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By Michael J. Magyar

The Federal Bureau of Mines has developed a hydrametallurgical method to recover aluminum, aluminum oxide, and fluxing salts from aluminum salt slags. The slag is leached with water at room temperature to produce a saturated brine slurry. Screening of the slurry yields an aluminum-rich fraction that can be returned to the dross furnace. The remaining slurry is vacuum filtered, yielding a clear brine solution and an aluminum oxide filter cake. Evaporation of the clear filtrate produces a high-purity fluxing salt for reuse in the dross furnace. Over 80 pct of the metallic aluminum is recovered in the aluminum-rich oversize fraction, while essentially all the fluxing salts are recovered by evaporation. This report contains the final results of an investigation on a process research unit scale, an economic evaluation of the method, and recommendations to further improve the process.

Jan 1, 1979

By E. A. Loria

The Bureau of Mines analyzed the effects of oxygen, nitrogen, and carbon on the tensile properties of electrorefined vanadium in terms of the Petch equation. The effects of the different impurities and grain sizes on the yield and flow stress between 2730 and 770 K were studied. For specimens of like composition, the values of the Petch parameters 01 and ky obtained by two different methods, extrapolation and grain size, were nearly the same. For high-purity electrorefined vanadium, the 01 value at 2730 K was 10,300 psi (5,150 psi shear). The 01 values for this metal at 1950 and 2730 K were lower by factors of 3 to 4 than for three less pure samples of commercial vanadium metal of equivalent grain size. Nitrogen was more effective than oxygen in increasing 01' the increase being about twice as much for the same impurity level. Carbon produced a slight increase in 01 up to 0.024 percent and then a gradual decrease in 01 to 0.11 percent, the maximum carbon content studied. The corresponding ky values followed the same trend in regard to oxygen and nitrogen additions, whereas the addition of carbon produced no variations at either temperature. Dislocations in vanadium are anchored by carbon, oxygen, and nitrogen with increasing firmness in that order. The high purity of electrorefined vanadium was confirmed by low yield stress and high ductility throughout the low temperature range. The metal also exhibited profuse twinning with high ductility at 1230 and 770 K. The effective surface energy for fracture, y, was found to lie between 3.3 and 3.6 x 1()4 erg cm-2?

Jan 1, 1966

By R. W. Huber

The successful development of a titanium prototype of the 81-mm. mortar base plate for the Army Ordnance Corps is outlined in this report. Information is presented dealing with forming, forging, and machining, welding and assembly techniques, and design changes relative to this prototype. INTRODUCTION The work of the Federal Bureau of Mines in making ductile titanium available2/ has resulted in the establishment of a new industry. Owing to its strategic importance and the combination of low density and high strength, titanium has received considerable attention as a structural metal. Titanium's favorable strength-to-weight ratio is of particular importance to the Army Ordnance for equipment that is transported by airplane or by foot soldiers.

Jan 1, 1956

By Joseph D. Davis

The term "fusain" was first adopted from the French by the American geologist J. J. Stevenson in 1911, according to Wheeler, (1),3 who applies it to that portion of coal resembling charcoal, which he treats as one of the four ingredients of banded bituminous coal. The term has since been adopted by American writers. The Germans use it with slightly different spelling - namely, fusit. It is the equivalent of "mother-of-coal" and "mineral charcoal" of the earlier British writers. The English word fusain is also applied to "a crayon of fine charcoal" and is derived from the Latin root fusus. OCCURRENCE OF FUSAIN IN COAL AND ITS RECOGNITION Fusain is fairly widely distributed in coals of all ranks in varying amounts. It is almost always present in very thin sheets between the bedding planes of the banded coal constituents and presents a jet-black silky appearance who n the coal is split away. As fusain has little cohesive power the coal splits readily along the planes where it occurs. Such fusain bands often attain appreciable thickness -- frequently 1/4 to 3/4 inch. -Beet (2) has reported a maximum thickness of 2 inches for fusain partings, and Sinnatt (3) has found it in the form of plates and lumps; one lump taken by him from the Peacock mine weighed 3-3/4 pounds. Bore (4) has found it in coal balls. Sinnatt (3) states that fusain occurs in two forms, "the first a hard compact variety occurring rather rarely, which can not be pulverized by pressure of the fingers the second type is the common substance" -- that is, a very friable, easily pulverized material. The writer has also found the two types of fusain in the same coal bed and has observed that the hard variety contained considerable calcium carbonate, which probably entered the material in situ by infiltration. Sinnatt further remarks that the layers of fusain (soft type) usually contain less moisture than the coal (or lose it more readily on exposure), and when exposed they quickly change to flocculent powder so that the fines of the coal as mined are likely to contain a major proportion of this substance.

Jan 1, 1929

By Van E. Shaw, D. J. Bauer

Conversion of euxenite concentrate to sulfates with sulfuric acid and solvent extraction of the yttrium- rare - earth mixture with EHPA were studied to determine extraction and separation characteristics . Digestion with 3.5 pounds of 96 percent sulfuric acid per pound of concentrate at 336 ° C for 4 hours resulted in an easily handled product with a yield in excess of 98 per- A thorium- free product was obtained by calcining the sulfated material for 3.5 hours at 650 ° C prior to leaching with water . Di ( 2 - ethylhexyl ) phosphoric acid solvent is an effective extractant with preference for cerium ( IV ) and heavy - group rare - earth elements including yttrium . Separation of complex rare - earth mixtures into light- and heavy - group fractions is feasible , and these fractions can be further processed to isolate ytterbium , neodymium , and dysprosium by changing processing conditions to obtain separation factors greater than two between these and adjacent elements .

Jan 1, 1965

By Christopher D. Risbrudt

In this comprehensive study of the use of wood products in coal mining, a sample of over 220 mines provided data by questionnaire. Wood use per ton of underground coal was found to vary substantially by mining process and region. In the Eastern Coal region, 1.6 board feet of wood was used per ton of coal, wel above the 0.6 board feet usage per ton in the West. The kind of timber used varied also by Region. Hardwood use is about 40 times greater than softwood in the Eastern Region. There, hardwoods are plentiful, relatively cheap and strong. In the West where softwood forests predominate, softwoods were 2-1/2 times more common in mine wood use than hardwoods. Nearly 80 percent of the wood used in underground coal mines is used in cross bars and props. Nearly 54 million cubic feet of wood products were used in coal mining in the sample year 1979; about twice as much going to underground mines as surface mines. Wood requirements for mining were projected to 2030 for a range of three oil price scenarios. Much greater wood use will be required for greater coal output.

Jan 1, 1982

By F. E. Block

The reaction between calcined dolomite and ferrosilicon has been studies with the aim of developing a continuous process for magnesium production. Small-scale tests were made in vacuum retorts similar to those used in the vacuum retort process as developed by Pidgeon (1)2/ and operated during the period of World War II in several Government-owned plants. Factors investigated with respect to the silicon efficiency were the reaction temperature, reaction time, amount of excess dolomite in the charge, and effect of adding sodium silicate to the charge to serve as a binder. Additional laboratory tests were made to study the reaction at elevated temperature but at atmospheric pressure. Silicon efficiencies exceeding 80 percent were found to result when operating in the temperature range from 1,750° to 1,800° C. for periods of 20 to 30 minutes.

Jan 1, 1956

By Gordon H. Dechman

This report presents the concept, design, and testing of a sonic velocity monitoring system for the early detection of slope failure in open pit mines. The heart of the system is a device for producing reproducible sonic signals in rock. Because changes in the velocity of sound through rock near the top of the pit wall are a measure of extent and rate of fracturing of the rock, velocity histories obtained from periodic, automatic sonic velocity surveys provide positive information about developing slope instability.

Jan 1, 1976

By Willard L. Hunter

A series of steel heats, one low-alloy and nine carbon, was made by the Bureau of Mines in a 1-ton arc furnace from ferrous scrap from incinerated refuse, steel cans, and detinned steel cans, both alone and blended with heavy-melting scrap. Two additional control heats, one of carbon steel and one of low-alloy steel, were made from electric furnace heavy-melting scrap to pro-vide comparative data. The steel products were cast into two 4-by 4-inch nominal 50-pound ingots; in most heats, an 8-by 8-inch nominal 7S0-pound ingot was also obtained. Tests of these ingots indicated that reinforcing bars of acceptable quality can be made from urban refuse components such as steel cans.

Jan 1, 1976

By J. E. Dooley

Reference mass spectra and analytical correlations for 20 alkylcycloalkyl sulfides and two dicycloalkyl sulfides are presented 'to provide information that will facilitate the identification of sulfur compounds occurring in natural or synthetic mixtures. Reference spectra indicate relative intensities in addition to parent and base peak sensitivities. Analytical correlations establish the ionic species that reflect major fragmentation paths for the com-pounds studied. Specifically, the correlations show that base peaks are formed by several different processes: (1) Cleavage of the bond a to the ring, (2) fragmentation of the alkyl chain, and (3) fragmentation of the ring plus fragment contribution from the alkyl chain. Useful correlations for deter-mining alkyl chain length involve the CnH2+3S+ and CnH2n+1 + ions. CnH2n-2+ and CnH2n-1 S+ ions reveal the number of carbon atoms in the cyclic ring. Other important ionic species are also discussed.

Jan 1, 1970

By J. R. Ruark

This report presents results of the research and development work and operations performed during stage II of the gas combustion retorting research program conducted by the Colorado School of Mines Research Foundation and six major oil companies at the Bureau of Mines Anvil Points Research Facilities. The experimental program, including retort modification and air-gas distributor development, effects of shale quality and particle-size distribution, and other variables on the process, is discussed. Although operating problems are not fully resolved, it appears that the gas combustion retorting process can be successfully applied to achieve oil yields in excess of 85 percent of Fischer assay at mass shale feed rates of 500 pounds per hour per square foot of cross-sectional bed area, approximately twice the rate previously demonstrated to be reasonably practicable.

Jan 1, 1971

By J. Roger Loebenstein

This report presents a U.S. Bureau of Mines study of the flow of arsenic-containing materials in the United States, based on the best data available in 1991, includes a consideration of arsenic as a byproduct of the processing of nonferrous metals, the fate of arsenic in manufacturing wastes, the quantity of arsenic used in products, tile fate of arsenic in dissipative uses, and the useful life of discarded products. Where possible, estimates are given of the amounts of arsenic lost from the materials flow. Arsenic byproduct of mining nonferrous metals. Historically, most U.S. production has been from the states of Montana, Washington, and Utah. The smelters in these states are believed to be the areas of the country where arsenic is most concentrated in the soil, tailings ponds, and waste dumps. Since the closure of the last domestic producer of arsenic in 1985, all arsenic has been derived from imported sources. Historically, arsenic was important in agricultural applications as an insecticide, herbicide, and cotton desiccant. As the environmental movement gained momentum and the toxicity of arsenic became better understood, most of the agricultural uses for arsenic were banned. Beginning about 1975, the use of arsenic as a wood preservative began to grow. After 1980, wood preservative uses became more important than agricultural applications. By 1990, 70% of the arsenic consumed in the United States was used by the wood preservative industry and 20% by the agricultural industry. The major source of domestic arsenic emissions in 1989 was from the U.S. copper processing indus¬try. About 7,800 mt/yr of arsenic was discarded in leach dumps, tailings, and slag. Another 800 mt/yr was liberated to the atmosphere and 1/100 mt/yr was exported in copper concentrates. On the consumption side, 9,200 mt/yr was lost, mostly from dissipative agricultural uses and the disposal of obsolete arsenical products.

Jan 1, 1994

By Wesley T. Holmes II, Lloyd H. Banning

Electric - smelting studies were made on titaniferous materials obtained from the Klukwan and Snettisham , Alaska ; Choteau , Mont .; and Iron Mountain , Wyo . , deposits with the objective of determining the feasibility of producing pig iron and an enriched titania slag in one test series and pig iron alone in another test series . In addition , related studies were conducted to determine the amenability of Choteau crude ore to wet -magnetic separation and to determine the quality of steel that could be produced from the titaniferous pig iron . The continuous smelting tests were made in a three - phase , submerged - arc , electric furnace , and the laboratory steelmaking tests were made in a singlephase electric - arc furnace . A continuous , belt - type , wet - magnetic separator was used in conjunction with a ball mill and a spiral classifier in recovering titaniferous magnetite from the crude Choteau ore . Pig irons containing less than 0.05 percent phosphorus or sulfur were readily produced from the titaniferous materials ; iron recoveries ranged from 92 to 98 percent . The Choteau ore was ground to minus 65 - mesh to produce a concentrate containing 60 percent or more iron . The steel produced from the titaniferous pig iron was a high - quality product .

Jan 1, 1964

By Stanton L. Tainter

When the disruption of gold mining stopped the usual source of siliceous flux needed by copper smelters , sandstone copper deposits in northern Arizona offered possibilities as a source of the flux during the war emergency . The Federal Geological Survey , while making a comprehensive survey of sandstone copper deposits , investigated the Warm Springs mining district in northcentral Coconino County in August 1943. A month later , J. H. Hedges , chief of the Tucson Division , Mining Branch , Bureau of Mines , examined the operations in connection with an application for an access road . Both investigations concluded that the district , as an emergency source of copper-bearing siliceous flux , had considerable merit , provided high prices for copper continued in effect . Early in 1944 , V. M. Ryan and S. B. Atherley requested assistance from the Bureau in exploring various deposits on their property . The Bureau / drilled 152 holes , aggregating 3,756 feet , on the Petoskey and Mackin groups of claims . This report is based upon churn drilling done under contract from October 7 to November 25 , 1944 .

Feb 1, 1947

By R. Karl Zipf, Z. T. Bieniawski

"Abstract. Based on the premise that understanding the fundamental mechanics of fine fragment formation in coal will lead to reducing coal dust problems in mines, a thorough study of the mechanics of crack propagation in coal was undertaken. Two approaches were considered in an attempt to understand and quantify the fracture process as it relates to fine fragment formation.In one approach, theoretical models are used which describe the size of the fracture process zone which may relate to the amount of structural damage and fine fragment formation on the new crack surface. The other approach is based on the relationship between crack tip stress intensity and new surface appearance for mixed mode crack propagation. Preliminary observations with a scanning electron microscope support the premise that fine fragment formation is related to fracture surface appearance and fracture initiation conditions.An experimental program designed to supply the input parameters for these approaches is presently underway. The experimentation features mixed mode fracture toughness testing, using a special mixed mode testing rig, and fracture velocity measurements with a crack propagation gage. The interpretation of this data via the approaches discussed will provide further understanding of the mechanics of fine fragment formation in coal."

Mar 1, 1989

By M. Hayashi

The Bureau of Mines conducted laboratory studies on low-grade vanadiferous silicates from the Pumpkin Buttes and Nine Mile Lake deposits of Wyoming to examine techniques for extracting vanadium and uranium. Recovery from low-grade sources such as these could contribute to future vanadium production and reduce reliance on vanadium imports. The Pumpkin Buttes samples contained 0.03 to 0.04 pct V205 and 0.06 to 0.12 pct U308; the Nine Mile Lake samples contained 0.02 to 1.0 pct V205 and 0.06 to 0.19 pct U308" Leaching the Pumpkin Buttes samples for 18 h at 800 C with addition of 200 lb/ton H2S04 resulted in recoverey of 80 pct of the vanadium contained in the samples. The Nine Mile Lake samples were readily leached, yielding 78 to 94 pct of the vanadium after 3 h at 800 C with addition of 100 lb/ton H2S04, A solvent extraction procedure was used to selectively recover urani-um from Pumpkin Buttes and Nine Mile Lake leach solutions and to recover vanadium from the raffinates. In batch shakeout tests, Alamine 336 recovered over 95 pct of the uranium from leach solution adjusted to pH 1. Di-2-ethylhexyl phosphoric acid and Cyanex 272 recovered vanadium from the uranium raffinate after reduction and adjustment to pH 2; vanadium extractions of up to 96 pet and 92 pct, respectively, were achieved.

Jan 1, 1985

By Henry M. Harris, Hal J. Kelly

Electrical dewatering tests are described in which the laboratory cells were designed for continuous operation using an endless metal belt as the anode . The test slurries were dilute , containing from 2.5 to 14.4 percent solids (specific gravity of 1.02 to 1.10 ) that were all minus 8 microns in size . Recovery of the solids of low water content was the practical objective of the investigation . Process variables evaluated and reported are : The effect of feed rate , amount of electrolyte , samples from different sources , and the use of two cells in series . These variables are evaluated on the basis of yield of clay per kilowatt - hour , recovery , and the amount of solids in the deposited clay . Recovery , yield , and solid content of the belt anode product are interdependent , and changes that will improve one of these characteristics often are accomplished at the expense of the others . Tests in which recoveries range from 50 to 60 percent usually result in yields of 8 to 9 kilograms (kg ) of dry clay per kilowatt- hour (kwhr ) . Under these conditions , the solid content of the deposited clay approximates 50 percent . One test sample , composed of kaolinite , showed very high yield , 13 to 16 kg per kwhr ; high recovery , 53 to 58 percent ; and 52 to 54 percent solids in the cake .

Jan 1, 1964

By D. Harrington

Ventilation of underground workings consists of establishment of such control of air currents that the underground workers may work in safety, with maximum comfort and efficiency, mad without impairment of health; and that the mine openings may be made subject to such control of air flow as to remove from the workings at ordinary times harmful gases and dusts, and at time of emergency, such as fire or explosion, there may be maintained as much or as little air flow as may be desired covering portions of the mine or the mine in its entirety. Control of air flow is the keystone of any ventilating structure, and this very essential feature is obtainable only by the installation of mechanically operated fans, to ether with other ventilating devices such as doors, overcasts, regulators, etc. Every mine, large or shall, coal or metal, should from the outset be equipped with a fan. While much has been written about natural ventilation and many claims have been made that in specific mines there is sufficient natural al" flow, there are few if any mines, coal or metal, where natural ventilation supplies anything like adequately safe or healthful conditions for underground workers even at ordinary times; and at a time of mine fire or explosion the mines depending upon natural ventilation are practically helpless, and certainly are decidedly dangerous to those unfortunates forced to be in them.

Jan 1, 1933

By W. I. Nelson

This paper which describes the milling practice of the Engels Copper Mining Co., is one of a series on milling methods being prepared for and published by the United States Bureau of Mines. ACKNOWLEDGMENTS Acknowledgment is made of the assistance rendered by J. Casagrande, mill foreman of the Engels concentrator, in collecting much of the data presented in this paper.

Jan 1, 1932

By H. L. Burmeister

This report describes the mining and milling practices used by the Eastern Magnesia Talc Co. at its Johnson, Vt., operation. The report also contains a description of the local geology and all available information on cost and performance data. Since 1925 the mine has produced continuously at an average annual rate of 54,000 tons, and the ratio of ore hoisted to finished product is roughly 2 to 1. Ore is stoped by a combination of shrinkage and sublevel methods. In any 24-hour period the mill produces an average total of 14 grades of finished talc product, 9 by dry grinding and air classification and 5 by wet grinding and flotation methods. The mine operates one shift per day, 5 days per week and the mill operates on a 3-shift, 5-1/2-day-per-week basis. Operating costs for 1958, on a percentage basis, were mining, 22.34; milling, 54.77; ore haulage, 2.89; and all other, 20.00 percent.

Jan 1, 1963