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By R. D. Hancock

The complex responsible for the poisoning of anion-exchange resins is identified as the anionic cobaltic penta¬cyanide mono aquo species. It is shown that, at high concentration, this species polymerizes in solutions of pH less than 9. A mechanism for poisoning is presented that involves adsorption of anionic cobalt cyanide by a normal ion-exchange process, followed by polymerization within the resin matrix to form complexes that are too large to diffuse readily through the resin pores. The effects of resin structure and functionality on the extent of cobalt poisoning are examined, and the effect of cobalt poisoning on the kinetics and equilibrium loading of uranium is discussed.

Jan 1, 1979

By P. T. Slatter

The role of viscometers for rheological characterization in the hydraulic transport of solids is discussed, and rheological models and phenomena pertinent to the hydraulic transport of backfill material are reviewed. The two main branches of viscometry (rotational and tube) for the measurement of mining slimes rheology are compared. The effects of solids concentration, particle size and chemical additives and the practical application of rheology in backfill system design are presented.

Jan 1, 1988

By V. P. Kolosyuk, A. M. Bryukhanov

Occurrences of hazardous events (explosions of methane or coal dust, fires, outbursts) have been investigated and presented as a flow of events in time. It has been shown that flows of hazardous events in a long time span are homogeneous, stationary and no-after effect flows and can be considered as stationary Poisson flows. A flow of CH4/coal dust explosions that had happened for the last 27 years in Ukraine was analyzed. The explosions have been statistically processed. Practicability of agreement of statistical and theoretical data on mathematical expectation and mean square deviation of time interval between explosion and the explosion intensity has been stated. Probability of an emergency event in time is expressed through an exponential function, while mathematical expectation of an accident and mean square deviation of time interval between successive explosions are in inverse proportion to the accident intensity. Accident probability for practical purposes can be determined as a product of accident intensity by calculated time interval.

Jan 1, 2003

By J. Gholamnejad

Determination of the optimum cut-off grades is one of the most important aspects of mine production planning. A cut-off is a grade below which we choose not to process material. This material is treated as waste and dumped. Dumping waste is accompanied by the rehabilitation cost which will affect the overall cost of final production and also the optimum cut-off grade. Rehabilitation cost is the cost per ton of rehabilitating material of a particular type of rock after it has been dumped as waste. One of the most popular algorithms for determination of the optimum cut-off grade is Lane?s method. Lane formulated the cut-off grade optimization, but he did not consider rehabilitation cost during the optimization process. This cost item should be evaluated first, and then considered during the cut-off grade optimization process. In this paper the rehabilitation cost is inserted directly into the cut-off grade optimization process using Lane?s theory. The cut-off grades obtained using the suggested method will be more realistic than ones using the original form of Lane?s formulations.

Jan 1, 2009

By S. Botes, H. van der Merwe

While the refractory lining contains the process on a steady-state basis, the tap-hole must provide a channel for transport of molten materials at discreet intervals, with thermal cycling as routine. The tap-hole introduces a discontinuity in any lining, and this fact can lead to failure in the region around the tap-hole before general lining failure occurs. Hence there is a need for a rapid and reliable tap-hole repair technique that can be readily implemented in conjunction with all types of linings. The UCAR®V Repair supplied by GrafTech is a durable solution capable of repairing all types of lining designs and has been extensively utilized in the ferroalloy industry. More than 20 UCAR®V Repairs have been successfully performed in South Africa alone. This paper describes the system in general and reviews recent repairs and their unique challenges.

Jan 1, 2014

By Q. G. Reynolds

The problem of direct-current plasma arc behaviour, interaction, and dynamics is considered in the context of metallurgical DC arc furnace applications. Particular attention is paid to the transient flow behaviour of arc systems. A mathematical formulation of the physics used to describe the arc system is presented, and includes the spatial and temporal evolution of fluid flow, heat transfer, and electromagnetism. Based on this formulation, a numerical model is developed using a finite difference approach on a regular cartesian grid in both two and three dimensions, with a special focus on robust stability, high resolution modelling, and high performance. A collection of results produced using the numerical model to study pilot plant-scale furnaces is then presented. These address a range of process and design variables and their effect on the numerical model?s results. Where possible, the qualitative behaviour of the model is compared to available experimental data. A number of novel effects and phenomena are seen in the dynamic behaviour of the DC plasma arc model for both single and multiple arc systems, which may lead to improved understanding, control, and manipulation of such systems where they occur in industrial applications. Keywords Pyrometallurgy, direct-current furnace, plasma arc, modelling.

Jan 1, 2010

A set of six design principles for rock engineering was developed by Bieniawski: design objectives; minimum uncertainty; simplicity of design components; state-of-the-art practice; optimization; and constructability. These principles translate into a ten-step design process. Although this methodology was developed for rock engineering, it is applicable to any design process, feasibility study, etc. Diligent use of such a process will ensure that a defensible design or evaluation has been carried out. Recently a ?strategic conversation? process has been identified by Ilbury and Sunter that includes the following ten steps: scope; players; rules of the game; key uncertainties; scenarios; SWOT analysis; options; decisions; measurable outcomes; and meaning of winning. A comparison of these steps with those of the design process shows a remarkable correlation. This is perhaps not surprising since engineering design is a strategic up-front issue, and front end loading in a project is critical to achieve the expected project performance. Based on the close correlation between the strategic conversation and engineering design processes, a circular design process, rather than a linear process, is proposed. The ?circle of design? better reflects the importance of review and monitoring in the two phases of successful design and implementation?defining the design, and executing the design.

Jan 1, 2009

By K. L. Morton

This technical note reviews the status quo of mud rushes and flooding, which have claimed them lives of many people in underground mines in South Africa and globally. Given that the causes are well known and can be managed, the note calls for the development of a national and global standard on flood and mud rush prevention in order to save lives.

Mar 30, 2026

By R. D. C. Shone

Consideration is given to the technical and economic feasibility of freeze desalination as a technique for the simultaneous provision of ice to cool deep mines and for the desalination of mine water. Freeze desalination has not been developed fully or commercially. For sea-water applications, it may not offer significant advantages over other methods of desalination but, for the unique mining application, a single dual purpose plant that produces desalinated ice could offer significant cost savings over combinations of separate desalinators and ice-makers. The current status 01 freeze desalination is reviewed, and the important aspects relating to mines are discussed. Some freezing processes that could be suitably modified are described. The possible use of conventional ice-making machines for desalinating mine water is also discussed.

Jan 1, 1987

The variety and sources of sampling errors have been studied since the late 1800s, but the pioneering work of Pierre Gy in the 1950s provided insights into sampling as an error generating process. Total sampling variance is a measure of the total sampling error, but disaggregating the variance into its component parts is problematical. Ten sources of error and error generating processes have been identified, some of which can be eliminated through rigorous application of the principle of correct sampling. Others can only be minimized but never eliminated. Three principal questions relating to the appropriate mass of a sample, the fragment size of the sample and the size of the associated error are addressed. These questions relate principally to the Fundamental Error (FE), the only error that can be estimated before the sampling event. Aspects of constitutional and distributional heterogeneity are examined, as are the essential components of Gy?s formula including the shape factor (?), the granulometric factor (g), the mineralogical composition factor (c), and the liberation factor, l. Applications of Gy?s equation to the problems of sampling in the minerals industry are explained using real-life examples. The approach to sampling taken by Pierre Gy provides an excellent inferential relationship between the mass of material to be sampled, the size of the fragments being sampled, and the relative variance of the sampling error. It also provides solutions for three of the main problems associated with the Theory of Sampling.

Jan 1, 2007

By A. Dabbagh

The aim of this research was to investigate the effect of coke particle size on the thermal profile of the charge bed in the sintering process of iron ore. Six different ranges of coke particle size that could be used in practice in the sintering line of Esfahan Steel Company (ESCO) were used while parameters such as ratios and particle sizes of other ingredients, ignition temperature, and suction power were kept constant. Thermal profiles were obtained by measuring the temperature changes at three points in the sintering bed. The influence of coke particle size on rate of temperature rise, maximum temperature of the sintering bed, and the flame front velocity of the sintering bed was determined by analysing the thermal profiles. Moreover, the cold strengths of the sinters were measured using the Tumbler method. The results indicated that the coke particle size has a significant impact on the thermal properties of the sintering bed. Based on the results, a coke particle size between 0.212 mm and 3.350 mm was determined as the optimal range for the specific conditions in the sintering line of ESCO. Keywords iron ore sintering, coke particle size, thermal profile, flame front velocity, Tumbler index.

Dec 1, 2013

By J. P. Beukes

The production of ferrochrome alloy from chromium bearing chromite ores is conducted at high temperature under highly reducing conditions. However, albeit completely unintended, it is impossible to completely exclude oxygen from all high temperature process steps, with the corresponding possibility arising for the generation of small amounts of Cr(VI) species. Certain Cr(VI) species are regarded as a carcinogenic, with specifically airborne exposure to these Cr(VI) species being associated with cancer of the respiratory system. With approximately three-quarters of the world?s viable chromite ore reserves located in South Africa, and annual ferrochrome production approaching almost half of total annual global output, aspects of Cr(VI) generation and control are of particular relevance and importance to the local industry, and naturally to the global industry at large. This paper seeks to examine theoretical and practical aspects associated with Cr(VI)generation (based largely on experience within the local South African industry, but considered to be generally encountered in the broader global industry context), together with mitigating measures that can be applied within the context of the production processes. From the discussions it is clear that significant improvements in various Cr(VI)-related aspects have been made by the South African ferrochrome industry. However, it is also evident that several areas of uncertainty still exist, which require further research in order to better quantify risks and enhance the efficacy of mitigating steps. Keywords Hexavalent chromium, Cr(VI), ferrochrome production, South Africa.

Jan 1, 2010

By J. E. Chilton

No regular monitoring of methane is required in areas of gassy coal mines outby the mining face. Methane ignitions that have occurred in mine outby areas indicate the need to provide better protection to workers. Handheld methane monitors are now used by some miners to make periodic measurements of methane at the working face. The IYONI II gas detector which is incorporated into a miner’s cap lamp and worn on a miner’s helmet can continuously provide an alarm signal whenever methane levels exceed a set level. Tests were conducted to evaluate the performance characteristics of this methane detector by measuring response times with methane gas supplied through a calibration fixture or adaptor. Other response time tests were performed with the detector in an environmental test box. Performance was also evaluated in a full scale test gallery where face methane emission and underground ventilation were simulated. Procedures for calibration by response time measurement of the IYONI II detector have been developed. In limited testing, the IYONI II detector was found to reliably detect the presence of 1 percent by volume methane.

Jan 1, 2003

By C. Ringas

Pipelines are used extensively in industry to convey various products. Internal corrosion of pipelines can lead to perforation and leakage of the product. A growing problem, not often accurately recognized, is internal corrosion of pipelines caused by bacteria. Microbiologically-induced corrosion (MIC) refers to corrosion caused by a variety of micro-organisms. This form of corrosion is not widely recognized in many industries, although it is widespread and causes many corrosion problems in pipelines, both internal and external. Sulphate-reducing bacteria (SRB) are responsible for the bulk of the corrosion problems caused by MIC. Corrosion caused by SRB is found extensively in water pipelines conveying raw, potable and waste water, as well as in pipelines conveying slurries. This problem also occurs in pipelines conveying crude oil. This paper describes internal corrosion problems of slurry pipelines caused by bacteria and outlines mitigation methods to improve slurry pipeline integrity, thereby extending the life of such pipelines.

Jan 1, 2007

By R. M. G. Machunter

The use of testwork to establish an economically feasible separating plant has been a long established practice in the mineral processing industry. However, uncertainties in orebody characteristics and equipment/plant operation can have a significant impact on the separation performance of a given project. This paper explores the impact of uncertainties derived during testwork at key processing stages on the overall performance of mineral processing flowsheets. Case studies for both mineral sand and iron ore projects will be used to illustrate the concepts studied in this paper.

Jan 1, 2007

By M. Steyn

Until 2000, pricing involved profit taking and cost covering combined with limited global published information. Market information was mostly subjective in nature and large resource companies benefited exclusively from aggregated company information and data. The market constituted producers and consumers only. The nineties saw massive cost cutting drives and re-engineering initiatives and this underwrote the structural changes evident in the late 1990s? economy. This supported South African producers on the international FOB cash cost curve, and ensured profitable coal mining operations. As the debate on relative scarcity of fossil fuels ensued, producers and buyers looked to the developing terminal coal market for direction. The much needed direction was provided when the API coal indices were developed and derivative trading was embraced to include financial institutions, trading houses and hedge funds. The liquidity of coal trades increased rapidly and vastly and market information became obtainable on a daily basis. Interpretation of current and future coal prices became available to all market players and contributed to the sophistication of the market that is now able to participate in risk management of prices, capital expenditure and brownfield developments.

Jan 1, 2010

Ausmelt is supplying commercial quantities of an alkyl hydroxamate flotation collector AM28 for flotation of oxide and supergene base metal ores and tailings. AM28 is a non-hazardous product used as a ten per cent to 50 per cent solution in dilute potassium hydroxide. It is a selective flotation collector for oxide or oxidised base metal minerals and replaces conventional sulfidisation for oxide mineral flotation. At Radio Hill, the AM28 is used in conjunction with traditional sulfide collectors, which allows simultaneous flotation of oxide and sulfide copper minerals. The Fox Resources Radio Hill copper concentrator near Karratha, Western Australia, is currently configured to treat supergene copper ore sourced from the West Whundo open pit. This Archean VMS type copper deposit has been deformed and remobilised with uplift, erosion and weathering to form a significant supergene zone. The sulfide copper minerals present in the upper zone are digenite and chalcocite with lesser chalcopyrite and covellite. Oxide copper minerals present include cuprite, with lesser malachite and azurite. Gangue minerals include quartz, talc and chlorite. Plant trials at Radio Hill are reported for supergene West Whundo ore, where the AM28 was stage added into the circuit at nominally 80 g/t. Plant data over three months shows the copper recovery increased consistently from around 50 - 60 per cent to above 70 per cent when AM28 was added. This has been proven statistically. The grade of the concentrate was consistent with and without AM28, at nominally 22 - 24 per cent copper.

Jan 1, 2007

This paper presents a quantitative approach to the problem of determining design capacity and field dimensions of underground coal mines using room- and-pillar mining systems. In evaluating these design variables, relationships among mining costs, number of production sections in mines, location of central shafts, mine field dimensions, section production, mine output, and cost of production losses due to underground man-traveling are analyzed. Thereby the unit cost of coal is expressed as a function of the design variables as well as input parameters such as seam angle, seam thickness, seam depth, underground traveling speed of men, mine recovery and plant recovery. The problem is then formulated as a nonlinear optimization model in terms of minimizing the unit cost of coal subject to a set of constraints and solved analytically for flat seams and numerically for inclined seams. Sensitivity analysis of the variables is also included in the paper.

Jan 1, 1987

By G. Dhakal, J. -I. Kodama, K. Neaupane, T. Yoneda

ABSTRACT Durability tests and evaluation of sub-zero temperature effects to some argillaceous clastic rocks were carried out. Welded tuff, limestone, sandstone and schist samples collected from different parts of Japan were tested and results are presented. Schist and dolomite from Ganesh Himal area along the higher Himalayas of Nepal were also tested, and the results are compared. The slaking tests were performed on all samples in pure water. The results reveal that the slaking index of schist from Japan is lower than that of schist from Nepal. Regarding carbonate rocks, the slaking index of limestone from Japan is higher than that of dolomite from Nepal. A tendency of decrease in slake durability with an increase in porosity is also observed. Freezing and thawing experiments conducted on welded tuff and schist reveal that crack initiates earlier but extends slower in schist than in welded tuff. It is also observed from the freeze-thaw experiment that the welded tuff deteriorates and wears faster than the schist. However, sandstone remains relatively intact for a long run of freeze-thaw cycles. Zusammenfassung Beständigkeitstests sowie die Bewertung der Auswirkungen von Minusgraden auf Tonschiefer Trümmergestein wurden durchgeführt. Dabei wurden geschweißter Tuff, Kalkstein, Sandstein und Schiefer aus verschiedenen Gebieten Japans sowie Schiefer und Dolomitgestein aus dem Ganesh Himal Gebiet, dem höheren Himalaya Nepals, untersucht und die Resultate verglichen. Für alle diese Gesteine wurden Slaking-Tests in reinem Wasser vorgenommen. Die Resultate zeigen, dass das Slaking von Schiefer aus Japan höher als das von Schiefer aus Nepal war, wohingegen bei kalkhaltigem Gestein das Slaking von Kalkstein aus Japan niedriger als das von Dolomitgestein aus Nepal ausfiel. Es wurde dabei auch eine Tendenz zur Löschbeständigkeitsverringerung bei gleichzeitig erhöhter Porosität beobachtet. Gefrier- und Tautests an geschweißtem Tuff und japanischem Schiefer zeigten, dass Risse in Schiefer schneller auftraten, aber sich langsamer ausweiteten als in geschweißtem Tuff. Bei Gefrier- und Tautests wurde ebenfalls beobachtet, dass geschweißter Tuff schneller verfällt und verschleißt als Schiefer. Sandstein hingegen blieb über lange Tau- und Gefrierzyklen intakt Résumé Des tests de solidités et l’évaluation de l’effet des températures en dessous de zéro sur les rocs argileux ont été effectués. Les rocs d’origine volcanique (cendre), les rocs calcaires, sableux et les schistes de différentes régions du Japon, ont été étudiés. Les schistes et les dolomites de la région de Ganesh Himal le long du haut Himalaya (Népal) ont été étudiés et comparés à ceux du Japon. Les tests de désintégration sur les rocs ont été effectués dans l’eau pure. Les résultats montrent que l’index de désintégration des schistes du Japon est inférieur aux schistes du Népal. En ce qui concerne les rocs carbonyles, l’index de désintégration des rocs calcaires du Japon est supérieur à ceux des dolomites du Népal. Une décroissance de la résistance à la durabilité est observée avec une plus grande porosité des rocs. Les tests de congélation-décongelation sur les schistes et les rocs d’origine volcanique (cendre) du Japon montrent une apparition précoce des fissures mais l’expansion des fissures est plus rapide dans les rocs volcaniques. Des tests similaires montrent que les rocs volcaniques (cendre) se désagrégent plus rapidement que les schistes. Cependant, les rocs sableux restent intacts après plusieurs cycles de congélation-décongélation.

Jan 1, 2003

This paper summarises some observations regarding the way SAG and AG mills work based on the last ten years of pilot plant operation, grinding circuit design and operational reviews for various projects in Australia and overseas. The main purpose is to promote discussion on key factors influencing breakage in a SAG mill. The focus of the paper is on two questions: ? How do mill lifters and liners really work and have an effect on grinding? ? How does the mill charge composition impact on grinding performance? The focus of the paper is on observations of mill behaviour in both pilot plant trials and plant operation, particularly on Cadia ore. DEM, by others, and JKSimMet modelling of SAG mill performance have greatly assisted in forming the ideas expressed in the paper and both are valuable tools in developing our understanding of the comminution process. Put in the `extreme' form the major observations and conclusions expressed in this paper are that: ? the main purpose of mill lifters is to reduce mill liner wear and not to promote rock breakage; ? the often promoted theory that balls impacting the ?toe of the charge? is a dominant form of breakage is incorrect; and ? fines production in a SAG mill is primarily a function of the rock load mass, with a secondary dependence on ball load for any given circuit configuration.

Jan 1, 2007