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By R. F. Waters

The Bureau of Mines developed laboratory-scale processes to recover sodium phosphates and metal values from waste sludges generated by the phosphate treatment of automobile and appliance components. After treatment of the sludge with NaOH, followed by coke or hydrogen reduction and sintering, zinc and lead were recovered as fume; the sinter was separated by leaching into a metallic product, chiefly iron and nickel, and high-purity disodium or trisodium phosphate.

Jan 1, 1971

By J. E. Pahlman

The Bureau of Mines conducted re-search to determine the resistance of basic refractories to corrosion by ash slags that would result from the burning of coal and lignite in metallurgical operations. Basic refractories are of economic interest because they are from one-third to one-half as expensive as 90-to 99-pct-alumina refractories. Static tests were performed at 1,300° C and dynamic tests at 1,400° to 1,650° C to investigate the stability of refractory specimens in a slag environment. In alkali-containing lignite ash slags, in order of decreasing resistance, magnesite, magnesite-chrome, and chrome-magnesite refractories all had corrosion resistances equal to or better than 90-to 99-pct-alumina refractories. These basic refractories formed slag penetration layers in dynamic tests, which helped protect them from further attack. Chemically bonded basic refractories in general did not have as good a resistance to slag attack as did burned refractories of the same composition. In very acidic coal ash slag, a chrome-magnesite refractory containing 30 pct MgO plus a slag inhibitor and direct-bonded magnesite-chrome refractories with 60 pct MgO had good resistance to attack. Chrome-magnesite refractories (30 to 40 pct MgO) were moderately to severely attacked, and refractories with greater than 70 pct MgO were severely attacked by this same slag.

Jan 1, 1982

Lower the respirable dust exposure of longwall shearer operators by keeping the dust cloud confined to the face. Approach Change the location of face-side machine cooling, water sprays. How It Works The dust breathed by the longwall shearer operator is usually produced by the shearer itself. The dust cloud originates at the face, and the exposure of the operator depends largely on how quickly this cloud spreads into the walkway. Water sprays on the shearer body can have a large effect on dust cloud spreading. Results to date indicate that sprays can help confine the dust cloud to the face if they are carefully placed. Otherwise they can make dust levels far worse. The worst offenders are often face-side sprays used to discharge cooling water from the cooling jackets of the shearer motors. These face-side sprays set up an air circulation pattern as illustrated in the drawing. Air induced by the sprays to flow towards the face, raises the air pressure in front of the face, which causes the air flow to turn and then move back over the shearer, bringing dust with it into the walkway.

Jan 1, 1981

By J. H. Perry, Joseph Cervik, G. N. Aul

The Bureau of Mines is conducting research to determine the effectiveness of long holes in degasifying an area of the Upper Split of the Lower Sunnyside coalbed at Kaiser Steel CO.'s Sunnyside No. 1 mine. These holes were drilled from the two outside entries of a section that was closed to mining because of excessive methane emissions. Two holes drilled to 430 and 450 feet produced initial gas flows of 160,000 and 127,000 cfd, respectively. Sixteen days after the completion of the second hole, the total gas production declined to just over 144,000 cfd. In 9 months of degasification, over 35 MMcf of commercial-quality gas has been removed from the coalbed. The combined gas flows declined to 106,000 cfd in the 9-month period. The two holes have reduced face emissions by about 40 pct.

Jan 1, 1978

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine if the primary gas toxicities evolved during the early (-300° C) and later (>400° C) combustion stages of mine conveyor belts could be predicted by a smoke particle characteristic. The experiments were conducted in an approximately 20-L furnace at set furnace temperatures of 150°, 250°, and 1,000° C, with a furnace airflow of 10 L/min. The variables studied, as a function of time, included hydrogen chloride and carbon monoxide concentrations, the average smoke particle diameter (d8 and number concentration (no), and the product of the average smoke particle diameter and concentration (dgn0) Other variables included the sample and furnace temperatures and the sample mass weight loss. Results show that the inverse of the smoke particle diameter-concentration product (ldgn0), correlates directly with the hydrogen chloride and carbon monoxide toxicities released in large quantities during the early and later stages of combustion.

Jan 1, 1989

By Van H. Manning

Of all the war work by the Bureau of Mines none ultimately covered such a variety of processes and equipment, employed as many men, or called for as large an outlay as that started in con- nection with the solution of problems relating to the use of noxious gases in warfare. Beginning with an investigation to develop the best type of gas mask, the scope of the work extended until it included researches relating to a wide range of devices, such as different types of poisonous and irritating gases and smokes, smoke screens, gas shells and gas bombs, flame throwers, trench projectors for firing gas bombs, signal lights, and incendiary bombs. The Bureau of Mines in starting this work selected the necessary personnel, pro- cured the early equipment, and for some months, from the begin- ning to June 30, 1917, paid the cost of the work from its own funds. The Bureau of Mines built up a research staff of more than 700 chemists, including many of the most prominent chemists in the country, and obtained the cooperation of many of the universities and chemical companies. When the results obtained through this research were to be applied by the War Department, the Director of the Bureau of Mines cooperated in the selection of men to have charge of manufacture or further development, recommending chemiste who subsequently received commissions in the Army. The personal cooperation with the War Department was thus very close. The bureau can fairly claim that because it started this work on gas warfare and received the hearty support of the Department of War, the Navy Department, the National Research Council, and State, educational, and private institutions, the country was in July, 1918, months ahead of where it would otherwise have been in the production of gas masks and other devices. The production of toxic gases then far exceeded the supply of shells. In addition the later work in gas-mask manufacture by the Surgeon General's Office of the Army, which resulted in the development of the best mask produced anywhere; in gas manufacture and gas proving-ground tests by the Bureau of Ordnance, and in the chemical warfare pro- gram of the Navy, including the use of smoke screens, shells and toxic gases, were the direct results of the bureau's experimental work. The American charcoal and soda lime, developed through the research work, are the best used by any nation. The Bureau of Mines was instrumental in developing satisfactory methods of manu- facturing chlorpicrin, phosgene, mustard gas, brombenzylcyanide, cyanogen chloride, and other noxious substances on a large scale. The bureau also developed a smoke funnel for the Navy which no doubt saved many ships from submarine attacks, and devised smoke barrages, signal lights, incendiary darts, etc., for the Army. The Ordnance Department of the Army asked for incendiary bombs and were furnished with bombs better than any made previously. Perhaps the greatest single result of the research work has been the demonstration of the value of the services that the chemist and chemical engineer can render in time of need and the recogni- tion of chemical investigations as a necessary function of the Gov- ernment.

Jan 1, 1919

By C. B. Manula, R. L. Sanford, R. A. Rivell

Development of the Rail-Haulage Sub-assembly for the Production Sub-system (UGMHS)* required the use of ,a newly formulated model in order to best satisfy the requirements. Many of the ideas of the former single-stage rail simulator included in the original version of UGMHS have been used, together with the results of experience gained in applying the earlier model to a variety of operating situations (Sanford, 1969). The sub-assembly is developed as an independent system and, as such, can be used to analyze track systems using production distri¬butions as data input. In addition, since this model is designed to replace the original sub-assembly in UGMHS, the linking procedure is identical with respect to bi-directional information flow. The flow of coal from production sections, for example, fills the mine cars, but a condition of "out of empties" or "full of loaded" at a loading station will shut down inby production sections. A requirements analysis was conducted to determine specifically how the model could best serve the user. Operating management had the largest input in developing the following requirements for the Rail Sub-assembly: a) data input in mixed narrative - numeric form to permit user identification of the input variables; b) a user option to extract several ranges of detail in model output, i.e., an average shift summary of minimum retrieval

Jan 1, 1974

By G. R. Peterson, K. E. Porter

The U.S. Bureau of Mines has estimated the potential availability of copper from 204 mines and deposits in market economy countries (MEC's). The evaluated properties have demonstrated resources totaling 436.4 million metric tons of contained copper and account for 90% of the Bureau of Mimes reserve base for copper in market economy countries. Total recoverable MEC copper resources are 340.8 million metric tons, 69% of which is from producing mines and 31% from nonproducing mines and deposits. Chile had the lowest estimated average total cost from producing mines of W.48 per pound of recoverable copper at a 0% discounted cash-flow rate of return (DCFROR), with estimated average total costs ranging from $0.40 to $0.81 per pound. The estimated average total cost of production, per pound of copper, for producing mines in the United States amounts to $0.57 in January 1988 dollars at a Wo DCFROR, with estimated total costs ranging from $0.36 to $0.85 per pound. In both real and nominal terms, the United States has, on average, significantly lowered its copper production costs since 1981. Rationalization of the industry and significant increases in productivity have made a strong improvement in the competitiveness of the U.S. copper industry to the extent that the United States should no longer be considered as a marginal producer of copper.

Jan 1, 1992

By J. W. Thompson

The Sullman, Picard & Ballot patent, No. 835120, is a process of concentrating ore which consists in mixing the powdered ore with water, adding a small proportion, a fraction of 1 per cent on the ore, of an oily liquid having a preferential affinity for metal- liferous matter, agitating the mixture until the oil-coated mineral matter forms into a froth and separating the froth from the remain- der by flotation. The process is known as an air-flotation process which consists in the use of a frothing agent in conjunction with such agitation of the ore pulp as will distribute the metallic particles of the ore throughout the mixture and produce bubbles of air and bring them in contact in the mixture with the metallic particles so dis- tributed. The bubbles will become attached to such metallic par- ticles, carrying them separately from the particles of gangue up through the surface of the mixture where they can be readily collected by skimming, by overflow, or by the use of other well-known devices. The air-flotation process was a patentable invention in the discov- ery made in March, 1905, and was not anticipated and is valid. Prior to that time there had been no suggestion in the arts that a propor- tion of 0.1 per cent of oil to ore or of any other fraction of 1 per cent of oil to ore would or might result in successful concentration. While the ascertainment that such a minute proportion of oil would affect a successful concentration of ore through a flotation process was a discovery, it was nevertheless of such a character, viewed with respect to the circumstances under which it was made, as to involve inven- tion and confer patentability. Claims 1 and 12 of the Sullman, Picard & Ballot patent, No. 835120, for a process of concentrating ore, known as the air-flotation process, are valid; but claim 9 is so indefinite as to render the claim void. The object of the Sullman, Greenway & Higgins patent, No. 962678, dated June 28, 1910, for improvements in ore concentration, is to separate metalliferous matter, graphite, and the like from gangue by means of oil, fatty acid, or other substances which have a prefer- ential affinity for metalliferous matter over gangue, and it is valid. The Greenway patent, No. 1099699, dated June 9, 1914, for improve- ments in the concentration of ores is invalid, as in view of the prior art the omission to use acid in the process can not confer patenta- bility.

Jan 1, 1917

By H. M. Lawrence

The recovery of phosphate rack from the ores in the land-pebble district of Florida is a simple washing and screening operation. In the gashing plants coarse phosphate only is saved. Log-Washer overflows and screen-undersize products containing an appreciable content of fine phosphate are discarded. The phosphate grains in the material discharged to waste are generally finer in size than the mesh--14 to 20 mesh or 0.346 to 0.03 inch--of the finest screen in the washer. The operators state that the washers ordinarily recover from 50 to 60 per cent of the phosphate content of the matrix mined. Any increase that can be effected in the recovery of phosphate would be of advantage to the industry and would conserve the mineral resources of the country. In considering possible methods that might increase the recovery obtained in phosphate-washing plants the application of flotation, if it could be successfully developed, seemed to warrant investigation.

Jan 1, 1928

By Fred N. Kissell

Experimental work by the Bureau of Mines indicates that when a coalbed is degassed by boreholes, the flow of methane may actually increase with time. This phenomenon appears to be the result of a relative-permeability effect; that is, the coalbed permeability to the gas increases sharply with decreasing water saturation. This report reviews the background of experimental evidence indicating a relative-permeability effect, and presents the results of a computer simulation of two-phase flow in coal.

Jan 1, 1975

By W. P. Yast, R. R. Slyers, J. H. Hildebrand

 The Bureau of Mines, in conducting investigations of atmospheres in mines and tunnels for the purposes of determining and combating hazards to the health and safety of workers, has from time to time closely cooperated with municipal, State and Federal agencies in safety work in engineering and ventilating probleme. Recently the writers have conducted experiments with animals and men breathing helium-oxygen mixtures under pressure. The object of this work was to determine whether helium-oxygen atmospheres can be utilized to advantage in place of normal air for caisson and diving work. In such work the permissible pressures and times of compression and decompression are limited by the physiological effects on man. The major effect is that the nitrogen, (which is the inert con- stituent of normal air and is absorbed by the body tissues and fluids in abnormal amounts when under pressure,) tends to form bubbles in the tissues on too rapid discompression from high pressures. The Bureau of Mines is interested in this problem on account of the pos- sibilities of mitigating caisson illness in tunnel construction and other engine eering operations requiring men to work in compressed air. In addition, the Navy Department is interested on account of the possibilities for extending the range of salvaging and marine engineering operations. The results of the experiments conducted by the writers lead to the following conclusions: Helium is without odor or taste and has physical properties which promise to be of interest physiologically and which have been found to have possibilities of creat practical use, especially in making a synthetic atmosphere that will re- duce the hazard of caisson disease. The substitution of helium for the nitrogen ordinarily present in the air we breathe has been found to result in an atmosphere which it as respirable as that provided by nature. The results obtained indicate that helium not only has the advantage of being less soluble than nitrogen, but

Feb 1, 1925

By Robert F. Holub

The Bureau of Mines has made a study of the magnitude of the variations of radon daughter mixtures, with the objective of determining whether these variations reflect the existing physical conditions in uranium mine atmospheres or if they are merely random or systematic errors. To accomplish this, many data have been plotted using a triangular graphing technique which shows that plateout affects RaA more than RaB or RaC, and that it is impossible to find simple correlations between working level ratios, radon daughter mixtures, and age.

Jan 1, 1978

By Yael Miron

Ammonium nitrate-fuel oil (AN-FO) mixtures are used as blasting agents in mining pyrite-bearing ores. The temperature of these ores can increase by the continuous, though at times slow, oxidation weathering of the pyrites. At elevated temperatures, AN-FO reacts exothermally with pyrite, and the reaction becomes self-sustained at 120° C ± 10° C. The Bureau of Mines has conducted an investigation to determine the reactivity of mixtures of AN-FO with pyrite containing ferrous sulfate. The results of tests in a heated vessel simulating a hot borehole demonstrate that small amounts of ferrous sulfate, a major product of pyrite weathering, initiate a self-sustained exothermic reaction with AN-FO at 80° C. Five pct by weight of urea was found sufficient to prevent a reaction among the three ingredients, at least within the limits of the test, which reached 180° C. Smaller amounts of urea and of potassium oxalate slowed down the reaction and delayed its onset to higher temperatures, but did not prevent it.

Jan 1, 1979

By N. S. Dalal, B. Jafari, V. Vallyathan

Electron spin resonance measurements have now been completed on the decay kinetics of the organic free radicals formed on crushing or grinding of a well characterized anthracite coal. The free radicals exhibit a complex decay pattern for the first few hours after the grinding, and a smooth decay thereafter. Parallel hemolysis studies indicate. a half-life of the decrease in the cytotoxicity of the fresh· dust to be about half-a-day. The cytotoxicity of the freshly-made dust decreases on addition of superoxide dismutase, catalase and sodium benzoate. The hemolysis rate is lower for the dust stored in buffers as compared to air. A chemical model will be presented to accomodate the cytotoxicity and spectroscopic data, and ~heir implicati6ns to pneumoconiosis.

Jan 1, 1988

By C. W. Lee

"Introduction of diesel engines in underground mines may generate severe health hazards associated with exhaust contaminants. One of the most important parameter in determining the optimal air quantity for hazard reduction is the exhaust dispersion. Through analyzing the exact solution of the diffusion equation and its approximation by finite difference method(FDM) , this paper aims at doing a fundamental research to find an efficient dispersion model suitable to the domestic mines. Diffusion coefficients are likely to be small in the underground airways with high ventilation resistance. This makes concentration profiles similar to the convection-based step functions. It is the case for fixed as well as moving engines. Concentration estimation by exact solution is almost impossible in the case of either a single engine moving at a variable speed or the existence of multiple engines. Application of FDM to the diffusion equation including turbulent dispersion results in the various problems; unstable concentration profiles depending on the engine location, nuctuating concentrations near the engine, and overestimation of the dispersion region of which error grows with waning diffusion coefficient.Convection-based dispersion model is found to fit well for dynamic simulation of exhaust dispersion from multiple diesel engines in the airways showing low diffusion coefficients. Its suitability is more likely in the regions with frequent equipment passage. Published"

Nov 1, 1995

By William L. Rice

Geochemical humus sampling techniques were used by the Bureau of Mines in investigating a potential large, low-grade gold deposit in the Orogrande district, Idaho. Conifer needle humus samples were processed by ashing and fire assay-atomic absorption analysis. An area bearing anomalous concentra¬tions of gold and silver was outlined by the geochemical method.

Jan 1, 1970

By M. C. Chapman, E. C. Westman, A. T. Iannacchione

Examination of seismic records during the time interval of the Sago Mine disaster in 2006 revealed a small amplitude signal possibly associated with an event in the mine. More needs to be understood about the seismicity from mine explosions in order to properly interpret critical seismic information. A seismic monitoring system located at NIOSH’s Lake Lynn Experimental Mine has monitored experimental gas and dust based explosions and impact tests. The seismic signatures from these different events were analyzed using standard waveform analysis procedures. The magnitude of seismic energy during a gas and dust explosion was found to be more dependent on mine entry geometry and seal behavior rather than on the amount of explosive fuel present. The results suggest a large explosion that’s not restricted can generate potentially the same magnitude as a small explosion that is restricted.

By W. E. Robinson

Oil-shale samples selected from a core of the Green River Basin (Wyoming) were studied to ascertain differences in the composition and/or chemical structure of the organic material in the samples relative to stratigraphic position within the Green River Formation. This involved a systematic study of the soluble organic material and the insoluble kerogen present in the samples. Emphasis was placed upon the distribution of the alkanes (normal and isoprenoid compounds) in the soluble extract and upon the aromaticity of the kerogen. In general, it was concluded that significant differences exist in the chemical structure of the oil-shale organic material from various strata within the Green River Formation of Wyoming. Most of the compositional and structural changes were not related to burial depth but were related to source material variations, environmental differences, or other factors.

By R. R. Sayers

The added hazards to mining incident to oil and gas wells penetrating the coal measures in proximity to mine workings , have long been recognized in those fields where the extraction of oil , gas , and coal , has been in progress for a number of years . The history of these fields is replete with stories of serious mine fires , explosions , and miraculous escapes from both fires and explosions due to either oil or gas finding its way into the mine workings through the strata , or by mining into an unknown or uncharted and abandoned oil or gas well that had not been properly plugged . The Director of the Bureau of Mines , in response to numerous requests from coal operators and oil and gas operators , called a meeting in 1913 to discuss necessary precationary measures to take when drilling oil or gas wells through workable coal beds and to try , if possible . to formulate a set of regulations that might serve as a guide to those persons preparing regulations covering the drilling of oil and gas wells in the various coal producing States . This meeting was attended by representatives of the coal , oil , and gas industries , State geologists , State mine inspectors , and representatives of the Bureau of Mines . A committee was appointed to prepare a set of regulations , which was later published as U.S.Bureau of Mines Technical Paper 53 ; the discussions and results of the meeting werepublished as U. S. Bureau of Mines Bulletin 65 . Later , the American Institute of Mining and Metallurgical Engineers appointed a committee to draft a model law for the use of the legislature of any State concerned . This committee made its report on April 27 , 1928 . Several of the coal mining States now have more or less comprehensive regulations governing the drilling of oil or gas wells through workable coal beds , others have regulations that are inadequate , while some have no regulations . The State of West Virginia recently enacted a law containing reg lations which are the result of a comprehensive and careful study of the problem .

Nov 1, 1929