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By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By M. N. Mathabathe, A. S. Bolokang, C. W. Siyasiya, R. J. Mostert, G. Govender

The b-solidifying g-TiAl intermetallic alloys of nominal composition Ti-48Al (binary alloy), Ti-48Al-2Nb (ternary alloy), Ti-48Al-2Nb-0.7Cr (quaternary alloy), and Ti-48Al-2Nb-0.7Cr-0.3Si (quinary alloy) (in at.%) were developed. The materials produced were tensile tested at room temperature. The as-cast microstructures and fracture surfaces of the tensile tested specimens were examined using conventional metallographic methods. Microstructural examination indicated that the alloys were comprised of lamellar structures (a2+g) embedded in columnar dendritic cores in the as-cast condition. However, the quinary alloy contained a Ti5Si3 second phase. The alloys exhibited no detectable ductility during tensile deformation, indicating the brittleness of all the materials. The fracture surfaces revealed that the alloys failed by translamellar fracture with correspondingly few cleavage facets.

Apr 1, 2021

By Ri McCrindle

"Analytical Chemistry is moving rapidly towards a concept where technicians have to do no more than press a button and print the result from an instrument that is a featureless ""black box"". In this environment we must ask how much traditional ''wet chemistry"" is still required for undergraduate students.Methods that can be fully automated will become increasingly important. An example of such a method is that of the slurry nebulisation and ICP-OES analysis of precious metal concentrate. Grinding the sample and adding Triton X100 as dispersant, complete analysis time is in the order of 90 min as apposed to the traditional Carius tube method which could take as long as 24 h. For most of the elements studied, the results using ""in-house"" reference material for calibration and as samples as well were within the 95% confidence level. Elements of low concentration in the sample (As, Bi and Se) were not within that level."

Jan 1, 2014

By U. Atici, R. Comakli

"Understanding rock properties is of vital importance in mining and civil engineering. Rock properties are generally determined through laboratory tests, which require a large number of uniformly shaped samples and technicians who use indirect methods to determine rock properties. The texture coefficient (TC), which represents various textural parameters including the size, shape, orientation, and relative proportions of grains and the matrix, is an efficient means for indirectly evaluating the mechanical behaviour of rocks. In this study, 12 different rocks (ten granites, one diorite, and one gabbro) were collected and their engineering properties. including specific gravity, porosity, P- and S-wave velocities, Schmidt rebound hardness, uniaxial compressive strength, and elasticity modulus, were investigated. Relationships between TC and these measured properties were assessed. Statistically significant (at the 95% confidence level) correlations were found between the TC and compressive strength, elasticity modulus, sound velocity (both compression and shear waves for dry and saturated samples), but no significant correlation was found with Schmidt rebound hardness. The results suggest that it is possible to use the relationships between TC and the mechanical properties of rocks in rock classification. IntroductionIn every aspect of rock engineering, knowing rock properties is essential for determining and predicting the behaviour of rocks and rock masses. Mechanical properties of rocks are important parameters in mining, geology, and engineering, and they are affected by textural characteristics such as grain size, grain shape, cement type, degree of cementation, mineral content, and the ratio of the grain area to the matrix area. The effects of textural properties on the physical and mechanical properties of rocks have been investigated for a long time, and previous studies revealed close relationships between single parameters related to rock texture and mechanical properties of rocks (Akesson et al. 2001; Gunsallus and Kulhawy 1984; Merriam, Rieke, and Kim, 1970: Onodera and Kumara 1980; Prikryl 2006; Ulusay, Tureli, and Bider, 1994; Tugrul and Zarif 1998). Rock properties are usually determined using mechanical tests, which require uniformly shaped and relatively large samples. However, it is not always possible to obtain such samples. Furthermore, rocks with similar textural and structural properties may exhibit different mechanical behaviour. Howarth and Rowlands (1987) developed a texture coefficient (TC) that expresses all the main textural parameters of a rock in a single dimensionless quantity based primarily on statistical assessment. The TC makes it possible to understand the effects of a rock’s textural properties on its mechanical properties using thin sections instead of large, uniform samples. Ersoy and Waller (1995) investigated the relationship between strength and TC for limestone, sandstone, and siltstone; they also examined the effect of rock properties and TC on drilling performance. Ozturk, Nasuf, and Bilgin (2004) explored the relationship between rock quality and TC by evaluating the uniaxial compressive strength (UCS) values of limestone, basaltic andesite, and tuff. Gupta and Sharma (2012) evaluated TCs as well as the petrophysical and mechanical properties of quartzite from the lower and higher Himalayas and found a strong relationship between TC and UCS. Similarly, Ozcelik, Bayram, and Yasitli (2013) investigated the relationship between TC and various parameters in marble by applying the statistical analyses developed by Ozturk, Nasuf, and Kahraman (2014)."

Jan 1, 2019

By M. A. El-Sayed

"Double oxide films (bifilms) are significant defects in light alloy castings that occur when, during melt handling, the oxidized surface of the melt is folded over onto itself and then entrained into the liquid metal, encapsulating a portion of the local atmosphere. These defects create crevices in the final castings and have been shown to decrease tensile and fatigue properties, and also to increase their scatter, making casting properties unreproducible and unreliable. This paper reports on two different experiments performed to study the behaviour of such defects in Al alloys. In the first experiment and as a proxy for a bifilm, air bubbles were held in an Al-5Mg alloy melt for varying periods of time before the melt was allowed to solidify. The composition of the gas content of the bubbles was subsequently analysed using mass spectrometry to ascertain how it changed with time. In the other experiment the influence of the age of bifilms on the mechanical properties of Al-5Mg castings was assessed by holding castings in the liquid state for different times before solidification, followed by mechanical property testing and SEM and EDX studies of the fracture surfaces of tensile test bars. This research could provide a better understanding of the behaviour of double oxide film defects, and may lead to the development of new techniques by which these defects could be eliminated, or at least deactivated, in light alloy castings. Introduction One of the major structural defects affecting the reproducibility of mechanical properties of aluminium castings is the double oxide film defect (El-Sayed and Essa, 2017; El-Sayed and Ghazy, 2017). This type of defect is usually created as a result of poor filling system design. Owing to the very high reactivity of liquid Al-Mg alloy with oxygen in the air, the surface of the liquid metal can be considered to be permanently coated with an oxide film (Weigel and Fromm, 1990). As a consequence of surface turbulence, the oxidized metal surface can become folded over onto itself, but not fused, and then submerged into the bulk liquid, with a portion of the mould atmosphere being entrapped within it (Campbell, 2003; Al- Sayed, 2016; El-Sayed, Hassanin, and Essa, 2016)."

Nov 1, 2018

By J. Mulenshi, J. Rosenkranz, P. Khavari, S. C. Chelgani

The geometallurgical concept has mainly been applied to primary ore deposits, starting from ore characterisation to the economic optimisation of the mining operation. However, as primary ore resources are becoming depleted and lower in grade, alternative sources need to be explored and a question of adaptability of the geometallurgical approach to the secondary resource repositories arises. The particle size distribution, chemical and mineralogical compositions of the Smaltjärnen historical tungsten tailings from physical separation in Yxsjöberg, Sweden were studied using drill core samples collected from different locations within the tailings repository in order to assess the amenability of the tailings to reprocessing. The tailings are dominated by the –600 to +149 μm particle size fraction. This fraction contains most of the elements of interest (W, Cu, S, Sn, Zn, Be, Bi and F) hosted by scheelite, chalcopyrite, pyrrhotite, cassiterite, danalite (both Zn and Be), bismuthinite and fluorite, respectively. The particle size distribution and mineralogical composition vary across the repository, suggesting a possible existence of geometallurgical domains, which require further assessment to evaluate metallurgical performance. Keywords: Historical tailings, tungsten, scheelite, geometallurgy, characterisation, mineralogy, reprocessing

Jan 1, 2020

By D. Moses, J. A. Onyango

Carbonatites are generally competent rock masses with rock mass rating class II rating 60–74. In spite of their competency, they tend to be affected by weak features like manganese-iron veins and/or in situ rock damage due to brecciation associated with carbonatite complexes. Rock slope failure in such hard rocks is complex since such structures within the rock mass form weak links that could potentially control slope instability. In this contribution, a numerical simulation using phase2 v 7.0 was carried out to investigate the influence of in situ rock damage on the stability of mine pit walls. The outcome reveals that, the existence of breccia in the competent rock mass has the capability to reduce the slope stability performance particularly at gentle dipping angles of emplacement in close range to the slope toe. However, as the emplacement position of breccia moves away from the pit wall, the stability performance increases at gentle dipping angle <50º. On the contrary, at the dipping angle of 50° the performance of slope reduced, and at steeper angles >50° the impact becomes negligible. Thus, from a series of analyses, mine design in brecciated rock masses, the ratio of 1:5 between the breccia distance from slope toe and pit depth should be implemented to counter its impact, and if the breccia is within or close to the pit limit, a deliberate effort must be made to mine it out.

Sep 1, 2025

By I. Nolet

Matte tapping is one of the most critical operations of a matte smelter. Every smelter has developed particular matte tapping practices and tap-hole repair strategies that are often based on the experience of the smelter personnel. As a result, very little information has been published on these critical topics. This paper aims at providing the information gathered from a survey conducted in the PGM and Ni industries on matte tapping practices and tap-hole maintenance strategies for different PGM-Ni matte smelting operations.

Jan 1, 2014

By J. Petersen, A. E. Lewis, J. Chivavava

Rare earth elements (REEs) have special properties that prompted their extensive use in high-tech applications. The demand for REE has, therefore, increased over the past years, resulting in the supply risk of the materials. Extraction from non-conventional low-grade ores, like easy-to-mine ion adsorption clays (IACs), by hydrometallurgical methods is being explored to supplement the supply of REEs. The extraction of REEs from low tenor IAC leach solutions requires enrichment using cost-effective methods such as precipitation. Therefore, the aim of this study was to understand the recovery of REEs from IAC leach solutions using various reagents for precipitation. In the first part of the study, recoveries of REEs from IAC leach solutions through direct precipitation using H2C2O4 and NH4HCO3, as well as antisolvent crystallization using C2H5OH, were predicted via thermodynamic modelling using OLI Stream Analyzer. Verification experiments were then conducted through the use of an agitated reactor. Simulation results showed that high yields of REEs were possible using each of the reagents, but large quantities of C2H5OH were required. Experimental results confirmed the high yields predicted from simulations. Precipitation with H2C2O4 was found to selectively recover REEs while rejecting Al. However, utilization of NH4HCO3 and C2H5OH resulted in the co-precipitation of Al. Furthermore, the yield of Y from antisolvent crystallization was significantly lower than the theoretical value. The product recovered from antisolvent crystallization consisted of well faceted, large crystalline particles, which filtered faster than the fine, amorphous REE carbonates recovered using NH4HCO3. REE oxalates were crystalline, larger than the REE carbonates and, overall, showed the highest filtration rate.

Dec 11, 2024

By P. van der Steen

This paper examines the historical developments in diamond beneficiation technology and the impacts on the industry. The art of diamond beneficiation has given way to the application of scientific process, but at considerable capital expenditure. The shift in beneficiation methodologies has been disruptive to the traditional skills set of the industry, but evolutionary change continues and has been beneficial to the quality of the final product.

Jan 1, 2010

By D. Minson, G. Lindner, S. Miskovic

Thickening is an essential process in the mining industry and currently one of the most costeffective technologies for recovering water from tailings streams. Improved performance of thickeners can lead to significant energy savings, and increased recovery of water close to the mill. Its performance is directly affected by the rheological properties of slurry at the raking zone. To further understand the dynamics of slurry inside thickeners, a multiphase particle-in-cell method (MP-PIC), is used to investigate its behaviour on a sliding channel. Parameters like particle-size distribution (PSD), rheological properties, and domain discretisation were benchmarked to study its influence on highly dense flows. The slurry concentration by weight of the samples ranged between 60 to 70% of solids by mass, under which conditions it is known to behave like a non-newtonian fluid. An experimental flume, 0.2 m wide and 2 m long, was used for validation under different angles and slurry composition. Visual analysis of the slurry height and shape, as well as velocity measurements, were compared with numerical data. The preliminary results show the ability of MP-PIC method to represent different types of highly dense flows, while still being computationally affordable and practical for industrial use. Keywords: High density thickener, CFD, MP-PIC, multiphase-flow

Jan 1, 2020

By O. T. Konina, V. A. Masloboev, A. V. Svetlov, E. A. Krasavtseva, D. V. Makarov, A. A. Goryachev

Dusting phenomena have been examined at the tailings storage facility of Apatit JSC Kirovsk, a mining operation located in the far north of the Russian Federation. The material composition of the tailings was identified. Existing dust suppression methods were examined. Field observations were undertaken and official data was obtained from the Murmansk Administration for Hydrometeorology and Environmental Monitoring, and analysed. A database was built for forecasting dusting according to critical scenarios in order to estimate the peak MPCs of suspended solids in the atmospheric air. Mitigation measures were formulated and recommended to the mining operation. Keywords: Mineral dust particles, apatite-nepheline ore concentration tailings, suspended solids MPC, climate change

Jan 1, 2020

By C. Birch, M. Katuruza

"The purpose of this study was to demonstrate unmanned aircraft system (UAS) technology in opencast highwall mapping using the experience at Isibonelo Colliery in Mpumalanga Province of South Africa. In opencast mines, geological mapping has evolved over time and there have been challenges in extracting valuable information from exposed highwalls due to restricted access for safety reasons. A UAS was used at Isibonelo Colliery to conduct highwall mapping, using drone-based digital photogrammetry techniques. A demonstration survey was undertaken during February 2018. The highwall flyover demonstration was planned for two areas (North and South pits) where field control points were placed by the mine survey department. A contractor used a DJI Phantom 4 (Pro) for the highwall mapping. Raw data was processed within 48 hours and a 3D model of the mapped pit area was produced. Further data extraction included obtaining updated weathering and lithological contact elevations and thicknesses for use in short-term planning. The results showed a good correlation between the resource model and the UAS data model. The project was considered a success and highwall flyover mapping and is now standard practice at Isibonelo Colliery.IntroductionDetailed geological mapping is crucial to the understanding of the structure of any mineral deposit. Several mapping methods may be applied depending on the available exposure/outcrop and nature of the orebody; for example, coal deposits typically suboutcrop only, therefore an opencut highwall provides the best exposure for mapping the geology. Mapped information, when incorporated into a resource model (generated from exploration borehole data), improves the understanding of the orebody or coal seam. This research paper focused on the use of unmanned aircraft system (UAS) technology for pit highwall mapping to generate data for updating geological models and avail the latest information to mine planning to improve the short-term plans."

Mar 1, 2019

By T. Mützea, L. Schützenmeister, G. Kacheb

High-Pressure Grinding Rolls (HPGR) are employed in cement plants worldwide. Although the technology has been mastered in the majority of applications, design-, scale-up- and operationalchallenges still exist today. In addition to modelling throughput, energy requirement and comminution success, the prediction and avoidance of malfunctions is of great importance in current research. The performance of the mill is highly influenced by the roll speed and the fineness of the feed material. Another parameter influencing the composition of mill feed is the circulating load, which is determined by the grinding circuit configuration, the target fineness and the separation efficiency of the classifier. In order to meet this circumstance and simultaneously maintain a reasonable level of material input and testing effort, a complete grinding circuit on a small technical scale was set up in the research centre of Thyssenkrupp Industrial Solutions AG. The present study varied the roll speed (0.5-2 m/s) and the proportion of fines in the feed (0-75 %) in order to investigate the influence of both parameters on the finish grinding of a Portland cement with a target fineness of 4000 cm²/g according to Blain. The experimental results are compared with model concepts and critically examined with regard to their transferability to industrial plants. Keywords: Cement grinding, grinding circuit, HPGR

Jan 1, 2020

By T. Matlou, S. Myendeki, V. Midzi, T. Zulu, H. Mabotja, T. Mulabisana, B. S. Zulu, L. Hlatshwayo, T. Makhateng

The Council for Geoscience (CGS) performed a macroseismic investigation following the occurrence of an earthquake in the Boksburg area on 11 June 2023. The event had a magnitude of ML 4.4 and a focal mechanism that showed the event as having strike-slip motion along a northwest-southeast oriented fault. The event resulted in aftershocks, some of which occurred away from the causative fault in the east in an area without a mapped fault. However, the cluster of past events in that area suggests that there is an active fault. Due to the size of the main earthquake, a macroseismic survey was conducted to determine its impact on the community in the region. Analysis of observed data obtained from questionnaires resulted in the creation of 153 intensity data points. Their distribution showed high intensity values close to the earthquake source area. However, the investigation highlighted a number of anomalies, such as the higher than expected intensity values observed far from the event epicentre. It could be that these anomalies are caused by site conditions, for example, amplification of ground motion due to thick soil layers.

Jan 12, 2025

By E. Marè, D. R. Groot, R. Engelbrecht, T. Coetsee

Hydrogen peroxide is often used as an oxidising agent in experimental waste electronic equipment (WEE) leaching work. However, the high cost of peroxide is a negative factor in its consideration in further process development. A few studies have reported on the efficient application of peroxide addition schedules to ensure optimum reagent consumption. Large quantities of unleached substrate material contained in WEE feed material result in a large dead volume of material in the leaching reactor. This factor necessitates fast reaction rates to enable the use of a high feed material throughput reactor to enhance overall project viability via hydrometallurgical processing. In this study the effects of hydrogen peroxide addition schedules on base metal leaching efficiency and solution temperatures were tested at laboratory scale. The results showed that overall peroxide consumption can be optimised to lower levels by matching peroxide additions to the particular feed material’s leaching behaviour. A simplified integrated model for peroxide decomposition is used to explain its effect on solution temperatures and leaching rates. Keywords: Peroxide consumption, waste electronic equipment, copper leaching, integrated model

Jan 1, 2020

By Z. L. Xue, J. L. Li, X. Y. Wang

"In low-carbon energy-efficient basic oxygen furnace (BOF) steelmaking processes, limestone partly or completely replaces the active lime. The effects of limestone calcination temperature (1200–1500°C) and time (5–15 minutes) on lime reactivity and CaO grain size were investigated. The reactivity was evaluated by titration with hydrochloric acid, and the CaO grain size was analysed using scanning electron microscopy. The results revealed that for calcination temperatures higher than 1300°C, the reactivity reached a maximum and then decreased . The higher the temperature, the earlier the peak of reactivity appears. The CaO grains grow with increasing temperature and time, which leads to the decrease of reactivity. Notably, the effects of temperature on CaO grain size and reactivity are more marked than that of time. To obtain active lime calcined at ultra-high temperature by flash heating, the calcination conditions should be 1300–1400°C for 10–15 minutes, or 1400–1500°C for 8–10 minutes. IntroductionLime is one of the most important slag-making materials for dephosphorization and desulphurization in the basic oxygen furnace (BOF) steelmaking process. The reactivity of lime is a measure of its capability to take part in slag-making. Lime having a reactivity of more than 300.0 mL (4 N HCl), determined by hydrochloric acid titration is generally referred to as active lime (Rusjan et al., 2007; Zeman, 2008). At present, the active lime used for BOF processes comes primarily from a kiln or shaft kiln, where limestone is preheated at 700– 900°C, and then calcined at 1050–1200°C (Drenhaus et al., 2010; Oates, 2007)."

Jan 1, 2016

By M. Z. Naghadehi, F. F. Nasategay, J. Sattarvand, R. Battulwar, E. E. Gohari

After the recent increase in catastrophic failures of tailings dams such as the Burmadinho, Brazil failure in 2019, the mining industry has actively engaged in the stabilisation of tailings dams. Most of the tailings storage facility (TSF) guidelines suggest a laborious action that can be facilitated through imaging by unmanned aerial vehicles (UAVs). Although UAVs are not unknown to most mining operations, automated rill detection through aerial image processing is a new concept. This study utilises images from sites in the U.S. and employs semantic segmentation with a UNet architecture to detect location and size of these rills. The developed model can be used as a tool for monitoring surface erosion of TSFs.

Sep 1, 2021

By T. M. Louw, L. Auret, S. M. Bradshaw, F. F. Noelle

Modern industrial processes undergo frequent process state shifts due to changes in demand, feedstock or maintenance operations. Multimodal continuous process monitoring is therefore required for effective plant operation. Steady state analysis is a key component in effective multimodal monitoring. Various issues still remain in determining the starting and ending times of transition states. High dimensionality of process data is a characteristic that makes it difficult to select variables to consider when conducting steady state analysis. In order to address these problems, steady state detection on the principal component space is proposed. First, data undergoes principle component analysis to reduce dimensionality, then existing multivariate steady state detection algorithms are applied on the principle component scores. A novel algorithm, threshold PCA-SSD, is proposed and compared to an existing technique for steady state detection. The algorithms are investigated on high dimensional synthetic data Keywords: Multimode process, steady state detection, principle component analysis

Jan 1, 2020

By G. Mucsi, F. Kristály, R. Szabó

Kaolin is one of the most important ingredients in porcelain manufacturing. Its main phase is clay mineral containing aluminum hydrosilicate, namely kaolinite. Beside kaolinite it also contains quartz, illite and feldspars, which impair its applicability. Kaolin is a non-reactive material, but metakaolin can be produced by heat treatment (calcination) of kaolin, which is also used by the cement and concrete industry due to its latent hydraulic (pozzolanic) properties. Beside thermal activation, reactive materials can also be produced by mechanochemical activation in general. This paper deals with the mechanochemical activation of kaolin. The raw material was classified into various size fractions, then ground in a batch stirred media mill under varying circumstances (residence time, circumferential velocity). After grinding, the structural changes of the products were investigated by X-ray diffractometry (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). In addition, the particle size distribution of the ground material was determined by laser scattering. As a result of the grinding experiments and analytical measurements of the products, it can be clearly seen that reactivity of kaolin can be improved significantly by mechanical activation in a stirred media mill, but due to its high energy density the circumstances were optimised carefully to avoid aggregation. Keywords: Kaolin, grinding, stirred media mill, mechanical activation, material structure

Jan 1, 2020