mine fires and explosions in the United States dates back about 30 years. Previous to that time, exploration for any distance ahead of fresh air was virtually impossible without great risk to life; moreover, the men called upon to render service at mine disasters were not well-versed in the properties and physiological effects of gases likely to be encountered. It was also impossible to work ahead of fresh air to restore ventilation, and if many stoppings were blown out by an explosion, air had to be introduced into whole areas or sections at once without knowledge of the conditions ahead; moving an explosive mixture of methane and air over live fire had to

Jan 1, 1938

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By A. Sand

A 2-dimensional computational model based on the discrete element method (DEM) is utilized for modeling of stamp-charged coke making. In this process, a large volume of coal is compacted to one single coal cake before entering the coke oven. Cake densification and mechanical strength development are key factors for the subsequent production of a high-quality coke. An approach is introduced for model calibration utilizing multiple control parameters obtained from a laboratory-scale stamping device. Experimental data on stamper rebound amplitude, attenuation and peak force are compared with simulation output in a pairwise manner by constructing a criteria space, which allows identification of model settings best satisfying the control parameters. The calibration procedure carried out by multiple criteria comparison aided model parameter selection for reproducing stamper behavior in response to the properties of the cake subjected to compaction. This modeling and calibration procedure offers possibilities for numerically studying the densification and mechanical strength development of coal cakes. However, the approach is also more widely applicable to other compaction processes.

Feb 27, 2013

By S. Ripke

Between 2002 and 2004, the performance of a six million ton per year iron ore beneficiation plant dropped significantly. In a classic case of “who done it,” was it the mine, the concentrator, an ore change, or something else? While average annual final product grade decreased 8% (indicated by an increase in silicate gangue from 2.76% to 2.99%), the weight recovery also decreased by 8% (from 37.92% to 34.79%). This represents a loss of 832,000 tons of iron ore worth about $16 million for the two year period! The concentrator had been optimized to produce a high grade wet concentrate as feed to the dry side of the plant. But, did optimizing an individual unit operation’s grade give the best overall plant performance? In this paper, the investigation and solution to this mystery will be revealed.

Jan 1, 2007

By José Mirão, Pedro Madureira, v Costa, Patrícia Conceição

"The exploration of seamounts south of the Azores during the EMEPC/Açores/G3/2007 campaign allowed for the collection of 30 Fe-Mn crusts from the Atlantis, Great Meteor, Small Hyeres, Irving and Plato seamounts, as well as from the East Azores Fracture Zone. These were the first samples of Fe-Mn crusts studied from these seamounts. The Fe-Mn crusts were analyzed using multiple analytical methods.The crusts are fairly homogeneous, showing typical textures for this type of occurrences. The Fe/Mn ratio, patterns and concentrations in rare earth elements, and the great homogeneity of the crusts lead to the conclusion that they have a hydrogenetic origin, precipitating directly from seawater. Although the content in Fe and Mn of the crusts is consistent with data available for the Atlantic, the mean concentration of Co is comparable to the average values for the Pacific. Cu and Ni show lower values than the ones known for the Pacific."

Sep 1, 2014

By Lee Nichols

Convergent Bitumen Recovery Context of discussion It should be noted that the CBR process is a conceptual bitumen recovery feed methodology, designed to provide supplemental bitumen to the oil sand operations of Northern Alberta. To date the following have beencompleted. ?Bench Scale testing. ?Peer group brainstorming. ?Energy Balance ?Confidentiality agreements have been signed with several companies Discussions are ongoing with industry and although conceptual atthis stage the process holds significant promise.

May 1, 2007

By R. Farnfield, W. Birch

Arguably, some of the most restrictive statutory blast vibration requirements attached to mineral extraction operations can be found in the United Kingdom. Such limitations are, as a rule for the UK, stipulated together with a required statistical confidence that has to be observed in the blast design process in order to ensure total planning compliance. A key element in this procedure is the effect imparted by vibration data scatter from previous blasts as this becomes reflected in the site’s operational standard error statistic and in turn directly influences the maximum instantaneous charge weights that can be justifiably employed. The greater the scatter, the lower the compliant charge weights become.

Jan 1, 2006

By D Craw, J Pope, B Peake

Southland contains over 70 per cent of New ZealandÆs recoverable coal resources, and an investigation into the potential effects of coal mining on SouthlandÆs water resources is therefore of interest. This paper investigates pit-lake water quality in relation to current mining activities within the sub-bituminous coal and lignite deposits of Southland. &nbsp; Water quality data was collected from pit-lakes in sub-bituminous and lignite deposits from October 2005 to March 2006. After periods of settled weather, turbidity increased with depth at the sub-bituminous pit-lake (10 - 21 NTUs from 5 - 30 m). In the stratified sub-bituminous pit-lake in March 2006, heavy rainfall caused higher turbidity in the epilimnion than the top of the hypolimnion (20 NTU vs 13 NTU) reflecting surface water runoff (up to 1993 NTUs) and epilimnion mixing. In contrast, turbidity at the lignite sites was variable due to the shallowness of the lakes, but noticeable increases following disturbance and adverse weather were recorded. High turbidity at the sub-bituminous deposits was attributed to the presence of clay minerals such as kaolinite whereas turbidity at the lignite sites was more likely short term and a result of heavier minerals such as quartz. &nbsp; Trace element concentrations at both sites were low when compared to mine waters in other coal areas in New Zealand and no samples exceeded ANZECC water quality trigger values for 80 per cent species protection. Pit-lake water pH levels were lower and more variable in the lignite deposit (4.18 - 7.30 vs 7.24 - 8.98 in the sub-bituminous deposits). In the lignite pit-lakes, higher concentrations of trace elements (eg Dissolved As - 0.034 ppm and Dissolved Mn - 1.09 ppm) and lower pH (ÿ4) were observed at the bottom of active pits compared to inactive pits. It is possible that quartz pebble conglomerates containing sulphide minerals within the lignite seams are responsible for this. &nbsp; Further investigation into the mine waters, waste rock and lake sediments will help get a better understanding of the results observed and long term processes that occur.

Jan 1, 2006

By Timothy C. Siegel

In response to a solicitation for ground improvement for the construction of a new hospital in Owensboro, Kentucky, the team of Berkel & Company Contractors and Dan Brown and Associates PC designed and installed lightly reinforced cast-in-place piles (known commercially as Cast-in place Ground improvement Elements or CGEs) as part of a composite ground system. The concept of the design is that the structure load is shared between the piles and the soil subgrade. The load sharing is controlled (to some degree) by the placement of a cushion between the pile head and the bottom of the overlying spread foundation. In an effort to confirm the design principles and to better understand the behavior of composite ground, the design-build team performed plate load tests on ground with a single CGE and with a group of CGEs. The small plate test (on ground with a single CGE) characterized the stiffness of the cushion. The large plate tests showed that the cushion will distribute the applied load to the CGEs and to the soil subgrade between the CGEs. On the basis of the plate tests, it was concluded that the plate stiffness can influence the test results. The use of a concrete layer was effective at supplementing the plate stiffness. The cushion was shown to be an important component of a composite ground system by allowing mobilization of the soil subgrade resistance and avoiding a stress concentration at the tops of the CGEs that would otherwise be present if the spread foundation and piles were rigidly connected. Because the composite ground system engages the resistance of the soil subgrade, the structural demand is reduced and consequently there is a potential for savings when compared to a conventional pile foundation. Several foundations for the new Owensboro hospital are being monitored for vertical movement during construction of the superstructure that will extend through 2011. At the time of this paper (mid 2011) the settlement of the foundations due to only part of the structural load (primarily the structural steel) has been negligible.

Jan 1, 2011

By Viviane Tavares

The technology advance of mobile devices makes consumers of these equipment do more constant exchanges, with this the obsolete devices discarding becomes an environmental problem, due its landfill accumulation. In order to minimize the environmental impacts caused by these equipment there?s the recycling necessity of polymers, ceramic and metallic materials. The main goal of this recycling is to study the printed circuit board of device mobile processing through ore treatment in order to recoup copper. Initially printed circuit boards were processed in a knives mill, in order to liberate the ferrous material, after that it was done the magnetic separation of the reduced residue. With the not magnetic fraction it was done the grain sized analysis and sulfuric acid and hydrogen peroxide leaching analysis. With the chemical analysis results proceeding from the leaching aliquot it was possible to observe that the leaching method with sulfuric acid and hydrogen peroxide presented greater copper recovery.

Jan 1, 2009

By Vidyaranya Bandi, Madhav Madhira, Kota Vijay Kiran

"Using hyperbolic relationships for the non-linear responses of shaft and base resistances, a method is proposed for estimating initial shaft and base stiffnesses and ultimate shaft and base resistances of a pile from pile load test results. An iterative procedure is used to arrive at the values of shaft-soil and base stiffnesses and the ultimate shaft and base resistances. The method is applied to load - displacement data available from pile load test results to illustrate its efficacy.INTRODUCTIONA pile foundation is the most effective and economical solution in transferring large vertical loads to deeper depths. As the pile is subjected to axial load, the soil mass surrounding the pile is vital in providing vertical support for the pile. The nature of pile–soil interaction is three dimensional and to complicate the problem further, response of soil is nonlinear. Finding a closed form solution to such problem is extremely difficult. Several methods were developed to study and predict the response of the composite pile–soil system. Faruque and Desai (1982) implemented both numerical and geometric non-linearities in their three dimensional finite element model. Rajashree and Sitharam (2001) developed a nonlinear finite element model of batter piles under lateral loading using a hyperbolic relation for static load condition and modified hyperbolic relation, including degradation and gap for cyclic load condition.The ultimate capacity of the pile is estimated considering the strengths and unit weights of soil layers with depth, overburden pressure and other relevant parameters. The estimated capacities always need to be validated by conducting initial maintained load test. The estimated capacity may differ with the actual at site since the values of strength, stiffness, interface resistance between pile and soil, lateral earth pressure coefficient with depth and soil stratification, etc., differ from the design parameters considered for estimating the ultimate capacity of pile. The estimation of axial capacity of piles involves considerable uncertainties in selection of appropriate design parameters and the design rules are not always consistent with the installation procedures/processes involved."

Jan 1, 2017

By Hani Henein

Recent innovations in atomization of molten metals have occurred in the area of single fluid atomization. Impulse Atomization (IA), one of the single fluid techniques, provides unique capabilities to study different regimes of atomization in a controlled environment. By changing processing variables, a mono-dispersed distribution of droplets above one millimeter in diameter can be produced. This is accomplished through proper characterization of the forces influencing the process and in particular the flow of melt through the orifice. This paper will discuss the approach and illustrate results with molten aluminum and cobalt.

Jan 1, 2006

By M Baker

Biodiversity offsets are conservation actions intended to compensate for the residual, unavoidable harm to biodiversity caused by development projects. The use of biodiversity offsets in the context of mining has significant potential for enabling mining to take place in areas with biodiversity values, where it would not otherwise be possible to meet the relevant legal tests under the Resource Management Act 1991, and potentially the Conservation Act 1987. This paper looks at the concept of biodiversity offsets (and environmental compensation generally) both in New Zealand and internationally, and considers how lessons learned overseas may be adapted for this country. In New Zealand the practice of biodiversity offsets and environmental compensation is ad hoc and variable. The challenge with biodiversity offsets is to establish a transparent and coherent means of identifying the overall priorities and objectives of adopting such an approach, as well as how the relevant values are measured and protected. Establishing a methodology for quantifying biodiversity value, and the need for clear policy guidelines on biodiversity offsets are identified as key areas in need of wider discussion.

Jan 1, 2007