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By J. D. Miller, Jon J. Kellar

Researchers in flotation chemistry have long sought to describe collector adsorption phenomena in greater detail including kinetics, orientation and interactions between adsorbed species. Now a quantitative description can be made in-situ using FTIR internal reflection spectroscopy. Details of the adsorption process at the surface of mineral crystals, machined into internal reflection elements, can be described from first principles, provided the refractive indices, incident angle, and wavelength of light are known. Collector orientation can be established based on spectral characteristics of plane polarized and perpendicular polarized light. Examples of the use of in-situ FTIR internal reflection spectroscopy are given for the sapphire-sodium dodecyl sulfate system and for the fluorite-sodium oleate system. It is expected that quantitative in-situ analysis of collector adsorption reactions by FTIR internal reflection spectro-scopy will continue to grow in importance and will provide an important new dimension in our understanding of flotation chemistry.

Jan 1, 1989

By K. Komnitsas

Activities in the mixed sulphides industry, such as mining and beneficiation, cause adverse impacts to the environment due to excavation, treatment and disposal of low-grade ores and tailings containing residual sulphide minerals. The greatest impact is caused by the oxidation of sulphide phases contained in the tailings and waste rock and the subsequent production of leachates characterized by low pH and high concentration of heavy and toxic elements and sulphates, called acid mine drainage, that contaminates soils, surface- and groundwater. Therefore, rehabilitation of these sites is required in order to render these pollution sources inactive and minimize environmental impacts. The calculation of risk, based on acid mine drainage probability and magnitude of consequences at the disposal sites offers engineers, environmental scientists and authorities a valuable tool for the selection and application of the best remediation technology. Several parameters, such as the chemical and mineralogical properties of the wastes, the most probable pathways the contaminants follow, the potential receptors and the exposure scenarios have to be taken into account. Therefore, risk is the most critical parameter in decision-making regarding management of mining wastes and rehabilitation of disposal sites.

Jan 1, 2002

By S. D. Hill

State-of-the art precious metal recovery practice uses cyanide leach solutions to extract the valuable constituents from ores, wastes, and tailings. Activated carbon is then used as an adsorbent in either a carbon-in-pulp system or counter-current flow columns to concentrate and recover the precious metals. Existing techniques for recovering precious metals from carbon prior to the precipitation or electrowinning of the metal involve either the use of dilute aqueous hydroxide solutions at elevated temperature and pressure or, as in a more recent method, the use of a strong cyanide soak followed by a water strip solution at an elevated temperature. Despite past Bureau efforts in the area of precious metal recovery, the ex- traction of gold from pregnant leach solutions remains the most serious drawback in carbon-in- pulp and heap leach processing of low-grade ores containing precious metal values. A second disadvantage in the current practice is the interference in adsorption and desorption that occurs due to the presence of other heavy metal cations in cyanide leach solutions. Specific objectives of current Salt Lake City Research Center precious metals research are to develop less energy intensive and more economic methods for recovering gold, silver, and by- product metals from low-grade resources. To meet these objectives, we are investigating noncyanide leaching reagents, ion exchange resins, solvent extractants, and novel electrowinnlng procedures.

Jan 1, 1984

By Frederico J. Price

This paper describes the production of a specific iron oxide pellet that has given very good and consistent results as feedstock for HYL-Process Direct Reduction Plants. The sponge iron originated from these pellets has been used for the economic making of almost 15 million tons of low carbon steel via electric arc furnace meltshops. An overview of mining, benefication, pelletizing direct reduction and steelmaking for this case is given with emphasis on the characteristics of the self-fluxing oxide pellets. HYL Operator and management training is described.

Jan 1, 1979

By Kambhampati C. Rao, Cecil Lue-Hing, Nabih P. Kelada, William B. Willborn

improvements in the analytical techniques for cyanide speciation can furnish useful information about the behavior of the different cyanide species in the receiving environment. This could be of help to the environmentally concerned public and the regulatory agencies in the assessment of cyanide limits for effluents, stream quality, and land disposal of cyanide bearing wastes. In addition the ability to distinguish the free cyanide and the weakly bound cyanide from the strong ULTRAVIOLET IRRADIATION UNIT (LAMP, COIU3' HOUSING) FIGURE 1 complexes, as well as transformation to thiocyanate is also needed by different industries, such as mining and metal finishing, etc., to evaluate the efficiency of several processes. Cyanide has been used for the recovery of gold since the late 19th century. Although cyanide leach solutions are mostly recovered and used again, a large quantity of cyanide bearing wastewater becomes unfit for use and has to be treated before it can be released into natural waterways.

Jan 1, 1992

By Katsunori Okaya, Toshio Inoue

Application of the discrete element method incorporating the simple kinetic model of the ball-to-ball and ball-to-wall interactions enables us to visualize the details of the grinding actions prevailing in the ball mills. We have developed a computer program to represent a generic mill model with which we can simulate tumbling mills, vibration mills, centrifugal mills and planetary mills. While the program can be used for various purposes including design of new equipment, one obvious application of it is the analysis of the conventional tumbling ball mills for better understanding and improvement. The purpose of this paper is to present a model and to observe its behavior in particular attention to the spatial distribution of the energy dissipation as well as the energy spectrum and their dependence on the major parameters such as mill speed, ball filling, liner configuration, slurry viscosity and the hardness of the ore.

Jan 1, 1995

By Kwadwo O. Adutwum, George M. Potter, Todd J. Harvey

Ashanti Goldfields Company (AGC) is the largest gold mining company in Western Africa. Their jewel operation is a highly inte­grated set of mines and plants situated in Obuasi, in the Ashanti region of Ghana. This operation is responsible for mining 5.5 mil­lion tonnes of ore at 4.6 git annually from a series of open pits and underground mines. The sulphide ore is highly refractory with untreated gold recoveries in the range of 30-40%. The milling facilities are quite varied and include an oxide treatment plant (OTP), a heap leach, a sulphide roaster circuit (PTP), a tailings treahnent plant (TIP) and the most recent, a sulphide treatment plant (STP). The sulphide treatment plant, the world's largest stirred tank biooxidation circuit, was commissioned in early 1994. This plant treats approximately 800 tonnes of refractory gold con­centrate per day with overall recoveries of75-85o/o(ll, Biooxidation was selected for its ease of operation and less exotic maintenance requirements as well as its ability to achieve comparable gold recoveries. Unfortunately, despite stirred tank biooxidation being one of the lower cost methods of treating refractory ores, it is still too costly for low grade refractory materials. GeoBiotics, Inc. has developed a proprietary technology that allows the economic treatment of lower grade refractory gold ores through heap biooxidation. AGC has a significant resource of low grade refractory sulphide ore. This ore is too low grade to warrant BIOX™ sulphide treatment and its oxide plant recov­ery is low at 35-45%. GeoBiotics and AGC have completed pre­liminary testing and economic analysis of heap biooxidation for this material. Additionally, the feasibility of producing a gravity concentrate from the tailings of the sulphide treatment plant has been explored. This concentrate would be coated onto the low grade sulphide and biooxidized concurrently. Gold recoveries for the biooxidized low grade sulphide have increased to 75% and the gravity recovery from the STP tailings has achieved 80% uti­lizing a Falcon concentrator. The preliminary economics of the proposed full scale plant are very favourable with a pre-tax IRR of 233% and a payback period of 6 months. This paper details the biooxidation testing, flow sheet devel­opment and preliminary economics of employing heap biooxi­dation for low grade refractory ore treatment at Ashanti Goldfields' Obuasi operation.

Jan 1, 1998

By T. E. Wilson

The length of Alaska’s coastline, combined with the presence of a significant number of fjords, encourages consideration of marine disposal of mine tailings. However, since various factors govern the viability of the submarine tailings disposal (STD) option, the decision making process is complex. An expert system, called Submarine Tailings Disposal Expert System (STADES) that will help mining project planners explore the feasibility of STD, was developed. Existing literature, supplemented by engineering recommendations, on the various aspects of marine disposal of tailings was reviewed and formed the knowledge base for the expert system. The shell used to develop the expert system was LEVEL5®.

Jan 1, 2001

By C. H. McGuirk

Computerized Preventive Maintenance is important in maintaining consistent and efficient operation in any industry utilizing sophisticated and expensive equipment on a continuous basis. At today's large bulk materials handling facilities, the problems of continuous operation of complex machines with their thousands of components exposed to abrasion, dirt, dust and the elements, are intensified and multiplied. Effective preventive maintenance can increase profits. Yet, the number of tasks to be performed is so staggering that it is beyond error-free human capacity. The computer must be an essential ele¬ment in any efficient and economical preventive maintenance system. Computerized preventive maintenance techniques have been successfully used in many fields, usually involving highly skilled and specialized personnel working under favorable and controlled conditions. Now, The Pittsburgh & Conneaut Dock Company has developed and is applying a computerized preventive maintenance system that is applicable to the bulk materials handling industry. The "system" has taken many years of intensive effort to develop and has been time-tested and proven during the past years on equipment handling materials with rugged physical characteristics and corrosive and abrasive qualities, under some of the most adverse weather conditions on the Great Lakes.

Jan 1, 1976

By L. E. Krys, K. D. Harrison, S. M. Nordwick, C. G. Anderson

Since 1984, nitrogen-species catalyzed pressure leaching has been utilized at the Sunshine Mining and Refining Company for the recovery of precious metals from a refractory sulfide concentrate, The process operates without the use of cyanide. The plant is now the only industrial-scale commercial application of this technology. Since the inception of the process, changes have been implemented to improve efficiencies and throughputs. Two of these changes, the replacement of nitric acid by sodium nitrite and a concentrate regrind, have recently been implemented. This paper will discuss the outcomes of these recently patented plant-process changes. In particular, a comparison between the previously used method and the new leach method is made. Also discussed is the potential applicability of the process to other materials. A companion publication (Anderson, Harrison and Keys, 1996) indicates possible mechanisms responsible for the success of these process changes.

Jan 1, 1997

By S. J. Porter, M. T. McRae

The Melbourne City Link project includes two three-lane highway tunnels, 1.6 and 3.4km long, respectively, which are both approximately 16 meters wide and 9 meters high. The tunnels will be excavated through interbedded, moderately to highly jointed siltstones and sandstones of the Silurian Age Melbourne Mudstone formation over the major parts of their lengths. The strength of the intact rock varies from less than 5 MPa to greater than 70 MPa. Based on the available information regarding the performance of large span tunnels in weak rock, it was considered that the commonly applied empirical design guidelines for tunnel support, based on rock mass classification systems, should be augmented by more explicit design methods. The support design was, therefore, validated by analytical procedures, including numerical analyses, which are described in this paper.

Jan 1, 1997

By J. B. Cabezas

The metallurgical processes that are frequently applied today use strong solutions and are of alkaline, acidic, or organic nature. These play a very important part in recovery of values from many ores. These solutions are of such a chemical nature that they are generally corrosive, flammable, and contaminating. In most cases, they are highly dangerous to the environment. Within the extractive metallurgical industry, it is also very common to have to deal with the handling of contaminating solutions with a high content of cyanide, arsenic, mercury, lead, copper kerosene, acid and many other components whose temporary or permanent confinement within the process must be adequate and absolute.

Jan 1, 1986

By Fabian Laumen, Sunny Schoone, Felix Leaman, ELISABETH CLAUSEN

The paper evaluates the attenuation behavior of acoustic emission (AE) signals in four different materials used in marine environments. The study aims to identify materials with the highest and lowest AE signal attenuation, providing insights into wave propagation and structural monitoring in deep-sea mining applications.

Dec 1, 2023

By J. Craynon, M. Karmis

Previous papers by the authors have presented a systems-engineering approach based on the premise that systems can only be optimized if all factors are considered and integrated into mine planning. This paper discusses the challenges inherent in optimizing the design of large-scale surface coal mining operations in Appalachia. Regulatory and permitting programs in the United States often focus on single parameters, rather than the full suite of desirable outcomes for sustainability. By utilizing geographic information system (GIS) tools to evaluate available data on environmental and social resources, the regulatory barriers which prevent operations from incorporating ecological and other sustainable development concerns into coal mine sustainability performance were identified. By analysis of the on-the-ground issues related to sustainability, the key parameters to be incorporated into an optimized coal mine design in Appalachia are discussed along with possible changes to the regulatory framework that would enhance incorporation of sustainability into coal mine design.

Jan 1, 2011

By M. Karmis

"The process of coal mining, as indeed of the mining of any stratified mineral, is inevitably followed by some degree of sinking of the superjacent strata and consequently of the surface." Royal Commission on Mining Subsidence, Second and Final Report, London, 1927. INTRODUCTION The above statement was used to describe mining subsidence in the classic report of the "Royal Commission on Mining Subsidence," published in 1927. In fact, this phenomenon has been recognized in Britain since the early fifteenth century, as revealed from court records of disputes and litigations related to property damage above mine workings (Shadbolt, 1978). The first attempts to investigate and analyze the mechanisms associated with mining subsidence, however, date back to the 1800's and were pursued by Belgian Engineers. This research effort was initiated as a result of the widespread movements and subsequent structural damage suffered by the City of Liege in the 1820's. The most notable achievement of the Belgian school of that era was he publication of Gonot's treatise "Loie de la Normal" in 1871 (Gongt, 1871).

Jan 1, 1982

By Moussa Wone, V. Nasri, F. Guimbal, D. Andre

The Magenta underground station was constructed in the heart of Paris in saturated soft soil and at shallow depth. To investigate the surface settlement and the deformation of the concrete liner, innovative techniques combined with a vast campaign of monitoring were applied. The monitoring data and a simple three-dimensional ?nite element analysis were used to assess the accuracy of the two-dimensional ?nite element model originally utilized in the design of the station. The deformation of the concrete liner was monitored using vibrating wire extensometers. Their performance was validated by the data obtained from monitoring and also by a simpli?ed ?nite element analysis.

Jan 1, 2003

By Hassan El-Shall, El-Sayed A. Abdel Aal

The major goal of this study is to decrease iron content in wet-process phosphoric acid. Reducing the amount of post-precipitated sludge in the acid is another important objective in this investigation. In order to achieve these goals, research efforts have focused on bench scale testing of an iron-chelating reagent to remove iron from phosphoric acid produced from South Florida high-iron and -magnesium phosphate concentrate, and plant testing using freshly produced concentrated acids for reducing the post- precipitated sludge. The data obtained in the above studies suggest that the addition point of the precipitating reagent is very important, as the precipitated iron compound has higher solubility at higher P2O5 concentrations. Up to 60% Fe2O3 removal efficiency is achieved depending on the amount of the reagent, concentration of acid used, and operating conditions. The addition of precipitating reagents to freshly concentrated phosphoric acid leads to a decrease of up to 84% in sludge volume percentage depending on acid type and clarification conditions. Decreasing the volume percentage of the sludge facilitates acid handling as well as decreases the adherent water- soluble P205 leading to lower total P2O losses.

Jan 1, 2002

By Prof. Dr. T. R. Boulos

The Egyptian marine phosphorite of Sebaiya West, the Nile Valley, consisting of both non-oxidized hard siliceous and oxidized leached friable ore types, is subjected to a roughing-cleaning silica flotation circuit for production of wet-process phosphoric acid concentrate. Operating at its maximum capacity of 268 t/hr, the following were the main problems encountered during the early stages of running the plant: 1. The tremendous amount of slimes generated by scrubbing the crushed ore causing turbidity in the plant thickener after a short time of operation, regardless of the added flocculant. 2. Rod mill choking leading to inefficient performance of all other equipment and poor flotation results. 3. The drastic increase in imported oleic acid price. Pulp density and slurry flowrate measurements at different points of the plant as well as ore microscopy, size distribution analysis, chemical analysis and x-ray diffraction analysis of representative ore samples coupled with Work Index measurements of feed samples showed that the wide variation in the ore's hardness was responsible for such problems. Application of the locally produced non-edible rice bran oil as a substitute to imported oleic acid in flotation resulted in total saving of U.S.$2 million in 1990. The total unsaturated fatty acid content of the oil is high, ranging from 75.2 to 81.5 mole % of which the C18-unsaturated fatty acid content ranges from 72 to 79 mole %.

Jan 1, 1993

By A. M. Al Taweel, V. K. Kasireddy

Intensive coal cleaning usually necessitates fine grinding of the feed in order to liberate inorganic constituents from the surrounding organic matrix. This however adversely affects the ability of flotation techniques to beneficiate coal. Such difficulties are mainly attributed to the increase of particle population density, the decrease in capture efficiency, and the greater tendency of inorganic components to report with the froth. A three-pronged approach was adopted in an attempt to overcome these difficulties. The aggregative flotation technique was used to reduce particle population densities and improve capture, while unconventional spargers were used to generate a wide range of bubble sizes. Use of unagitated flotation columns allowed for the maintenance of countercurrent flows in both the recovery and washing sections. The combined effect of these parameters enabled the recovery of 92% of the carbon content of coal having an average particle size of 20.5 µ m, while rejecting 85% of the ash. This was accomplished using 2 kg of fuel oil per tonne of coal in a column 2 meters high operating at 2-3 tph/m3, a capacity which compares favourably with conventional cells.

Jan 1, 1989

By S. K. Mohanty, T. M. Dittrich, M. J. Allen, M. Dardona, A. C. Strzelecki, J. Hovey, Boukhalfa. H.

Rare earth elements (REEs) have many critical uses in advanced technology and the lack of a reliable domestic supply has been identified by the US DOE as a vulnerability to US economic security. Our research focuses on developing an economical process for extracting REEs from coal fly ash and power plant wastewater sludge by coupling a hydrothermal extraction process with the engineering of a ligand-associated media for concentrating REEs from the extraction liquid. Ash samples have been collected from two Detroit-area Power plants that burn 100% low sulfur coal (Trenton Channel) or fuel blends of 75% low sulfur coal and 25% high sulfur coal or 70% low sulfur coal, 15% high sulfur coal, and 15% petcoek (Monroe Power Plant). Ash samples are then subjected to hydrothermal conditions from 100-350 °C for 1-24 h at Los Alamos National Laboratory and leachate concentrations are measured by inductively coupled plasma-mass spectroscopy (ICP-MS) and compared to hydrofluoric acid digestion results. Experiments designed to aid in ligand selection and loading optimization show that di-(2-ethylhexyl)methanediphosphonic acid (H2DEH or DIPEX™) can be successfully loaded to a commercially available swellable organically modified silica (SOMS) media. Preliminary results show that DIPEX-associated SOMS surface loading can exceed 4x on a mass/mass basis and in simplified sorption experiments with Nd solutions (~pH 2), the DIPEX-SOMS media can sorb >90 mg Nd per g of media. Recovery of the sorbed Nd with low pH solutions has had low efficiency with the high (4 g DIPEX/ g dry media); however, near complete recovery was achieved with lower surface loadings (0.05 g DIPEX/ g dry media). Column experiments are being conducted to evaluate the optimal ligand/media ratio for repeated use. Completive sorption with Fe and other major cations are also being evaluated.

Jan 1, 2019