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By J. Roger Loebenstein

ASARCO Incorporated, the only domestic arsenic producer, terminated copper-smelting operations and the associated recovery of byproduct arsenic trioxide at Tacoma, W A. in 1985. It still shipped small quantities of trioxide from its remaining stocks in 1987. Imports for consumption of arsenic trioxide were slightly higher than in 1986. Domestic Data Coverage.-Shipments of small amounts of arsenic trioxide from remaining stocks by Asarco were reported voluntarily to the Bureau of Mines.

Jan 1, 1989

By M. J. Ferrante

Relative enthalpies of cuprous iodide (CuI) were measured at the Bureau of Mines to provide thermodynamic data for the advancement of min-eral technology. Enthalpy measurements between 298.15 and 1,396.3 K were made with a copper-block drop calorimeter. The temperatures of transition were measured by differential scanning calorimetry (DSC). Reversible transitions were determined at 643 K with a standard enthalpy of transition [(6Htr)] = 0.74 kca1/mol, at 679 K with a [6Htr = 0.65 kca1/mo1, and at 868 K] with a standard enthalpy of fusion [(6H~) = 1.895 kca1/mol.] Tabulated values are listed at selected temperature increments from 298.15 to 1,600 K for the standard relative enthalpy (HO -H298), heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)!T]. The enthalpy data are also given in the form of equations and combined with thermodynamic data from other investigations to derive values of standard entha1pies of formation [(~HfO)], Gibbs energies of formation [(6GfO)], and logarithms of the equilibrium constants of formation (log Kf).

Jan 1, 1987

By Fred N. Kissell

Methane-flow and pressure data taken from a mine in the Pocahontas No. 3 coalbed are compared with flow rates from lump coal obtained in laboratory experiments. From this, it is concluded that the main source of gas is the intact coalbed rather than a "crushed zone" near the working face. The permeability and sorption capacity of the intact coalbed are calculated and gas emission rates are theoretically accounted for.

Jan 1, 1972

By Launa G. Mallett, Dana Reinke, Charles Vaught, Michael J. Brnich

As mines become safer and major disasters fewer, the number of experienced emergency responders is decreasing. This decrease will create a gap in response expertise which could have serious ramifications during future mine disasters. While working toward safety goals which may make emergency response obsolete, it would be reckless not to acknowledge that the potential for disaster still exists and that the protection of miners in such circumstances must remain a priority. The Mine Emergency Response Interactive Training Simulation (MERITS) is a computerized mine emergency simulation that meets a variety of needs. It allows personnel in leadership positions to test their knowledge and skill. Groups of individuals composed of representatives from mining companies, labor, and government agencies can practice working together during the simulated mine emergency much in the same way an actual emergency would require. An individual could also run the program to enhance his or her response skills. With this training tool, responders will be able to learn from their mistakes before facing situations with potentially catastrophic consequences. This paper discusses MERITS and its use in providing command center training.

This chapter presents MSHA data on mine employment and active mining operations during 1986-1995. Figures 3-1 through 3-10 show, for each commodity, the location of mine operations in 1995, and employee hours and active mining operations by year during 1986-1995 for mine operators. For coal and nonmetal operators, the number of active mining operations and the number of employee hours decreased over the 10-year period. For metal operators, the number of active operations decreased, while the number of employee hours increased. For stone and sand and gravel operators, the number of active operations and the number of employee hours remained about the same. Figures 3-11 and 3-12 show that over the 10-year period, there was an increase in the proportion of hours worked by contractors in coal mining, while the overall employment decreased. For metal, nonmetal, stone, and sand and gravel combined, the proportion of contractor hours increased, with overall employment also increasing. Table 3-1 shows the distribution of hours worked during 1986-1995 by commodity and type of operation. For coal, the majority of hours worked were in underground mines. For metal, nonmetal, and stone, the largest number of hours worked were in mills and preparation plants. For sand and gravel, all work hours other than office were in surface mines. [ ]

Jan 5, 2000

By H. C. George

This report presents a comprehensive tabulation of lifting cost data collected from oil companies in many different fields. These data were collected during the writer's studies of surface equipment and methods of pumping oil wells, in practically all of the important oil fields in the United States and are based on average operating conditions at 57 groups of properties with a total of 4,497 producing wells. Although lifting cost is only a part of the total cost of producing oil, it nevertheless gives a representative cost figure for purposes of comparison.

Jan 1, 1923

By L. C. Headley

Surface areas of two synthetic and three natural consolidated porous samples were obtained by the Orr low-pressure permeametry technique. The results suggest that the Orr technique is a useful substitute for the low-temperature gas adsorption (BET) method for determining the surface area of rock samples. It was more rapid than the BET method, and the surface-area values obtained were larger but agreed better with BET values than values calculated from the Kozeny-Carman equation. Efforts were unsuccessful to demonstrate the influence of channel-size distribution on pressure-flow rate curves by means of experimental data and a parallel channel model.

Jan 1, 1971

By S. C. Tadolini, T. M. Barczark

Mines in the western United States have had limited choices for standing support. Wood cribs were often too soft and unstable. The introduction of the Can support in the earl v 1990s provided an effective alternative, (lilt/ it remains the dominant form of tail¬gate support. Water-filled prestressing cells are now used to cap the Can and preload it to provide an active roof load. The Cluster Prop, consisting of three timber wedge props bundled to¬gether; provides more capacity than (m equivalent sized Call support and improves transport efficiency. However the Cluster Prop is less stable and does not maintain a consistent load throughout its loading profile. Pumpable roof supports are another alternative support, but the \' have not been proven in high deformation en¬vironments. This paper compares the performance characteristics o f these various support systems.

Provide low-cost fire protection for big bulldozers. Approach A fire protection system, previously used on mobile logging equipment and adapted to surface coal augers, has now been adapted for use on large mining bulldozers. How It Works Heat sensors mounted in the engine compartment and hydraulic hose areas detect the fire, usually before the operator does. This causes the system to automatically discharge A-B-C class dry chemical extinguisher through a fixed piping system. The system can also be manually activated from either the opera-tor's cab or ground level. Location of the principal components of the system are shown in the drawing The heat sensors of the sys-tem consist of bimetallic strip switches which operate at about 10000F temperature. Switch operation results in release of compressed gas from a small storage cylinder. The gas expands to blow the dry chemicals out of the nozzles, in a spray that lasts about 15 seconds. The compressed gas used is usually nitrogen, although carbon dioxide is also used.

Jan 1, 1978

Native asphalt was produced in 1977 by six companies in four States. Leading States were Texas and Utah. Output declined 39% to 1,237,000 tons valued at $18,874,000. Bituminous limestone was produced by Whites Uvalde Mines and by Uvalde Rock Asphalt Co. in Uvalde County, Tex.; by Southern Stone Co. in Colbert. Ala.; and by Barton County Rock Asphalt Co. in Barton County, Mo. Gilsonite was produced by American Gilsanite Co. in Uinta County. Utah, and by Ziegler Chemical and Mineral Corp. in Weber County. Utah. The asphalt was used for streets and roads, and for other purposes.

Jan 1, 1980

By Terry J. Close

The Gates of the Mountains Wilderness study area is underlain by intrusive and sedimentary rocks, mainly limestone. No limestone has been produced from the study area; suitable material is more readily available elsewhere. Small amounts of gold, sapphires, and corundum were produced from a placer deposit along the banks of the Missouri River. The remaining gravel contains low mineral values. Other alluvial deposits along the Missouri River and Beaver Creek contain no identified economic resources other than sand and gravel. Some deposits could provide suitable construction material for local use.

Jan 1, 1984

By D. J. Parker, D. Harrington, L. H. Harrison

The necessity for protection against the hazards of lightning manifests itself from time to time in the mining industry by reason of loss of life, damage to electrical equipment, fires in surface structures at mines, and accidents in the handling and use of explosives. This paper is intended to assemble, correlate, and present some of the salient. points embodied in the available literature on the subject and at the same time give some factual data concerning instances of such loss of, life and damage to property, with special application to the mining industry The annual loss of life and destruction of property by lightning is considerable; the former may be prevented to a limited extent, though use of common sense as to exposure is required and not always followed; the latter can be prevented to a considerable degree. The manufacturers of electrical equipment,, through improved types of lightning arresters,, have done much toward the protection of electrical equipment, with consequent safeguarding of life and of property. Education based on unfortunate experiences has gone far to discourage the handling of explosives and blasting accessories during thunder storms, especially in open pits and quarries, and to a much smaller extent in underground workings. The lowly lightning rod plays an important role in the protection of certain types of buildings (especially isolated buildings), stacks, monuments, and other structures. LIGHTNING PHENOMENA In 1751, Franklin proved that lightning was simply a visible display of electricity - an extended spark; and until a generation ago little had been added to his exposition, to define the various phases of the phenomenon. Matters pertaining to lightning are discussed in the following references:

By R. S. Olsen

The Bureau of Mines is engaged in a continuing research effort toward the recovery of alumina from kaolinitic clay and other nonbauxitic domestic minerals. Hydrochloric acid extraction of calcined clay is among the acid processes under consideration. Although aluminum is easily leached from calcined clay, the presence of fines and slimes in the leached residue has hindered the application of this and other acid leaching processes. A clay feed preparation method was therefore developed that eliminated the slimy nature and the separation problems normally associated with leached clay residues. The preparation process consists of crushing the raw clay to minus 20 mesh, dampening the crushed clay with a fine water mist while tumbling on a rotating disk, and calcining the misted clay at 750° C. The misting process increases residue settling rates threefold to 9 cm/min (18 ft/hr) and filtration rates by two orders of magnitude. Leaching-kinetics were determined for misted clay feeds in a batch, stirred-tank reactor. Rapid leaching occurred during the first 85 to 90 pct of the extraction. The linear relationship of extraction to time during this initial phase corresponded to a zero order reaction with a rate constant of around 10 pct/min.

Jan 1, 1981

By L. C. IlsLey

The Bureau of Mines has collected field data and made laboratory investigations of trailing- cable performance in the hope of developing a better and safer cable for use with permissible mining machines . Because of their better insulation and performance , only rubber- sheathed cables were finally considered . The cables tested represented the product of six manufacturers . : After consideration of the results of the preliminary investigations , the conditions under which cables are used in mines , and the better performance of the later types of cables that were submitted as the investigation progressed , the bureau formulated a performance - test requirement and notified the cable manufacturers as follows : The hazards of the trailing cable are such that the bureau has been unable to extend beyond the machine its formal approval to cover the cable as at present developed . However , in the attempt to reduce the hazard as much as possible , cables passing certain tests will be recommended for this service and it is hoped that several cables will be developed to meet this requirement .

Sep 1, 1930

By Charles C. Boley

The Bureau of Mines dried and carbonized two wood wastes, one softwood (redwood) and one hardwood (oak), using continuous, vertical entrainment techniques previously developed for use with coal. It was demonstrated that these techniques are readily applicable to wood waste and that appreciable changes in the yields of carbonization products can be obtained by varying operating conditions. A limited amount of experimental work was done on briquetting the charcoals. Firm briquets were formed with oak charcoal, although greater quantities of starch binder than used commercially for kiln-produced charcoal were required. Redwood charcoal did not briquet successfully under the test conditions employed.

Jan 1, 1969

By H. M. Lawrence

"In the land-pebble district of Florida a lively interest in the possibilities of obtaining increased recoveries of phosphate rock is evident. Research in several directions is being carried on by companies operating in the district to increase the yields obtained by the washing plants. The Bureau of Mines is cooperating with this research program to promote more efficient plant practice and to avoid unnecessary depletion of mineral resources.Washing practice, as carried on in the district at present for the recover of phosphate rock from the crude ores or matrix, is not a complicated process. Flow sheets of the several companies are similar, although the equipment varies with the preferences of the individual operators. For disintegrating the matrix log washers are favored, although revolving drums equipped with flights to break up lumps of clay are also used. Fine sand is removed by screening. Vibrating screens have become well established in the district, although stationary flat screens and trammels are also employed.The writer acknowledges with appreciation the cooperation of the phosphate companies in the land-pebble district; suggestions and criticism by Will. H. Coghill, supervising engineer, Ore Dressing Section of the Bureau of Mines; and the laboratory assistance of J. O. Davie, J. W. Pamplin, and E. Roca, cooperative fellows of the University of Alabama.Losses in the Finer SizesOf the phosphate that is not recovered by present washing methods the greater portion is in the finer sizes. In these sizes the phosphate grains are accompanied by grains of sand - largely quartz - of the same size, and recovery of these phosphate grains as a commercial product is not possible by simple washing methods. Phosphate recoveries approaching complete extraction can only be effecte by applying metallurgical processes, either mechanical or chemical. As yet, most of these processes have not advanced much beyond the laboratory or perhaps the pilot-plant stage. Such processes may have some application to the beneficiation of phosphatic ores or washer rejects, but a discussion of them is not within the scope of this paper."

Apr 1, 1929

Improve the field-of-view into the front-right blind spot for drivers of large haulage trucks, thereby reducing the growing collision hazard in surface mines. Approach Reduce the glare problem found in the first generation fresnel lens blind area viewer design by eliminating the upward-looking section of the fresnel lens and adding a rear hood to reduce backlighting. How It Works The first generation blind area viewer was developed and in-mine tested as an aid to improved visibility for large haulage trucks. Other aids were improved left-and right-hand mirrors. Evaluations showed that a blind area viewer mounted on the right-front of the radiator deck was effective and was readily accepted by drivers. Nevertheless, because glare was a problem under certain conditions, a low-profile viewer was developed. Glare control louvers from the earlier design were kept and a backlighting glare control hood was added. The height of the hardware was reduced by eliminating the top three inches of the fresnel lens. This portion of the lens contained an upward-looking segment which originally was thought to be needed so the driver could see the horizon when he looked through the viewer and be better

Jan 1, 1982

By L. A. Readdy

No text. A set of geophysical well logs for U.S. B.M. Pilot Hole "X", Piceance Creek Basin, Colorado.

Jan 1, 1977

By Yael Miron

ANFO blasting agents may undergo an exothermic reaction when they contact warm ore bodies that contain pyrite and its weathering products. The reaction is very fast at temperatures above 80° C. Urea, when present in sufficient amounts, inhibits this reaction at temperatures below 180° C. But urea-ammonium nitrate mixtures are very hygroscopic and, in certain climates, may be difficult to handle in the field. Reaction-inhibiting characteristics of three compounds were reported by the Bureau of Mines in 1979. Recently, the Bureau investigated the reaction-inhibiting qualities of five additional compounds. Mixtures of ANFO, pyrite, weathering product, and prospective inhibitors were slowly heated, under conditions simulating a hot borehole, to determine prospective inhibitor capability at temperatures up to ~175° C. Small-scale thermal tests of the same mixtures were used for verification and clarification of results. Two organic compounds, phthalimide and xanthine, similar in structure to urea, failed to inhibit the reaction. Zinc oxide and calcium carbonate were found inferior to urea, though zinc oxide raised the onset of reaction from 80° C to about 140° C. Only magnesium oxide was found to be similar to urea in its inhibitory ability at temperatures below 175° C. Based on results from analysis of quenched residues, the use of more than 5 wt-pct magnesium oxide is recommended.

Jan 1, 1982

Remotely monitor overburden response to longwall mining using time domain reflectometry (TDR) and a combination of hardware and software, as part of the U.S. Bureau of Mines (USBM) program to characterize subsidence. Background TDR was developed in the 1960's as a method to locate, discontinuities in coaxial transmission cables. In this method, voltage pulses sent along a cable are reflected by cable defects. The pulse reflections are used to determine the type and magnitude of the defects. The TDR concept was extended to material property measurement by embedding cables into particular materials and evaluating the cable's dielectric behavior as material properties were modified. This technique was adapted by the USBM in 1978 for use in monitoring rock movement during underground mining. The same concept is utilized today. A coaxial cable is grouted into a rock mass that is expected to deform. Progressive rock movement causes the cable to deform, as shown in figure 1, and changes to occur in the cable's electrical properties, which then produce changes in TDR reflection signatures. The technology has advanced to the point where it is now possible to distinguish shear deformation from tensile deformation and to quantify rock mass displacements by analyzing the TDR signatures.

Jan 1, 1995