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By Seth C. Schaefer

The Federal Bureau of Mines studied the Gibbs free energies of formation of chromous fluoride (CrF2), chromic fluoride (CrF3), and chromium (II,III) fluorides (CrF2.40 and CrF2.45) with high-temperature galvanic cells employing calcium fluoride doped with 1 mole-pct yttrium fluoride as the electrolyte. Free-energy changes were obtained from open-circuit potential measurements for the following cells: Cr, CrF2 // CaF2 // NiF2, Ni (a) NiO, NiF2 // CaF2 // CrF3 , Cr203 (b) CrF2 , CrF2.40 // CaF2 // NiF2, Ni (c) and CrF2 ?45 , CrF3 // CaF2 // NiF2, Ni (d) with the following overall reactions Cr(s) + NiF2 (s) = Ni(s) + CrF2 (s) (1) 3NiO(s) + 2CrF3 (s) = 3NiF2 (s) + Cr203 (s) (2) 5CrF2 (s) + NiF2 (s) = 5CrF2.4O (s) + Ni(s) (3) and 3.64CrF2.45 + NiF2 (s) = 3.64CrF3 (s) + Ni (s) . (4) These results were combined with the best available literature values of ?Gf° of NiF2, NiO, and Cr203 to deduce Gibbs free energies of formation for the chromium fluorides expressed as follows: ?Gf°(CrF2) = -179.31 + 24.33 X 10-3T ± 0.43 kcal-mole. (5) (858.1 - 964.9 K) ?Gf° (CrF3) _ -226.16 + 1.82 X 10-3T ± 0.79 kcal/mole (6) (880.8 - 957.8 K) ?Gf°(CrF2.40) _ -213.65 + 32.14 X 10-3T ± 0.44 kcal/mole (7) (0053.9 - 936.8 K) and ?Gf°(CrF2.45) _ -176.17 - 12.67 X 10-3T ± 0.80 kcal/mole (8) (875.1 - 937.6 K). Free energies and equilibrium fluorine pressures for three univariant and one bivariant equilibria are illustrated.

Jan 1, 1976

By William Cochran

The Bureau of Mines investigated mine subsidence caused by recent underground mining, estimated the extent of damages, and formulated a procedure for evaluating subsidence costs. On the basis of the quantity of material removed from beneath the surface, bituminous coal mining currently causes more extensive subsidence problems than mining of other minerals; costs are highest in areas such as western Pennsylvania where urban and suburban development and related types of land use conflict with mineral recovery. The Bureau of Mines estimated subsidence costs, including surface damages and control costs, for a 12-county area in western Pennsylvania for 1968. Total surface damages attributable to the underground production of bituminous coal in the 1-year period were $295,000; in addition, 12.4 million tons of coal, valued at $4.3 million, was left in place to minimize potential surface damage. Of the total subsidence cost ($4.6 million), $2.7 million was classified as external or social costs, not reflected in the market value of bituminous coal; this averaged $0.05 per ton of production, or slightly less than 1 percent of the market value.

Jan 1, 1971

By J. F. Barkley

Two major problems in the operation of air preheaters for boilers are corrosion and the accumulation of deposits on the heating surfaces. Corrosion or loss of metal necessitates replacement of parts; the accumulation of deposits decreases the size of the gas and air passages, resulting in increased pressure drop for the same gas flow, and also affects the heat transfer. These items, either singly or together, limit the capacity and efficiency at which the equipment can be operated and affect its availability, even causing undesirable shutdowns under extreme conditions The field and laboratory work on regenerative air preheaters described in this report covers research on the relative corrosion resistance of different materials, such as various metals, special metal coverings, and fired clays, and studies on deposits, their nature, analyses, and corrosive effects. This is the first report on cooperative work of The Air Preheater Corp., of New York City, and the Federal Bureau of Mines.

Jan 1, 1953

By F. P. Haver

Because State and Federal agencies have limited the amount of sulfur oxides that can be discharged to the atmosphere, most copper smelters plan to convert the S02 in offgases to sulfuric acid. In some cases, however, it might be preferable to use a nonsmelting method to fix the sulfur in the form of a discardable product. Research by the Federal Bureau of Mines has shown that sulfur in copper concentrate can be converted into insoluble anhydrite (CaS04) by roasting the concentrate with lime (CaO). After leaching the calcine to recover metal values, the residue may be discarded without harm to the environment. The process can use a rougher flotation product, thus reducing separation costs and saving valuable minerals (for example, molybdenite) that are now lost in making cleaner concentrate. In tests, rougher concentrate was pelletized with the theoretical amount of lime and roasted for 1 hour in a 6-1/2-inch-ID by 11-foot-long rotary kiln at 700° C. Sulfur retention was about 97 percent. Leaching the calcine with 20 percent RCI extracted approximately 99 percent of the copper, 73 percent of the iron, and 91 percent of the molybdenum. After the molybdenum was removed from the leach solution by adsorption on activated carbon, copper with a purity in excess of 99 percent was obtained by cementation on sponge iron. The strip solution then could be spray-roasted at 500° C to recover the RCI for recycle and obtain F2O3 as a byproduct.

Jan 1, 1975

By G. S. Scott

The investigation of the causes, behavior, and control of anthracite mine fires, which the Bureau of Mines has been carrying on has yielded several publications directly applicable to mine-fire problems. 3/, 4/, 5/, 6/, 7/, 8/ As a further step in elucidating the causes of heating in certain anthracites subjected to oxidation, reliable information vial needed relative to the actual amount of heat that is liberated when a unit volume of oxygen combines with anthracite at varying temperatures.

Jan 1, 1939

By J. B. Zink

The Bureau of Mines developed a spectrochemical method to determine six constituents in coal ash in the following concentration ranges: silica 9 to 63 percent, alumina 7.5 to 35 percent, ferric oxide 2 to 30 percent, calcium oxide 1 to 29 percent, magnesium oxide 0.5 to 6 percent, and titanium oxide 0.5 to 4 percent. Samples of coal ash are fused with a mixture of lithium tetraborate and vanadium pentoxide. The resulting beads are crushed, mixed with powdered graphite, and briquetted. The pellets are analyzed spectrographically, using controlled high-voltage spark excitation. Vanadium serves as the internal standard. Effects due to matrix variations are minimized by fusion with lithium tetraborate. Intensity ratios of selected analytical lines are determined photometrically, Concentrations are read from analytical curves, prepared from synthetic standards, relating log intensity ratios to log concentration. A combustion procedure is used to determine sulfur tri-oxide. The method is most useful when large numbers of coal ashes must be analyzed but a high degree of accuracy is not essential.

Jan 1, 1967

By A. Sainato, S. J. Schatzel, D. M. Hyman, J. C. LaScola

The Bureau of Mines determined the gas contents of 135 oil shale samples obtained from approximately 630 ft of core drilling. Drilling was done within a projected mining zone of the Cathedral Sluffs Mine, located in the Piceance Basin of western Colorado. Methane contents were determined by the modified direct method, which can measure the volumes of several gases released from or reacted with mine rock without destructive sample treatment. Over the duration of the test, nitrogen was largely unreactive, CO2 increased slightly, oxygen decreased markedly, and methane increased more than the total increase of all contained gases. The gas volumes were normalized per unit sample mass and are given in cubic centimeters per gram. Common time irzdices for test duration of 3, 40, and 125 days were used to compare methane desorption among samples. The means of the sample populations for these indices were 0.0316, 0.114, and 0.195 cm3/g, respectively. These quantities are lower than those reported in a Bureau emissions study at the Horse Draw Mine in the Piceance Basin. Oil shale samples that were gas enriched beyond the mean methane contents frequently contained bitumens and pyrite.

Jan 1, 1987

By A. F. Colombo

The western Mesabi range nonmagnetic taconites containing about 34 percent Fe were evaluated by the Bureau of Mines in a 900-pound-per-hour pilot plant employing a selective flocculation-desliming-cationic flotation technique. The flotation step was a reverse flotation process and involved the flotation of the gangue minerals. The objective of the research was to increase the availability of domestic raw materials for the iron and steel industry. The beneficiated ores yielded concentrates containing 62 to 64 percent Fe and less than 5.5 percent Si02 with accompanying iron recoveries that averaged about 75 percent. Comparable flotation results were obtained with either fresh or 80 to 90 percent reclaimed water. Recycled waters having turbidities as high as 5,000 ppm Si02 did not affect the flotation process. Reclaimed waters containing residual calcium contents of less than 10 ppm gave better flotation concentrates than those containing 15 ppm.

Jan 1, 1976

By Jack I. Paige

In this Bureau of Mines study, two fluidized-bed reactors were designed, built, and operated, one as a sorber for S02 and the other as a contactor for the regeneration of the sulfur-laden alkalized alumina. The target of 90 percent removal of S02 from a flue gas stream containing 0.3 percent S02 was attained by using a sorbent feed of 10-15 grams per minute into a 5-inch bed depth of alkalized alumina. The sorption unit was operated at about 330° C. Complete regeneration of the laden alkalized alumina containing 5 to 10 percent sulfur was accomplished in approximately 1/2 hour. An excess of reformed propane at about 730° C was the regenerating gas. Attrition losses, a major problem with this sorbent, ranged from 0.9 to 7.9 percent of the inventory. Data from these tests demonstrate, within experimental error, the validity of equations developed from short-term, thin-bed tests related to sorption and regeneration rates.

Jan 1, 1970

By R. M. Santmyers

Of the sand and miscellaneous silica produced in the United States , ordinary sand and gravel are , of course , the most important, at least as regards volume of output . The building- construction industry absorbs approximately 75 per cent of the total value of all quartz and silica , as shown in Table 2 of Quartz and Silica, Part I, under "General summary . " Because of their unusual physical properties tripoli and diatomite find extremely wide uses in industry, and as the commercial deposits of these ninerals , especially tripoli , are scattered, large quantities enter into interstate commerce . Whereas ordinary sand and gravel are bulky commodities , these specialties have a fairly high unit value and hence can be transported relatively long distances .

Aug 1, 1931

By K. S. Gritton

The Bureau of Mines investigated the feasibility of numerlcally modeling the sorption of cobalt, a vulnerable strategic and critical metal, from spent copper leach solutions in a multiple-compartment ion-exchange (MCIX) column. Equilibrium resin loadings, cobalt-sorption kinetics, and resin-fluidization characteristics were determined in simple laboratory tests, and a numerical model was developed to predict cobalt extraction and the MCIX-column resin inventory based upon the test results. The model was implemented on a microcomputer to approximate the solution to the set of differential equations that govern model performance. Results compared very well with data from 12 pilot-scale MCIX-column experiments. The average difference between predicted and actual cobalt extractions was 3.2 pct; the maximum difference was 9.3 pet. The actual and predicted resin inventories differed by an average of 5.8 pet, and the maximum difference was 12.0 pct.

Jan 1, 1987

By L. C. IlsLey

Through the cooperation of the Pennsylvania Department of Mines the writer obtained from State, records detailed information concerning coal-mine accidents occurring in Pennsylvania bituminous mines during 1939, particularly those nonfatal accidents in which the injured person lost 60 or more days? time from mark. The writer wishes to acknowledge assistance received from Pennsylvania State officials, especially Richard Maize, secretary of mines, and. Joseph J, Walsh, deputy secretary of mines; also to Thomas Dickinson,3/ of the Bureau of Mines, who rendered valuable assistance in assembling the data an the several tables.

Jan 1, 1941

By John R. Reigart

The Tri-State district, as its name indicates, is composed of portions of three States, the southeastern corner of Kansas, the northeastern corner of Oklahoma, and an adjacent strip of Missouri east of these portions of Kansas and Oklahoma. An area approximately 40 miles long in a northeasterly-southwesterly direction, and 30 miles wide at right angles thereto, containing minable occurrences of ore at widely scattered locations, comprises the district. However, what has been and is the main productive area, is a strip about 35 miles long and 10 miles wide, which begins at Miami, Okla., as its southern extremity and runs in a northeasterly direction through Commerce, Picher, and Hockerville, Okla., Baxter Springs and Galena, Kans., and Joplin, Webb City-Carterville and Carthage, Mo. Almost the entire present production comes from the area between Commerce and Baxter Springs.

Jan 1, 1932

By Janet Torma-Krajewski, Pauline Lewis, Paul Gust, Lisa Steiner, Kean Johnson

Ergonomics processes described in the literature have been associated mostly with manufacturing, financial, electronics, and office settings where working conditions tend to be rather constant and repetitive. The information presented in this document demonstrates, however, that an ergonomics process can also be implemented in a setting such as mining where working conditions frequently change and workers are periodically exposed to extreme weather conditions. This document describes how Bridger Coal Company implemented an ergonomics process at its Jim Bridger Mine from 2001 through 2004. The process developed by the Ergonomics Committee, the promotion of the process to management and employees, and the impacts of the process on working conditions at the mine are reviewed. Barriers overcome and lessons learned are also described. Quotes from Bridger Coal Company employees are included in the document to add a personal perspective. Other industries with working conditions similar to mining, such as construction and agriculture, may find this information useful.

Jan 9, 2006

By H. R. Shell

Of three known compounds in the ternary system K20 - PbO - SiO2, one having the composition K2Pb4Si8021 crystallizes into a structure with asbestiform properties. This compound, whose silicon-oxygen ratio is between that of the layer silicates (for example, mica) and the double-chain amphiboles, crystallizes in the tetragonal system. It malts, apparently congruently, at 779° C. The fiberized product prepared from crystals is fluffy and closely resembles natural asbestos in appearance, but is more brittle and has less strength. However, potassium-lead silicate may be separated into fibers with a uniform diameter of 200-300 A.U., and the fibers show with the electron microscope the s criteria that have been interpreted as indicating a hollow tube structure in chrysotile asbestos. Since very few inorganic crystalline compounds have such a structure, the material has unusual scientific interest. Microcrystalline potassium-lead silicate was rapidly and completely formed when powdered glass of the same composition was heated to 650° - 700° C, but macrocrystals grew only slowly from the viscous massive glass. Maximum growth rate was 0.12mm. per hour at 700° C.

Jan 1, 1957

By W. H. Tomlinson

One of the more important functions of the Federal Bureau of Mines is conservation of the life and health of employees of the mineral and allied industries. Since its very beginning the Bureau has encouraged competition between mine rescue and first-aid teams as a means of stimulating interest in safety and accident-prevention work. In addition to sponsoring competition on a national and international scale during the past 45 years, the Bureau has also assisted State mining departments, mining companies, and mining organizations in holding State, district, company, and other local meets. This assistance includes providing instructors to train teams, judges, and other contest officials. The Bureau has also furnished problems and outlines for working them, judges I discount sheets (scorecards), contest rules, and problem judges. In fact, Bureau representatives participate in nearly all State, district, and company contests and have bad complete charge of some contests.

Jan 1, 1956

By A. J. Farstad

The current emphasis on energy needs in the United State sand abroad has placed an increased demand on the coal mining industry. The United States is fortunate to have abundant coal reserves. However, coal mining techniques and technology have not kept pace with the increased demand for coal. Consequently, coal mining in the United States continues to be one of the most hazardous industries. One of the daily hazards faced by coal miners is the sudden and unexpected occurrences of roof falls. The research program described in this final report focuses attention on the problems of unstable roof conditions in coal mines and describes prototype equipment which, with further development, has potential of being able to warn miners of impending roof falls in mines. Westinghouse Electric Corporation, Geophysical Instrumentation Systems Group was awarded a contract to develop and test a microseismic roof fall warning system based on general specifications derived from earlier Bureau of Mines research [1], [2]. During the first year of this two year effort (Contract H0242045) the electronic monitoring systems were de signed and built while the second year of the contract was devoted to equipment field testing in working coal mines.

Jan 1, 1976

By John Ward Smith

The potential economic value of oil shale depends on the products from thermal degradation of the rock, because no other practical method for producing valuable material from oil shale has been found. Detailed study of thermal degradation behavior can aid in characterizing oil shales and their deposits and in evaluating oil-shale processing methods, Numerous publications describe various pyrolysis properties of oil shales (see surveys 3, 9, 11 and articles 1, 2, 4-8, 10, 12),4 but they do not describe a generally applicable analytical procedure for detailed evaluation of thermal degradation products. The analytical method presented here for such evaluations is designed to provide for: 1. Control of retorting conditions--temperature, heating, rate, reaction atmosphere--plus some control over retort pressure and carrier-gas flow, 2. Precise direct gravimetric measurement of the thermal degradation products--oil, water, gas, and spent charge (residue after thermal treatment of the charge). 3. Samples of all products. 4. Determination of the identities and amounts of gaseous compounds produced. 5. Elemental analysis and gross heating value of all products. 6. Determination of the distribution in the retorting products of the elements present in the original samples.

Jan 1, 1962

By Peter Grandone

Bureau of Mines engineers engaged in studying stimulative methods of recovering oil have been making a series of tests on the effectiveness' of methods that may be applied in water flooding oil-bearing sandstones. The report gives the test procedures and results of a study of the rates and pressures used for injecting water into several sandstone formations in the Mid-Continent fields for the purpose of learning more about the mechanics and efficiency of the flooding process and to provide useful information for operators of water floods in this area.

Jan 1, 1949

By John C. Holtz

"INTRODUCTION Information on the gaseous products from the detonation of explosives has been obtained in two ways. In the first, the atmosphere in mines is analyzed after blasting, and in the second, the gases found after detonating an explosive in a testing apparatus are analyzed. The Bureau of Mines, in a cooperative research 3/ that compared data obtained in the field with those obtained in the testing station, showed that the results were not in entire agreement. The production of carbon monoxide was found to be governed chiefly by the oxygen balance of the explosive, but the production of oxides of nitrogen did not change in so simple a manner. Because of the increasing interest in correlations between the composition of the explosive and the production of toxic gases, it seemed desirable to continue the investigation.PURPOSE OF INVESTIGATIONAs field tests are both time consuming and expensive and as field results are affected by factors that are not always under control of or clearly evaluated by the operator, the purpose of this investigation is to develop a testing-station procedure that will reproduce the gaseous products quantitatively under known conditions analogous to those that may be expected in the field. In addition, the factors affecting the formation of toxic gases, particularly oxides of nitrogen, will be studied,"

Apr 1, 1940