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By Elizabeth A. Johnson

Minor-element behavior and interaction in the copper matte-iron silicate slag system have been studied by the Bureau of Mines. In the present work, the possibility of interactions among the minor elements As, Sb, Bi, Se, and Te was investigated. Equilibrations of matte, slag, and one of each of the five minor elements were performed at 1,250° C under typical matte smelting atmospheres of CO, CO2, and S02 for mattes containing 40, 50, and 60 pct Cu. Results are compared with those of a previous Bureau of Mines study in which all five minor elements were present simultaneously.

Jan 1, 1984

By Richard L. Unger

Equipment is the primary cause of injury in 11% of all mining accidents and a secondary cause in another 10%. Purchasers should select new equipment carefully to ensure that the machine incorporates good ergonomic design criteria that maximize the safety of their mine workers. One potential problem area is the workstation-the control center of the machine. Safety problems often occur when the workstation provides insufficient clearance or visibility to the operator or has controls that are difficult to reach. This is especially true for underground mines, where confined space is an issue. In reclined or stooped postures, operators will have less strength and agility and often experience reduced visibility. We have conducted and published much research in Human Factors design of mining machine workstations. This information is currently being compiled into a series of Human Factors design recommendation reports. The reposts dl cover many topics, including workstation layout, control design, seating, and visibility. Each topic has a list of basic or first principles of design. Understanding these principles is the key to designing or purchasing a workstation that is both safe and efficient. Following is a sampling of these main topics and first principles.

Aug 1, 1996

By J. Douglas Causey

In 1986, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied the 7,940-acre Southern Otay Mountain Wilderness Study Area (CA-060-029), and the 5,750-acre Western Otay Mountain Wilderness Study Area (CA-060-028) in order to evaluate their mineral resources. The wilderness study areas are located in San Diego County, CA, about 20 miles southeast of San Diego. No mineral resources were identified in the Southern or Western Otay Mountain Wilderness Study Areas, based on literature, field observations, and sample results. The wilderness study areas are underlain by a complex blend of Late Jurassic, moderately metamorphosed sedimentary and volcanic rocks. Evidence of mineralization is not obvious.

Jan 1, 1987

By William K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/ AgC1 reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrodes to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 2010

By Louis A. Turnbull, JOSEPH J. SHIELDS

The Bell & Zoller Coal & Mining Co. recently completed construction of two slopes at Mine 3 near Zeigler , Ill . The slopes are in the Big Muddy River Valley , and construction was particularly difficult because the strata from the surface to a depth of 70 feet comprise water saturated sandy clay and sand . Many mining companies have similar shaft- and slope - sinking problems , and because these slopes were satisfactorily completed and now are in use the methods followed during construction are described in this information circular . It is believed that other companies with similar problems . will benefit by adopting the methods followed at Mine 3 .

Apr 1, 1949

By D. G. Kuehn

Mass spectrographic studies have been conducted on the positive ions and neutral species of glow discharges containing 1.0 pct S02 and 1.0 pct CO in helium. Measurements were conducted for gas pressures from 3.5 to 10.1 torr using both dc and 60-Hz ac excitation. The ion species that were observed included S+, SO+, SO+, 0+, O2+, C+, CO+, and CO2+ with lesser amounts of SO3+, (CO)2+, SCO+, and (SO?CO)+ or CS+2. Interpretation of the functional dependence of the various ionic and neutral species on pressure and applied power showed that CO reacted with the SO formed in the discharges to produce CO2 and sulfur. Deposition of elemental sulfur was observed in the plasma container.

Jan 1, 1973

By M. D. Schlesinger

Mercury exists in coal at very low levels; the structure of coal, the vapor pressure of mercury, and its almost universal occurrence introduce unusual problems into the analytical methods. Round-robin analyses by several laboratories, each using its own techniques, indicate that the average mercury content of coal is about 0.2 part per million. Some western coals are as low as 0.05 ppm.

Jan 1, 1971

By J. P. Barkley

"The accompanying tabulation gives the results of a series of operating tests on two types of small stokers. One was an inclined, natural-draft, moving-grate, overfeed ""hand-stoker"" fired and manipulated by hand; the other was. a horizontal, forced-draft, stationary-grate, underfeed, mechanical unit-stoker operated by an electric motor. These were installed as shown by the accompanying sketches (figs. 1 and 2) under horizontal return tubular boilers of a nominal rating of 150 bl.h.p. each.The steam load carried by these boilers was a rather typical heating load. It was fairly constant and of about 30 bl.h.p. throughout the summer months, with small variation between day and night. During the winter months the daily variations were dependent upon the outside temperature. The boilers were banked a considerable part of the night.As noted in the table, two kinds of coal were used. The size of one kind was run-of-mine and the other 11/4 inch nut and clack. These coals from two different mines of the New River district both caked considerably during burning, the nut and slack more than the other. Analyses of the coal were as follows:"

Jun 1, 1929

By Charles Vaught

The U.S. Bureau of Mines evaluated the self-contained self-rescuer (SCSR) donning proficiency of 243 miners. These workers were from eight underground coal mines in the eastern United States. The objectives of the study were (1) to gather information on skill levels, since all miners in the study had prior instruction and opportunity to practice donning the apparatus, and (2) to summarize a quality control procedure useful in conducting periodic evaluations of donning proficiency. The sampling procedure used proved to be both reasonable and efficient in gathering information on training effectiveness. It also provided a good statistical base for making informed site-specific decisions regarding SCSR training needs. Results from the observed samples at each of the eight mines indicate a wide variability across sites. The rate at which miners failed to isolate their lungs varied from 3.3 to 40.0 pet. Concomitantly, proficiency rates (miners either performing adequately or demonstrating a perfect 3 + 3 sequence) ranged from 13.3 to 63.3 pet.

Jan 1, 2010

By D. G. Kesterke

The electrolytic reduction of uranium dioxide to molten uranium in fluoride baths at approximately 1,200° C was demonstrated. Electrolyte constituents were BaF2, UF4, and either MgF2 or LiF. Preliminary laboratory-scale experiments were made in which the uranium oxide was added continuously for 3 to 5 hours to the cell during electrolysis. Over 1,000 grams of metal of 99-8 percent purity was made in some tests, Major impurities were aluminum, barium, iron, silicon, carbon, and oxygen. The effects of cell design, geometry, and bath composition were investigated. Electrode arrangement was the most important factor in cell performance.

Jan 1, 1963

By L. E. Schultze

The Bureau of Mines devised a technique to recover a Zn-Pb concen-trate from a geothermal brine. More than 99 pct of the Zn and Ph was precipitated by treating the brine with H2S and controlling the pH with lime. Recycle of the sulfide precipitates increased crystal size and resulted in easily filterable products. A typical sulfide precipitate contained 53 pct ZnS, 8 pet PbS, 24 pct MnS, and 15 pct FeS. Addition of sulfide as FeS or CaS was not effective in precipitating Zn and Pb, but Zn in the brine was selectively removed with a strongly basic ion-exchange resin. A proposed flowsheet for metals recovery is discussed.

Jan 1, 1985

By N. A. Gokcen

This Bureau of Mines report reviews and summarizes recent studies of the rates of chlorination of aluminous resources with CO and C12 mixtures with and without COC12. No reaction mechanism could be obtained from the existing results; however, diffusional barriers in the gas and solid layers probably control the chlorination rate in thermogravimetric experiments. Fluidized beds of particles smaller than 0.1 mm appeared to show very little solid layer diffusional barrier. For optimum chlorination the particle size should probably be less than 8 mm, the calcination temperature approximately 700° C, and the chlorination temperature from 650° to 750° C. Relatively rapid chlorination with COC12 in thermogravimetric experiments was attributed partly to the simultaneous supply of reductant and chlorinator by one gas to the sample reaction site. Comparable results for chlorination of fluidized beds with COC12 are not available. Equimolar mixtures of CO and C12 produced the optimum rate of reaction. Addition to the calcine of 10 to 20 wt-pct NaCl accelerated the rate of chlorination, and addition of SiC14 to the gas mixture decreased the rate of chlorination of SiO2 drastically, but at the expense of chlorination of significant fractions of Al2O3. Further research in various areas is suggested.

Jan 1, 1983

By J. E. Gebhardt

External control of the electrochemical potential of a bed of mineral particles has been investigated by the Bureau of Mines as a method for controlling particle inter-action with organic collectors and thus, flotation response. A cylindrically shaped, 200-to 300-g bed of sulfide mineral particles was used as the working electrode to examine the potential distribution in the bed. The dissolved oxygen concentration of the electrolyte had a significant effect on the potential profile across the mineral bed. Low oxygen levels were necessary to achieve uniform electrochemical potential distributions. Flotation separation of a chalcocite-pyrite mineral mixture by controlled potential was achieved using ethylxanthate, but the flotation behavior of chalcocite and pyrite from the mixture does not follow the flotation behavior of the individual minerals. That is, the presence of another sulfide mineral alters the flotation behavior with ethylxan-thate. Galvanic interaction due to mineral-to-mineral contact between chalcocite and pyrite contributes to differences in the recovery. Chalcocite dissolution products had a deleterious effect on pyrite flotation by activating flotation below -0.1 V (saturated calomel electrode) and depressing flotation above -0.1 V. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1985

By M. F. Dunn

A handbook to provide a quick reference guide for selecting and using jet fans in a variety of conditions was prepared. The document is intended for use by front-line supervision, ventilation engineers, and mine planners. Included are discussions of jet fan characteristics, selection and use critieria, and do's and don't's for easier operation, safety, and performance. The handbook is based on research at three underground metal/nonmetal mines having cross-sectional areas of 900 to 2,000 ft2.

Jan 1, 1983

By W. K. Tolley

This report presents data collected during research by the Bureau of Mines on corrosion of grinding media. Corrosion rates of eight alloys commonly used in grinding media were tested in synthetic mill water using an ultrasonic grinding device especially designed for this work. Electro-chemical measurements showed variations in corrosion rates for these alloys between 9.8 mpy for medium-carbon steels and 0.14 mpy for high chromium white irons. Bureau data are discussed along with data from the literature to indicate that corrosion causes less than 10 pct of the wear of grinding media in commercial grinding mills. A comparison of corrosion rates for various types of grinding media shows that alloying elements and electrochemically active inclusions in steel affect the corrosion behavior of the media.

Jan 1, 1984

By N. S. Dalal, X. Shi, V. Vallyathan

"Electron spin resonance (ESRJ spectrum of the hydroxyl (· OH) radical spin adduct with .the spin trap 5,5-dimethyl-1-pyrrolintt-N-oxide has been obtained in suspensions of freshly ground quartz particles. The concentration of the spin adduct (and hence of the • OH radicals) increases with the amount of grinding. The dust's potential for the generation of the· OH radicals is maximum when fresh (i.e., immediately after grinding) and decreases to 50% in about a day on storage in air. Studies involving metal chelates .indicate that the • OH radical formation involves mainly the silica surface and H20 rather than the Fenton reaction. The results suggest that hydroxyl radical reaction(s) could be important in the lipid peroxidation and fibrogenicity by quartz dust, particularly .in acute silicosis. INTRODUCTIONIn this paper we report on our electron spin resonance (ESR) detection of the formation of hydroxyl (·OH) radicals in aqueous suspensions of freshly crushed quartz particles. This work was undertaken with a view to find possible clues to the role of free radicals in the pathogenesis of quartz-induced fibrogenicity, commonly known as silicosis. We noted that while silicosis is one of the major health hazards in coal and mineral industries, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still poorly ·understood (Reiser and Last, 1979; Singh and .Rahman, 1987). It is generally thought, nevertheless, that the action of quartz particles on the biological membranes is the starting point of the silicotic process (Parazzi et - al., 1968). A possible clue to the mechanism of the membrane damage by quartz particles, in terms of the role of oxygenated free radicals, is suggested by the following observations. A suspension of quartz particles in contact with alveolar macrophages has been reported (Gabor et al., 1975; Koike et al., 1982) to initiate an enhancement of lipid peroxidation, defined broadly as the oxidative deterioration of polyunsaturated components of lipids. Hydroxyl (· OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (Halliwell and Gutteridge, 1985) and of initiating lipid peroxidation in lysosomal membranes. (Fong et al., 1973). Arong other lines, it is known that exposure of cell membranes, fatty acids, and unsaturated food oils to ionizing radiation, which generates· OH radicals, causes rapid peroxidation (Halliwell and Gutteridge, 1985). Thus • OH radicals (and also other oxygenated species such as Oi, 10 2, and H20 2) might be expected to play a role in the toxicity of quartz. Earlier studies of the aqueous chemistry of quartz suspensions have reported detection of H2O 2 (Kalbanev et al., 1980), implicating the formation of ·OH radicals as transient species. However, we are not aware of any report of the detection of • OH radicals in quartz reactions, and thus the present study was undertaken. Since it-is known that, because of their high reactivity (hence short lifetime) in aqueous media, the • OH radicals cannot be detected via ESR directly (Finkelstein et al., 1980; Buettner, 1982) we have used .ESR combined with the spin-trap methodology (Finkelstein et al., 1980) for studying the· OH formation. The results show that· OH radicals are indeed formed in aqueous suspensions of freshly ground quartz; thus pointing to ·a possible new clue to the cytotoxicity of freshly formed quartz particles and thereby to silica fibrogenicity."

Jan 1, 1988

By R. V. Higgins

Many contributions to methods of forecasting the performance of waterfloods of a five-spot pattern have been made by investigators. In most of these forecasting methods, a previously selected sweep efficiency is used, and other simplifying assumptions are employed to obtain the objective. In this paper the calculated oil recoveries from several five-spot single- and multiple-layer stratified reservoirs were made with a minimum of assumptions, and because of the techniques used, no previously selected sweep efficiency was required. As a result, the accuracy of the forecast is increased. Permeability curves and continuously changing saturation gradients are used in every section of the pattern. By means of a potentiometric model, the flood pattern is divided into channels, the centers of which are the streamlines. The channels are divided into cells. As flood water enters, the permeability and saturation of each cell change with time. In this study the production from multiple-sand layers of different absolute permeability but with the same relative permeability-saturation relations are combined. The results are shown for a single- and 10-layer reservoir with a permeability variation of 0.60. The oil rate, water-oil ratio, and recovery are shown as functions of time for a 2- and 20-centipoise oil starting in primary phase and after fill-up.

Jan 1, 1962

By R. V. Ramani, C. B. Manula, A. Owili-Eger

The mine ventilation system consists of the fan, the roadways, and the regulatory devices. Sufficient fresh air must reach each working face in the mines to render harmless noxious, toxic, and respirable pollutants and to provide for the breathing of men. This is achieved by the proper selection of fan and regulatory devices. Because a mining system is dynamic, the mine ventilation system must also be dynamic. In short, mine ventilation engineers are frequently called upon to provide answers to the following questions: 1. Given a mine or the projected plan of a mine, what fan must be selected for the quantities specified in the section? At what point in its characteristic must it be operated? Are any speed changes or changes in blade settings warranted? 2. What should be the regulation in a section to insure cer¬tain desired quantity in that section? How does it affect the overall ventilation system? 3. What are the effects of driving a new shaft? Where should it be located? What size fan should be installed in the shaft? How does this affect the overall ventilation sys¬tem? 4. How much quantity increases can be obtained by cleaning up falls and streamlining roadways and by driving addi¬tional parallel airways? These questions are in no way exhaustive, nor are answers easy. Most of the operational and planning problems discussed above are to a cer¬tain extent solved by ventilation engineers using rules of thumb from experience. Both natural conditions and regulatory requirements have changed so drastically recently that use of scientific methods in ventilation planning and of faster methods in evaluating the plans is a must. Fortunately, computers offer the greatest hope for good

Jan 1, 1975

By Maria I. De Rosa

Combustible materials, when burned, produce toxic gases and smoke, which may vary dramatically from one material to another, with resultant different total toxicity and smoke obscuration levels. This U.S. Bureau of Mines report presents smoke property data acquired for a variety of mine combustibles and shows that there exists a correlation between the smoke properties, the relative toxicity, and the smoke obscuration levels of those combustibles tested. These correlations can be used to devise simple, standard tests for determining the toxic and smoke obscuration hazards of mine materials during fire.

Jan 1, 1989

By Martin H. Stanezyk

The Bureau of Mines investigated leaching of selected copper sulfide minerals and a composite of impure flotation concentrates at elevated temperatures and pressures with ammoniacal solutions. Copper 1 (tractions of 96 percent were obtained by leaching chalcopyrite at 75° C under oxidizing conditions for 60 minutes. An extraction of 99 percent of the copper contained in the composite concentrate was obtained by leaching the product for 90 minutes at 75° C. In tests of bornite, chalcocite, and covellite, 90 to 97 percent of the copper was extracted at 20° C provided an 8-hour reaction period was used. At 75° C essentially complete dissolution of the copper from these three minerals was accomplished in 60 minutes. Additions of ammonium sulfate to the leach solutions were required to obtain high-percentage extractions of the copper from bornite, chalcocite, and covellite. Although ammonium sulfate was not required when digesting chalcopyrite, copper extraction was enhanced and less free ammonia was required when ammonium sulfate was added to the leach pulps. The chemistry of leaching copper minerals was studied. It was C, termined that chalcocite altered to covellite as one step in the dissolution When leaching iron-bearing copper sulfides, hydrated iron oxide formed on the mineral surfaces, indicating that a diffusion process prevailed. No evidence of covellite was detected.

Jan 1, 1966