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By J. E. Chilton, Jr. Dubaniewicz

Many mines rely on toxic gas sensors to help maintain a safe and healthy work environment. This report describes a prototype monitoring system developed by the U.S. Bureau of Mines (USBM) that uses light to power and communicate with several remote toxic gas sensors. The design is based on state-of-the-art optical-to-electrical power converters, solid-state diode lasers, and fiber optics. This design overcomes several problems associated with conventional wire-based systems by providing complete electrical isolation between the remote sensors and the central monitor. The prototype performed well during a 2-week field trial in the USBM Pittsburgh Research Center Safety Research Coal Mine.

Jan 1, 1995

By Alton B. Cook

Data are presented to show oil vaporization resulting from the passage of natural gas through a sand-packed tube saturated with synthetic reservoir oils. The Bureau of Mines performed 13 experiments, using reservoir oils synthesized with base crude oils of approximately 22°, 35°, and 45° API, at 100°, 175°, or 250° F and 1,100, 2,600, or 4,100 psia. It has been determined that the amount of vaporization is significant if proper conditions exist. These experiments show that oil vaporization depends on pressure, temperature, volatility of the oil, and amount of gas cycled. Increases in each of these conditions increase the volume of oil vaporized.

Jan 1, 1969

By Judith A. Eisele

The possibility of improving the volatilization of gold through the formation of a metal-gold chloride vapor complex was investigated. Gold-silica mixtures, containing ferrous and nonferrous minerals and salts as additives, were treated in a laboratory tube furnace with a flow of chlorine gas at various temperatures. The addition of pyrite (FeS2) to a charge of gold-silica increased the volatility of the gold from 3, 20, and 62 percent of the total gold to 62, 93, and 100 percent at 200°, 300°, and 400° C, respectively. Chemical analyses of the condensate indicated the volatile species to be FeAuCl6.

Jan 1, 1971

By E. Aamland

Preparation of high-purity magnesium-yttrium alloys by electroreduction of Y2O3 dissolved in a YF3-LiF bath and the subsequent deposition of yttrium in a molten magnesium cathode was investigated in laboratory-scale apparatus. Parameters such as temperature, current density, and electrolyte density were studied. Electrolysis was conducted in a specially designed MgO diaphragm cell at temperatures ranging from 780° to 970° C. Alloys containing up to 55 weight-percent yttrium were prepared at cathode current efficiencies of 21 to 60 percent. Cell design and operation are described, and some of the limiting conditions pertaining to the method are discussed.

Jan 1, 1973

By Doris M. Hyde

The impact of mining activities on the economy in both 1983 and 1984 was minimal. The most recent available data on the gross domestic product (GDP) indicated a level of $1.6 billion in 1983.2 The estimated value for the production of cement, aragonite, and salt was about $17 million in that year, down from the estimated $20 million in 1982. No data are available on the economic impact of the large petroleum refinery at Freeport on Grand Bahama Island, but it represents the major mineral-related activity. Cement production remained at only a fraction of the 800,000 tons per year of plant capacity. The offshore search for hydrocarbons continued in 1984, and some companies were about to enter the third year of seismic and geological surveying around Andros and Grand Bahamas Islands. Getty Oil (Bahamas) Co. Inc.; Breoco Ltd., a subsidiary of REO Development Corp. of Tulsa, Oklahoma; and Natomas Petroleum (Bahamas) Ltd. were the first companies to be awarded exploration licenses. These companies were committed to drilling at least one well before the end of the third exploration year. Other companies actively engaged in exploration included Exxon Corp., Atlantic Richfield Co. (ARCO), Chevron Oil Bahamas Ltd., and Esso Oil Bahamas Ltd. Geophysical Services Inc. (GSI) of Dallas, Texas, and Petroleum Services (Bahamas) Ltd. of Englewood, Colorado, ran another seismic survey line during 1984. This 1,533-mile line was in the Great Bahama Bank and Cay Sal Bank areas off the southeast Florida coast, and tied in with a 4,530-mile program GSI ran in 1981-82. These surveys were nonexclusive and publicly available through GSI.

Jan 1, 1986

By J. E. Pahlman

As part of its goal to minimize the requirements for mineral commodities through conservation and substitution, the Bureau of Mines is conducting research to determine the resistance of alumina refractories to corrosion by alkali-containing slags that could result from burning of the abundant Western lignites in metallurgical operations. Static corrosion tests were performed at 1,000° to 1,350° C and dynamic tests were performed at 1,400° to 1,600° C to investigate the stability of refractory specimens in slag environments. In general, the degree of refractory attack increased with decreasing alumina content in the refractory and with increasing alkali content of the lignite ash. The parabolic kinetics observed in static tests suggested that a reaction product layer is formed through which ionic diffusion must occur to sustain the reaction with the refractory material. The linear kinetics observed in dynamic tests in high-viscosity slags indicated a shearing of the reaction product layer by viscous slags. The observed lesser attack of refractories by low-viscosity slags can be explained on this basis. Two 99-percent-alumina refractories and two 90-percent-alumina refractories formed an expanded protective layer with the more viscous slags but not with the less viscous slags. Corrosion of 90-percent-alumina refractories increased exponentially with temperature. In refractories with the same nominal alumina content, those that contain a combination of a-Al203 and mullite (3A1203?2Si02) have better corrosion resistance than those containing a combination of a-Al203, cristobalite (Si02 mineral), and mullite. In alkali environments (1,300 to 1,400° C), 90-to 99-percent-alumina refractories are recommended for use as furnace linings.

Jan 1, 1980

By R. Hogg

"Some basic features of the science and technology of particle systems are reviewed in the context of agglomeration processes. Emphasis is placed on the force of interaction among particles and with their environment and on their dependence on particle characteristics and interfacial phenomena. The complex role these forces play in the various stages of agglomerate formation, growth, consolidation and structure development, and their influence on final product properties is discussed.INTRODUCTION Agglomeration is an example of a process where the technology has generally preceded the science. Process development• has very often been by trial-and-error albeit with an eye on some basic principles. Nevertheless there is' a scientific basis to the process and a better understanding of the fundamentals can surely lead to improvements in process design and control.Successful processes for the agglomeration of fine particles depend on proper control of the adhesional forces between particles, to encourage agglomerate formation and growth and to provide adequate mechanical strength in the product. At the same time the rheology of the particulate system can be critical to the rearrangement of particles necessary to permit densification of the agglomerate and the development of an agglomerate structure appropriate to the end-use requirements.AGGLOMERATION SYSTEMSUltimately, the performance, of any agglomeration process depends on the• characteristics of the particles and their environment. The specific effects, however, are often complex and may be very difficult to pinpoint by simple observation of the process. A typical agglomeration process involves a number of concurrent or consecutive steps - adhesion, growth, compaction, etc., - each of which is affected by the characteristics of the system, but not necessarily in the same way. The effect of particle size, say on agglomerate growth may be quite different from its effect on compaction and its optimum value may differ widely from one stage to the other. Obviously there.is a general need for compromise in the design and operation, of agglomeration systems. Furtnermore, an understanding of the details of the process and their complexities can be critical to process optimization and improved product quality control."

Jan 1, 1989

"The dust/lung research of the Center has several long-range objectives:* better methods for the early diagnosis of coal workers' pneumoconiosis (CWP);* methods to modify the disease process;* tests to identify toxic products; and* tests to identify individuals with heightened susceptibility to pneumoconiosis.A major immediate objective is to define the mechanism of dust-induced lung disease. This means determining:* dust characteristics that are important in causing lung diseases;* important interactions between dust and lungs; and* earliest detectable stages of the disease.Several of the Center's projects involve exposing lung cells in culture (in vitro) or animal lungs (in vivo) to samples of the suite of characterized mineral dusts described earlier. The responses of the lung cells or tissues to the dusts are being studied in order to better understand how inhaled dusts cause lung disease.One project is studying the effect of dust exposure on the production of mucus by rat tracheal explants in vitro. Mucus is a major factor in clearing inorganic dusts from the lung. Results thus far have shown that exposure of tracheal cultures to coal dust caused a decrease in micin production in comparison to parallel cultures without dust. To examine the effect of in vivo coal dust exposure, rats were maintained in an inhalation chamber for two weeks, and control rats were in an identical, but dust-free chamber. Tracheal explants results indicate that the effect of in vivo dust exposure is similar to that noted in the in vitro experiments.Pulmonary alveolar macrophages (PAMs) are a key component of the lung's response to inhaled particulates, and they play several important roles in pulmonary inflammatory and repair processes. PAMs are the cells that actually ingest dust particles. Other studies have shown that they play a critical role in the development of silicosis and asbestosis. The Center is studying the effect of dust exposure on the release of oxygen free radicals (superoxide) by PAMs. Intercellular production of superoxide occurs when PAMs phagocytize particles, such as inhaled bacteria, and is an essential mechanism by which PAMs kill ingested, bacteria. A number of complex physiological events occur during this process which are not clearly understood. It is thought that PAMs containing indigestible materials, such as mineral dusts, overproduce superoxide, or inappropriately release it into the surrounding tissues. If true, this would cause toxicity to surrounding lung cells by peroxidation of the lipids in the cell membranes. In vitro exposure of PAMs to low or high doses of kaolin is inert. Preliminary studies indicate that coating the quartz particles with a surfactant reduces toxicity."

Nov 1, 1988

Roof bolting is a slow, expensive, and absolutely necessary mining activity. Roof-bolting activities also account for the largest percentage of lost-time injuries in underground coal mines. Dull bits result in the application of excessive force, which bends drill steel; and changing starter and finisher steel was the most significant source of injuries associated with roof bolting. The tungsten carbide (WC) roof-bolt drill bits currently used in American, Canadian, and Australian coal mines are capable of drilling only one or two 4-ft holes and then they are resharpened once or twice to drill another one or two holes. Often, in medium-hard rock formations (sandstone), as many as 20 to 30 bits may be required to drill a single 4-ft hole. Objective To compare the performance, longevity, and cost of newly developed polycrystalline diamond compact (PDC) roof-bolt drill bits against WC bits. Research and Background Diamonds for industrial use have been scarce throughout history and continuous attempts have been made to produce synthetic diamonds. The first synthetic diamonds were manufactured in 1953. Economically produced synthetic diamonds are 1 to 10 µm in size, but in this size range, they are totally unsuitable for industrial applications. In 1972, General Electric Co. developed a process to sinter the artificially developed, minuscule diamond particles into usable products. In this process, several layers of diamond-particles-and cobalt mixture are overlaid on WC substrates and sintered at 2,350° F and 1,000,000 psi. The final product is known as PDC. Today, PDC's are available in many shapes, but their size is limited to 3/4 in, or less, in length or diameter, because pressures greater than 1,000,000 psi are required to manufacture larger PDC's. At present, diamond and PDC arc the hardest and strongest commercial materials available for wear surfaces. The PDC used in this study had a hardness 3.61 times greater than that of WC.

Jan 1, 1992

By D. Harrington

"A tabulation is printed below showing the accident record of the thirty-two mines of the Anaconda Copper Mining Co., in Montana, for the years 1915, 1916, 1917, 1918, 1919 and 1920, with summation for the six years. The table gives the number of shifts worked by each mine with the serious plus fatal accident rate for each 10,000 shifts worked.It is seen that in a total of 16,460,767.5 shifts worked by employees of the company's mines during this six-year period, there were only 2,005 serious and fatal accidents and of these, 200 were fatalities, leaving 1,805 serious accidents (a serious accident being one in which 14 or more days' time are lost). This is at a rate of 9,120 shifts per serious accident and at a rate of 82,304 shifts per fatality. Hence, if 300 days be adopted as a year's work, there would be one fatality per 274.3 years of work in these mines and one serious accident for every 30.4 years work.According to Bureau of Mines Technical Paper 286, (Metal-mine accidents in U. S. in 1919, by W. W4 Adams), during the years 1916, 1917, 1918, and 1919, the metal mines of the United States worked a total of 210,548,640 shifts and had 39,705 serious accidents. During the same years, according to the following tabulation, the mines of the above-mentioned company worked 11,958,978 shifts and had a serious accident rate of 0.995 accidents per 10,000 shifts worked. If the metal mines of the United States, working these 210,548,640 shifts, had this company's serious accident rate of 0.995 serious accidents per 10,000 shifts, the total number of serious accidents would have been only 21,000 or the country's metal-mine serious accidents would have been reduced nearly one-half, and there would be 18,705 fewer serious accidents than actually occurred."

Jun 10, 1921

By R. V. Ramani, C. B. Manula, A. Owili-Eger

All the input data required to operate the ventilation simulator except the title, are entered with I10 or F1O.O formats. The title is entered with (18A4) format. The floating points are designated by (FP) and the integers by (INT)

Jan 1, 1975

By M. J. Ankeny

The expression "firing open, unconfined shots," as used in this circular, means the firing of explosive charges not confined in boreholes. Examples are the so-called mudcap shots, adobe or dobe shots, or bulldozing shots consisting of explosive charges placed on, under, or between rocks for the purpose of breaking them. The practice of firing open, unconfined shots is not uncommon in coal mines, despite the fact that numerous mine explosions and dust ignitions have resulted from this practice. The usual method of preparing such shots is to place the explosive with its detonator on top of a piece of rock or coal and cover it with clay, loam, sand, or road dust; frequently no covering of any kind is used. In some mines, an open charge of explosive is placed on timbers to dislodge them or in crevices in the roof to break down loose rock that cannot be dislodged with a bar or pick. The explosive charges may be made and fired singly, although sometimes several charges are placed on one large piece of rock with a detonator in each charge, and all charges are fired simultaneously. Although it is general practice to use permissible shot-firing devices, which will not ignite gas or dust to fire these charges, electric power from the regular mine circuits is sometimes used. When the shot is fired, any coal dust that may be present is thrown into suspension by the blast and may be ignited by the intense hot flame of the explosive or by an arc or spark at the leg wires or the end of the firing leads if power from the regular mine circuit is used to fire the shot. Even if there is not enough coal dust present to form a dust cloud, open, unconfined shots can readily ignite methane.

Jan 1, 1952

By Bruce K. Cantrell, Stephen W. Stein, Kenneth L. Williams, David Hassel, Harvey Patashnick

In June 1992, the Mine Safety and Health Administration (MSHA) published the "Report of the Coal Mine Respirable Dust Task Group, Review of the Program to Control Respirable Coal Mine Dust in the United States." As one of its recommendations, the report called for the accelerated development of two mine dust monitors: (1) a fixed-site monitor capable of providing continuous information on dust levels to the miner, mine operator, and to MSHA, if necessary, and (2) a personal sampling device capable of providing both a short-term personal exposure measurement as well as a full-shift measurement. In response to this recommendation, the National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Center, initiated the development of a fixed-site machine-mounted continuous respirable dust monitor. The technology chosen for monitor development is the Rupprecht and Patashnick Co., Inc. tapered element oscillating microbalance. Laboratory and in-mine tests have indicated that, with modification, this sensor can meet the humidity and vibration requirements for underground coal mine use. NIOSH is continuing that effort by developing prototypes of a continuous dust monitor based on this technology. These prototypes are being evaluated in underground coal mines as they become available. This effort, conducted as a joint venture with MSHA, is nearing completion with every promise of success. The immediate benefit of this effort will be to researchers, regulatory personnel, and mine personnel, by permitting evaluation of specific mining practices to see which expose mine workers to excessive dust levels. Using this information, mine personnel can optimize mining procedures to reduce dust exposure. MSHA and the operators will also be able to use the dust concentration data to judge whether dust plan parameters are adequate to continuously maintaining environmental dust levels below the applicable standard. The second development recommended by the Dust Task Group was a person-wearable version of the continuous dust monitor. It will be a monitoring system designed to provide a measurement of worker exposure to respirable dust, both during and at the end of the shift.

By D. Harrington, C. W. Owings

Each year at least one and in some years several explosions are reported as having resulted from firing of mudcapped shots in coal mines; undoubtedly a number of small or local explosions occur that are not reported; in addition there are numerous accidents, some of them fatal, attributable to this reprehensible blasting practice. It is surprising that so few explosions and other accidents from this cause occur since the practice of firing mudcapped, Even in gassy "adobe," "dobe," "sand blast," or "bulldozed" shots is widespread. mines where general blasting is safeguarded by being done with permissible explo- sives, rocks or bowlders frequently are blasted with mudcapped shots of dynamite; even if permissible explosives are used, this type of shooting is dangerous. The usual method of preparing a mudcapped shot is to place the explosive, either in loose or cartridge form, with the detonator or "cap" on top of a piece of rock or coal and cover it with several handfuls of moist clay, loam, sand, or When the shot is road dust; in many cases there is no covering of any kind. fired a dense cloud of dust, together with an intensively hot fleme, are thrown into suspension, and if the dust is explosive or ignitable an explosion or igni- tion is likely to result practically simultaneously. The presence of gas greatly increases the explosibility of the dust, as well as the probability of an ignition. Every shot, of any known explosive, fired in a coal mine without having the charge properly confined in a drill hole and tamped with incombustible stemming to the collar of the hole, is capable of initiating an explosion that may cause the death of every man in the mine. Attention has recently been directed to this unsafe practice by an explo- sion resulting from a flagrant disregard of safe blasting practices in one of our The mine had been idle for several years most productive coal-mining regions. and was being prepared for reopening on a different system of mining. Six to 10 inches of bottom coal had been left in place during former mining operations, but in the new system it was felt desirable to remove the bottom coal left in certain parts of the mine. Instead of drilling holes in the coal, loading them, and fir- ing in the usual safe manner, five or six charges of dynamite were placed on top of the coal in each of several rooms; and while the men were at the mouth of the

Aug 1, 1929

To permit better cap lamp positioning for users of dust helmets. Approach The present design of the dust helmet prevents use of the miner's cap lamp when the front shield is raised, When the shield is raised I the cap lamp is directed at the mine roof or back, making the lamp useless in the event the miner needs to wear his self-rescuer. A flip bracket was designed by the Bureau of Mines to correct this situation. How It Works The safety hat is modified by the addition of lamp clips, a bracket and a hinge on the cap lamp and face shield. Two clips hold the lamp cord firmly to the helmet. When the safety hat shield is raised, compressive force from the lamp cord causes the cap lamp hinge to swing open about 90%, allowing the lamp

Jan 1, 1984

By T. D. Moore

The use of a partially slotted 6.5-inch-inside-diameter vertical pipe to remove methane from a longwall gob area at a depth of 2,260 feet in the Pocahontas No. 3 coalbed was investigated. The value of gas removed by such a pipe under free-flow conditions was found to equal the cost of the installation in this case. Approximately 25 percent of the available methane passed through the pipe without the use of an exhauster; an additional 10 percent was removed when an exhauster was employed. The diversion of methane through a vertical slotted pipe to the surface permitted the use of increased mining rates and decreased the ventilation air requirements.

Jan 1, 1972

By Richard J. Bielicki

The possibility of replacing the brattice cloth closest to the coal mine working face with an air curtain mounted on top of a continuous-mining machine or with a diffuser fan was explored by the Bureau of Mines. Preliminary tests conducted at a full-scale model working face with the brattice end set at 18 feet showed that the air curtain improved face ventilation only slightly and was not nearly as effective as placing the brattice at 10 feet. A 2,000-ft3/min diffuser was more effective than the air curtain. It is concluded that the air curtain probably could not function as a line brattice extension, although the diffuser fan may have some potential.

Jan 1, 1975

By J. E. Murphy

Field freezing was used by the Bureau of Mines to effect the redistribution of the components in a cerium-12.5-atomic-percent-iron alloy. The application of the electric field caused the iron to migrate toward the anode. A field intensity of 0.04 v/cm and a current density of 240 amp/cm2 were used. The conditions that yielded the greatest redistribution of alloy components were a small thermal gradient along the specimen (from 5° C/cm to 10° C/cm) and a very slow freezing rate (0.15 cm/hr). Under these conditions it was possible to process specimens of ½ -inch diameter as compared with the capillary-size specimens used by most previous investigators.

Jan 1, 1968

By Ann G. Kim

Methane in coal constitutes a serious hazard in coal mining. Draining the methane in advance of mining can mitigate this hazard, conserve energy, and offer economic benefits. This Bureau of Mines report evaluates the Pittsburgh coalbed in Greene County, Pa., to determine if advance drainage is feasible. The gas content of virgin reserves in Greene County is estimated at 100 to 200 ft3/ton, a total of over 370 billion ft3 of gas in an area approximately 310 mi2. Because of the similarity to natural gas, drained coalbed gas could be recovered and added to pipeline supplies of natural gas. The value of conserved gas would offset the cost of drainage and extend energy resources.

Jan 1, 1975

By C. R. Kindall

Recently 30 men wore viewing the demonstration of a now portable electric arc-welding outfit. A few hours later 17 of the 30 men reported to the doctor for treatment. They were suffering from traumatic conjunctivitis. In two cases the gain was very severe and the symptoms were similar to those of iritis. orphine had to be administered to afford relief from pain. Only two men of the 30 wera not affected in some way from this exposure. These two men were thick-lensed orange-colored glasses. Several of the men wore orange-colored glasses with thin lenses, but the latter were not heavy enough to afford protection.against an exposure as long as took place. The distance of the eye from the are also in- fluences the possibility of injury. Conjunctivitis is an inflammation of the con- junctiva; the conjunctiva is the mucous membrane covering the inside of the eye- lids and part of the eyeball. Traumatic conjunctivitis is caused by foreign bodies in the eye, exposure of the eyes to high winds, dust, smoke, intense light from electric arc lamps, and from electric welding apparatus. In the instance mentioned above, the inflammation was due to the ultra-violet rays. The ultra-violet rays lie beyond the violet rays in the spectrum and are invisible to the eye. In some cases the effect is so severe that, in addition to conjunctivitis, an inflammation of the skin similar to sunburn is produced. The symptons of conjunctivitis caused by intense light or by the ultra- violet rays are marked photophobia (abnormal intolerance to light), excessive secretion of tears, intense starting of the lid, contraction of the pupil, some- times swelling of the lid, and small ulcers developing on the eyeball or cornea. Unless properly treated by a physician immediately, chronic inflammation of the conjunctiva, cornea, iris, or retina, and possibly blindness, may result. Under proper treatment most cases get wall in a few days. All treatments should be under the direction of a physician. That usually advised is to place ice packs on the patient's eyes three or four times daily. The pack should be left on from 15 minutes to an hour. The eyes should be irrigated with normal salt solution (a teaspoonful to a quart of sterile vater) or a saturated solution of boric acid several times daily. If there is a discharge of pus, a few drops of a 25 per cent solution of argyrol or a 5 per cent solution of protargol should bo placed in the eyes three to six times daily. The patient should be confined to a darkened room until his condition improves in order to avoid complications. These treatments will reduce the swelling, give the patient confort, and prevent the development of chronic conjunctivitis. In severe cases it may be necessary to administer morphine to relieve the pain.

Oct 1, 1920